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CN104788170B - Alkalescent slow-release compound fertilizer, silicon substrate alkalescent sustained release composite microbe fertilizer and preparation method thereof - Google Patents

Alkalescent slow-release compound fertilizer, silicon substrate alkalescent sustained release composite microbe fertilizer and preparation method thereof Download PDF

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CN104788170B
CN104788170B CN201510050315.1A CN201510050315A CN104788170B CN 104788170 B CN104788170 B CN 104788170B CN 201510050315 A CN201510050315 A CN 201510050315A CN 104788170 B CN104788170 B CN 104788170B
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姜明光
孙顶国
宋文东
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Abstract

本发明涉及一种弱碱性缓释复混肥、硅基弱碱性缓释复合微生物肥及其制备方法。弱碱性缓释复混肥,包括水溶性的硅酸盐20‑200重量份、聚磷酸铵50‑400重量份、有机质载体200‑700重量份,所述聚磷酸铵的PH值大于等于7。硅基弱碱性缓释复合微生物肥,在弱碱性缓释复混肥的基础上加入有益菌母料。本发明选用聚磷酸铵,自身不但含有较高含量的N和P,而且聚磷酸铵的特有聚合度和超强的络合金属阳离子的功能,使其具备突出的长效缓释性和螯合土壤中的中微量元素的能力,磷和铵的释放速度慢,因此作用持久;(硅元素可以印制重金属被植物吸收;PH值为7‑8.5,有利于土壤改良。The invention relates to a weak alkaline slow-release compound fertilizer, a silicon-based weak alkaline slow-release compound microbial fertilizer and a preparation method thereof. Weakly alkaline slow-release compound fertilizer, comprising 20-200 parts by weight of water-soluble silicate, 50-400 parts by weight of ammonium polyphosphate, and 200-700 parts by weight of organic carrier, the pH value of the ammonium polyphosphate is greater than or equal to 7 . Silicon-based weak alkaline slow-release compound microbial fertilizer is based on weak alkaline slow-release compound fertilizer with beneficial bacteria masterbatch. The present invention selects ammonium polyphosphate, which not only contains relatively high content of N and P, but also possesses outstanding long-acting slow-release and chelating properties due to its unique degree of polymerization and super-strong function of complexing metal cations. The ability of medium and trace elements in the soil, the release rate of phosphorus and ammonium is slow, so the effect is long-lasting; (silicon can print heavy metals and be absorbed by plants; PH value is 7-8.5, which is beneficial to soil improvement.

Description

弱碱性缓释复混肥、硅基弱碱性缓释复合微生物肥及其制备 方法Weak alkaline slow-release compound fertilizer, silicon-based weak alkaline slow-release compound microbial fertilizer and preparation thereof method

技术领域technical field

本发明属于化肥领域,具体涉及弱碱性缓释复混肥、硅基弱碱性缓释复合微生物肥及二者的制备方法。The invention belongs to the field of chemical fertilizers, and in particular relates to a weak alkaline slow-release compound fertilizer, a silicon-based weak alkaline slow-release compound microbial fertilizer and their preparation methods.

