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CN104831002B - A kind of sugar clarification production line - Google Patents

A kind of sugar clarification production line Download PDF

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CN104831002B
CN104831002B CN201510204213.0A CN201510204213A CN104831002B CN 104831002 B CN104831002 B CN 104831002B CN 201510204213 A CN201510204213 A CN 201510204213A CN 104831002 B CN104831002 B CN 104831002B
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heating device
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CN104831002A (en
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李凯
李文
杭方学
陆海勤
谢彩锋
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Guangxi University
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    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • C13B20/02Purification of sugar juices using alkaline earth metal compounds
    • C13B20/04Purification of sugar juices using alkaline earth metal compounds followed by saturation
    • C13B20/06Purification of sugar juices using alkaline earth metal compounds followed by saturation with carbon dioxide or sulfur dioxide
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • C13B20/16Purification of sugar juices by physical means, e.g. osmosis or filtration
    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13BPRODUCTION OF SUCROSE; APPARATUS SPECIALLY ADAPTED THEREFOR
    • C13B20/00Purification of sugar juices
    • C13B20/16Purification of sugar juices by physical means, e.g. osmosis or filtration
    • C13B20/165Purification of sugar juices by physical means, e.g. osmosis or filtration using membranes, e.g. osmosis, ultrafiltration

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
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  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

一种制糖澄清生产线,包括依次连接的混合汁箱、卧螺式离心机、第一加热装置、硫熏装置、第二加热装置、多级陶瓷膜超滤系统以及板框压滤机。本发明在甘蔗混合汁澄清过程中只添加了少量的石灰和SO2,由于所加入的SO2较少,所得成品糖中含硫量极少,且色值低、纯度高、灰分低,从而保证了成品糖能满足高端客户的需求。另外,在甘蔗汁澄清过程采用了陶瓷膜超滤澄清,由于陶瓷膜上结垢造成的膜阻力较小,因此陶瓷膜过滤甘蔗汁的膜渗透通量较大,且陶瓷膜通量衰减速度慢,可维持较高的膜通量过滤,从而延长膜清洗周期和减少膜清洗频率。

A sugar clarification production line includes a mixed juice tank, a horizontal screw centrifuge, a first heating device, a sulfur fumigation device, a second heating device, a multi-stage ceramic membrane ultrafiltration system and a plate and frame filter press connected in sequence. In the present invention, only a small amount of lime and SO 2 are added in the clarification process of the sugarcane mixed juice. Since the added SO 2 is less, the sulfur content in the finished sugar is very small, and the color value is low, the purity is high, and the ash content is low, thereby It ensures that the finished sugar can meet the needs of high-end customers. In addition, in the sugarcane juice clarification process, ceramic membrane ultrafiltration is used for clarification. Due to the small membrane resistance caused by scaling on the ceramic membrane, the membrane permeation flux of the ceramic membrane for filtering sugarcane juice is relatively large, and the flux decay rate of the ceramic membrane is slow. , can maintain a high membrane flux filtration, thereby prolonging the membrane cleaning cycle and reducing the frequency of membrane cleaning.

Description

一种制糖澄清生产线A sugar clarification production line

技术领域technical field

本发明涉及制糖工程技术领域,具体是一种制糖澄清生产线。The invention relates to the technical field of sugar refining engineering, in particular to a sugar refining clarification production line.

背景技术Background technique

我国是世界上第三大产糖大国,年产白砂糖已超过1000万吨。目前,根据制糖澄清工艺的不同,生产耕地白砂糖的方法主要有两种:第一是亚硫酸法,第二是碳酸法。这两种方法虽然都能生产出符合国家质量标准的白砂糖,但是不论是亚硫酸法还是碳酸法都存在或多或少的不足之处。亚硫酸法在澄清过程中加入了较多SO2作为澄清剂,导致成品糖中有较多硫的残留,对于高端客户来说存在一定的局限性;而碳酸法则需要大量的石灰作为澄清剂,并产生大量的强碱性滤泥难以处理,不利于生态环保。这也是导致近些年来国内的一些糖厂采用“二步法”生产高品质白砂糖的原因,但是“二步法”生产工艺流程较长,设备投资成本大,能耗高,不能被广泛采用。my country is the third largest sugar producing country in the world, with an annual output of more than 10 million tons of white granulated sugar. At present, according to different sugar clarification processes, there are mainly two methods for producing farmland white granulated sugar: the first is the sulfurous acid method, and the second is the carbonic acid method. Although these two methods can produce white granulated sugar meeting national quality standards, there are more or less deficiencies in both the sulfurous acid method and the carbonic acid method. The sulfurous acid method adds more SO2 as a clarifying agent in the clarification process, resulting in more sulfur residues in the finished sugar, which has certain limitations for high-end customers; while the carbonic acid method requires a large amount of lime as a clarifying agent, And produce a large amount of strongly alkaline filter mud that is difficult to handle, which is not conducive to ecological protection. This is also the reason why some domestic sugar factories have adopted the "two-step method" to produce high-quality white sugar in recent years. However, the "two-step method" has a long production process, high equipment investment costs, and high energy consumption, so it cannot be widely used. .

随着社会的发展以及科学技术的不断进步,膜分离技术这个物理分离过程开始引起了制糖人士的广泛关注。分离膜根据其制造材料的不同可分为无机膜和有机膜两种。基于无机陶瓷膜具有机械强度大、化学稳定性高、耐高温、耐腐蚀、耐氧化、抗微生物能力强、分离精密度高以及易清洗等优点,因此其被广泛认为是最适合制糖工业化生产的膜材料。With the development of society and the continuous advancement of science and technology, membrane separation technology, a physical separation process, has attracted widespread attention from sugar producers. Separation membranes can be divided into inorganic membranes and organic membranes according to their manufacturing materials. Based on the advantages of inorganic ceramic membranes such as high mechanical strength, high chemical stability, high temperature resistance, corrosion resistance, oxidation resistance, strong anti-microbial ability, high separation precision and easy cleaning, it is widely considered to be the most suitable for industrial sugar production. membrane material.

