CN104804589A - A self-illuminating advertising printing coating - Google Patents
A self-illuminating advertising printing coating Download PDFInfo
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- CN104804589A CN104804589A CN201510196444.1A CN201510196444A CN104804589A CN 104804589 A CN104804589 A CN 104804589A CN 201510196444 A CN201510196444 A CN 201510196444A CN 104804589 A CN104804589 A CN 104804589A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Paints Or Removers (AREA)
Abstract
Description
技术领域 technical field
本发明涉及涂料领域，尤其涉及一种自发光广告印刷涂料。 The invention relates to the field of coatings, in particular to a self-luminous advertisement printing coating.
背景技术 Background technique
自发光涂料是利用自发光原理，在有光亮的时候，涂层蓄光1小时既能达到光能饱和。在没有光亮的时候，自发光涂层利用蓄存的光能自行发光12小时以上，其已经广泛的应用在户外广告牌、交通设施指示牌等领域。 Self-illuminating coatings use the principle of self-illumination. When there is light, the coating can store light for 1 hour to reach light energy saturation. When there is no light, the self-luminous coating uses the stored light energy to emit light for more than 12 hours. It has been widely used in outdoor billboards, traffic facility signs and other fields.
然而，现有的广告牌表面用自发光涂料普遍存在附着力差，耐候性弱的缺点。由于广告牌长时间暴漏在阳光或者雨天，风吹日晒，雨水侵蚀，表面的涂膜很容易开裂并出现脱落，尤其在弯曲部等部分的涂膜很容易脱落，为了解决自发光涂料的这一缺点，很有必要开发出附着力强，耐候性好的自发光涂料产品。 However, the existing self-luminous coatings for the surface of billboards generally have the disadvantages of poor adhesion and weak weather resistance. Because billboards are exposed to the sun or rain for a long time, the wind and sun, and rain erosion, the coating film on the surface is easy to crack and fall off, especially at the bending part and other parts. In order to solve the problem of self-luminous coating For this shortcoming, it is very necessary to develop self-luminous coating products with strong adhesion and good weather resistance.
发明内容 Contents of the invention
本发明的目的在于克服上述现有技术存在的不足，提供一种附着力强、耐候性好和固化速度快的自发光广告印刷涂料。 The object of the present invention is to overcome the shortcomings of the above-mentioned prior art, and provide a self-luminous advertising printing coating with strong adhesion, good weather resistance and fast curing speed.
为达到上述目的，本发明是通过以下技术方案实现的： To achieve the above object, the present invention is achieved through the following technical solutions:
一种自发光广告印刷涂料，按重量份数计包括下列组分：丙烯酸树脂25~35份、聚乙烯蜡10~20份、乙酸乙酯5~15份、丙二醇甲醚醋酸酯2~8份、碳酸二甲酯1~5份、稀土发光粉3~9份、增稠剂2~7份、流平剂1~10份、润湿剂2~6份、溶剂20~30份。 A self-luminous advertising printing coating, comprising the following components in parts by weight: 25-35 parts of acrylic resin, 10-20 parts of polyethylene wax, 5-15 parts of ethyl acetate, and 2-8 parts of propylene glycol methyl ether acetate , 1~5 parts of dimethyl carbonate, 3~9 parts of rare earth luminescent powder, 2~7 parts of thickener, 1~10 parts of leveling agent, 2~6 parts of wetting agent, 20~30 parts of solvent.
优选的，所述丙烯酸树脂为氨基丙烯酸树脂、环氧丙烯酸树脂中的至少一种。 Preferably, the acrylic resin is at least one of aminoacrylic resin and epoxy acrylic resin.
优选的，所述增稠剂为甲基纤维素、羟丙基甲基纤维素、羧甲基纤维素钠、羟乙基纤维素中的至少一种。 Preferably, the thickener is at least one of methylcellulose, hydroxypropylmethylcellulose, sodium carboxymethylcellulose, and hydroxyethylcellulose.
优选的，所述流平剂为聚二甲基硅氧烷、烷基改性有机硅氧烷、聚醚聚酯改性有机硅氧烷中的至少一种。 Preferably, the leveling agent is at least one of polydimethylsiloxane, alkyl-modified organosiloxane, and polyether polyester-modified organosiloxane.
优选的，所述润湿剂为聚氧乙烯烷基酚醚、聚氧乙烯脂肪醇醚、磺酸盐、脂肪酸中的至少一种。 Preferably, the wetting agent is at least one of polyoxyethylene alkylphenol ether, polyoxyethylene fatty alcohol ether, sulfonate, and fatty acid.
优选的，所述溶剂为乙二醇、乙酸乙酯、乙酸丁酯中的至少一种。 Preferably, the solvent is at least one of ethylene glycol, ethyl acetate, and butyl acetate.
