CN105874048B - Laundry composition - Google Patents
Laundry composition Download PDFInfo
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- CN105874048B CN105874048B CN201480065245.0A CN201480065245A CN105874048B CN 105874048 B CN105874048 B CN 105874048B CN 201480065245 A CN201480065245 A CN 201480065245A CN 105874048 B CN105874048 B CN 105874048B
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- composition according
- anion
- siloxanes
- composition
- polymer
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- -1 polysiloxane Polymers 0.000 claims abstract description 72
- 229920000642 polymer Polymers 0.000 claims abstract description 51
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- 239000001913 cellulose Substances 0.000 claims abstract description 22
- 229920002678 cellulose Polymers 0.000 claims abstract description 22
- 125000002091 cationic group Chemical group 0.000 claims abstract description 18
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 17
- 150000001450 anions Chemical class 0.000 claims abstract description 17
- 239000007788 liquid Substances 0.000 claims abstract description 15
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 13
- 239000004744 fabric Substances 0.000 claims abstract description 10
- 239000003205 fragrance Substances 0.000 claims abstract description 9
- 238000007046 ethoxylation reaction Methods 0.000 claims abstract description 8
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 8
- 150000008052 alkyl sulfonates Chemical class 0.000 claims abstract description 6
- CRQWZKDIVBSAJD-UHFFFAOYSA-N 1-dodecoxydodecane;sodium Chemical compound [Na].CCCCCCCCCCCCOCCCCCCCCCCCC CRQWZKDIVBSAJD-UHFFFAOYSA-N 0.000 claims abstract description 4
- SPBPMWWOBCFOHX-UHFFFAOYSA-N methoxymethane;sulfuric acid Chemical compound COC.OS(O)(=O)=O SPBPMWWOBCFOHX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000005227 alkyl sulfonate group Chemical group 0.000 claims abstract 2
- 239000003599 detergent Substances 0.000 claims description 31
- 238000002360 preparation method Methods 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 150000003839 salts Chemical class 0.000 claims description 13
- 125000000129 anionic group Chemical group 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 11
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 108090000790 Enzymes Proteins 0.000 claims description 9
- 102000004190 Enzymes Human genes 0.000 claims description 9
- 229920006317 cationic polymer Polymers 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 9
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 7
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 7
- 239000002689 soil Substances 0.000 claims description 7
- 238000012546 transfer Methods 0.000 claims description 7
- 239000002738 chelating agent Substances 0.000 claims description 6
- 239000012875 nonionic emulsifier Substances 0.000 claims description 4
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- 239000006081 fluorescent whitening agent Substances 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000006210 lotion Substances 0.000 claims description 2
- 230000000873 masking effect Effects 0.000 claims 1
- 239000000516 sunscreening agent Substances 0.000 claims 1
- 229920001296 polysiloxane Polymers 0.000 abstract description 26
- 239000000975 dye Substances 0.000 description 23
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000000126 substance Substances 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 230000003165 hydrotropic effect Effects 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 229920002125 Sokalan® Polymers 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229920000289 Polyquaternium Polymers 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 150000002500 ions Chemical class 0.000 description 4
- 239000003595 mist Substances 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000004676 glycans Polymers 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 3
- 235000021286 stilbenes Nutrition 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 2
- 229920006243 acrylic copolymer Polymers 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 235000014121 butter Nutrition 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 150000001768 cations Chemical group 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003605 opacifier Substances 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
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- 150000004804 polysaccharides Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- CZCBTSFUTPZVKJ-UHFFFAOYSA-N rose oxide Chemical compound CC1CCOC(C=C(C)C)C1 CZCBTSFUTPZVKJ-UHFFFAOYSA-N 0.000 description 2
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 235000013599 spices Nutrition 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical group CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical class OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 229940071104 xylenesulfonate Drugs 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 1
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- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical class CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- PMPJQLCPEQFEJW-UHFFFAOYSA-L disodium;2-[2-[4-[4-[2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical class [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1C=CC1=CC=C(C=2C=CC(C=CC=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-UHFFFAOYSA-L 0.000 description 1
- VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 1
- 229940006461 iodide ion Drugs 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 239000001102 lavandula vera Substances 0.000 description 1
- 235000018219 lavender Nutrition 0.000 description 1
- 229930007744 linalool Natural products 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZOCHHNOQQHDWHG-UHFFFAOYSA-N n-hexan-3-ol Natural products CCCC(O)CC ZOCHHNOQQHDWHG-UHFFFAOYSA-N 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- ROSDSFDQCJNGOL-UHFFFAOYSA-N protonated dimethyl amine Natural products CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 229930007790 rose oxide Natural products 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- ABDKAPXRBAPSQN-UHFFFAOYSA-N veratrole Chemical compound COC1=CC=CC=C1OC ABDKAPXRBAPSQN-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to liquid laundry compositions, it contains (a) surfactant, the surfactant includes both the anionic surfactant that weight ratio is 5: 1 to 1: 3 and nonionic surfactant, (b) fabric-softening anion polysiloxane, and (c) cationic cellulose polymer；(d) fragrance, wherein anionic surfactant includes one of following or a variety of: linear alkylbenzene sulfonate (LAS), with or mixtures thereof average 1 to 3 mole lauryl ether sodium sulfonate, primary alkyl sulfonate, methyl ether sulfate and secondary alkyl sulfonate of ethoxylation unit；And the purposes of the composition softening fabrics.