据相关文献报道,有甘蔗糖厂将混合汁(甘蔗汁)依次经过加灰、粗滤、陶瓷膜超滤澄清后得到的澄清甘蔗汁送去蒸发、煮糖。这种方法将陶瓷膜直接过滤甘蔗汁获得澄清汁,省去了制糖过程加硫、加灰、沉淀等一系列复杂的澄清工序,从而大大缩短了整个制糖工艺流程,但是这种方法仍有较多不足之处:(1)这中方法虽然能获得色泽清亮透明、浊度极小的甘蔗澄清汁,但是由于陶瓷膜超滤很难截留一些分子量较小的色素,且这些小分子色素在蔗糖结晶过程是一类极易附着在蔗糖晶体表面的色素,因此这种方法生产出的白砂糖色值较高,其色值在500~600IU之间,很难达到国家一级白砂糖色值(≤150IU)的要求;(2)在传统的亚硫酸法制糖澄清工艺中,虽然其对有色物质的去除率也较小,但是由于其引入的SO2对糖品中的色素通过氧化还原反应的作用对其漂白,因而抑制了制糖结晶过程小分子色素在蔗糖晶体表面的附着,并且糖汁中氨基酸和还原糖极易发生美拉德反应生成美拉德色素,美拉德色素亦是一种极易在蔗糖晶体表面附着的色素,而硫的存在能够抑制美拉德反应的发生,因此传统的亚硫酸法制糖澄清工艺所制得的白砂糖的色值比上述膜法澄清工艺低得多。因此,这种方法得到的糖只能当作原糖,经过再一步的精炼才能获得高品质的糖,但是这必定大大增加了生产成本,不为糖厂普遍接受。According to relevant literature reports, there are sugarcane sugar factories to send the clarified sugarcane juice obtained after mixing juice (sugarcane juice) through adding ash, coarse filtration, and ceramic membrane ultrafiltration to clarify successively to evaporate and boil sugar. This method directly filters sugarcane juice with ceramic membranes to obtain clarified juice, which saves a series of complicated clarification procedures such as sulfur addition, ash addition, and precipitation in the sugar production process, thereby greatly shortening the entire sugar production process. There are many deficiencies: (1) although this method can obtain the sugarcane clarified juice with clear and transparent color and little turbidity, it is difficult to retain some pigments with less molecular weight due to ceramic membrane ultrafiltration, and these small molecular pigments In the sucrose crystallization process, it is a kind of pigment that is easy to attach to the surface of sucrose crystals. Therefore, the white sugar produced by this method has a high color value, and its color value is between 500 and 600IU. It is difficult to achieve the national first-class white sugar color. value (≤150IU); (2) In the traditional sulphite sugar clarification process, although its removal rate of colored substances is small, the SO 2 introduced by it affects the pigment in the sugar through redox The action of the reaction bleaches it, thereby inhibiting the attachment of small molecular pigments on the surface of sucrose crystals during the sugar crystallization process, and the amino acids and reducing sugars in sugar juice are prone to Maillard reactions to generate Maillard pigments, and Maillard pigments also It is a pigment that is easily attached to the surface of sucrose crystals, and the presence of sulfur can inhibit the occurrence of Maillard reaction. Therefore, the color value of white granulated sugar produced by the traditional sulfite sugar clarification process is better than that of the above-mentioned membrane clarification process. much lower. Therefore, the sugar obtained by this method can only be used as raw sugar, and high-quality sugar can be obtained through further refining, but this must greatly increase the production cost, which is not generally accepted by sugar factories.

为了使膜过滤得到的甘蔗澄清汁能加工出质量较好的白砂糖,发明专利CN103725802A中,发明人将甘蔗汁依次经过粗过滤、陶瓷膜精过滤、有机膜预浓缩、离子交换树脂除盐脱色、MVR蒸发浓缩、结晶后得到精制糖。这种方法虽然能够得到品质较好的精制糖,但是其亦存在着较多问题:(1)甘蔗汁的pH值普遍在5.6左右,显酸性,发明人未用石灰乳(或其它物质)将甘蔗汁的pH调节至中性左右后再处理,这会导致蔗糖在加工过程严重转化损失,从而降低蔗糖的回收率;(2)采用有机纳滤或者有机反渗透膜浓缩甘蔗汁,通量较小、浓缩倍数低、易污染,这不仅增加了蔗糖加工的时间,导致蔗糖转化较多,而且增加了设备的投资成本;(3)离子交换树脂脱色属于精脱色,甘蔗汁的色值普遍在1500~2500IU,色值较高,这不仅增加了离子交换树脂的负荷还降低了离子交换树脂的寿命,并且树脂污染快,再生较困难;(4)甘蔗汁的电导率在3000~6000us/cm,要将甘蔗汁中的盐分除去会使得脱盐树脂的负荷较大,设备投资成本较大,并且甘蔗汁的电导率虽然较大,但是其对制糖过程影响较小,不必花费高额成本将其除去;(5)蒸发工段是用蒸汽加热蔗汁,使蔗汁沸腾后,水分挥发,达到浓缩的目的,目前糖厂普遍采用五效压力真空蒸发系统,从清汁变成糖浆要蒸发的水分约为65%~80%,需要消耗较多的蒸汽,同时也产生大量的二次蒸汽(汁汽),这些产生的二次蒸汽温度还很高,可供糖汁加热或者煮糖使用,因此蒸发工段既是蒸汽的消费者,又是低压蒸汽的供应站,同时还供给糖厂其他部门热水,故有糖厂第二锅炉之称,MVR蒸发器取代了传统的制糖过程的五效压力真空蒸发虽然能获得较低的蒸发温度,从而获得质量较好的糖浆,但是MVR蒸发的温度较低,其产生的二次蒸汽的压力和温度都比五效压力真空蒸发低得多,可利用的效率较低,如果直接抽用来自锅炉降温减压的乏汽作为加热或煮糖用汽,能耗会非常高。In order to process the clarified sugarcane juice obtained by membrane filtration into white sugar with better quality, in the invention patent CN103725802A, the inventor sequentially passes the sugarcane juice through coarse filtration, ceramic membrane fine filtration, organic membrane pre-concentration, ion exchange resin desalination and decolorization , MVR evaporates, concentrates, and crystallizes to obtain refined sugar. Although this method can obtain refined sugar with better quality, it also has many problems: (1) the pH value of sugarcane juice is generally around 5.6, which is acidic, and the inventor has not used milk of lime (or other substances) to The pH of sugarcane juice is adjusted to be around neutral before processing, which will lead to serious conversion loss of sucrose during processing, thereby reducing the recovery rate of sucrose; (2) using organic nanofiltration or organic reverse osmosis membrane to concentrate sugarcane juice, the flux is relatively low Small size, low concentration ratio, and easy pollution, which not only increases the time of sucrose processing, leads to more sucrose conversion, but also increases the investment cost of equipment; (3) The decolorization of ion exchange resin belongs to fine decolorization, and the color value of sugarcane juice is generally in the 1500~2500IU, the color value is high, which not only increases the load of ion exchange resin but also reduces the life of ion exchange resin, and the resin is polluted quickly and regeneration is difficult; (4) the conductivity of sugarcane juice is 3000~6000us/cm In order to remove the salt in sugarcane juice, the load of desalting resin will be larger, and the investment cost of equipment will be larger. Moreover, although the conductivity of sugarcane juice is larger, it has little impact on the sugar production process, and it is not necessary to spend a lot of money to convert it (5) The evaporation section uses steam to heat the cane juice, so that after the cane juice is boiled, the water evaporates to achieve the purpose of concentration. At present, sugar factories generally use a five-effect pressure vacuum evaporation system to change the water that needs to be evaporated from clear juice to syrup. It is about 65% to 80%. It needs to consume more steam, and also produces a large amount of secondary steam (juice steam). The temperature of the secondary steam is still high, which can be used for heating juice or boiling sugar. Therefore The evaporation section is not only a consumer of steam, but also a supply station of low-pressure steam. At the same time, it also supplies hot water to other departments of the sugar factory, so it is called the second boiler of the sugar factory. The MVR evaporator replaces the five-effect pressure of the traditional sugar production process. Although vacuum evaporation can obtain a lower evaporation temperature, thereby obtaining better quality syrup, but the MVR evaporation temperature is lower, and the pressure and temperature of the secondary steam generated by it are much lower than the five-effect pressure vacuum evaporation, which can be used The efficiency is low. If the exhaust steam from the boiler cooling and decompression is directly used as heating or sugar cooking steam, the energy consumption will be very high.

