CN103897460A - Noctilucent powder for painting iron tower - Google Patents
Noctilucent powder for painting iron tower Download PDFInfo
- Publication number
- CN103897460A CN103897460A CN201410153504.7A CN201410153504A CN103897460A CN 103897460 A CN103897460 A CN 103897460A CN 201410153504 A CN201410153504 A CN 201410153504A CN 103897460 A CN103897460 A CN 103897460A
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- CN
- China
- Prior art keywords
- powder
- iron
- varnish
- zinc
- rare earth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000843 powder Substances 0.000 title claims abstract description 84
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 74
- 229910052742 iron Inorganic materials 0.000 title abstract description 9
- 238000010422 painting Methods 0.000 title abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 56
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229910052761 rare earth metal Inorganic materials 0.000 claims abstract description 42
- 150000002910 rare earth metals Chemical class 0.000 claims abstract description 42
- 239000002966 varnish Substances 0.000 claims abstract description 41
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 229910000831 Steel Inorganic materials 0.000 claims description 26
- 239000010959 steel Substances 0.000 claims description 26
- 230000001680 brushing effect Effects 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 230000005540 biological transmission Effects 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Luminescent Compositions (AREA)
Abstract
本发明涉及夜间发光材料，具体为一种用于涂刷铁塔的夜光粉。解决了目前夜间荧光粉不能有效涂覆在输电线路铁塔上的技术问题。一种用于涂刷铁塔的夜光粉，是采用以下步骤制成的，（a）将铜粉、锌粉、铁粉放入清漆中搅拌均匀，清漆的质量与铜粉、锌粉、铁粉三者质量之和的质量比为2:1；将加入上述金属粉末的清漆加热至280℃~320℃，加热时间为20~30分钟；（b）加热完毕后加入稀土发光粉，并搅拌均匀；（c）将上述混合物冷却到常温就得到用于涂刷铁塔的夜光粉。本发明通过合理的配方组合以及合适的温度及加热时间使得制备出的夜光粉能够有效涂覆在铁塔等表面为铁的材质表面，且涂覆效果良好，不易因风吹日晒等外部因素而脱落，可以长期起到警示作用。The invention relates to a luminous material at night, in particular to a luminous powder for painting iron towers. It solves the technical problem that the fluorescent powder at night cannot be effectively coated on the transmission line tower. A luminous powder for painting iron towers, which is made by the following steps: (a) put copper powder, zinc powder and iron powder into the varnish and stir evenly, the quality of the varnish is the same as that of copper powder, zinc powder and iron powder The mass ratio of the sum of the three masses is 2:1; heat the varnish added with the above metal powder to 280 ° C ~ 320 ° C, and the heating time is 20 ~ 30 minutes; (b) add rare earth luminescent powder after heating, and stir evenly ; (c) Cool the above mixture to normal temperature to obtain luminous powder for painting iron towers. The present invention enables the prepared luminous powder to be effectively coated on the surface of iron towers and other materials with a good coating effect and is not easy to be damaged by external factors such as wind, sun, etc. through reasonable formula combination, suitable temperature and heating time. If it falls off, it can play a warning role for a long time.
Description
Technical field
The present invention relates to noctilucence material, be specially a kind of luminescent powder for brushing steel tower.
Background technology
Because electric power pylon part is erected at periphery or the rural area in city, to night there is no light, some pedestrians, by bike or do not have the vehicle of lamp easily to clash into steel tower, easily cause that personnel's is injured.There is at present a kind of Rare-earth Long Persistence Luminescent Phosphor powder, this powder can play at night warning function after being coated on iron tower of power transmission line, but the defect of this powder is to be difficult to comparatively firmly spread upon on steel tower for a long time, runs into will coming off of exposing to the weather, and does not have due warning function; Therefore according to this situation, be quite essential and want a kind of luminescent powder that sticks to difficult drop-off on steel tower that can be steady in a long-term.