Description
Technical field
The present invention relates to laundry compositions.More particularly it relates to the laundry composition for the softening that is in the suds.
Background technique
Textile fabric, including clothes are traditionally cleaned with laundry detergent.After cleaning, fabric may often be felt
It is coarse to sense of touch.This point in order to prevent, the sense of touch through going through is coarse after especially multiple wash cycle, and Development Technology increases
The pliability of fabric, including the conditioner composition added when rinsing and the softening system being added in detergent composition.
Fabric-softening polysiloxanes has been used for providing pliability from laundry detergent composition for fabric.But
There are problems that the preparation stability in terms of unacceptable mist degree.
Summary of the invention
In a first aspect, including the present invention relates to liquid laundry detergent compositions:
(a) 15 to 40wt.% surfactant, the surfactant include the anion that weight ratio is 5: 1 to 1: 3
Both surfactant and nonionic surfactant；
(b) 0.1 to 5wt.% fabric-softening anion polysiloxane；
(c) 0.05 to 2.5wt.% cationic cellulose polymer；
(d) 0.001 to 3wt.% fragrance；With,
Wherein the anionic surfactant includes one of following or a variety of: linear alkylbenzene sulfonate (LAS) has
Lauryl ether sodium sulfonate, the primary alkyl sulfonate, methyl ether of average 1 to 3 mole of ethoxylation unit (ethoxylation)
Or mixtures thereof sulfate and secondary alkyl sulfonate.
Preferably, the weight ratio of anion and nonionic surfactant is 5: 1 to 1: 2, more preferable 5: 1 to 1: 1.25,
Even more preferably 5: 1 to 1: 1, most preferably 4: 1 to 1: 1.
The molecular weight of preferred anionic polysiloxanes is 1,000 to 100,000, more preferable 2,000 to 50,000, even more
It is preferred that 5,000 to 50,000, most preferably 10,000 to 50,000.
The anionic group content of preferred anionic polysiloxanes is at least 1mol%, preferably 2mol%.
It is preferred that the anion polysiloxane includes carboxyl polysiloxanes.
It is preferred that in the form of an emulsion by polysiloxanes, more preferably in the form of non-ionic emulsion, most preferably with branching it is non-from
Sub- emulsifier is added in preparation.
The anion polysiloxane of preferred levels is 0.1 to 2.5wt.%, preferably 0.1 to 2wt.% there are level.
It is preferred that the liquid detergent composition has 6 to 10 pH's, more preferable 6.5 to 9.5 pH, most preferably 7 to 9
PH, such as 7.5 to 8.5 pH.
The preferred levels of cationic polymer be 0.1 to 2wt.%, more preferable 0.1 to 1wt.%, most preferably 0.1 to
0.75wt.%.
Preferred cationic cellulose polymer is by introducing modified hydroxyether cellulosic (the i.e. quaternary ammonium of cation group
The hydroxyethyl cellulose of change).
Preferably, the weight ratio of polysiloxanes and cationic polymer is 5: 1 to 1: 1.
Optionally it is preferable that composition is further included selected from fatty acid or its salt, dope dye (shading
Dye), enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, opacifier, fluorescer and/or go
The ingredient of dirty polymer.
In second aspect, the present invention provides the purposes of composition softening fabrics according to a first aspect of the present invention.
Detailed description of the invention
Terms used herein " including (comprising) " indicate to include (including), by ... constitute (made up
Of), by ... form (composed of), by ... form (consisting of) and/or substantially by ... form
(consisting essentially of)。
All percentages of citation are wt%, based on the total amount in laundry composition, unless otherwise indicated.
The present invention relates to laundry composition, containing surfactant, cationic cellulose polymer, fabric-softening yin
Ion polysiloxanes and fragrance, the surfactant include weight ratio be 5: 1 to 1: 3 anionic surfactant and it is non-from
Both sub- surfactants.
Form of the invention
The present invention can be employed as any (such as gel and the aqueous solution of many forms of liquid laundry compositions
Body).It is preferred that they are main cleaning product (mainwashproduct).It can be used can be can to dilute or not dilutable use
In the laundry composition form of main washing.Laundry composition can be, for example, isotropic liquid or surfactant-structured
Liquid.Particularly preferred form of the invention includes composition, detergent/softening agent product, " is softened in washing " with offer.