因此,如能将传统的亚硫酸法制糖澄清工艺与膜分离技术耦合,在甘蔗汁进入陶瓷膜之前先将甘蔗汁的pH值调节至中性偏碱,然后再将甘蔗汁进行低强度的硫熏,使甘蔗汁的硫熏强度为4~6mL,再进入陶瓷膜超滤澄清得到甘蔗澄清汁,最后再将甘蔗澄清汁送去蒸发浓缩、煮糖结晶,即可得到质量较好的白砂糖。这种方法得到的甘蔗汁因有少量的硫护色,既能抑制美拉德色素的生成,又能防止小分子色素在蔗糖晶体表面附着,生产出的甘蔗澄清汁色值低、纯度高、浊度低,最终便可得到与碳酸法相媲美的高品质的耕地白砂糖。Therefore, if the traditional sulfite sugar clarification process can be coupled with membrane separation technology, the pH value of the sugarcane juice should be adjusted to neutral and alkaline before the sugarcane juice enters the ceramic membrane, and then the sugarcane juice is subjected to low-intensity sulfur Smoke the sugarcane juice so that the sulfur fumigation strength of the sugarcane juice is 4-6mL, and then enter the ceramic membrane ultrafiltration to obtain the clarified sugarcane juice, and finally send the clarified sugarcane juice to evaporation concentration, boiling sugar crystallization, and then you can get white sugar with good quality . The sugarcane juice obtained by this method has a small amount of sulfur to protect the color, which can not only inhibit the generation of Maillard pigment, but also prevent the small molecule pigment from adhering to the surface of the sucrose crystal. The sugarcane clarified juice produced has low color value, high purity, With low turbidity, high-quality farmland white granulated sugar comparable to that of carbonic acid can be finally obtained.

发明内容Contents of the invention

本发明的目的是提供一种制糖澄清生产线,解决了传统的亚硫酸法制糖澄清工艺澄清效果较差、所得成品糖含硫量高、品质低以及传统膜分离技术处理甘蔗汁得到的成品糖色值高的技术问题。The purpose of the present invention is to provide a sugar clarification production line, which solves the problem of the poor clarification effect of the traditional sulfite sugar clarification process, high sulfur content and low quality of the finished sugar, and the color of the finished sugar obtained by processing sugarcane juice with traditional membrane separation technology. High technical issues.

为了实现上述目的,本发明采用了以下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:

一种制糖澄清生产线,包括依次连接的混合汁箱、卧螺式离心机、第一加热装置、硫熏装置、第二加热装置、多级陶瓷膜超滤系统以及板框压滤机。A sugar clarification production line includes a mixed juice tank, a horizontal screw centrifuge, a first heating device, a sulfur fumigation device, a second heating device, a multi-stage ceramic membrane ultrafiltration system and a plate and frame filter press connected in sequence.

所述卧螺式离心机与第一加热装置之间连接有第一缓冲箱,硫熏装置与第二加热装置之间连接有第二缓冲箱,第二加热装置与多级陶瓷膜超滤系统之间连接有第三缓冲箱。A first buffer tank is connected between the decanter centrifuge and the first heating device, a second buffer tank is connected between the sulfur fumigation device and the second heating device, and the second heating device and the multi-stage ceramic membrane ultrafiltration system A third buffer box is connected between them.