Summary of the invention
The present invention is that solution fluorescent material at current night can not effectively be coated in the technical problem on iron tower of power transmission line, and a kind of luminescent powder for brushing steel tower is provided.
The present invention realizes by the following technical solutions: a kind of luminescent powder for brushing steel tower, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 48 ~ 50%, copper powder is 19 ~ 21%, zinc powder 5 ~ 8%, iron powder 23 ~ 26%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 280 ℃ ~ 320 ℃, and be 20 ~ 30 minutes heat-up time; The fineness of copper powder is 40～60 μ m, and the fineness of zinc powder is 100～120 μ m, and the fineness of iron powder is 70～100 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
The present invention adds copper powder, zinc powder, iron powder in varnish and stirs, then heating, the time of heating and temperature can be guaranteed fully effect between three kinds of metal-powders and varnish, the mass ratio adding can make effectively to mix between varnish and metal-powder, and makes mixture reach certain viscosity; After so the varnish mixture of viscosity mixes with rare earth luminous powder again, can under the prerequisite of guaranteeing noctilucence effect, firmly stick to the surface of steel tower, and can not come off for a long time; The add-on of copper powder, iron powder, zinc powder and rare earth luminous powder has guaranteed that final product can well adhere to each other with iron material matter, and does not affect noctilucence effect.
Described varnish, has another name called polish, is to be the coating that main film forming substance is added solvent composition by resin.Because coating and film are all transparent, thereby also claim Clear paint.
Described rare earth luminous powder comprises that weight ratio is the aluminum oxide of Strontium carbonate powder 35-45%, calcium carbonate 3-5%, rare earth oxide 9-28% and surplus; Rare earth luminous powder and varnish are the product that can buy on market.
Further, described Heating temperature is 300 ℃, 30 minutes heat-up times; For described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 49%, and copper powder is 20%, zinc powder 6%, iron powder 25%.
Adopt the product that said components and temperature, time parameter are prepared to apply better effects if, more difficult drop-off.
The present invention is by rational formula combination and suitable temperature and make heat-up time the luminescent powder of preparing can effectively be coated in the material surface that the surfaces such as steel tower are iron, and apply respond well, be difficult for, because the external factor such as expose to the weather comes off, can playing for a long time warning function.
Embodiment
1 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 48%, copper powder is 21%, zinc powder 5%, iron powder 26%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 280 ℃, and be 30 minutes heat-up time; The fineness of copper powder is 60 μ m, and the fineness of zinc powder is 100 μ m, and the fineness of iron powder is 80 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
2 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 49%, copper powder is 20%, zinc powder 6%, iron powder 25%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 290 ℃, and be 22 minutes heat-up time; The fineness of copper powder is 45 μ m, and the fineness of zinc powder is 120 μ m, and the fineness of iron powder is 100 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
3 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 50%, copper powder is 19%, zinc powder 8%, iron powder 23%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 300 ℃, and be 28 minutes heat-up time; The fineness of copper powder is 50 μ m, and the fineness of zinc powder is 110 μ m, and the fineness of iron powder is 70 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
4 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 49%, copper powder is 20%, zinc powder 7%, iron powder 24%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 310 ℃, and be 20 minutes heat-up time; The fineness of copper powder is 40 μ m, and the fineness of zinc powder is 105 μ m, and the fineness of iron powder is 90 μ m; (b) after heating, add rare earth luminous powder, and stir, (c) said mixture is cooled to normal temperature just to obtain the luminescent powder for brushing steel tower.
5 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 48%, copper powder is 21%, zinc powder 5%, iron powder 26%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 320 ℃, and be 24 minutes heat-up time; The fineness of copper powder is 55 μ m, and the fineness of zinc powder is 115 μ m, and the fineness of iron powder is 90 μ m; (b) after heating, add rare earth luminous powder, and stir, (c) said mixture is cooled to normal temperature just to obtain the luminescent powder for brushing steel tower.