Preferably, liquid detergent composition has 6 to 10 pH's, more preferable 6.5 to 9.5 pH, most preferably 7 to 9
PH, such as 7.5 to 8.5 pH.
Surfactant
Detergent composition includes both anionic surfactant and nonionic surfactant.
Anionic surfactant includes one of following or a variety of: linear alkylbenzene sulfonate (LAS) has average 1 to 3
Mole ethoxylation unit lauryl ether sodium sulfonate, primary alkyl sulfonate, methyl ether sulfate and secondary alkyl sulfonate or
Its mixture.
The weight ratio of anionic surfactant and nonionic surfactant is 5: 1 to 1: 3, and preferred anionic surface is living
Property agent and nonionic surfactant weight ratio be 5: 1 to 1: 2, more preferable 5: 1 to 1: 1.25, even more preferably 5: 1 to 1:
1, most preferably 4: 1 to 1: 1.
Surfactant can be selected from " Surface Active Agents ", volume 1, Schwartz&Perry,
Interscience 1949 rolls up 2, Schwartz, Perry&Berch, Interscience 1958, by Manufacturing
" McCutcheon ' s Emulsifiers and Detergents " latest edition published by Confectioners Company or
" Tenside-Taschenbuch ", H.Stache, the second edition, Carl Hauser Verlag, surface-active described in 1981
Agent.It is preferable to use surfactant be saturation.
The suitable nonionic detergent compounds that can be used particularly including have hydrophobic group and reactive hydrogen former
The compound (such as aliphatic alcohol, acid, amide or alkyl phenol) and alkylene oxide (especially individual ethylene oxide or epoxy second of son
Alkane is together with propylene oxide) reaction product.Specific nonionic detergent compounds are C6To C22Alkyl phenol-ethylene oxide contracting
Object is closed, usually 5 to 25 EO, i.e., each 5 to 25 ethylene oxide units of molecule, and aliphatic series C8To C18Primary or secondary straight chain or
The condensation product of branched-chain alcoho and ethylene oxide, usually 5 to 40 EO.
Alcohol ethoxylate is formed by primary or secondary alcohols and reacting ethylene oxide.Usual aliphatic series C8To C18Primary or secondary straight chain
Or branched-chain alcoho alcohol ethoxylate is generated with ethylene oxide needed for mole reacted.Preferred alcohol ethoxylate tool
There are 2 to 40, preferably 3 to 30, more preferable 5 to 20 are connected to the ethylene oxide unit of aliphatic chain.
The suitable anionic detergent compounds that can be used can be for the alkyl containing about 8 to about 22 carbon atoms
Organic sulfate and sulfonate water-soluble alkali metal salts, the term alkyl used includes the moieties of higher acyl.It closes
The example of suitable synthetic anionic detergent compound is sodium alkyl sulfate and alkylsurfuric acid potassium, especially by sulphating higher
C8To C18Those of alcohol (such as being generated by butter or coconut oil) acquisition, alkyl C9To C20Benzene sulfonic acid sodium salt and potassium, especially straight chain
Secondary alkyl C10To C15Benzene sulfonic acid sodium salt；And alkyl glyceryl ether sulphates, especially it is originated from higher alcohol and the source of butter or coconut oil
Those of synthol from petroleum ether.Preferred anionic detergent compounds are C11To C15Sodium alkyl benzene sulfonate and C12To C18
Sodium alkyl sulfate.The sulfonate for including as hydrotropic agent (hydrotrobe) can be additionally considered to be as defined herein
Anionic surfactant.Also applicable surfactant be, for example, described in EP-A-328 177 (Unilever) that
A bit, resistance to saltouing property, alkyl polyglucoside surfactant and alkyl monoglycosides described in EP-A-070 074 are shown.
Existing total amount is 15 to 40wt.% to surfactant in the composition.The level of surfactant is preferably 16
To 35wt.%, more preferably at least 18 to 32wt.%.
It is preferred that the amount of nonionic detergent is 1 to 25wt.%, more preferable 2 to 20wt.%.
Preferably, the nonionic components of detergent with the 20 to 75wt.% of total surfactant content, more preferable 25 to
60wt.% exists.
Nonionic surfactant preferably includes alcohol ethoxylate.
Preferred nonionic surfactant is with average 7 to 9 moles of ethoxylation unit (ethoxylation)
C12-C15Alkyl chain.
The amount of preferred anionic surfactant be 1 to 25wt.%, more preferable 2 to 20wt.%, most preferably 4 to
20wt.%.
Preferably, the anionic component of detergent with the 25 to 80wt.% of total surfactant content, more preferable 40 to
80wt.%, most preferably 50 to 80wt.% exist.
Anionic surfactant preferably includes linear alkylbenzene sulfonate (LAS).
In order to explain the level of the surfactant present in preparation, fatty acid and its salt are not included in surface-active
In the level of agent.
In addition to above-mentioned nonionic and anionic surfactant, other surfactants, such as both sexes, two also may be present
Property ion and cationic surfactant.