混合汁箱进口与甘蔗糖厂压榨提汁工段和石灰乳罐连接,混合汁箱出口与卧螺式离心机进口连接,卧螺式离心机出口与第一缓冲箱进口连接,第一缓冲箱出口与第一加热装置入口连接,第一加热装置出口与硫熏装置糖汁入口连接,硫熏装置糖汁出口与第二缓冲箱入口连接,第二缓冲箱出口与第二加热装置入口连接,第二加热装置出口与第三缓冲箱入口连接,第三缓冲箱出口与多级陶瓷膜超滤系统入口连接,多级陶瓷膜超滤系统透过液出口与甘蔗澄清汁储箱入口连接,甘蔗澄清汁储箱出口与蒸发浓缩、煮糖结晶工段连接,多级陶瓷膜超滤系统浓缩液出口与板框压滤机入口连接,板框压滤机滤液出口连接至第一缓冲箱入口。The inlet of the mixed juice box is connected with the squeezing and extracting section of the sugarcane sugar factory and the lime milk tank, the outlet of the mixed juice box is connected with the inlet of the decanter centrifuge, the outlet of the decanter centrifuge is connected with the inlet of the first buffer tank, and the outlet of the first buffer tank It is connected with the inlet of the first heating device, the outlet of the first heating device is connected with the sugar juice inlet of the sulfur fumigation device, the sugar juice outlet of the sulfur fumigation device is connected with the inlet of the second buffer tank, the outlet of the second buffer tank is connected with the inlet of the second heating device, and the The outlet of the second heating device is connected to the inlet of the third buffer tank, the outlet of the third buffer tank is connected to the inlet of the multi-stage ceramic membrane ultrafiltration system, the permeate outlet of the multi-stage ceramic membrane ultrafiltration system is connected to the inlet of the sugarcane clarified juice storage tank, and the sugarcane clarification The outlet of the juice storage tank is connected to the evaporative concentration and sugar boiling crystallization section, the concentrated solution outlet of the multi-stage ceramic membrane ultrafiltration system is connected to the inlet of the plate and frame filter press, and the filtrate outlet of the plate and frame filter press is connected to the inlet of the first buffer tank.

所述第一加热装置包括串联的第一列管式换热器、第二列管式换热器以及第三列管式换热器,其中有一个加热器起轮洗更换作用。The first heating device includes a first tube-and-tube heat exchanger, a second tube-and-tube heat exchanger, and a third tube-and-tube heat exchanger connected in series, and one of the heaters plays the role of washing and replacing in rotation.

所述第二加热装置包括串联的第四列管式换热器、第五列管式换热器以及第六列管式换热器,其中有一个加热器起轮洗更换作用。The second heating device includes a fourth tube-and-tube heat exchanger, a fifth tube-and-tube heat exchanger, and a sixth tube-and-tube heat exchanger connected in series, and one of the heaters plays the role of washing and replacing in rotation.

所述硫熏装置包括并联的第一立式硫熏器和第二立式硫熏器,其中有一个硫熏器起轮洗更换作用。The sulfur fumigation device includes a first vertical sulfur fumigation device and a second vertical sulfur fumigation device connected in parallel, wherein one sulfur fumigation device plays the role of washing and replacement in rotation.

所述硫熏装置的硫气入口与二氧化硫供气源连接。The sulfur gas inlet of the sulfur fumigation device is connected with a sulfur dioxide gas supply source.

所述多级陶瓷膜超滤系统为五级并联的陶瓷超滤膜,每级陶瓷膜由两个膜组件组成,其中有一级起轮洗更换作用。The multi-stage ceramic membrane ultrafiltration system is a five-stage parallel ceramic ultrafiltration membrane, and each stage of ceramic membrane is composed of two membrane modules, one of which plays the role of washing and replacement in rotation.

与现有技术相比较,本发明具备的有益效果:Compared with the prior art, the present invention has the beneficial effects:

(1)在甘蔗混合汁澄清过程只添加了少量的石灰和SO2,由于所加入的SO2较少,所得成品糖中含硫量极少,且色值低、纯度高、灰分低,从而保证了成品糖能够满足高端客户的需求。另外,在甘蔗汁澄清过程采用了陶瓷膜超滤澄清,由于陶瓷膜上结垢造成的膜阻力较小,因此陶瓷膜过滤甘蔗汁的膜渗透通量较大,且陶瓷膜通量衰减速度慢,可维持较高的膜通量过滤,从而延长膜清洗周期和减少膜清洗频率。(1) Only a small amount of lime and SO 2 are added in the clarification process of sugarcane mixed juice. Because the added SO 2 is less, the sulfur content in the finished sugar is very little, and the color value is low, the purity is high, and the ash content is low, thereby It ensures that the finished sugar can meet the needs of high-end customers. In addition, in the sugarcane juice clarification process, ceramic membrane ultrafiltration is used for clarification. Due to the small membrane resistance caused by scaling on the ceramic membrane, the membrane permeation flux of the ceramic membrane for filtering sugarcane juice is relatively large, and the flux decay rate of the ceramic membrane is slow. , can maintain a high membrane flux filtration, thereby prolonging the membrane cleaning cycle and reducing the frequency of membrane cleaning.

(2)采用了由五级并联的陶瓷超滤膜组成的多级陶瓷膜超滤系统,每级由两个膜组件组成,有一级起更换轮洗作用,保证了陶瓷膜超滤系统能够长时间稳定的运行。(2) A multi-stage ceramic membrane ultrafiltration system composed of five-stage parallel ceramic ultrafiltration membranes is adopted. Each stage is composed of two membrane modules, and one stage acts as a replacement wheel for washing, ensuring the long-term performance of the ceramic membrane ultrafiltration system. Time to run stably.

(3)采用了卧螺式离心机粗滤甘蔗汁,相对于传统甘蔗汁的粗滤设备滚筒筛、曲筛以及振动筛等,卧螺式离心机具有结构紧凑、分离效率高、出产能力大、附属设备少等优点。(3) A decanter centrifuge is used to coarsely filter sugarcane juice. Compared with traditional sugarcane juice coarse filtration equipment such as drum sieve, curved sieve and vibrating screen, the decanter centrifuge has compact structure, high separation efficiency and large production capacity. , Less auxiliary equipment and so on.

