CN104803469A - Ozone, ultraviolet light and ultrasonic wave synergistic wastewater treatment device and working method thereof - Google Patents
Ozone, ultraviolet light and ultrasonic wave synergistic wastewater treatment device and working method thereof Download PDFInfo
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 120
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 23
- 230000002195 synergetic effect Effects 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000007788 liquid Substances 0.000 claims abstract description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 230000004087 circulation Effects 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- 239000007789 gas Substances 0.000 claims description 64
- 238000005273 aeration Methods 0.000 claims description 18
- 239000002699 waste material Substances 0.000 claims description 18
- 238000001514 detection method Methods 0.000 claims description 13
- 230000008569 process Effects 0.000 claims description 9
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 230000008859 change Effects 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 238000004064 recycling Methods 0.000 claims 5
- 239000012530 fluid Substances 0.000 claims 4
- 235000011089 carbon dioxide Nutrition 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 230000007812 deficiency Effects 0.000 claims 1
- 230000009711 regulatory function Effects 0.000 claims 1
- 238000005070 sampling Methods 0.000 abstract description 10
- 231100000331 toxic Toxicity 0.000 abstract description 8
- 230000002588 toxic effect Effects 0.000 abstract description 8
- 230000003647 oxidation Effects 0.000 abstract description 7
- 238000007254 oxidation reaction Methods 0.000 abstract description 7
- 238000005516 engineering process Methods 0.000 abstract description 6
- 239000002351 wastewater Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 4
- 238000012544 monitoring process Methods 0.000 abstract 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000002925 chemical effect Effects 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000010891 toxic waste Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/34—Treatment of water, waste water, or sewage with mechanical oscillations
- C02F1/36—Treatment of water, waste water, or sewage with mechanical oscillations ultrasonic vibrations
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/32—Details relating to UV-irradiation devices
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/78—Details relating to ozone treatment devices
- C02F2201/782—Ozone generators
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
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Abstract
本发明公开了一种臭氧、紫外光、超声波协同作用废水处理装置及其工作方法，该装置包括带有超声波振子和紫外灯的反应仓、带有超声波频率调节功能的超声波发生器和臭氧发生器的控制器、水箱和电源，所述反应器通过管道和电路连接控制器，所述超声波发生器通过电路连接超声波振子，所述水箱通过管道连接控制器，所述电源通过电路连接控制器。工作方法包括：进液、废水处理、气液循环、取样监测。优越性：将臭氧、紫外光、超声波三种氧化处理技术协同作用，将其合成在同一反应器中，该反应器中可提供不同频率的超声波和不同频率的紫外灯，所处理的有毒有害废水可循环处理直至处理至满意最佳效果。
The invention discloses an ozone, ultraviolet light and ultrasonic wave synergistic wastewater treatment device and its working method. The device includes a reaction chamber with an ultrasonic vibrator and an ultraviolet lamp, an ultrasonic generator with an ultrasonic frequency adjustment function, and an ozone generator. A controller, a water tank and a power supply, the reactor is connected to the controller through a pipeline and a circuit, the ultrasonic generator is connected to an ultrasonic vibrator through a circuit, the water tank is connected to the controller through a pipeline, and the power supply is connected to the controller through a circuit. The working methods include: liquid intake, waste water treatment, gas-liquid circulation, and sampling monitoring. Superiority: Synergize the three oxidation treatment technologies of ozone, ultraviolet light and ultrasonic wave, and synthesize them in the same reactor, which can provide ultrasonic waves of different frequencies and ultraviolet lamps of different frequencies, and the toxic and harmful wastewater treated It can be processed cyclically until the best effect is satisfied.
Description
(一)技术领域：(1) Technical field:
本发明涉及有毒有害废水的处理装置及工作方法，特别是一种臭氧、紫外光、超声波协同作用废水处理装置及工作方法。The invention relates to a treatment device and working method for toxic and harmful waste water, in particular to a waste water treatment device and working method for the synergistic effect of ozone, ultraviolet light and ultrasonic waves.