Fabric-softening anion polysiloxane
Polysiloxanes and its chemical property are described in such as The Encyclopedia of Polymer Science, the
In volume 11, page 765.
Composition is with 0.05 to 5wt.%, preferably 0.1 to 2.5wt.%, more preferably 0.1 to 2wt.% level packet
Anion polysiloxane containing fabric-softening.
The example of fabric-softening anion polysiloxane is to introduce carboxyl, sulfate group (sulphate), sulfo group, phosphate
The polysiloxanes of base (phosphate) and/or phosphonate group (phosphonate) functionality.
Preferred anion polysiloxane is carboxy-functionalized polysiloxanes.
For present invention disclosed herein, anion polysiloxane can be acid or anionic form.For example, for carboxyl
Functionalized polysiloxanes can exist in the form of carboxylic acid or carboxylate anion.
The example of commercially available material are as follows: X-22-3710, X-22-162C and X-22-3701 E from Shin Etsu；
CSi 2342 and Tego polishR20 from Evonik；SFD 209 from DowCorning；From Siltech's
Silube CS-1,CP-1 Silphos J208；Pecosil PS-100, PS112, PS from Phoenix Chemical
11220,WDS 100；And the Hansa LPF 711 from CHT Beitlich.
The molecular weight of preferred anionic polysiloxanes is 1,000 to 100,000, more preferable 2,000 to 50,000, even more
It is preferred that 5,000 to 50,000, most preferably 10,000 to 50,000.
The anionic group content of preferred anionic polysiloxanes is at least 1mol%, preferably 2mol%.
Preferably, in the form of an emulsion by polysiloxanes, it is more preferably added in preparation in the form of non-ionic emulsion.It is more excellent
Selection of land lotion is prepared by nonionic emulsifier, and the more preferable nonionic emulsifier is the nonionic emulsifier of branching, for example,
EcosurfEH-3 (Dow Chemical) or Berol 840 (Akzo Nobel).
Cationic polymer
The composition is with 0.05 to 2.5wt.%, preferably 0.1 to 2wt.%, more preferable 0.1 to 1wt.%, most preferably
0.1 to 0.75wt.% level includes cationic cellulose polymer.
The term refers to the polymer with overall positive charge.
Preferred cationic cellulose polymer is by introducing modified hydroxyether cellulosic (the i.e. quaternary ammonium of cation group
The hydroxyethyl cellulose of change).
The preferred type of cationic cellulose polymer is suitable for the invention to introduce quaternary ammonium salt with modified
Those of cellulose polysaccharide skeleton.Preferably, quaternary ammonium salt is connected to polysaccharide skeleton by ethoxy or hydroxypropyl.Preferably, season
The nitrogen of the electrification of ammonium salt has one or more alkyl substituents.
Cellulose is the polysaccharide with glucose as monomer, particularly, for via β-Isosorbide-5-Nitrae glucosides key connection D-
The straight chain polymer of glucopyranose units, and be linear, non-branching polymer.
The example of cationic cellulose polymer is the epoxide reactive hydroxyethyl cellulose replaced with trimethyl ammonium
Salt, in the art according to the international nomenclature of cosmetic composition (International Nomenclature for
Cosmetic Ingredients) it is known as polyquaternium 10 (Polyquatemium 10), and available commercially from The Dow
Chemical Company, the polymer as Polymer LR and JR series are commercially available.Other polymer are by The Dow
Chemical Company is commercially available with trade name SoftCAT.Other suitable cationic cellulose types include and lauryl two
The polymeric quaternary ammonium salts for the epoxide reactive hydroxyethyl cellulose that methyl ammonium replaces, in the art according to cosmetic composition
International nomenclature is known as polyquaternium 24.
The representative instance of preferred cationic cellulose polymer includes cocodimonium hydroxypropyl base oxethyl fiber
Element (cocodimethylammonium hydroxypropyl oxyethyl cellulose), Lauryldimonium Hydroxypropyl
Base oxethyl cellulose (lauryldimethylammonium hydroxypropyl oxyethyl cellulose), tristearin
Base dimethyl ammonium hydroxypropyl ethoxy cellulose (stearyldimethylammonium hydroxypropyl oxyethyl
) and ammonium chloride hydroxyethyl cellulose cellulose；Cellulose 2- ethoxy 2- hydroxyl 3- (trimethyl ammonium) propyl ether
Salt, polyquaternium -4, Polyquaternium-10, polyquaternium -24 and Polyquaternium-67 or their mixture.
It is highly preferred that cationic cellulose polymer is quaternized hydroxyether cellulosic cationic polymer.These are usually
Referred to as Polyquaternium-10.Suitable commercial cationic cellulosic polymer product used according to the invention is by The Dow
Chemical Corporation is commercially available with trade name UCARE.