(4)在甘蔗汁进入陶瓷膜超滤系统澄清之前,先将甘蔗汁的pH值调节至7.5~7.8,然后再对甘蔗汁进行低强度的硫熏,使甘蔗汁的硫熏强度控制在4~6mL之间,其具有如下好处:a.加入石灰乳调节后蔗汁的pH值为微碱性,经过硫熏、加热、超滤等工序后,其pH值会下降至7.0~7.2,然后再将澄清后的甘蔗汁送去蒸发浓缩、煮糖结晶,从而便可防止了甘蔗汁在加工过程由于pH较低导致蔗糖转化较多的技术问题;b.在传统的亚硫酸法制糖澄清工艺中需要加入较多的SO2(硫熏强度为25~30mL)与石灰乳反应生成较多的CaSO3沉淀来吸附蔗汁中的非糖杂质,来达到澄清甘蔗汁的目的,由于加入的硫较多往往导致最终成品糖中硫的残留较多,从而影响了成品糖的品质,而本发明在现有的亚硫酸法制糖澄清工艺的基础上,用陶瓷超滤膜来除去蔗汁中绝大部分非糖杂质,并往甘蔗汁中加入少量的SO2,甘蔗汁因有硫护色,既能抑制美拉德色素的生成,又能防止小分子色素在蔗糖晶体表面附着,生产出的甘蔗澄清汁色值低、纯度高、浊度低,最终便可得到与碳酸法相媲美的高品质的耕地白砂糖。(4) Before the sugarcane juice enters the ceramic membrane ultrafiltration system for clarification, adjust the pH value of the sugarcane juice to 7.5-7.8, and then carry out low-intensity sulfur fumigation on the sugarcane juice, so that the sulfur fumigation intensity of the sugarcane juice is controlled at 4 Between ~6mL, it has the following advantages: a. The pH value of sugarcane juice after adding lime milk to adjust is slightly alkaline, after sulfur fumigation, heating, ultrafiltration and other processes, its pH value will drop to 7.0 ~ 7.2, and then Then the clarified sugarcane juice is sent to evaporation concentration and boiled sugar crystallization, thereby preventing the sugarcane juice from the technical problem of more sucrose conversion due to the low pH in the processing process; b. In the traditional sulfite sugar clarification process It is necessary to add more SO 2 (sulfur fumigation intensity is 25-30mL) to react with milk of lime to generate more CaSO 3 precipitates to absorb non-sugar impurities in sugarcane juice to achieve the purpose of clarifying sugarcane juice. Due to the addition of sulfur More often lead to more sulfur residues in the final finished sugar, thereby affecting the quality of the finished sugar, and the present invention uses ceramic ultrafiltration membranes to remove the absolute sulfur in sugarcane juice on the basis of the existing sulfite sugar clarification process. Most of the non-sugar impurities, and add a small amount of SO 2 to the sugarcane juice, because the sugarcane juice has sulfur to protect the color, it can not only inhibit the formation of Maillard pigment, but also prevent the small molecule pigment from attaching to the surface of the sucrose crystal, and the produced Sugarcane clarified juice has low color value, high purity, and low turbidity, and finally high-quality farmland white sugar comparable to carbonation can be obtained.

(5)将膜浓缩液经板框压滤机处理后,再回流到粗滤甘蔗汁储存箱中,避免将浓缩液直接排掉,造成浪费的问题。(5) After the membrane concentrate is processed by a plate and frame filter press, it is then returned to the coarsely filtered sugarcane juice storage tank to avoid the problem of waste due to direct draining of the concentrate.

附图说明Description of drawings

图1为本发明所述的制糖澄清生产线的示意图。Fig. 1 is the schematic diagram of the sugar clarification production line of the present invention.

图中:甘蔗糖厂压榨提汁工段1;石灰乳罐2;混合汁箱3;卧螺式离心机4;第一缓冲箱5;第一列管式换热器6;第二列管式换热器7;第三列管式换热器8;第一立式硫熏器9;第二立式硫熏器10;第二缓冲箱11;第四列管式换热器12;第五列管式换热器13;第六列管式换热器14;第三缓冲箱15;多级陶瓷膜超滤系统16;甘蔗澄清汁储箱17;板框压滤机18;蒸发浓缩、煮糖结晶工段19;二氧化硫供气源20。In the picture: sugarcane sugar factory pressing and extracting section 1; lime milk tank 2; mixed juice tank 3; horizontal screw centrifuge 4; first buffer tank 5; first tube-and-tube heat exchanger 6; second tube-and-tube heat exchanger Heat exchanger 7; third tubular heat exchanger 8; first vertical sulfur fumigation device 9; second vertical sulfur fumigation device 10; second buffer tank 11; fourth tubular heat exchanger 12; Five-tube heat exchanger 13; sixth tube-type heat exchanger 14; third buffer tank 15; multi-stage ceramic membrane ultrafiltration system 16; sugarcane clarified juice storage tank 17; plate-and-frame filter press 18; evaporation and concentration 19. Sugar boiling crystallization section 19; sulfur dioxide gas supply source 20.

具体实施方式Detailed ways

下面通过实施例对本发明的技术方案作进一步阐述。The technical solution of the present invention will be further elaborated below through examples.

实施例1Example 1

一种制糖澄清生产线,包括依次连接的混合汁箱3、卧螺式离心机4、第一加热装置、硫熏装置、第二加热装置、多级陶瓷膜超滤系统16以及板框压滤机18。A sugar clarification production line, including a mixed juice box 3, a decanter centrifuge 4, a first heating device, a sulfur fumigation device, a second heating device, a multi-stage ceramic membrane ultrafiltration system 16, and a plate and frame filter press connected in sequence Machine 18.

所述卧螺式离心机4与第一加热装置之间连接有第一缓冲箱5,硫熏装置与第二加热装置之间连接有第二缓冲箱11,第二加热装置与多级陶瓷膜超滤系统之间连接有第三缓冲箱15。A first buffer tank 5 is connected between the decanter centrifuge 4 and the first heating device, a second buffer tank 11 is connected between the sulfur fumigation device and the second heating device, and the second heating device and the multi-stage ceramic membrane A third buffer tank 15 is connected between the ultrafiltration systems.