(二)背景技术：(two) background technology:
随着科学技术的发展，越来越多的有机物被用于工业生产的活动过程中，产生的废水具有毒性大，成分复杂，难降解的特点，如果这些废物不加以处理直接向外界排放，会对环境和人类健康造成很大的威胁。难降解的有毒有害废物的处理已经引起国内外的重视。臭氧是一种氧化性极强的氧化剂，具有杀菌，消毒，除色等功能，它的氧化能力强，处理速度快。紫外光具有杀菌消毒的作用。超声波是一种频率高于20000赫兹的声波，在水中传播距离远，利用超声的机械作用、空化作用、热效应和化学效应，可对液体进行灭菌、促进化学反应作用。With the development of science and technology, more and more organic matter is used in the process of industrial production, and the waste water produced has the characteristics of high toxicity, complex composition and difficult degradation. If these wastes are discharged directly to the outside without treatment, they will It poses a great threat to the environment and human health. The treatment of refractory toxic and hazardous waste has attracted attention both at home and abroad. Ozone is a highly oxidizing oxidizing agent, which has the functions of sterilization, disinfection, and color removal. It has strong oxidizing ability and fast processing speed. Ultraviolet light has the effect of sterilization and disinfection. Ultrasound is a sound wave with a frequency higher than 20,000 Hz. It travels far in water. It can sterilize liquids and promote chemical reactions by using the mechanical action, cavitation action, thermal effect and chemical effect of ultrasonic waves.
随着工业生产废液物质成分的复杂性，传统的物化加生化的二级处理工艺已经无法满足对有毒有害成分的彻底去除。而且臭氧的成本相对较高，在气液传播接触中，臭氧向液体的传播速率慢，在液体中产生气泡，恶化了臭氧在水中的传播，而一般情况下，臭氧在液体中的溶解度相对较低，影响了臭氧的氧化作用。但是通过多种氧化技术的协同作用，能够提高臭氧的利用。本专利将臭氧，超声波，紫外光协同作用，能够将废水中高浓度的有毒有害有机物氧化成二氧化碳和水，整个氧化过程更加环保高效。With the complexity of the composition of industrial waste liquid, the traditional secondary treatment process of physicochemical and biochemical has been unable to completely remove toxic and harmful components. Moreover, the cost of ozone is relatively high. In the gas-liquid transmission contact, the propagation rate of ozone to the liquid is slow, and bubbles are generated in the liquid, which deteriorates the propagation of ozone in water. In general, the solubility of ozone in liquid is relatively low. Low, affecting the oxidation of ozone. However, through the synergistic effect of multiple oxidation technologies, the utilization of ozone can be improved. This patent combines ozone, ultrasonic waves, and ultraviolet light to oxidize high-concentration toxic and harmful organic substances in wastewater into carbon dioxide and water, and the entire oxidation process is more environmentally friendly and efficient.
(三)发明内容：(3) Contents of the invention:
本发明的目的在于提供一种臭氧、紫外光、超声波协同作用废水处理装置及工作方法，将臭氧、紫外光、超声波三种氧化处理技术协同作用，将其合成在同一反应器中，该反应器中可提供不同频率的超声波和不同频率的紫外灯，所处理的有毒有害废水可循环处理直至处理至满意最佳效果。The object of the present invention is to provide a kind of ozone, ultraviolet light, ultrasonic synergistic effect wastewater treatment device and working method, three kinds of oxidation treatment technologies of ozone, ultraviolet light, ultrasonic synergistic effect, it is synthesized in the same reactor, this reactor Ultrasonic waves of different frequencies and ultraviolet lamps of different frequencies can be provided in the center, and the toxic and harmful wastewater to be treated can be recycled until the best treatment effect is satisfied.
一种臭氧、紫外光、超声波协同作用废水处理装置，其特征在于它包括带有超声波振子和可更换频率的紫外灯的反应仓、带有超声波频率调节功能的超声波发生器和臭氧发生器的控制器、水箱和电源，所述反应器通过管道和电路连接控制器，所述超声波发生器通过电路连接超声波振子，所述水箱通过管道连接控制器，所述电源通过电路连接控制器。A kind of ozone, ultraviolet light, ultrasonic wave synergy waste water treatment device, it is characterized in that it comprises the reaction chamber with ultrasonic vibrator and the ultraviolet lamp of replaceable frequency, the ultrasonic generator with ultrasonic frequency adjustment function and the control of ozone generator The reactor, the water tank and the power supply, the reactor is connected to the controller through the pipeline and the circuit, the ultrasonic generator is connected to the ultrasonic vibrator through the circuit, the water tank is connected to the controller through the pipeline, and the power supply is connected to the controller through the circuit.
