CN104817877B - Ecological organic soybean environmental protection quick-drying offset ink - Google Patents
Ecological organic soybean environmental protection quick-drying offset ink Download PDFInfo
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- CN104817877B CN104817877B CN201510097121.7A CN201510097121A CN104817877B CN 104817877 B CN104817877 B CN 104817877B CN 201510097121 A CN201510097121 A CN 201510097121A CN 104817877 B CN104817877 B CN 104817877B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Wood Science & Technology (AREA)
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Abstract
The present invention relates to the component of a kind of ecological organic soybean environmental protection quick-drying offset ink, including following parts by weight be made 20 30 parts of plant soybean oil, it is Abietyl modified tree refer to 35 40 parts, 50 60 parts of pigment, 8 12 parts of plant linseed oil, 15 parts of white oil, 2.5 8 parts of auxiliary agent, 0.5 2 parts of di-tert-butyl methyl phenol.Ecological organic soybean environmental protection quick-drying offset ink provided by the invention can be used for printing, and relative to traditional ink, its VOC content is reduced to 5% or so by original 30%~60%.And, surface drying time (after print) after printing can reach 30 minutes or so, 6~10 minutes set time, solve the problems, such as that current soya-bean ink drying time is long, that is, the ecological organic soybean environmental protection quick-drying offset ink of the present invention, has more superior printing performance, can substitute existing traditional ink completely and promote the use of.
Description
Technical field
The present invention relates to ink material technical field, more particularly to a kind of ecological organic soybean environmental protection quick-drying offset ink.
Background technology
In traditional ink, 30%~60% petroleum mineral oil (category organic solvent, containing aromatic hydrocarbons) is typically contained.Work as print
During brush, the drying of ink needs these mineral oil that volatilize, and can discharge a large amount of organic solvents, causes serious atmosphere pollution.Entirely
Ball every year the organic volatile caused by ink (VOC, VollitileOrganicChemicals) discharge amount of pollution up to tens
Ten thousand tons.These organic volatiles, the greenhouse effects more serious than carbon dioxide can be formed, and under irradiation by sunlight can shape
Into oxide and photochemical fog, atmospheric environment is seriously polluted.For printing worker, due to being chronically in the VOC of high concentration,
Human body and nervous system are caused greatly to damage.Therefore how to reduce the content of VOC in ink turns into the weight of various countries' Environment control
In it is weight.
And the mineral oil that soya-bean ink is during traditional ink is formulated 20%~50% is replaced by the soybean of nature environmental protection
Oil, so as to reduce the VOC content in ink.According to recognizing for American soybean Association (American Soybean Association)
Calibration is accurate, if ink used in sheet-fed offset press belongs to soya-bean ink containing more than 20% soybean oil solvent.
However, soybean oil is semi-drying oil (traditional ink uses drying oil), therefore, oxygen polymerisation causes to do slowly
It is dry partially slow.That is, the drying property of soya-bean ink is poor, during sheet-fed printing, drying time is up to 12-24 hours.It is in addition, right
For ink, influence its drying property is more than vegetable oil, and the also factor such as resin, mineral oil, binder also can very great Cheng
The drying property of ink is influenceed on degree.
In soya-bean ink manufacturing enterprise now, no matter external or domestic, can also effectively it be solved without an enterprise
The certainly drying problem of soya-bean ink, this also turns into the problem that soya-bean ink can not be widelyd popularize and popularized.
- China in 2008 proposes the national strategy of industrial transformation upgrading, but because world economic situation at that time influences, no
Obtain the plan for not abandoning transition and upgrade temporarily；- new leading group in 2013 proposes the policy of transition and upgrade again, and energetically
Propulsion implement-has won initial success；And as the national transition and upgrade strategy of ink-how to respond of traditional manufacture, turn into enterprise
The task of top priority of industry.
And the research and development success of ecological organic quick-drying soybean environment-friendly ink, effectively fill up the technological gap of industry.Not only solve
Determine the transition problems of traditional manufacture raw material, also the strategy for national transition and upgrade contribute to a strength；For offset printing oil
Developing direction-transition of ink serves the effect of guidance.