The counter ion counterionsl gegenions of cationic polymer are freely selected from halogen ion: chloride ion, bromide ion and iodide ion；Or hydrogen-oxygen
Root, phosphate radical, sulfate radical, bisulfate ion, ethyl sulphate, methylsulfate, formate and acetate.
Many above-mentioned cationic cellulose polymers can be synthesized with a variety of different molecular weight with it is commercially available.Preferred cationic
The molecular weight of polymer be 10,000 to 2,000,000 dalton, more preferable 100,000 to 1,000,000 dalton, even more
It is preferred that 250,000 to 1,000,000 dalton.
Fragrance
The existence range of fragrance is 0.001 to 3wt.%, preferably 0.1 to 1wt.%.The example of many suitable fragrance exists
CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 published by CFTA Publications
1993 Chemicals of OPD published by International Buyers Guide and Schnell Publishing Co
It is provided in Buyers Directory 80th Annual Edition.
It there are a variety of perfume compositions is universal phenomenon in preparation.In the present compositions, it is contemplated that will there are four types of or
More kinds of, preferably five kinds or more, more preferable six kinds are obtained more kinds of or even seven kinds or more different perfume compositions.
In spice mixture, preferably 15 to 25wt.% is fragrant (top notes) for head.Head perfume is by Poucher (Journal
Of the Society of Cosmetic Chemists 6 (2): 80 [1955]) it defines.Preferred head perfume (or spice) be selected from tangerine oil,
Linalool, bergamio (linalyl acetate), lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
Preferably laundry treatment compositions are free of peroxygen bleach, such as SODIUM PERCARBONATE, sodium perborate and peracid.
Optional member
Detergent composition can optionally include one or more following optional members: fatty acid or its salt, dope dye,
Enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, fluorescer, opacifier and/or decontamination polymerization
Object.
Fatty acid
Composition also may include the salt of fatty acid or fatty acid, such as soap.Example includes C6-C22Fatty acid and its sodium, potassium
And ammonium salt.In order to explain the level of the surfactant present in preparation, fatty acid and its salt are not included in surface-active
In the level of agent.
Fatty acid is 0.25 to 12wt.%, preferably 0.5 to 10wt.% there are level.
Builder and chelating agent
Detergent composition can also optionally the organic detergent builder containing low relative levels or chelating agent material.Example
Including alkali metal, citrate, succinate, malonate, carboxymethyl succinates, carboxylate, multi-carboxylate and more acetyl
Yl carboxylic acid salt (polyacetyl carboxylate).Particular instance includes oxygen disuccinic acid, mellitic acid, benzene polycarboxylic acid, second
Ethylenediamine tetraacetic acid (EDTA), diethylene-triamine pentaacetic acid, alkyl or alkenyl succinic acid, the sodium of nitrilotriacetic acid and citric acid, potassium and
Lithium salts.Other examples are DEQUESTTM, the organic phospho acid salt form chelating agent and alkane hydroxyethylidene diphosphonic acid salt sold by Thermophos.
Other suitable organic washing-assisting detergents include polymer and the copolymerization of the known higher molecular weight with builder capacity
Object.For example, such material include suitable polyacrylic acid, poly and poly propenoic acid maleic acid and they
Salt, such as by BASF with title SOKALANTMThose of sale.Another suitable builder is sodium carbonate.
If used, builder material may be constructed about the 0.5% to 20wt% of composition, preferably 1wt% to 10wt%.
Preferred builder level is less than the 10wt% of composition, and preferably smaller than 5wt%.
Preferably, laundry detergent preparation is that phosphate free helps the laundry detergent preparation washed, that is, contains and be less than
The phosphate of 1wt.%.
Dope dye
Dope dye deposits on fabric during the washing or rinse step of washing process, provides visible color for fabric
It spends (hue).The toning of white garments can be completed according to Consumer Preferences with any color.Blue and purple are particularly preferred
Tone, and it is therefore preferable that dyestuff or dye mixture are that those of blue or violet hue are generated in white fabrics.Make
Dope dye is preferably blue or purple.
Dope dye chromophore is preferably selected from: monoazo, bisazo, triphenyl methane, three benzo dioxazines
(triphenodioxazine), phthalocyanine, naphthalene lactim (naptholactam), azine and anthraquinone.Most preferably monoazo, double
Azo, azine and anthraquinone.
Most preferably, dyestuff has at least one sulfonated group (sulfonate group).
Preferred dope dye is selected from direct dyes, acid dyes, hydrophobic dye, the dye of positive ion and reactive dye.
If comprising dope dye is present in composition with 0.0001 to 0.01wt%.