上述所述臭氧、紫外光、超声波协同作用废水处理装置还包括支架，所述支架上固定反应器、控制器和水箱。The aforementioned ozone, ultraviolet light, and ultrasonic synergistic wastewater treatment device also includes a bracket on which a reactor, a controller, and a water tank are fixed.
上述所述反应器包括仓体、上法兰、气体传感器、可更换频率的紫外灯、超声波振子、臭氧进气曝气头、下法兰；所述仓体呈方柱形，仓体顶部装配上法兰，仓体底部装配下法兰；所述上法兰上有气体检测口和臭氧出气口，所述气体检测口通过气体管道连接气体传感器，所述臭氧出气口通过气体循环管道连接控制器中的气泵；所述下法兰上有液体排空口、液体循环出口和臭氧进气曝气头，所述臭氧进气曝气头通过臭氧进气管道连接控制器中的臭氧发生器，所述液体循环出口通过液体循环管道连接控制器中的水泵；所述仓体相对两侧的外壁装有超声波振子，所述紫外灯位于仓体正中，并用石英灯管罩住；所述仓体的上部有进液口，所述进液口通过液体进液管道连接控制器中的水泵；所述仓体上有至少两个取样口。The above-mentioned reactor includes a chamber body, an upper flange, a gas sensor, an ultraviolet lamp with a replaceable frequency, an ultrasonic vibrator, an ozone inlet aeration head, and a lower flange; the chamber body is square column-shaped, and the top of the chamber body is assembled The upper flange is equipped with a lower flange at the bottom of the warehouse; the upper flange has a gas detection port and an ozone gas outlet, the gas detection port is connected to a gas sensor through a gas pipeline, and the ozone gas outlet is connected to a gas circulation pipeline for control The air pump in the device; the lower flange has a liquid emptying port, a liquid circulation outlet and an ozone air intake aeration head, and the ozone air intake aeration head is connected to the ozone generator in the controller through an ozone air intake pipe, The liquid circulation outlet is connected to the water pump in the controller through a liquid circulation pipeline; ultrasonic vibrators are installed on the outer walls of the opposite sides of the warehouse body, and the ultraviolet lamp is located in the middle of the warehouse body and covered with a quartz lamp tube; the warehouse body There is a liquid inlet on the upper part, and the liquid inlet is connected to the water pump in the controller through a liquid inlet pipe; there are at least two sampling ports on the warehouse body.
上述所述控制器包括控制终端系统、臭氧发生器、超声波发生器、水泵、气泵和电流电压显示表；所述臭氧发生器通过臭氧进气管道连接反应器中的臭氧进气曝气头；所述水泵的输入端通过水箱出液管道连接水箱，水泵的输出端通过液体进液管道和液体循环管道连接反应器的仓体；所述气泵的输入端连接臭氧发生器和气体循环管道，气泵的输出端通过臭氧进气管道连接臭氧进气曝气头，所述臭氧进气管道连接控制器中的臭氧气体流量计，所述气体循环管道上有阀门；所述的电流电压显示表连接在控制器的总电路上；所述控制终端系统通过电路控制臭氧发生器、超声波发生器、水泵和气泵。The above-mentioned controller includes a control terminal system, an ozone generator, an ultrasonic generator, a water pump, an air pump, and a current and voltage display table; the ozone generator is connected to the ozone inlet aeration head in the reactor through an ozone inlet pipeline; The input end of the water pump is connected to the water tank through the liquid outlet pipeline of the water tank, and the output end of the water pump is connected to the warehouse body of the reactor through the liquid inlet pipeline and the liquid circulation pipeline; the input end of the air pump is connected to the ozone generator and the gas circulation pipeline, and the air pump The output end is connected to the ozone inlet aeration head through the ozone inlet pipeline, and the ozone gas inlet pipeline is connected to the ozone gas flowmeter in the controller, and there is a valve on the gas circulation pipeline; the current and voltage display table is connected to the controller On the total circuit of the device; the control terminal system controls the ozone generator, the ultrasonic generator, the water pump and the air pump through the circuit.
上述所述控制终端系统由基于Labview的应用程序开发。The control terminal system mentioned above is developed by the application program based on Labview.
上述所述电源由太阳能和交流电协同提供，在太阳能充足的时候全部由太阳能提供，太阳能不足的时候由太阳能和交流电协同提供。The above-mentioned power supply is provided by solar energy and alternating current. When the solar energy is sufficient, all are provided by solar energy, and when the solar energy is insufficient, the solar energy and alternating current are jointly provided.