本发明的有益效果： Beneficial effects of the present invention:
本发明制备的自发光广告印刷涂料，将涂料印刷到广告牌的表面，再经加热熔融后，使涂料与广告牌形成紧密结合。本发明具有固化速度快、光泽度好、耐候性好和使用寿命长等优点，适用于户外自发光广告牌等印刷领域。 In the self-illuminating advertisement printing paint prepared by the invention, the paint is printed on the surface of the billboard, and after being heated and melted, the paint and the billboard form a close combination. The invention has the advantages of fast curing speed, good gloss, good weather resistance and long service life, and is suitable for printing fields such as outdoor self-luminous billboards.
具体实施方式 Detailed ways
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进。这些都属于本发明的保护范围。 The present invention will be described in detail below in conjunction with specific embodiments. The following examples will help those skilled in the art to further understand the present invention, but do not limit the present invention in any form. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention. These all belong to the protection scope of the present invention.
一种自发光广告印刷涂料，按重量份数计包括下列组分：丙烯酸树脂25~35份、聚乙烯蜡10~20份、乙酸乙酯5~15份、丙二醇甲醚醋酸酯2~8份、碳酸二甲酯1~5份、稀土发光粉3~9份、增稠剂2~7份、流平剂1~10份、润湿剂2~6份、溶剂20~30份。 A self-luminous advertising printing coating, comprising the following components in parts by weight: 25-35 parts of acrylic resin, 10-20 parts of polyethylene wax, 5-15 parts of ethyl acetate, and 2-8 parts of propylene glycol methyl ether acetate , 1~5 parts of dimethyl carbonate, 3~9 parts of rare earth luminescent powder, 2~7 parts of thickener, 1~10 parts of leveling agent, 2~6 parts of wetting agent, 20~30 parts of solvent.
本发明制备的自发光广告印刷涂料，具有附着力强、耐候性好和固化速度快等优点。 The self-luminous advertisement printing paint prepared by the invention has the advantages of strong adhesion, good weather resistance, fast curing speed and the like.
实施例1 Example 1
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：氨基丙烯酸树脂35份、聚乙烯蜡10份、乙酸乙酯5份、丙二醇甲醚醋酸酯8份、碳酸二甲酯5份、稀土发光粉3份、甲基纤维素7份、聚二甲基硅氧烷1份、聚氧乙烯烷基酚醚2份、乙二醇30份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 35 parts of aminoacrylic resin, 10 parts of polyethylene wax, 5 parts of ethyl acetate, 8 parts of propylene glycol methyl ether acetate, 5 parts of dimethyl carbonate 3 parts, 3 parts of rare earth luminescent powder, 7 parts of methyl cellulose, 1 part of polydimethylsiloxane, 2 parts of polyoxyethylene alkylphenol ether, 30 parts of ethylene glycol.
实施例2 Example 2
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：环氧丙烯酸树脂25份、聚乙烯蜡10份、乙酸乙酯15份、丙二醇甲醚醋酸酯2份、碳酸二甲酯1份、稀土发光粉9份、羟丙基甲基纤维素2份、烷基改性有机硅氧烷10份、聚氧乙烯脂肪醇醚6份、乙酸乙酯20份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 25 parts of epoxy acrylic resin, 10 parts of polyethylene wax, 15 parts of ethyl acetate, 2 parts of propylene glycol methyl ether acetate, dimethyl carbonate 1 part, 9 parts of rare earth luminous powder, 2 parts of hydroxypropyl methylcellulose, 10 parts of alkyl modified organosiloxane, 6 parts of polyoxyethylene fatty alcohol ether, 20 parts of ethyl acetate.
实施例3 Example 3
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：氨基丙烯酸树脂30份、聚乙烯蜡15份、乙酸乙酯10份、丙二醇甲醚醋酸酯5份、碳酸二甲酯3份、稀土发光粉6份、羧甲基纤维素钠4份、聚醚聚酯改性有机硅氧烷5份、磺酸盐4份、乙酸丁酯25份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 30 parts of aminoacrylic resin, 15 parts of polyethylene wax, 10 parts of ethyl acetate, 5 parts of propylene glycol methyl ether acetate, 3 parts of dimethyl carbonate 6 parts, 6 parts of rare earth luminescent powder, 4 parts of sodium carboxymethyl cellulose, 5 parts of polyether polyester modified organosiloxane, 4 parts of sulfonate, 25 parts of butyl acetate.
实施例4 Example 4
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：环氧丙烯酸树脂33份、聚乙烯蜡18份、乙酸乙酯13份、丙二醇甲醚醋酸酯7份、碳酸二甲酯4份、稀土发光粉8份、羟乙基纤维素6份、烷基改性有机硅氧烷9份、脂肪酸5份、乙酸乙酯28份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 33 parts of epoxy acrylic resin, 18 parts of polyethylene wax, 13 parts of ethyl acetate, 7 parts of propylene glycol methyl ether acetate, dimethyl carbonate 4 parts, 8 parts of rare earth luminous powder, 6 parts of hydroxyethyl cellulose, 9 parts of alkyl modified organosiloxane, 5 parts of fatty acid, 28 parts of ethyl acetate.