混合汁箱3进口与甘蔗糖厂压榨提汁工段1和石灰乳罐2连接,混合汁箱3出口与卧螺式离心机4进口连接,卧螺式离心机4出口与第一缓冲箱5进口连接,第一缓冲箱5出口与第一加热装置入口连接,第一加热装置出口与硫熏装置糖汁入口连接,硫熏装置糖汁出口与第二缓冲箱11入口连接,第二缓冲箱11出口与第二加热装置入口连接,第二加热装置出口与第三缓冲箱15入口连接,第三缓冲箱15出口与多级陶瓷膜超滤系统16入口连接,多级陶瓷膜超滤系统16透过液出口与甘蔗澄清汁储箱17入口连接,甘蔗澄清汁储箱17出口与蒸发浓缩、煮糖结晶工段19连接,多级陶瓷膜超滤系统16浓缩液出口与板框压滤机18入口连接,板框压滤机18滤液出口连接至第一缓冲箱5入口。The inlet of the mixed juice box 3 is connected with the pressing and extracting section 1 of the sugarcane sugar factory and the lime milk tank 2, the outlet of the mixed juice box 3 is connected with the inlet of the decanter centrifuge 4, and the outlet of the decanter centrifuge 4 is connected with the inlet of the first buffer tank 5 Connection, the outlet of the first buffer tank 5 is connected with the inlet of the first heating device, the outlet of the first heating device is connected with the sugar juice inlet of the sulfur fumigation device, the sugar juice outlet of the sulfur fumigation device is connected with the inlet of the second buffer tank 11, and the second buffer tank 11 The outlet is connected to the inlet of the second heating device, the outlet of the second heating device is connected to the inlet of the third buffer tank 15, the outlet of the third buffer tank 15 is connected to the inlet of the multi-stage ceramic membrane ultrafiltration system 16, and the multi-stage ceramic membrane ultrafiltration system 16 is transparent The liquid outlet is connected to the inlet of the sugarcane clarified juice storage tank 17, the outlet of the sugarcane clarified juice storage tank 17 is connected to the evaporative concentration, sugar boiling and crystallization section 19, the outlet of the concentrated solution of the multi-stage ceramic membrane ultrafiltration system 16 is connected to the inlet of the plate and frame filter press 18 Connection, the filtrate outlet of the plate and frame filter press 18 is connected to the inlet of the first buffer tank 5 .

所述第一加热装置包括串联的第一列管式换热器6、第二列管式换热器7以及第三列管式换热器8,其中有一个加热器起轮洗更换作用。The first heating device includes a first tube-and-tube heat exchanger 6 , a second tube-and-tube heat exchanger 7 and a third tube-and-tube heat exchanger 8 connected in series, and one of the heaters plays the role of washing and replacing in rotation.

所述第二加热装置包括串联的第四列管式换热器12、第五列管式换热器13以及第六列管式换热器14,其中有一个加热器起轮洗更换作用。The second heating device includes a fourth tubular heat exchanger 12 , a fifth tubular heat exchanger 13 and a sixth tubular heat exchanger 14 connected in series, and one of the heaters plays the role of washing and replacement in rotation.

所述硫熏装置包括并联的第一立式硫熏器9和第二立式硫熏器10,其中有一个硫熏器起轮洗更换作用。The sulfur fumigation device includes a first vertical sulfur fumigation device 9 and a second vertical sulfur fumigation device 10 connected in parallel, wherein one sulfur fumigation device plays the role of washing and replacement in rotation.

所述硫熏装置的硫气入口与二氧化硫供气源20连接。The sulfur gas inlet of the sulfur fumigation device is connected with a sulfur dioxide gas supply source 20 .

所述的多级陶瓷膜超滤系统16为五级并联的陶瓷超滤膜,每级陶瓷膜由两个膜组件组成,其中有一级起轮洗更换作用。The multi-stage ceramic membrane ultrafiltration system 16 is a five-stage ceramic ultrafiltration membrane in parallel, and each stage of ceramic membrane is composed of two membrane modules, one of which plays the role of washing and replacement in rotation.

实施例2Example 2

本实施例为利用实施例1所述制糖澄清生产线进行实际生产的一个实例,具体操作步骤如下:This embodiment is an example of actual production using the sugar clarification production line described in Example 1, and the specific steps are as follows:

(1)加灰:往甘蔗糖厂的混合汁中加入浓度为8.0°Be石灰乳,调节甘蔗汁的pH值至7.6,防止甘蔗汁中的蔗糖在酸性条件下转化,导致蔗糖分损失,得到加灰甘蔗汁;(1) Liming: adding milk of lime with a concentration of 8.0 ° Be to the mixed juice of the sugarcane sugar factory, adjusting the pH value of the sugarcane juice to 7.6, preventing the sucrose in the sugarcane juice from converting under acidic conditions, resulting in the loss of sucrose, and obtaining limed cane juice;

(2)粗滤:利用孔径为50.0μm的卧螺式离心机对加灰甘蔗汁进行过滤,得到粗滤甘蔗汁;(2) Coarse filtration: Utilize a decanter centrifuge with an aperture of 50.0 μm to filter the ash-added sugarcane juice to obtain the coarsely filtered sugarcane juice;

(3)第一次加热:用列管式换热器将粗滤甘蔗汁加热至55℃,利于下一步硫熏过程蔗汁对SO2的吸收,得到第一次加热甘蔗汁;(3) Heating for the first time: heating the coarsely filtered sugarcane juice to 55°C with a shell and tube heat exchanger, which is beneficial to the absorption of SO by the sugarcane juice in the next step of sulfur fumigation process, and obtaining the sugarcane juice heated for the first time;

(4)硫熏:利用硫熏装置对第一次加热甘蔗汁进行硫熏,得到硫熏强度为4mL的硫熏甘蔗汁;(4) Sulfur fumigation: Utilize the sulfur fumigation device to carry out sulfur fumigation to the sugarcane juice heated for the first time to obtain sulfur fumigation sugarcane juice with a sulfur fumigation intensity of 4 mL;

(5)第二次加热:用列管式换热器将硫熏甘蔗汁加热至80~90℃,得到第二次加热甘蔗汁;(5) Second heating: heat the sulfur-smoked sugarcane juice to 80-90°C with a tube-and-tube heat exchanger to obtain the second heating sugarcane juice;

(6)陶瓷膜超滤澄清:以膜孔径为0.05μm的多级陶瓷膜超滤系统对第二次加热甘蔗汁进行超滤澄清,得到澄清甘蔗汁和膜浓缩液;(6) ceramic membrane ultrafiltration clarification: the second heating sugarcane juice is carried out ultrafiltration clarification with a multi-stage ceramic membrane ultrafiltration system with a membrane pore size of 0.05 μm, to obtain clarified sugarcane juice and membrane concentrate;

(7)蒸发、结晶:澄清甘蔗汁经蒸发浓缩和煮糖结晶后,即可得到白砂糖;(7) Evaporation and crystallization: After the clarified sugarcane juice is concentrated by evaporation and crystallized by boiling sugar, white granulated sugar can be obtained;

(8)膜浓缩液回收:利用板框压滤机对膜浓缩液进行过滤,并将过滤液与粗滤甘蔗汁混合,重复步骤(3)~(7)。(8) Recovery of the membrane concentrate: filter the membrane concentrate with a plate and frame filter press, mix the filtrate with the coarsely filtered sugarcane juice, and repeat steps (3) to (7).

