CN103897460B - Luminous powder for painting iron towers - Google Patents
Luminous powder for painting iron towers Download PDFInfo
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- CN103897460B CN103897460B CN201410153504.7A CN201410153504A CN103897460B CN 103897460 B CN103897460 B CN 103897460B CN 201410153504 A CN201410153504 A CN 201410153504A CN 103897460 B CN103897460 B CN 103897460B
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 106
- 239000000843 powder Substances 0.000 title claims abstract description 82
- 229910052742 iron Inorganic materials 0.000 title abstract description 25
- 238000010422 painting Methods 0.000 title description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 62
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 52
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 42
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 42
- 239000002966 varnish Substances 0.000 claims abstract description 42
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims abstract 7
- 239000010959 steel Substances 0.000 claims abstract 7
- 230000001680 brushing effect Effects 0.000 claims abstract 6
- 239000002994 raw material Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 abstract description 7
- 230000005540 biological transmission Effects 0.000 abstract description 4
- -1 steel tower Chemical compound 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000003973 paint Substances 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Paints Or Removers (AREA)
- Luminescent Compositions (AREA)
Abstract
Description
技术领域 technical field
本发明涉及夜间发光材料，具体为一种用于涂刷铁塔的夜光粉。 The invention relates to a luminous material at night, in particular to a luminous powder for painting iron towers.
背景技术 Background technique
由于输电铁塔部分架设在城市的周边或者农村，到了夜间没有灯光，一些行人、骑自行车或者没有灯的车辆容易撞击铁塔，容易造成人员的受伤。目前有一种稀土夜光粉，这种粉涂在输电线路铁塔上之后可以在夜间起到警示作用，但是这种粉末的缺陷在于很难长期较为牢固的涂抹在铁塔上，遇到风吹日晒的就会脱落，起不到应有的警示作用；因此根据这种情况，颇切需要一种能够长期稳定的粘附在铁塔上不易脱落的夜光粉。 Since the power transmission towers are partly erected around the city or in the countryside, there are no lights at night, some pedestrians, bicycles or vehicles without lights are likely to hit the towers, which may cause injuries to people. At present, there is a kind of rare earth luminous powder, which can act as a warning at night after being applied on the transmission line tower, but the defect of this powder is that it is difficult to apply it firmly on the tower for a long time, and it will be exposed to wind and sun. It will fall off, and the due warning effect cannot be achieved; therefore, according to this situation, there is a strong need for a luminous powder that can adhere to the iron tower for a long time and is not easy to fall off.
发明内容 Contents of the invention
本发明为解决目前夜间荧光粉不能有效涂覆在输电线路铁塔上的技术问题，提供一种用于涂刷铁塔的夜光粉。 In order to solve the technical problem that the current fluorescent powder cannot be effectively coated on the iron tower of the transmission line at night, the invention provides a luminous powder for painting the iron tower.
本发明是采用以下技术方案实现的：一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为48~50%，铜粉为19~21%，锌粉5~8%，铁粉23~26%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至280℃~320℃，加热时间为20~30分钟；铜粉的细度为40～60μm，锌粉的细度为100～120μm，铁粉的细度为70～100μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 The present invention is realized by adopting the following technical solutions: a luminous powder for painting iron towers, which is made by the following steps: (a) the raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, The four raw materials of rare earth luminescent powder, copper powder, zinc powder and iron powder are calculated according to the mass percentage, the rare earth luminescent powder is 48~50%, the copper powder is 19~21%, the zinc powder is 5~8%, and the iron powder is 23~ 26%; put copper powder, zinc powder, and iron powder into the varnish and stir evenly, and the mass ratio of the quality of the varnish to the sum of the masses of copper powder, zinc powder, and iron powder is 2:1; the above metal powder will be added The varnish is heated to 280 ℃ ~ 320 ℃, and the heating time is 20 ~ 30 minutes; the fineness of copper powder is 40 ~ 60 μm, the fineness of zinc powder is 100 ~ 120 μm, and the fineness of iron powder is 70 ~ 100 μm; (b ) After heating, add rare earth luminescent powder and stir evenly; (c) Cool the above mixture to normal temperature to obtain luminous powder for painting iron towers.