一种臭氧、紫外光、超声波协同作用废水处理装置的工作方法，其特征在于具体步骤如下：A working method of an ozone, ultraviolet light and ultrasonic wave synergistic wastewater treatment device, characterized in that the specific steps are as follows:
(1)打开电源，将控制器中的水泵开关向左侧打开，水箱中的废液从水箱出液口依次通过水箱出液管道、水泵和液体进液管道进入反应器的仓体，待废液充满仓体后关闭水泵开关。(1) Turn on the power, turn on the water pump switch in the controller to the left, and the waste liquid in the water tank enters the reactor chamber through the liquid outlet pipe of the water tank, the water pump and the liquid inlet pipe in turn from the liquid outlet of the water tank, and waits for the waste liquid to Turn off the water pump switch after the liquid is full of the chamber body.
(2)打开臭氧发生器开关和气泵开关，关闭阀门，臭氧发生器生产臭氧，臭氧通过臭氧进气管道从臭氧进气曝气头进入反应器；(2) Open the ozone generator switch and the air pump switch, close the valve, the ozone generator produces ozone, and the ozone enters the reactor from the ozone inlet aeration head through the ozone inlet pipe;
(3)针对不同性质的废液，安装合适频率的紫外灯，打开紫外灯和超声波发生器，调节超声波发生器和臭氧气体流量计以提供不同频率的超声波和不同流量的臭氧；(3) For waste liquids of different natures, install UV lamps with appropriate frequencies, turn on the UV lamps and ultrasonic generators, and adjust the ultrasonic generators and ozone gas flowmeters to provide ultrasonic waves of different frequencies and ozone of different flows;
(4)将控制器中的水泵开关向右侧打开，仓体中的液体可依次通过液体循环液管道、水泵、液体进液管道循环进入仓体，同时打开气体循环管道上的阀门，仓体中未反应的臭氧依次经气体循环管道、臭氧发生器、臭氧进气管道循环进入仓体反应；(4) Turn on the switch of the water pump in the controller to the right, the liquid in the warehouse body can circulate into the warehouse body through the liquid circulation liquid pipeline, the water pump, and the liquid inlet pipeline in turn, and at the same time open the valve on the gas circulation pipeline, the warehouse body The unreacted ozone in the tank circulates through the gas circulation pipeline, ozone generator, and ozone intake pipeline to enter the chamber for reaction;
(5)通过取样口分别取样检测仓体不同位置废液的各项指标值或通过取样口投加摧化剂，反应过程通过气体传感器检测反应过程中气体的变化；(5) Sampling and detecting various index values of the waste liquid at different positions of the chamber through the sampling port or adding a catalyzer through the sampling port, and detecting the change of the gas during the reaction process through the gas sensor;
(6)待废液的各项指标值符合预期目标时，关闭电源，处理后的液体通过液体排空口排出，仓体内的气体通过气体检测口排出。(6) When the index values of the waste liquid meet the expected goals, turn off the power, the treated liquid is discharged through the liquid emptying port, and the gas in the chamber is discharged through the gas detection port.
上述所述步骤(1)-(6)中查看电流电压显示表显示的电流电压值，进而得到本装置工作过程的功率。Check the current and voltage values displayed by the current and voltage display table in the above-mentioned steps (1)-(6), and then obtain the power of the device in the working process.
上述所述步骤(5)中的气体包含二氧化碳、臭氧和氧气。The gas in the above-mentioned step (5) includes carbon dioxide, ozone and oxygen.
本发明的优越性：Advantages of the present invention:
(1)将臭氧、紫外光、超声波三种氧化技术集成在一个反应器中，缩小了反应器体积，提高了反应效率，降低了成本。(1) The three oxidation technologies of ozone, ultraviolet light and ultrasonic wave are integrated in one reactor, which reduces the volume of the reactor, improves the reaction efficiency and reduces the cost.
(2)通过更换灯管的形式提供不同频率的紫外灯。(2) Provide ultraviolet lamps of different frequencies by replacing the lamp tube.