Fluorescer
The composition preferably comprises fluorescer (fluorescent whitening agent).Fluorescer is well-known and many this
Fluorescer is commercially available.In general, these fluorescers are with the form supply and use of its alkali metal salt, such as sodium salt.Described group
The total amount for closing one or more fluorescers used in object is usually 0.005 to 2wt.%, preferably 0.01 to 0.1wt.%.It is excellent
The fluorescer classification of choosing are as follows: two-styrylbiphenyl compounds, such as Tinopal (trade mark) CBS-X, two-amine two-sulfonic acid of stilbene
Compound, such as Tinopal DMS pure Xtra and Blankophor (trade mark) HRH and pyrazoline compounds, such as
Blankophor SN.Preferred fluorescer are as follows: 2- (4- styryl -3- sulfo group phenyl) -2H- naphtho- [1,2-d] 1-Sodium-1,2,4-Triazole,
4,4 '-bis- { [(4- anilino- -6- (N- methyl-N-2- ethoxy) amino -1,3,5-triazines -2- base)] amino } stilbene -2-2 ' bis-
Disodium sulfonate, 4,4 '-bis- { [(4- anilino- -6- morpholinyl -1,3,5-triazines -2- base)] amino } stilbene -2-2 ' disulfonates
With 4,4 '-bis- (2- sulfostyryl) biphenyl disodium salts.
Polymer
Composition may include one or more polymer.By promoting dirt to become scrappy in solution or suspension
(retail) and/or prevent dyestuff from shifting, polymer can contribute to cleaning process.Polymer can also contribute to decontamination process.
Dyestuff transfer, antiredeposition and soil release polymer are detailed further below.
Composition may include one or more polymer.Example is carboxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl
Cellulose, poly(ethylene glycol), poly- (vinyl alcohol), ethoxylated polyamine, polycarboxylate/salt, such as polyacrylate/salt, Malaysia
Acid/acrylic copolymer and lauryl methacrylate/acrylic copolymer.
Dye transfer inhibitor
Modern detergent compositions are usually using polymer as so-called ' dye transfer inhibitor '.These polymer are anti-
Only dye migration, especially during long soaking time.In general, such dye transfer inhibitor includes polyvinylpyrrolidone
Polymer, polyamines N- oxide polymer, n-vinyl pyrrolidone and N- vinyl imidazole copolymer, manganese phthalocyanine, peroxide
Compound enzyme and its mixture, and be typically based on the total amount of laundry composition and exist with 0.01 to 10wt.% level.
Antiredeposition polymer
Design antiredeposition polymer suspends or disperses dirt.In general, antiredeposition polymer be ethoxylation and/or
Propoxylated polyethylene imine or polycarboxylate/salt material, for example, by trade mark ACUSOL purchased from Dow Chemical, with
Alcosperse is purchased from Akzonobel or the homopolymer or copolymer based on acrylic acid by Sokolan purchased from BASF.
Soil release polymer
The example of suitable soil release polymer includes poly- (vinyl esters), such as C1-C6The graft copolymer of vinyl esters,
It is preferred that being grafted to poly- (vinyl acetate) on polyalkylene oxide backbones.Such commercially available detergent includes the material of SOKALAN type,
Such as SOKALAN HP-22, it is purchased from BASF (Germany).Different types of other suitable soil release polymers include commercially available material
ZELCON 5126 (coming from DuPont) and MILEASET (coming from ICI).If it does, can be based on the total amount of laundry composition
It include soil release polymer with 0.01 to 10wt.% level.The further example of soil release polymer is with trade name
The terephthalic acid/diol copolymer of Texcare, Repel-o-tex, Gerol, Marloquest, Cirrasol sale.
Hydrotropic agent
If it is liquid form, liquid detergent composition can include optionally hydrotropic agent, can prevent liquid
Crystalline substance is formed.Therefore addition hydrotropic agent facilitates the clarification of composition/transparent.Suitable hydrotropic agent includes but is not limited to
Propylene glycol, ethyl alcohol, glycerol, urea, benzene sulfonate, toluene fulfonate, xylenesulfonate or cumene sulfonate.Suitable salt includes
But it is not limited to sodium, potassium, ammonium, monoethanolamine, triethanolamine.Sulfonate is also considered anionic surface as defined herein
Activating agent.Preferably, hydrotropic agent is selected from propylene glycol, xylenesulfonate, ethyl alcohol and urea, to provide optimum performance.It is water-soluble
The amount of growth regulator is usually 0 to 30%, and preferably 0.5 to 30%, more preferably 0.5 to 30%, most preferably 1 to 15%.
Enzyme
Enzyme can also exist in preparation.Preferred enzyme include protease, lipase, pectate lyase, amylase,
Cutinase, cellulase, mannase.If it does, enzyme stabilization can be made with known enzyme stabilizers, such as boric acid.
Embodiment
The preparation method of preparation
Using Janke&Kunkel IKA RW20 overhead type mixer, by water and water-soluble helped with the shear rate of 150rpm
Long agent mixes 2-3 minutes under environment temperature (about 22 DEG C).Before addition surfactant and fatty acid, addition
Salt and alkali simultaneously mix 5 minutes.Mixture can show slight exotherm in the point.After being cooled to 30 DEG C of <, addition sun
Ionomer (LR400 added as an aqueous solution) solution and any remaining component, such as fragrance, preservative, dye
Material and polysiloxanes.Polysiloxanes is added with 1wt.%, and is added in the form of an emulsion.It is according to the present invention with number
Preparation is comparison preparation with letter.