本发明将铜粉、锌粉、铁粉加入清漆中并搅拌均匀，然后加热，加热的时间与温度能够确保三种金属粉末与清漆之间充分作用，加入的质量比可以使清漆与金属粉末之间有效混合，且使混合物达到一定的粘度；如此粘度的清漆混合物再与稀土发光粉混合后，可以在确保夜间发光效果的前提下牢固的粘附在铁塔的表面，且长期不会脱落；铜粉、铁粉、锌粉与稀土发光粉的加入量保证了最终产物可以与铁材质很好的粘附在一起，且不影响夜间发光效果。 In the present invention, copper powder, zinc powder and iron powder are added into the varnish and stirred evenly, and then heated. The heating time and temperature can ensure sufficient interaction between the three metal powders and the varnish, and the added mass ratio can make the varnish and metal powder It can be effectively mixed between the two parts, and the mixture can reach a certain viscosity; after mixing the varnish mixture with such viscosity with rare earth luminous powder, it can firmly adhere to the surface of the iron tower under the premise of ensuring the luminous effect at night, and it will not fall off for a long time; copper The addition of powder, iron powder, zinc powder and rare earth luminescent powder ensures that the final product can be well adhered to the iron material without affecting the luminous effect at night.
所述清漆，又名凡立水，是由树脂为主要成膜物质再加上溶剂组成的涂料。由于涂料和涂膜都是透明的，因而也称透明涂料。 The varnish, also known as varnish, is a coating composed of resin as the main film-forming substance plus a solvent. Since both the paint and the coating film are transparent, it is also called transparent paint.
所述稀土发光粉包括重量比为碳酸锶35-45%、碳酸钙3-5%、稀土氧化物9-28%和余量的氧化铝；稀土发光粉与清漆均为市场上可以购买到的产品。 The rare earth luminescent powder includes aluminum oxide with a weight ratio of 35-45% of strontium carbonate, 3-5% of calcium carbonate, 9-28% of rare earth oxide and the balance; both the rare earth luminescent powder and varnish are commercially available product.
进一步的，所述加热温度为300℃，加热时间30分钟；为所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为49%，铜粉为20%，锌粉6%，铁粉25%。 Further, the heating temperature is 300°C, and the heating time is 30 minutes; the four raw materials of the rare earth luminescent powder, copper powder, zinc powder, and iron powder are calculated according to mass percentage, and the rare earth luminescent powder is 49%, and the copper powder is 20%. %, zinc powder 6%, iron powder 25%.
采用上述组分以及温度、时间参数制备出的产品涂覆效果更好，更不易脱落。 The coating effect of the product prepared by adopting the above-mentioned components, temperature and time parameters is better, and it is less likely to fall off.
本发明通过合理的配方组合以及合适的温度及加热时间使得制备出的夜光粉能够有效涂覆在铁塔等表面为铁的材质表面，且涂覆效果良好，不易因风吹日晒等外部因素而脱落，可以长期起到警示作用。 The present invention enables the prepared luminous powder to be effectively coated on the surface of iron towers and other materials with a good coating effect and is not easy to be damaged by external factors such as wind, sun, etc. through reasonable formula combination, suitable temperature and heating time. If it falls off, it can play a warning role for a long time.