6 one kinds of luminescent powders for brushing steel tower of embodiment, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 50%, copper powder is 19%, zinc powder 8%, iron powder 23%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 280 ℃, and be 26 minutes heat-up time; The fineness of copper powder is 60 μ m, and the fineness of zinc powder is 120 μ m, and the fineness of iron powder is 70 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
Product of the present invention can be brushed the position below 3 meters at steel tower, and this kind of material is after daytime, solar light irradiation excited, absorb and storage power, to night can self light emission function, product repeatedly optically absorbing luminous, and can unlimitedly recycle.
Claims (2)
1. the luminescent powder for brushing steel tower, it is characterized in that, adopt following steps to make: (a) raw materials used rare earth luminous powder, copper powder, zinc powder, iron powder and the varnish of comprising, described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 48 ~ 50%, copper powder is 19 ~ 21%, zinc powder 5 ~ 8%, iron powder 23 ~ 26%; First copper powder, zinc powder, iron powder are put into varnish and stirred, the mass ratio of the quality of varnish and copper powder, zinc powder, iron powder three quality sum is 2:1; The varnish that adds above-mentioned metal-powder is heated to 280 ℃ ~ 320 ℃, and be 20 ~ 30 minutes heat-up time; The fineness of copper powder is 40～60 μ m, and the fineness of zinc powder is 100～120 μ m, and the fineness of iron powder is 70～100 μ m; (b) after heating, add rare earth luminous powder, and stir; (c) said mixture is cooled to normal temperature just obtain the luminescent powder for brushing steel tower.
2. the luminescent powder for brushing steel tower as claimed in claim 1, is characterized in that, described Heating temperature is 300 ℃, 30 minutes heat-up times; For described rare earth luminous powder, copper powder, zinc powder, four kinds of raw materials of iron powder calculate according to mass percent, rare earth luminous powder is 49%, and copper powder is 20%, zinc powder 6%, iron powder 25%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153504.7A CN103897460B (en) | 2014-04-17 | 2014-04-17 | Luminous powder for painting iron towers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410153504.7A CN103897460B (en) | 2014-04-17 | 2014-04-17 | Luminous powder for painting iron towers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103897460A true CN103897460A (en) | 2014-07-02 |
| CN103897460B CN103897460B (en) | 2016-03-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410153504.7A Active CN103897460B (en) | 2014-04-17 | 2014-04-17 | Luminous powder for painting iron towers |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349042A (en) * | 2015-11-20 | 2016-02-24 | 杨京广 | Silicon carbide coating and use method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084364C (en) * | 1997-03-17 | 2002-05-08 | 姜祖斌 | Thermosetting luminescent powder coating material and production thereof |
| US20050158526A1 (en) * | 2002-09-12 | 2005-07-21 | Nippon Sheet Glass Co., Ltd. | Luminescent-film-coated product |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
-
2014
- 2014-04-17 CN CN201410153504.7A patent/CN103897460B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1084364C (en) * | 1997-03-17 | 2002-05-08 | 姜祖斌 | Thermosetting luminescent powder coating material and production thereof |
| US20050158526A1 (en) * | 2002-09-12 | 2005-07-21 | Nippon Sheet Glass Co., Ltd. | Luminescent-film-coated product |
| CN101864228A (en) * | 2010-06-04 | 2010-10-20 | 王大鹏 | Thick-slurry type self-luminous traffic marking paint and preparation method thereof |
| CN101948658A (en) * | 2010-09-26 | 2011-01-19 | 上海朗琦土木工程技术有限公司 | Road guardrail coating with width marking and warning function and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105349042A (en) * | 2015-11-20 | 2016-02-24 | 杨京广 | Silicon carbide coating and use method thereof |
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| Publication number | Publication date |
|---|---|
| CN103897460B (en) | 2016-03-23 |
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