The content of the invention
It is a primary object of the present invention to for above-mentioned deficiency of the prior art, there is provided a kind of ecological organic soybean ring
Protect quick-drying offset ink.
To achieve the above object, ecological organic soybean environmental protection quick-drying offset ink provided by the invention, including following weight
The component of number is made：
Preferably, the auxiliary agent includes wax liquor, manganese and cobalt, and the weight ratio of the wax liquor, manganese and cobalt is 1：0.1-0.8：
0.1-0.8。
Preferably, the composite drier is selected from indeterminate plant oil, high molecular polymerization oil, rare earth oxide, isooctyl acid, glue
Matter calcium copolymerization.
Preferably, one or more of mixing of the pigment in red, blue pigment, mineral black and yellow pigment.
Preferably, the red is lithol rubine or fuchsin, and the blue pigment is phthalocyanine blue, and the mineral black is charcoal
Black, the yellow pigment is benzidine yellow or transparent yellow.
Preferably, in addition to gel calcium carbonate 1-5 parts.
Pass through above-mentioned technical proposal, ecological organic soybean environmental protection quick-drying offset ink provided by the invention can be used for printing
Brush, relative to traditional ink, its VOC content is reduced to 5% or so by original 30%~60%.Moreover, the table after printing
Face drying time (after print) can reach 30 minutes or so, 6~10 minutes set time, when solving current soya-bean ink drying
Between it is long the problem of, that is to say, that ecological organic soybean environmental protection quick-drying offset ink of the invention, there is more superior printing
Can, it can substitute existing traditional ink completely and promote the use of.
Embodiment
The embodiment of the present invention is described in detail below.It is it should be appreciated that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to limit the invention.
Ecological organic soybean environmental protection quick-drying offset ink provided by the invention, including the component of following parts by weight are made：
Wherein, chief component of the plant soybean oil as ecological organic soybean environmental protection quick-drying offset ink, it is a kind of
Decompose resin, the effect as solvent.
Abietyl modified tree refers to the chief component as ecological organic soybean environmental protection quick-drying offset ink, has bonding agent
Effect, play the instrumentality of dispersion color and auxiliary material, there is certain mobility, ink is formed after printing uniform thin
Layer, the film layer formed with some strength after drying, and pigment is shielded, make it be difficult to come off.
Chief component of the pigment as ecological organic soybean environmental protection quick-drying offset ink, ink can be given with different face
Color and colour saturation, and make ink that there is certain viscosity and drying property.
Plant linseed oil is the important component of ecological organic soybean environmental protection quick-drying offset ink, and having, which reduces ink, glues
Degree, prevents stripping phenomenon, ink is had operation adaptive.At the same time it can also increase glossiness and improve drying property.
Important component of the white oil as ecological organic soybean environmental protection quick-drying offset ink, play regulation ink viscosity
Effect.
Important component of the auxiliary agent as ecological organic soybean environmental protection quick-drying offset ink.In the preferred case, this is helped
Agent includes wax liquor, manganese and cobalt, and the weight ratio of the wax liquor, manganese and cobalt is 1：0.1-0.8：0.1-0.8.Wherein, wax liquor can change
The rub resistance and mobility of kind ink, reduce viscosity, improve the finish of film layer, reduce paper fussed phenomenon.Manganese and cobalt are made
For drier, drying property can be improved.
Composite drier is the important component of ecological organic soybean environmental protection quick-drying offset ink.Composite drier is suitable
The additive that rubber alloy printing ink is dried, for quick-drying without skinning, it is dry by mode of printing reaction on ink printer device for it
It is dry, there is oxidation filming, trigger polymerization, catalysis to dry, improve the work(such as ink colorant power, adhesive force, resistance to emulsion, water resistance
Energy.Under preferable case, the composite drier is selected from indeterminate plant oil, high molecular polymerization oil, rare earth oxide, isooctyl acid, glue
Matter calcium copolymerization.
Important component of the di-tert-butyl methyl phenol as ecological organic soybean environmental protection quick-drying offset ink, has
Reduction and antioxidant effect, it can prevent ink from mechanically drying conjunctiva.