步骤(4)所述的硫熏装置为两个并联的立式硫熏器,其中有一个硫熏器起轮洗更换作用。The sulfur fumigation device described in step (4) is two parallel vertical sulfur fumigation devices, one of which plays the role of washing and replacement in rotation.

步骤(6)所述的陶瓷膜的操作参数如下:跨膜压差为0.1~0.3Mpa,膜面流速为4~5m/s、过滤温度为80~90℃。The operating parameters of the ceramic membrane in step (6) are as follows: the transmembrane pressure difference is 0.1-0.3Mpa, the membrane surface flow velocity is 4-5m/s, and the filtration temperature is 80-90°C.

步骤(6)所述的多级陶瓷膜超滤系统为五级并联的陶瓷超滤膜,每级陶瓷膜由两个膜组件组成,其中有一级起轮洗更换作用。The multi-stage ceramic membrane ultrafiltration system described in step (6) is a five-stage ceramic ultrafiltration membrane connected in parallel, and each stage of ceramic membrane is composed of two membrane modules, one of which plays a role of washing and replacement in rotation.

步骤(8)所述的板框压滤机需要硅藻土助滤。The plate and frame filter press described in step (8) needs diatomite filter aid.

实施例2加工出的白砂糖各理化指标如下表所示:The physical and chemical indexes of the white granulated sugar processed in embodiment 2 are shown in the following table:

*中华人民共和国国家标准GB317-2006 * The National Standard of the People's Republic of China GB317-2006

实施例3Example 3

本实施例为利用实施例1所述制糖澄清生产线进行实际生产的另一个实例,具体操作步骤如下:This embodiment is another example of actual production using the sugar clarification production line described in Embodiment 1, and the specific operation steps are as follows:

(1)加灰:往甘蔗糖厂的混合汁中加入浓度为8.5°Be石灰乳,调节甘蔗汁的pH值至7.5,防止甘蔗汁中的蔗糖在酸性条件下转化,导致蔗糖分损失,得到加灰甘蔗汁;(1) Liming: adding milk of lime with a concentration of 8.5 ° Be to the mixed juice of the sugarcane sugar factory, adjusting the pH value of the sugarcane juice to 7.5, preventing the sucrose in the sugarcane juice from converting under acidic conditions, resulting in the loss of sucrose, and obtaining limed cane juice;

(2)粗滤:利用孔径为150.0μm的卧螺式离心机对加灰甘蔗汁进行过滤,得到粗滤甘蔗汁;(2) Coarse filtration: Utilize a decanter centrifuge with an aperture of 150.0 μm to filter the ash-added sugarcane juice to obtain the coarsely filtered sugarcane juice;

(3)第一次加热:用列管式换热器将粗滤甘蔗汁加热至65℃,利于下一步硫熏过程蔗汁对SO2的吸收,得到第一次加热甘蔗汁;(3) Heating for the first time: heating the coarsely filtered sugarcane juice to 65°C with a shell and tube heat exchanger, which is beneficial to the absorption of SO by the sugarcane juice in the next step of sulfur fumigation process, and obtaining the sugarcane juice heated for the first time;

(4)硫熏:利用硫熏装置对第一次加热甘蔗汁进行硫熏,得到硫熏强度为6mL的硫熏甘蔗汁;(4) Sulfur fumigation: Utilize the sulfur fumigation device to carry out sulfur fumigation to the sugarcane juice heated for the first time, to obtain sulfur fumigation sugarcane juice with a sulfur fumigation intensity of 6 mL;

(5)第二次加热:用列管式换热器将硫熏甘蔗汁加热至80~90℃,得到第二次加热甘蔗汁;(5) Second heating: heat the sulfur-smoked sugarcane juice to 80-90°C with a tube-and-tube heat exchanger to obtain the second heating sugarcane juice;

(6)陶瓷膜超滤澄清:以膜孔径为0.10μm的多级陶瓷膜超滤系统对第二次加热甘蔗汁进行超滤澄清,得到澄清甘蔗汁和膜浓缩液;(6) ceramic membrane ultrafiltration clarification: the second heating sugarcane juice is carried out ultrafiltration clarification with a multi-stage ceramic membrane ultrafiltration system with a membrane pore size of 0.10 μm, to obtain clarified sugarcane juice and membrane concentrate;

(7)蒸发、结晶:澄清甘蔗汁经蒸发浓缩和煮糖结晶后,即可得到白砂糖;(7) Evaporation and crystallization: After the clarified sugarcane juice is concentrated by evaporation and crystallized by boiling sugar, white granulated sugar can be obtained;

(8)膜浓缩液回收:利用板框压滤机对膜浓缩液进行过滤,并将过滤液与粗滤甘蔗汁混合,重复步骤(3)~(7)。(8) Recovery of the membrane concentrate: filter the membrane concentrate with a plate and frame filter press, mix the filtrate with the coarsely filtered sugarcane juice, and repeat steps (3) to (7).

步骤(4)所述的硫熏装置为两个并联的立式硫熏器,其中有一个硫熏器起轮洗更换作用。The sulfur fumigation device described in step (4) is two parallel vertical sulfur fumigation devices, one of which plays the role of washing and replacement in rotation.

步骤(6)所述的陶瓷膜的操作参数为:跨膜压差为0.1~0.3MPa、膜面流速为4~5m/s、过滤温度为80~90℃。The operating parameters of the ceramic membrane in step (6) are: transmembrane pressure difference of 0.1-0.3 MPa, membrane surface flow velocity of 4-5 m/s, and filtration temperature of 80-90°C.

步骤(6)所述的多级陶瓷膜超滤系统为五级并联的陶瓷超滤膜,每级陶瓷膜由两个膜组件组成,其中有一级起轮洗更换作用。The multi-stage ceramic membrane ultrafiltration system described in step (6) is a five-stage ceramic ultrafiltration membrane connected in parallel, and each stage of ceramic membrane is composed of two membrane modules, one of which plays a role of washing and replacement in rotation.