具体实施方式 detailed description
实施例1一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为48%，铜粉为21%，锌粉5%，铁粉26%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至280℃，加热时间为30分钟；铜粉的细度为60μm，锌粉的细度为100μm，铁粉的细度为80μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 1 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, and the rare earth luminous powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to mass percentage, rare earth luminescent powder is 48%, copper powder is 21%, zinc powder is 5%, iron powder is 26%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 280°C for 30 minutes; copper powder The fineness of zinc powder is 60 μm, the fineness of zinc powder is 100 μm, and the fineness of iron powder is 80 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) Cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
实施例2一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为49%，铜粉为20%，锌粉6%，铁粉25%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至290℃，加热时间为22分钟；铜粉的细度为45μm，锌粉的细度为120μm，铁粉的细度为100μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 2 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, and the rare earth luminescent powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to mass percentage, rare earth luminescent powder is 49%, copper powder is 20%, zinc powder is 6%, iron powder is 25%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of the masses of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 290°C for 22 minutes; The fineness of zinc powder is 45 μm, the fineness of zinc powder is 120 μm, and the fineness of iron powder is 100 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) Cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
实施例3一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为50%，铜粉为19%，锌粉8%，铁粉23%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至300℃，加热时间为28分钟；铜粉的细度为50μm，锌粉的细度为110μm，铁粉的细度为70μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 3 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, the rare earth luminous powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to mass percentage, rare earth luminescent powder is 50%, copper powder is 19%, zinc powder is 8%, iron powder is 23%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of the masses of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 300°C for 28 minutes; The fineness of zinc powder is 50 μm, the fineness of zinc powder is 110 μm, and the fineness of iron powder is 70 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) Cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
实施例4一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为49%，铜粉为20%，锌粉7%，铁粉24%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至310℃，加热时间为20分钟；铜粉的细度为40μm，锌粉的细度为105μm，铁粉的细度为90μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀，（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 4 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, and the rare earth luminescent powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to the mass percentage, rare earth luminescent powder is 49%, copper powder is 20%, zinc powder is 7%, iron powder is 24%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of the masses of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 310°C for 20 minutes; The fineness of zinc powder is 40 μm, the fineness of zinc powder is 105 μm, and the fineness of iron powder is 90 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
实施例5一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为48%，铜粉为21%，锌粉5%，铁粉26%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至320℃，加热时间为24分钟；铜粉的细度为55μm，锌粉的细度为115μm，铁粉的细度为90μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀，（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 5 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminous powder, copper powder, zinc powder, iron powder and varnish, and the rare earth luminous powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to mass percentage, rare earth luminescent powder is 48%, copper powder is 21%, zinc powder is 5%, iron powder is 26%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 320°C for 24 minutes; copper powder The fineness of zinc powder is 55 μm, the fineness of zinc powder is 115 μm, and the fineness of iron powder is 90 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
实施例6一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的：（a）所用原料包括稀土发光粉、铜粉、锌粉、铁粉以及清漆，所述稀土发光粉、铜粉、锌粉、铁粉四种原料按照质量百分比计算，稀土发光粉为50%，铜粉为19%，锌粉8%，铁粉23%；先将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至280℃，加热时间为26分钟；铜粉的细度为60μm，锌粉的细度为120μm，铁粉的细度为70μm；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。 Example 6 A luminous powder for painting iron towers, which is made by the following steps: (a) The raw materials used include rare earth luminescent powder, copper powder, zinc powder, iron powder and varnish, and the rare earth luminescent powder, copper Powder, zinc powder, iron powder four raw materials are calculated according to mass percentage, rare earth luminescent powder is 50%, copper powder is 19%, zinc powder is 8%, iron powder is 23%; first put copper powder, zinc powder, iron powder into Stir evenly in the varnish, the mass ratio of the mass of the varnish to the sum of the masses of copper powder, zinc powder and iron powder is 2:1; heat the varnish added with the above metal powder to 280°C for 26 minutes; The fineness of zinc powder is 60 μm, the fineness of zinc powder is 120 μm, and the fineness of iron powder is 70 μm; (b) After heating, add rare earth luminescent powder and stir evenly; (c) Cool the above mixture to room temperature to obtain Paint the luminous powder on the iron tower.
本发明所述产品可以涂刷在铁塔3米以下的位置，该种材料是经过白天太阳光照射激发后，吸收并储存能量，到了夜间会自发光功能，产品反复吸光发光、并可无限次循环使用。 The product of the present invention can be painted on the position below 3 meters of the iron tower. This kind of material absorbs and stores energy after being excited by sunlight during the day, and has a self-luminous function at night. The product repeatedly absorbs light and emits light, and can be recycled infinitely use.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084364C (en) * | 1997-03-17 | 2002-05-08 | 姜祖斌 | Thermosetting luminescent powder coating material and production thereof |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2004024444A1 (en) * | 2002-09-12 | 2004-03-25 | Nippon Sheet Glass Company, Limited | Articles coated with luminescent film |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084364C (en) * | 1997-03-17 | 2002-05-08 | 姜祖斌 | Thermosetting luminescent powder coating material and production thereof |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
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