In the preferred case, pigment is one or more of mixed in red, blue pigment, mineral black and yellow pigment
Close.It is further preferable that the red is lithol rubine or fuchsin, the blue pigment is phthalocyanine blue, and the mineral black is charcoal
Black, the yellow pigment is benzidine yellow or transparent yellow.
In a preferred embodiment of the invention, in addition to gel calcium carbonate 1-5 parts, the gel calcium carbonate are used as a kind of
Inserts, printing ink concentration can be adjusted, moreover it is possible to increase the thickness of ink film layer, improve its wearability, meanwhile, it can reduce into
This.
It should be noted that the ecological organic soybean environmental protection quick-drying offset ink of the present invention can pass through existing various systems
Preparation Method is made.Such as：Preparation method can be：
(1) plant soybean oil, modified rosin resin are added in reactor, liquid level blanketing with inert gas, are warming up to 150-
200 degrees Celsius, open stirring；
(2) 200-250 degrees Celsius is warming up to, insulation 100-120min or so；
(3) plant linseed oil is added, stirs 30-60min；
(4) gel calcium carbonate is added, and it is 180-220 degrees Celsius to keep reactor temperature, is stirred 30 minutes；
(5) add pigment, auxiliary agent, di-tert-butyl methyl phenol in step product (4), after grinding distribution, add multiple
Close drier, white oil is finished product.
It should be noted that when gel calcium carbonate need not be added, then step (4) is omitted.
It can be used for printing according to ecological organic soybean environmental protection quick-drying offset ink provided by the invention, relative to traditional
Ink, its VOC content are reduced to 5% or so by original 30%~60%.Moreover, the surface drying time after printing (after print)
It can reach 30 minutes or so, 6~10 minutes set time, solve the problems, such as that current soya-bean ink drying time is long, also
It is to say, ecological organic soybean environmental protection quick-drying offset ink of the invention, there is more superior printing performance, can substitute completely
Existing traditional ink and promote the use of.
The present invention will be described in detail by way of examples below.Embodiment 1-6 is used for illustrating ecological organic soybean ring
Protect quick-drying offset ink.
Embodiment 1
Proportionally configure following component：
Wherein, pigment is any one in 20 parts of red, 20 parts of blue pigment, mineral black 20 and yellow pigment 20.Auxiliary agent
Including 1.0 parts of 1.0 parts of wax liquor, 1.0 parts of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Embodiment 2
Proportionally configure following component：
Wherein, pigment is any one in 18 parts of red, 18 parts of blue pigment, mineral black 18 and yellow pigment 18.Auxiliary agent
Including 0.8 part of 1.5 parts of wax liquor, 0.5 part of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Embodiment 3
Proportionally configure following component：
Wherein, pigment includes 15 parts of red, 15 parts of blue pigment, mineral black 15 and yellow pigment 10.Auxiliary agent includes wax liquor 1.0
0.8 part of part, 0.8 part of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Embodiment 4
Proportionally configure following component：
Wherein, pigment includes 16 parts of red, 16 parts of blue pigment, mineral black 15 and yellow pigment 13.Auxiliary agent includes wax liquor 0.8
0.7 part of part, 1 part of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Embodiment 5
Proportionally configure following component：
Wherein, pigment includes 17 parts of red, 16 parts of blue pigment, mineral black 18 and yellow pigment 14.Auxiliary agent includes wax liquor 0.5
0.2 part of part, 0.3 part of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Embodiment 6
Proportionally configure following component：
Wherein, pigment includes 20 parts of red, 20 parts of blue pigment, mineral black 20 and yellow pigment 15.Auxiliary agent includes wax liquor 0.8
0.5 part of part, 0.5 part of manganese and cobalt.
It is made by existing preparation method and forms ecological organic soybean environmental protection quick-drying offset ink finished product of the present invention.
Test case
Printed using ecological organic soybean environmental protection quick-drying offset ink made from embodiment 1-6, test ecological organic soybean
The performance of environmentally friendly quick-drying offset ink, referring specifically to table 1.