(3)通过不同频率的超声波与臭氧紫外光协同作用，通过超声波的空化作用，能够促使有毒有害废水中有机物的化学键断裂，增大氧气与有毒有害废液的接触，与紫外光共同催化臭氧产生更多的羟基自由基，提高了催化反应效率。(3) Through the synergistic effect of ultrasonic waves of different frequencies and ozone ultraviolet light, the cavitation of ultrasonic waves can promote the breaking of chemical bonds in organic matter in toxic and harmful wastewater, increase the contact between oxygen and toxic and harmful waste liquid, and jointly catalyze ozone with ultraviolet light Generate more hydroxyl radicals and improve the catalytic reaction efficiency.
(4)整个反应过程中废液通过液泵能够循环进入反应仓，未反应的臭氧循环进入反应仓反应，提高了反应效率。(4) During the whole reaction process, the waste liquid can be circulated into the reaction chamber through the liquid pump, and the unreacted ozone can be circulated into the reaction chamber for reaction, which improves the reaction efficiency.
(5)反应装置供电部分由太阳能转换而来，实现氧化过程的环保高效。(5) The power supply part of the reaction device is converted from solar energy to realize the environmental protection and high efficiency of the oxidation process.
(6)本反应装置的控制终端由基于Labview的应用程序控制，实现了整个操作过程的自动化。(6) The control terminal of the reaction device is controlled by the application program based on Labview, which realizes the automation of the whole operation process.
(四)附图说明：(4) Description of drawings:
图1为本发明所涉一种臭氧、紫外光、超声波协同作用废水处理装置的流程图。Fig. 1 is a flow chart of an ozone, ultraviolet light and ultrasonic synergistic wastewater treatment device involved in the present invention.
图2为本发明所涉一种臭氧、紫外光、超声波协同作用废水处理装置的结构示意图。Fig. 2 is a structural schematic diagram of an ozone, ultraviolet, and ultrasonic synergistic wastewater treatment device involved in the present invention.
其中，1为气体检测口、2为上法兰、3为支架、4为取样口、5为紫外灯、6为超声波振子、7为仓体、8为臭氧进气曝气头、9为下法兰、10为液体排空口、11为液体循环出口、12为臭氧出气口、13进液口、14为臭氧进气管道、15为液体进液管道、16为液体循环管道、17为气体循环管道、18为阀门、19为控制器、20为氧气进气口、21为水箱出液管道、22为水箱、23为水箱出液口、24为臭氧气体流量计、25为气泵开关、26为水泵开关、27为臭氧发生器开关、28为电流电压显示表、29为气体传感器。Among them, 1 is the gas detection port, 2 is the upper flange, 3 is the bracket, 4 is the sampling port, 5 is the ultraviolet lamp, 6 is the ultrasonic vibrator, 7 is the chamber body, 8 is the ozone air inlet aeration head, 9 is the bottom Flange, 10 is the liquid emptying port, 11 is the liquid circulation outlet, 12 is the ozone gas outlet, 13 is the liquid inlet, 14 is the ozone inlet pipe, 15 is the liquid inlet pipe, 16 is the liquid circulation pipe, 17 is the gas Circulation pipeline, 18 is a valve, 19 is a controller, 20 is an oxygen inlet, 21 is a water tank outlet pipe, 22 is a water tank, 23 is a water tank outlet, 24 is an ozone gas flow meter, 25 is an air pump switch, 26 It is a water pump switch, 27 is an ozone generator switch, 28 is a current and voltage display table, and 29 is a gas sensor.
(五)具体实施方式：(5) Specific implementation methods:
实施例：一种臭氧、紫外光、超声波协同作用废水处理装置(见图2)，其特征在于它包括带有超声波振子和可更换频率的紫外灯5的反应仓、带有具有超声波频率调节功能的超声波发生器和臭氧发生器的控制器19、水箱22和电源，所述反应器通过管道和电路连接控制器19，所述超声波控制器通过电路连接超声波振子，所述水箱22通过管道连接控制器19，所述电源通过电路连接控制器。Embodiment: a kind of ozone, ultraviolet light, ultrasonic wave synergy waste water treatment device (see figure 2), it is characterized in that it comprises the reaction chamber that has the ultraviolet lamp 5 of ultrasonic vibrator and replaceable frequency, has ultrasonic frequency adjustment function The controller 19, water tank 22 and power supply of ultrasonic generator and ozone generator, described reactor is connected controller 19 by pipeline and circuit, described ultrasonic controller is connected ultrasonic vibrator by circuit, and described water tank 22 is connected and controlled by pipeline device 19, and the power supply is connected to the controller through a circuit.