背景技术Background technique

硅元素是植物重要的营养元素,大部分植物体内含有硅。检测表明,生产1000公斤稻谷,水稻地上部分二氧化硅的吸收量达150公斤,超过水稻吸收氮磷钾的总和。从水稻、小麦、大麦、大豆、扁豆、茴香六种作物灰分中,营养元素硅、磷、钾、钙、镁、铁、锰的氧化物占灰分的80%左右,其中硅氧化物占14.2%-61.4%。施硅肥有利于提高作物的光合作用,作物在施用硅肥后,可使作物表皮细胞硅质化,使作物的茎叶挺直,减少遮阴,使叶片光合作用。如水稻施硅后,叶片角度缩水25.4度,冠层光合作用提高10%以上。硅肥可增强作物对病虫害的抵抗力,减少病虫危害,作物吸收硅后,在体内形成硅化细胞,使茎叶表层细胞壁加厚,角质层增加,从而提高防虫抗病能力,特别是对稻瘟病、叶斑病、茎腐病、小粘菌核病、白叶枯病及螟虫、小麦白粉病、锈病、麦蝇、棉铃虫等。硅肥可提高作物抗倒伏,由于作物的茎秆直,使抗倒伏能力提高80%左右。硅肥可使作物体内通气性增强,作物体内含硅量增加,使作物导管刚性加强,促使通气性,这对水稻苹果等喜硅作物有重要意义。不但可促进作物根系生长,还可预防根系的腐烂和早衰,特别对防治水稻的烂根病有重要作用。提高作物抗逆性,施硅肥后,产生的硅化细胞有效地调节叶片气孔的开闭,挖掘水分蒸腾作用,提高作物的抗旱、抗干热风和抗低温能力。硅能减少磷在土壤中的固定,活化土壤中的磷,并促进磷在作物体内的运转,从而提高结实率。硅肥是保健肥料,能改良土壤,矫正土壤的酸度,提高土壤盐基,促进有机肥分解,抑制土壤病菌。硅是品质元素,有改善农产品品质的作用,并有利于贮存和运输。Silicon is an important nutrient element for plants, and most plants contain silicon. Tests show that when 1,000 kg of rice is produced, the amount of silicon dioxide absorbed by the aboveground part of the rice reaches 150 kg, exceeding the sum of nitrogen, phosphorus, and potassium absorbed by the rice. From the ashes of rice, wheat, barley, soybeans, lentils, and fennel, the oxides of nutrients silicon, phosphorus, potassium, calcium, magnesium, iron, and manganese account for about 80% of the ash, of which silicon oxides account for 14.2%. -61.4%. The application of silicon fertilizer is beneficial to improve the photosynthesis of crops. After applying silicon fertilizer to crops, it can make the epidermis cells of crops silicified, make the stems and leaves of crops straight, reduce shading, and make leaves photosynthetic. For example, after applying silicon to rice, the leaf angle shrunk by 25.4 degrees, and the photosynthesis of the canopy increased by more than 10%. Silicon fertilizer can enhance the resistance of crops to diseases and insect pests and reduce the damage of diseases and insect pests. After the crops absorb silicon, they will form silicified cells in the body, thicken the cell walls on the surface of stems and leaves, and increase the cuticle, thereby improving the ability of insect resistance and disease resistance, especially for rice. Plague, leaf spot, stem rot, sclerotinia, bacterial blight and stem borer, wheat powdery mildew, rust, wheat fly, cotton bollworm, etc. Silicon fertilizer can improve the lodging resistance of crops. Because the stalks of crops are straight, the lodging resistance ability is increased by about 80%. Silicon fertilizer can enhance the air permeability of crops, increase the silicon content in crops, strengthen the rigidity of crop ducts, and promote air permeability, which is of great significance to silicon-loving crops such as rice and apples. It can not only promote the growth of crop roots, but also prevent root rot and premature aging, especially for the prevention and treatment of rice root rot. Improve the stress resistance of crops. After applying silicon fertilizer, the silicified cells produced can effectively regulate the opening and closing of leaf stomata, excavate water transpiration, and improve the ability of crops to resist drought, dry hot wind and low temperature. Silicon can reduce the fixation of phosphorus in the soil, activate phosphorus in the soil, and promote the operation of phosphorus in crops, thereby increasing the seed setting rate. Silicon fertilizer is a health-care fertilizer that can improve soil, correct soil acidity, increase soil base, promote organic fertilizer decomposition, and inhibit soil bacteria. Silicon is a quality element, which can improve the quality of agricultural products and is beneficial to storage and transportation.

土壤酸化是制约我国农业可持续发展的主要问题之一,我国土壤酸化问题十分严重,各类酸化土壤面积大约有2亿hm2。近年来,随着工业发展,酸雨的不断增加、化肥的大量使用、农作物连续收获移走土壤中碱性物质等,导致土壤酸化进一步加剧。土壤酸化后会导致土壤中Ca、Mg、P等营养元素大量淋失;且土壤中重金属活性会大大增加,酸性土壤重金属毒害是抑制作物生长和导致作物减产的主要因素。Soil acidification is one of the main problems restricting the sustainable development of agriculture in China. The problem of soil acidification in China is very serious. The area of various acidified soils is about 200 million hm 2 . In recent years, with the development of industry, the continuous increase of acid rain, the extensive use of chemical fertilizers, the continuous harvesting of crops to remove alkaline substances in the soil, etc., have further aggravated soil acidification. Soil acidification will lead to a large amount of leaching of nutrients such as Ca, Mg, and P in the soil; and the activity of heavy metals in the soil will greatly increase. The poisoning of heavy metals in acidic soil is the main factor that inhibits crop growth and leads to crop yield reduction.

我国土壤重金属污染问题已日趋严重,对人们的身体健康已产生很大的威胁。而农作物其体内累积的重金属通过食物链进入人体后,会给人类身体健康带来潜在的危害。因此,也急需一种不会使土壤酸化的肥料,以应用于农业生产。The problem of heavy metal pollution in my country's soil has become increasingly serious, posing a great threat to people's health. The heavy metals accumulated in crops enter the human body through the food chain, which will bring potential harm to human health. Therefore, also be badly in need of a kind of fertilizer that can not make soil acidification, to be applied to agricultural production.