Table 1
Table 2
Table 3
Stability/haze measurement
It samples and is added in the cuvette of 1cm from each preparation and measured by UV-Vis, take the reading at 500nm
Number.The measurement of the UV-Vis provides the level of haze of product.Lesser reading indicates lesser mist degree.
Table 4
From table 4, it is clear that, compared with dimethyl silicone polymer, the preparation of anion polysiloxane preparation has small obtain
More mist degrees.
Also from table 4 it is clear that, with when preparation introduce cationic guar polymer when compared with, use cationic fiber
The preparation of plain polymer preparation has much smaller mist degree.
Claims (28)
1. liquid laundry detergent compositions include :-
(a) 15 to 40wt.% surfactant, the anion and non-ionic surface active for being 5:1 to 1:3 comprising weight ratio
Agent；
(b) 0.1 to 5wt.% fabric-softening anion siloxanes；
(c) 0.05 to 2.5wt.% cationic cellulose polymer；
(d) 0.001 to 3wt.% fragrance；With,
Wherein anionic surfactant includes one or more following groups: linear alkylbenzene sulfonate (LAS) has 1 to 3 to be averaged
Mole ethoxylation lauryl ether sodium sulfonate, primary alkyl sulfonate, methyl ether sulfate and secondary alkyl sulfonate or it is mixed
Close object.
2. composition according to claim 1, wherein the weight ratio of anion and nonionic surfactant is 5:1 to 1:2.
3. composition according to claim 1, wherein the weight ratio of anion and nonionic surfactant is 5:1 to 1:
1.25。
4. composition according to claim 1, wherein the weight ratio of anion and nonionic surfactant is 5:1 to 1:1.
5. composition according to claim 1, wherein the weight ratio of anion and nonionic surfactant is 4:1 to 1:1.
6. composition according to claim 1 or 2, wherein anion siloxanes has 1,000 to 100,000 molecular weight.
7. composition according to claim 1 or 2, wherein anion siloxanes has 2,000 to 50,000 molecular weight.
8. composition according to claim 1 or 2, wherein anion siloxanes has 5,000 to 50,000 molecular weight.
9. composition according to claim 1 or 2, wherein anion siloxanes has 10,000 to 50,000 molecular weight.
10. composition according to claim 1 or 2, wherein anion siloxanes includes carboxyl siloxanes.
11. composition according to claim 1 or 2, wherein siloxanes is added into the preparation of emulsion form.
12. composition according to claim 1 or 2, wherein siloxanes is added into the preparation of non-ionic emulsion form.
13. composition according to claim 1 or 2, wherein using collateralization nonionic emulsifier, siloxanes is added into lotion
In the preparation of form.
14. composition according to claim 1 or 2, wherein liquid detergent composition has 6 to 10 pH.
15. composition according to claim 1 or 2, wherein liquid detergent composition has 6.5 to 9.5 pH.
16. composition according to claim 1 or 2, wherein liquid detergent composition has 7 to 9 pH.
17. composition according to claim 1 or 2, wherein liquid detergent composition has 7.5 to 8.5 pH.
18. composition according to claim 1 or 2, wherein cationic polymer exists with 0.1 to 2wt.% concentration.
19. composition according to claim 1 or 2, wherein cationic polymer exists with 0.1 to 1wt.% concentration.
20. composition according to claim 1 or 2, wherein cationic polymer exists with 0.1 to 0.75wt.% concentration.
21. composition according to claim 1 or 2, wherein cationic cellulose polymer is quaternized hydroxyethyl cellulose.
22. composition according to claim 1 or 2, wherein the weight ratio of siloxanes and cationic polymer is 5:1 to 1:1.
23. composition according to claim 1 or 2, wherein anion siloxanes exists with 0.1 to 2.5wt.% concentration.
24. composition according to claim 1 or 2, wherein anion siloxanes exists with 0.1 to 2wt.% concentration.
25. composition according to claim 1 or 2, wherein there is anion siloxanes at least anionic group of 1mol% to contain
Amount.
26. composition according to claim 1 or 2, wherein there is anion siloxanes at least anionic group of 2mol% to contain
Amount.
27. composition according to claim 1 or 2, wherein composition is further included selected from fatty acid or its salt, masking dye
Material, enzyme, antiredeposition polymer, dye transfer inhibiting polymers, builder, chelating agent, sun-screening agent, fluorescent whitening agent and/or
The ingredient of soil release polymer.