上述所述臭氧、紫外光、超声波协同作用废水处理装置还包括支架3，所述支架3上固定反应器、控制器19和水箱22。The aforementioned ozone, ultraviolet light, and ultrasonic synergistic wastewater treatment device also includes a bracket 3 on which a reactor, a controller 19 and a water tank 22 are fixed.
上述所述反应器包括仓体7、气体传感器29、上法兰2、可更换频率的紫外灯5、超声波振子6、臭氧进气曝气头8、下法兰9；所述仓体7呈方柱形，仓体7顶部装配上法兰2，仓体7底部装配下法兰9；所述上法兰2上有气体检测口1和臭氧出气口12，所述气体检测口1通过气体管道连接气体传感器29，所述臭氧出气口12通过气体循环管道17连接控制器19中的气泵；所述下法兰9上有液体排空口10、液体循环出口11和臭氧进气曝气头8，所述臭氧进气曝气头8通过臭氧进气管道14连接控制器19中的臭氧发生器，所述液体循环出口11通过液体循环管道16连接控制器19中的水泵；所述仓体7相对两侧的外壁装有超声波振子6，所述紫外灯5位于仓体7正中，并用石英灯管罩住；所述仓体7的上部有进液口13，所述液体进液口13通过液体进液管道15连接控制器中的水泵；所述仓体7上有两个取样口4。The reactor described above includes a chamber body 7, a gas sensor 29, an upper flange 2, an ultraviolet lamp 5 with a replaceable frequency, an ultrasonic vibrator 6, an ozone air inlet aeration head 8, and a lower flange 9; Square column shape, the upper flange 2 is assembled on the top of the warehouse body 7, and the lower flange 9 is assembled on the bottom of the warehouse body 7; the upper flange 2 has a gas detection port 1 and an ozone gas outlet 12, and the gas detection port 1 passes through the gas The pipeline is connected to the gas sensor 29, and the ozone gas outlet 12 is connected to the air pump in the controller 19 through the gas circulation pipeline 17; the liquid discharge port 10, the liquid circulation outlet 11 and the ozone air intake aeration head are arranged on the lower flange 9 8. The ozone inlet aeration head 8 is connected to the ozone generator in the controller 19 through the ozone inlet pipeline 14, and the liquid circulation outlet 11 is connected to the water pump in the controller 19 through the liquid circulation pipeline 16; 7. Ultrasonic vibrators 6 are installed on the outer walls of the opposite sides. The ultraviolet lamp 5 is located in the middle of the warehouse body 7 and is covered with a quartz lamp tube; the upper part of the warehouse body 7 has a liquid inlet 13, and the liquid inlet 13 The water pump in the controller is connected through the liquid inlet pipeline 15; two sampling ports 4 are arranged on the warehouse body 7.
上述所述控制器包括控制终端系统、臭氧发生器、超声波发生器、水泵、气泵和电流电压显示表28；所述臭氧发生器通过臭氧进气管道14连接反应器中的臭氧进气曝气头8；所述水泵的输入端通过水箱出液管道21连接水箱22，水泵的输出端通过液体循环管道16和液体进液管道15连接反应器的仓体；所述气泵的输入端连接臭氧发生器和气体循环管道17，气泵的输出端通过臭氧进气管道14连接臭氧进气曝气头8，所述臭氧进气管道14连接控制器19中的臭氧气体流量计24，所述气体循环管道17上有阀门18；所述电流电压显示表28连接在控制器的总电路上；所述控制终端系统通过电路控制臭氧发生器、超声波控制器、水泵和气泵。The above-mentioned controller includes a control terminal system, an ozone generator, an ultrasonic generator, a water pump, an air pump, and a current and voltage display table 28; 8; the input end of the water pump is connected to the water tank 22 through the water tank outlet pipeline 21, and the output end of the water pump is connected to the warehouse body of the reactor through the liquid circulation pipeline 16 and the liquid inlet pipeline 15; the input end of the air pump is connected to the ozone generator And gas circulation pipeline 17, the output end of air pump connects ozone intake aeration head 8 by ozone gas inlet pipeline 14, and described ozone gas inlet pipeline 14 connects the ozone gas flowmeter 24 in the controller 19, and described gas circulation pipeline 17 There is a valve 18 on it; the current and voltage display meter 28 is connected to the total circuit of the controller; the control terminal system controls the ozone generator, ultrasonic controller, water pump and air pump through the circuit.