Table 1
By upper table can, ecological organic soybean environmental protection quick-drying offset ink VOC content provided by the invention is by original
30%~60% come is reduced to 5% or so.Moreover, the surface drying time (after print) after printing can reach 30 minutes left sides
The right side, 6~10 minutes set time, solve the problems, such as that current soya-bean ink drying time is long, that is to say, that of the invention is organic
Ecological soybean environmental protection quick-drying offset ink, there is more superior printing performance, existing traditional ink can be substituted completely and
Promote the use of.
China is a large agricultural country, and the main production country of global soybean, develops the vegetable oil using soya-bean ink as representative
Base oil ink, not only conforms with the policy of national energy industry development, while can promote domestic vegetable fat industrial expansion, expands and plants
The application of thing grease, mitigate the consumption and import of non-renewable oil, save foreign exchange.Meanwhile in recent years, environmental protection and health
The printed matter such as global problem, papers and magazines is turned into and life is closely bound up, the environmental issue of printing-ink, which necessarily enjoys, looks steadily
Mesh.Therefore, ecological organic soybean environmental protection quick-drying offset ink provided by the invention meets national environmental protection policy, opens print line
New era of industry.
And the research and development success of ecological organic soybean environmental protection quicksetting ink, not only solve the transition of traditional manufacture raw material
Problem, also the strategy for national transition and upgrade contribute to a strength；Guidance is served for developing direction-transition of offset ink
Effect.
It is essentially all that can not meet drying still it should be noted that, although occurring various soya-bean inks on the market
Time requirement, and in order to meet that drying time requires, the content of plant soybean oil is below in most of so-called soya-bean ink
The soybean oil solvent of the identification standard more than 20% of American soybean Association, therefore, its VOC content is higher, it is impossible to meets energy-saving ring
The requirement of guarantor.
The preferred embodiments of the present invention are the foregoing is only, not thereby limit its scope of the claims, it is every to utilize the present invention
The equivalent structure or equivalent flow conversion that description is made, are directly or indirectly used in other related technical areas,
Similarly it is included within the scope of the present invention.
Claims (4)
1. a kind of ecological organic soybean environmental protection quick-drying offset ink, it is characterised in that the component including following parts by weight is made：
The composite drier is selected from indeterminate plant oil, high molecular polymerization oil, rare earth oxide, isooctyl acid, colloid calcium combined polymerization
Into；
The auxiliary agent includes wax liquor, manganese and cobalt, and the weight ratio of the wax liquor, manganese and cobalt is 1：0.1-0.8：0.1-0.8.
2. ecological organic soybean environmental protection quick-drying offset ink according to claim 1, it is characterised in that the pigment is selected from
One or more of mixing in red, blue pigment, mineral black and yellow pigment.
3. ecological organic soybean environmental protection quick-drying offset ink according to claim 2, it is characterised in that the red is
Lithol rubine or fuchsin, the blue pigment are phthalocyanine blue, and the mineral black is carbon black, and the yellow pigment is for benzidine yellow or thoroughly
Bright Huang.
4. ecological organic soybean environmental protection quick-drying offset ink according to claim 1, it is characterised in that also including colloidal-carbon
Sour calcium 1-5 parts.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510097121.7A CN104817877B (en) | 2015-03-04 | 2015-03-04 | Ecological organic soybean environmental protection quick-drying offset ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510097121.7A CN104817877B (en) | 2015-03-04 | 2015-03-04 | Ecological organic soybean environmental protection quick-drying offset ink |
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| Publication Number | Publication Date |
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| CN104817877A CN104817877A (en) | 2015-08-05 |
| CN104817877B true CN104817877B (en) | 2018-01-12 |
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| CN108976898A (en) * | 2018-07-13 | 2018-12-11 | 广州市印域科技有限公司 | A kind of natural drying type offset lithography paper base oil ink and preparation method thereof |
| CN111777948A (en) * | 2020-06-29 | 2020-10-16 | 武汉湖一印务有限责任公司 | UV reverse gloss oil and preparation method of printed matter applying UV reverse gloss oil |
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| US5166258A (en) * | 1991-02-19 | 1992-11-24 | Westvaco Corporation | Modified rosin esters and their use in printing inks |
| CN103342922B (en) * | 2013-07-30 | 2015-04-22 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
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