发明内容Contents of the invention

本发明为了解决现有肥料有效硅含量低,硅的吸收利用率低的技术问题,提供一种弱碱性缓释复混肥、硅基弱碱性缓释复合微生物肥并提供所述两种肥料的制备方法。In order to solve the technical problems of low effective silicon content and low silicon absorption and utilization rate in existing fertilizers, the present invention provides a weakly alkaline slow-release compound fertilizer, a silicon-based weakly alkaline slow-release compound microbial fertilizer and provides the two Fertilizer preparation method.

本发明的技术解决方案是:Technical solution of the present invention is:

弱碱性缓释复混肥,其特殊之处在于:包括水溶性的硅酸盐20-200重量份、聚磷酸铵50-400重量份、有机质载体200-700重量份,所述聚磷酸铵的PH值大于等于7。The weak alkaline slow-release compound fertilizer is special in that it includes 20-200 parts by weight of water-soluble silicate, 50-400 parts by weight of ammonium polyphosphate, 200-700 parts by weight of organic carrier, and the ammonium polyphosphate The PH value is greater than or equal to 7.

聚磷酸铵,是金属阳离子耦合剂,增加作物对金属阳离子的吸收率,为弱碱性,本身含有一定聚合度的缓释功能,补充磷氮两种植物所需的元素。Ammonium polyphosphate is a metal cation coupling agent that increases the absorption rate of metal cations by crops. It is weakly alkaline and has a slow-release function with a certain degree of polymerization. It can supplement phosphorus and nitrogen, two elements needed by plants.

水溶性的硅酸盐中的硅含量比较高,硅的吸收利用率高,与各类重金属结合产生絮凝,抑制作物在酸性环境中对重金属的吸收,避免进入植物食品链,形成单硅酸后又有超强的渗透性,使作物更易吸收养分;起效迅速;硅酸盐中的硅素能够增产增收水稻等喜硅作物,增强作物表皮硬度和亮度。The silicon content in water-soluble silicate is relatively high, and the absorption and utilization rate of silicon is high. It combines with various heavy metals to produce flocculation, inhibits the absorption of heavy metals by crops in an acidic environment, and avoids entering the plant food chain. After forming monosilicic acid It also has super permeability, which makes it easier for crops to absorb nutrients; the effect is rapid; the silicon in the silicate can increase the production and income of silicon-loving crops such as rice, and enhance the hardness and brightness of the crop epidermis.

有机质载体的加入,不仅为土地提供大量有机质,从而有利于作物生长,而且避免硅酸钾与聚磷酸铵单独配合发生化学反应,影响聚磷酸铵聚合功能的发挥。The addition of organic matter carrier not only provides a large amount of organic matter for the land, which is beneficial to the growth of crops, but also avoids the chemical reaction of potassium silicate and ammonium polyphosphate alone, which affects the polymerization function of ammonium polyphosphate.

上述弱碱性缓释复混肥还包括含N元素的质量分数在30%以上的化合物200-400重量份,含N元素的质量分数在30%以上的化合物为尿素或者其他含氮化合物。The above-mentioned weak alkaline slow-release compound fertilizer also includes 200-400 parts by weight of a compound containing more than 30% of the N element by mass fraction, and the compound containing more than 30% of the N element by mass fraction is urea or other nitrogen-containing compounds.

上述弱碱性缓释复混肥中的有机质载体为硝化腐殖酸铵、发酵烟沫或者稻壳粉或者腐殖酸或者蘑菇渣中的至少一种。腐殖酸本身为弱碱性,硝化之后,增加腐殖酸的活性,增加N元素,与含N元素的质量分数在30%以上的化合物中的N元素结合,形成弱碱性的硝化腐殖酸铵,降低硅酸钾与聚磷酸铵化学反应的程度。发酵烟沫含有烟碱,具有驱虫作用,可以补充有机质,疏松土壤,安全不含重金属,来源广泛,可以将烟厂垃圾有效利用,自然碳化速度相比秸秆等有机质快很多,转化成有机质的周期短,有机质的作用时间长,本身含有8个NPK,NPK含量相对较丰富。The organic matter carrier in the weak alkaline slow-release compound fertilizer is at least one of nitrated ammonium humate, fermented smoke, rice husk powder, humic acid or mushroom dregs. Humic acid itself is weakly alkaline. After nitrification, the activity of humic acid is increased, N element is increased, and it combines with N element in the compound with a mass fraction of N element above 30% to form weakly alkaline nitrifying humic acid. Ammonium acid, reducing the degree of chemical reaction between potassium silicate and ammonium polyphosphate. Fermented smoke contains nicotine, which has the effect of repelling insects, can supplement organic matter, loosen the soil, is safe and does not contain heavy metals, and has a wide range of sources. It can effectively use tobacco factory waste. The natural carbonization speed is much faster than organic matter such as straw, and it can be converted into organic matter. The cycle is short, and the action time of organic matter is long. It contains 8 NPKs, and the NPK content is relatively rich.