实施例5 Example 5
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：氨基丙烯酸树脂22份、聚乙烯蜡11份、乙酸乙酯6份、丙二醇甲醚醋酸酯3份、碳酸二甲酯2份、稀土发光粉4份、羧甲基纤维素钠3份、聚醚聚酯改性有机硅氧烷2份、聚氧乙烯脂肪醇醚3份、乙酸丁酯21份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 22 parts of aminoacrylic resin, 11 parts of polyethylene wax, 6 parts of ethyl acetate, 3 parts of propylene glycol methyl ether acetate, 2 parts of dimethyl carbonate 4 parts, 4 parts of rare earth luminescent powder, 3 parts of sodium carboxymethyl cellulose, 2 parts of polyether polyester modified organosiloxane, 3 parts of polyoxyethylene fatty alcohol ether, 21 parts of butyl acetate.
实施例6 Example 6
本发明的自发光广告印刷涂料，按重量份数计包括下列组分：环氧丙烯酸树脂25份、聚乙烯蜡15份、乙酸乙酯7份、丙二醇甲醚醋酸酯8份、碳酸二甲酯2份、稀土发光粉4份、羟乙基纤维素5份、聚二甲基硅氧烷3份、脂肪酸5份、乙二醇23份。 The self-luminous advertising printing coating of the present invention comprises the following components in parts by weight: 25 parts of epoxy acrylic resin, 15 parts of polyethylene wax, 7 parts of ethyl acetate, 8 parts of propylene glycol methyl ether acetate, dimethyl carbonate 2 parts, 4 parts of rare earth luminescent powder, 5 parts of hydroxyethyl cellulose, 3 parts of polydimethylsiloxane, 5 parts of fatty acid, 23 parts of ethylene glycol.
性能测试 Performance Testing
本发明的主要技术性能如表1所示： Main technical performance of the present invention is as shown in table 1:
表1 Table 1
从表1可见，本发明制备的自发光广告印刷涂料，具有附着力强、耐候性好和固化速度快等优点。 It can be seen from Table 1 that the self-luminous advertising printing coating prepared by the present invention has the advantages of strong adhesion, good weather resistance and fast curing speed.
以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变形或修改，这并不影响本发明的实质内容。 Specific embodiments of the present invention have been described above. It should be understood that the present invention is not limited to the specific embodiments described above, and those skilled in the art may make various changes or modifications within the scope of the claims, which do not affect the essence of the present invention.
Claims (6)
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510196444.1A CN104804589A (en) | 2015-04-23 | 2015-04-23 | A self-illuminating advertising printing coating |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107141926A (en) * | 2017-07-05 | 2017-09-08 | 合肥思博特软件开发有限公司 | A kind of printing coatings of self-luminescence advertisement and preparation method thereof |
| CN107674527A (en) * | 2017-11-21 | 2018-02-09 | 马鞍山松鹤信息科技有限公司 | A kind of billboard printing coatings and its preparation technology |
| CN111961382A (en) * | 2020-07-23 | 2020-11-20 | 珠海市斗门联邦彩色塑料印制有限公司 | Noctilucent coating, preparation method thereof and shrink label containing noctilucent coating |
| CN113166583A (en) * | 2018-11-23 | 2021-07-23 | 巴斯夫涂料有限公司 | Self-release pigmented in-mold coatings (IMC) for coating substrates |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107141926A (en) * | 2017-07-05 | 2017-09-08 | 合肥思博特软件开发有限公司 | A kind of printing coatings of self-luminescence advertisement and preparation method thereof |
| CN107674527A (en) * | 2017-11-21 | 2018-02-09 | 马鞍山松鹤信息科技有限公司 | A kind of billboard printing coatings and its preparation technology |
| CN113166583A (en) * | 2018-11-23 | 2021-07-23 | 巴斯夫涂料有限公司 | Self-release pigmented in-mold coatings (IMC) for coating substrates |
| CN113166583B (en) * | 2018-11-23 | 2024-12-10 | 巴斯夫涂料有限公司 | Self-release pigmented in-mold coatings (IMC) for coating substrates |
| CN111961382A (en) * | 2020-07-23 | 2020-11-20 | 珠海市斗门联邦彩色塑料印制有限公司 | Noctilucent coating, preparation method thereof and shrink label containing noctilucent coating |
| CN111961382B (en) * | 2020-07-23 | 2021-12-07 | 珠海市斗门联邦彩色塑料印制有限公司 | Noctilucent coating, preparation method thereof and shrink label containing noctilucent coating |
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