上述所述控制终端系统由基于Labview的应用程序开发。The control terminal system mentioned above is developed by the application program based on Labview.
上述所述电源由太阳能和交流电协同提供，在太阳能充足的时候全部由太阳能提供，太阳能不足的时候由太阳能和交流电协同提供。The above-mentioned power supply is provided by solar energy and alternating current. When the solar energy is sufficient, all are provided by solar energy, and when the solar energy is insufficient, the solar energy and alternating current are jointly provided.
一种臭氧、紫外光、超声波协同作用废水处理装置的工作方法(见图1)，其特征在于具体步骤如下：A kind of working method (see Fig. 1) of ozone, ultraviolet light, ultrasonic synergy wastewater treatment device, it is characterized in that concrete steps are as follows:
(1)打开电源，将控制器19中的水泵开关26向左侧打开，水箱22中的废液从水箱出液口23依次通过水箱出液管道21、水泵和液体进液管道15进入反应器的仓体7，待废液充满仓体7后关闭水泵开关26。(1) Turn on the power supply, turn on the water pump switch 26 in the controller 19 to the left, and the waste liquid in the water tank 22 enters the reactor through the water tank liquid outlet pipe 21, the water pump and the liquid inlet pipe 15 successively from the water tank liquid outlet 23 The bin body 7, close the water pump switch 26 after the waste liquid is full of the bin body 7.
(2)打开臭氧发生器开关27和气泵开关25，关闭阀门18，臭氧发生器生产臭氧，臭氧通过臭氧进气管道14从臭氧进气曝气头8进入反应器；(2) open the ozone generator switch 27 and the air pump switch 25, close the valve 18, the ozone generator produces ozone, and the ozone enters the reactor from the ozone inlet aeration head 8 through the ozone inlet pipeline 14;
(3)针对不同性质的废液，安装合适频率的紫外灯5，打开紫外灯5和超声波发生器，调节超声波发生器和臭氧气体流量计24以提供不同频率的超声波和不同流量的臭氧；(3) For waste liquids of different properties, install the ultraviolet lamp 5 of suitable frequency, turn on the ultraviolet lamp 5 and the ultrasonic generator, adjust the ultrasonic generator and the ozone gas flow meter 24 to provide the ultrasonic waves of different frequencies and the ozone of different flows;
(4)将控制器19中的水泵开关26向右侧打开，仓体7中的液体可依次通过液体循环液管道16、水泵、液体进液管道15循环进入仓体7，同时打开气体循环管道17上的阀门18，仓体7中未反应的臭氧依次经气体循环管道17、臭氧发生器、臭氧进气管道14循环进入仓体7反应；(4) Turn on the water pump switch 26 in the controller 19 to the right, and the liquid in the warehouse body 7 can enter the warehouse body 7 through the liquid circulation liquid pipeline 16, the water pump, and the liquid inlet pipeline 15 in turn, and open the gas circulation pipeline at the same time Valve 18 on the 17, the unreacted ozone in the storehouse body 7 enters storehouse body 7 reaction through gas circulation pipeline 17, ozone generator, ozone inlet pipeline 14 circulations successively;
(5)通过取样口4分别取样检测仓体7不同位置废液的各项指标值或通过取样口4投加摧化剂，反应过程通过气体传感器29检测反应过程中气体的变化；(5) Sampling and detecting various index values of the waste liquid in different positions of the chamber body 7 through the sampling port 4 or adding a catalyzer through the sampling port 4, and detecting the change of gas during the reaction process through the gas sensor 29;
(6)待废液的各项指标值符合预期目标时，关闭电源，处理后的液体通过液体排空口10排出，仓体7内的气体通过气体检测口1排出。(6) When the index values of the waste liquid meet the expected goals, turn off the power, the treated liquid is discharged through the liquid emptying port 10, and the gas in the chamber body 7 is discharged through the gas detection port 1.
上述所述步骤(1)-(6)中查看电流电压显示表28显示的电流电压值，进而得到本装置工作过程的功率。Check the current and voltage values shown in the current and voltage display table 28 in the above-mentioned steps (1)-(6), and then obtain the power of the device in the working process.
上述所述步骤(5)中的气体包含二氧化碳、臭氧和氧气。The gas in the above-mentioned step (5) includes carbon dioxide, ozone and oxygen.
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