28. according to claim 1 to any one of 27 composition softening fabrics purposes.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13194580 | 2013-11-27 | ||
| EP13194580.0 | 2013-11-27 | ||
| PCT/EP2014/075144 WO2015078764A1 (en) | 2013-11-27 | 2014-11-20 | Laundry compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105874048A CN105874048A (en) | 2016-08-17 |
| CN105874048B true CN105874048B (en) | 2018-12-04 |
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| CN201480065245.0A Active CN105874048B (en) | 2013-11-27 | 2014-11-20 | Laundry composition |
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| Country | Link |
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| EP (1) | EP3074496B1 (en) |
| CN (1) | CN105874048B (en) |
| AR (1) | AR098530A1 (en) |
| BR (1) | BR112016011888B1 (en) |
| CL (1) | CL2016001277A1 (en) |
| WO (1) | WO2015078764A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3101102B2 (en) * | 2015-06-05 | 2023-12-13 | The Procter & Gamble Company | Compacted liquid laundry detergent composition |
| WO2018060056A1 (en) * | 2016-09-29 | 2018-04-05 | Unilever Plc | Laundry composition |
| CN106497690A (en) * | 2016-10-12 | 2017-03-15 | 易洁(北京)科技有限公司 | A kind of liquid detergent processing technology |
| EP3415603A1 (en) * | 2017-06-13 | 2018-12-19 | The Procter & Gamble Company | Consumer product |
| WO2018231750A1 (en) | 2017-06-13 | 2018-12-20 | The Procter & Gamble Company | Process for treating at least one garment |
| EP3415602A1 (en) * | 2017-06-13 | 2018-12-19 | The Procter & Gamble Company | Consumer product |
| EP3415590B1 (en) * | 2017-06-13 | 2023-07-05 | The Procter & Gamble Company | Consumer product |
| US20180355294A1 (en) * | 2017-06-13 | 2018-12-13 | The Procter & Gamble Company | Consumer product |
| WO2019166476A1 (en) * | 2018-03-02 | 2019-09-06 | Unilever Plc | Laundry composition |
| WO2019166477A1 (en) * | 2018-03-02 | 2019-09-06 | Unilever Plc | Laundry composition |
| US11814607B2 (en) | 2018-03-02 | 2023-11-14 | Conopco, Inc. | Laundry additive composition comprising a soil release polymer/silicone mixture |
| WO2019238350A1 (en) * | 2018-06-14 | 2019-12-19 | Unilever Plc | Detergent |
| US11220657B2 (en) | 2019-12-31 | 2022-01-11 | Henkel IP & Holding GmbH | Solid perfume composition delivering softening |
| US11447722B2 (en) | 2020-01-30 | 2022-09-20 | Henkel Ag & Co. Kgaa | Detergent composition for textile softening and anti-redeposition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1745167A (en) * | 2003-02-03 | 2006-03-08 | 西巴特殊化学品控股有限公司 | Washing agent and fabric softener formulations |
| CN102037112A (en) * | 2008-05-28 | 2011-04-27 | 宝洁公司 | Fabric softening laundry detergents with good stability |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GR76189B (en) | 1981-07-13 | 1984-08-03 | Procter & Gamble | |
| GB8803036D0 (en) | 1988-02-10 | 1988-03-09 | Unilever Plc | Liquid detergents |
| WO2004041986A1 (en) * | 2002-11-04 | 2004-05-21 | The Procter & Gamble Company | Fabric treatment compositions comprising oppositely charged polymers |
| US20060030513A1 (en) * | 2004-08-03 | 2006-02-09 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Softening laundry detergent |
| JP5305677B2 (en) * | 2008-02-05 | 2013-10-02 | 株式会社 資生堂 | Cleaning fee |
-
2014
- 2014-11-20 WO PCT/EP2014/075144 patent/WO2015078764A1/en active Application Filing
- 2014-11-20 EP EP14802032.4A patent/EP3074496B1/en active Active
- 2014-11-20 CN CN201480065245.0A patent/CN105874048B/en active Active
- 2014-11-20 BR BR112016011888-0A patent/BR112016011888B1/en active IP Right Grant
- 2014-11-26 AR ARP140104415A patent/AR098530A1/en active IP Right Grant
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- 2016-05-25 CL CL2016001277A patent/CL2016001277A1/en unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1745167A (en) * | 2003-02-03 | 2006-03-08 | 西巴特殊化学品控股有限公司 | Washing agent and fabric softener formulations |
| CN102037112A (en) * | 2008-05-28 | 2011-04-27 | 宝洁公司 | Fabric softening laundry detergents with good stability |
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| Publication number | Publication date |
|---|---|
| EP3074496B1 (en) | 2017-07-26 |
| CN105874048A (en) | 2016-08-17 |
| BR112016011888A2 (en) | 2017-08-08 |
| BR112016011888B1 (en) | 2021-11-23 |
| WO2015078764A1 (en) | 2015-06-04 |
| AR098530A1 (en) | 2016-06-01 |
| EP3074496A1 (en) | 2016-10-05 |
| CL2016001277A1 (en) | 2016-10-21 |
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