步骤(8)所述的板框压滤机需要硅藻土助滤。The plate and frame filter press described in step (8) needs diatomite filter aid.

实施例3加工出的白砂糖各理化指标如下表所示:The physical and chemical indexes of the white granulated sugar processed in embodiment 3 are shown in the following table:

*中华人民共和国国家标准GB317-2006。 * The National Standard of the People's Republic of China GB317-2006.

Claims (6)

1.一种制糖澄清生产线,其特征在于,包括依次连接的混合汁箱、卧螺式离心机、第一加热装置、硫熏装置、第二加热装置、多级陶瓷膜超滤系统以及板框压滤机;1. A clarification production line for sugar refining, characterized in that it comprises a mixed juice box, a horizontal screw centrifuge, a first heating device, a sulfur fumigation device, a second heating device, a multistage ceramic membrane ultrafiltration system and a plate frame filter press; 所述卧螺式离心机与第一加热装置之间连接有第一缓冲箱,硫熏装置与第二加热装置之间连接有第二缓冲箱,第二加热装置与多级陶瓷膜超滤系统之间连接有第三缓冲箱;A first buffer tank is connected between the decanter centrifuge and the first heating device, a second buffer tank is connected between the sulfur fumigation device and the second heating device, and the second heating device and the multi-stage ceramic membrane ultrafiltration system A third buffer box is connected between them; 混合汁箱进口与甘蔗糖厂压榨提汁工段和石灰乳罐连接,混合汁箱出口与卧螺式离心机进口连接,卧螺式离心机出口与第一缓冲箱进口连接,第一缓冲箱出口与第一加热装置入口连接,第一加热装置出口与硫熏装置糖汁入口连接,硫熏装置糖汁出口与第二缓冲箱入口连接,第二缓冲箱出口与第二加热装置入口连接,第二加热装置出口与第三缓冲箱入口连接,第三缓冲箱出口与多级陶瓷膜超滤系统入口连接,多级陶瓷膜超滤系统透过液出口与甘蔗澄清汁储箱入口连接,甘蔗澄清汁储箱出口与蒸发浓缩、煮糖结晶工段连接,多级陶瓷膜超滤系统浓缩液出口与板框压滤机入口连接,板框压滤机滤液出口连接至第一缓冲箱入口。The inlet of the mixed juice box is connected with the squeezing and extracting section of the sugarcane sugar factory and the lime milk tank, the outlet of the mixed juice box is connected with the inlet of the decanter centrifuge, the outlet of the decanter centrifuge is connected with the inlet of the first buffer tank, and the outlet of the first buffer tank It is connected with the inlet of the first heating device, the outlet of the first heating device is connected with the sugar juice inlet of the sulfur fumigation device, the sugar juice outlet of the sulfur fumigation device is connected with the inlet of the second buffer tank, the outlet of the second buffer tank is connected with the inlet of the second heating device, and the The outlet of the second heating device is connected to the inlet of the third buffer tank, the outlet of the third buffer tank is connected to the inlet of the multi-stage ceramic membrane ultrafiltration system, the permeate outlet of the multi-stage ceramic membrane ultrafiltration system is connected to the inlet of the sugarcane clarified juice storage tank, and the sugarcane clarification The outlet of the juice storage tank is connected to the evaporative concentration and sugar boiling crystallization section, the concentrated solution outlet of the multi-stage ceramic membrane ultrafiltration system is connected to the inlet of the plate and frame filter press, and the filtrate outlet of the plate and frame filter press is connected to the inlet of the first buffer tank. 2.如权利要求1所述制糖澄清生产线,其特征在于,所述第一加热装置包括串联的第一列管式换热器、第二列管式换热器以及第三列管式换热器,其中有一个加热器起轮洗更换作用。2. The sugar clarification production line according to claim 1, wherein the first heating device comprises a first tubular heat exchanger, a second tubular heat exchanger and a third tubular heat exchanger connected in series. Heaters, one of which plays the role of washing and replacing. 3.如权利要求1所述制糖澄清生产线,其特征在于,所述第二加热装置包括串联的第四列管式换热器、第五列管式换热器以及第六列管式换热器,其中有一个加热器起轮洗更换作用。3. The sugar clarification production line according to claim 1, wherein the second heating device comprises a fourth tubular heat exchanger, a fifth tubular heat exchanger and a sixth tubular heat exchanger connected in series. Heaters, one of which plays the role of washing and replacing. 4.如权利要求1所述制糖澄清生产线,其特征在于,所述硫熏装置包括并联的第一立式硫熏器和第二立式硫熏器,其中有一个硫熏器起轮洗更换作用。4. The clarification production line of sugar refining as claimed in claim 1, wherein said sulfur fumigation device comprises a first vertical sulfur fumigation device and a second vertical sulfur fumigation device connected in parallel, wherein one sulfur fumigation device plays a round wash Replacement role. 5.如权利要求1所述制糖澄清生产线,其特征在于,所述硫熏装置的硫气入口与二氧化硫供气源连接。5. The sugar clarification production line according to claim 1, wherein the sulfur gas inlet of the sulfur fumigation device is connected to a sulfur dioxide gas supply source. 6.如权利要求1所述制糖澄清生产线,其特征在于,所述多级陶瓷膜超滤系统为五级并联的陶瓷超滤膜,每级陶瓷膜由两个膜组件组成,其中有一级起轮洗更换作用。6. The clarification production line for sugar refining as claimed in claim 1, wherein the multi-stage ceramic membrane ultrafiltration system is a five-stage parallel ceramic ultrafiltration membrane, and each stage of ceramic membrane is composed of two membrane modules, of which there is a It plays the role of wheel washing replacement.
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CN105331750A (en) * 2015-10-30 2016-02-17 吴苏文 Clarifying method for sugaring mixed juice
CN105886669A (en) * 2016-04-29 2016-08-24 广西尚唐高科技有限公司 Device and process for treating membrane filtration concentrated liquor generated in membrane based sugar production
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CN107937628A (en) * 2017-05-23 2018-04-20 中国科学院过程工程研究所 The cane sugar manufacture system and its processing method that a kind of full constituent utilizes
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