上述弱碱性缓释复混肥中的聚磷酸铵的聚合度为1-50中的至少一种。The degree of polymerization of the ammonium polyphosphate in the weak alkaline slow-release compound fertilizer is at least one of 1-50.

上述弱碱性缓释复混肥中的聚磷酸铵的聚合度为n1和n2,n1不等于n2,1≤聚合度n1≤20,n1水溶性好,20≤聚合度n2≤50,n2水溶性稍差,但是增强肥料缓释功能。The degree of polymerization of the ammonium polyphosphate in the above-mentioned weak alkaline slow-release compound fertilizer is n1 and n2, n1 is not equal to n2, 1≤degree of polymerization n1≤20, n1 has good water solubility, 20≤degree of polymerization n2≤50, n2 is water soluble The performance is slightly worse, but it can enhance the slow-release function of fertilizers.

上述弱碱性缓释复混肥中的n1与n2的质量比为4∶(0.5-1)。两种聚合度的聚磷酸铵配合使用,一方面满足水溶性的要求,另一方面确保弱碱性缓释复混肥的缓释效果。The mass ratio of n1 and n2 in the weak alkaline slow-release compound fertilizer is 4:(0.5-1). The combined use of ammonium polyphosphate with two degrees of polymerization can meet the requirement of water solubility on the one hand, and ensure the slow-release effect of weakly alkaline slow-release compound fertilizer on the other hand.

上述弱碱性缓释复混肥中,水溶性的硅酸盐包括硅酸钾、硅酸钠、硅酸钾钠中的至少一种,优选硅酸钾,可以补充作物所需的硅元素和钾元素。硅酸钾的形态优选粉体速溶硅酸钾,其生产过程简单,溶解速度快,离子硅,能被作物有效吸收,改善作物品质,将土壤中的重金属聚合,防止重金属在酸化环境下向作物体内输送,避免进入食物链;固体硅酸钾的生产过程相对复杂,溶解速度慢。In the above-mentioned weak alkaline slow-release compound fertilizer, the water-soluble silicate includes at least one of potassium silicate, sodium silicate, and potassium-sodium silicate, preferably potassium silicate, which can supplement the silicon element and Potassium. The form of potassium silicate is preferably powder instant potassium silicate. Its production process is simple, its dissolution speed is fast, and ionic silicon can be effectively absorbed by crops, improve crop quality, aggregate heavy metals in the soil, and prevent heavy metals from being released into crops in an acidified environment. Transport in the body to avoid entering the food chain; the production process of solid potassium silicate is relatively complicated and the dissolution rate is slow.

上述弱碱性缓释复混肥还包括以下至少一种辅料,硫酸镁10-50重量份,硝酸锌5-15重量份,四水八硼酸钠5-15重量份,仲钼酸铵1-10重量份。硫酸镁和硝酸锌补充镁锌元素;四水八硼酸钠为碱性,硼元素是作物开花结果所需的元素,豆科作物对钼很敏感,可增产。The weak alkaline slow-release compound fertilizer also includes at least one of the following auxiliary materials, 10-50 parts by weight of magnesium sulfate, 5-15 parts by weight of zinc nitrate, 5-15 parts by weight of sodium octaborate tetrahydrate, 1-2 parts by weight of ammonium paramolybdate 10 parts by weight. Magnesium sulfate and zinc nitrate supplement magnesium and zinc elements; sodium octaborate tetrahydrate is alkaline, boron is an element required for crops to bloom and bear fruit, and leguminous crops are very sensitive to molybdenum, which can increase production.

一种硅基弱碱性缓释复合微生物肥,其特征在于:除了上述弱碱性缓释复混肥中的上述配方之外,还包括有益菌母料30-50重量份,有益菌母料中的有益菌数量100-200亿个/g。有益菌母料在碱性环境生存,解磷解钾,分泌抗生素、吲哚乙酸、细胞分裂素,促进植物生长。A silicon-based weakly alkaline slow-release compound microbial fertilizer is characterized in that: in addition to the above formula in the above-mentioned weakly alkaline slow-release compound fertilizer, it also includes 30-50 parts by weight of beneficial bacteria masterbatch, beneficial bacteria masterbatch The number of beneficial bacteria in it is 10-20 billion/g. The beneficial bacteria masterbatch survives in an alkaline environment, decomposes phosphorus and potassium, secretes antibiotics, indole acetic acid, and cytokinins, and promotes plant growth.

上述硅基弱碱性缓释复合微生物肥中,为保证有益菌活性,添加淀粉20-60重量份。In the silicon-based weakly alkaline slow-release compound microbial fertilizer, 20-60 parts by weight of starch is added to ensure the activity of beneficial bacteria.

一种弱碱性缓释复混肥的制备方法,其特殊之处在于:包括以下步骤:A preparation method of weakly alkaline slow-release compound fertilizer, which is special in that it comprises the following steps:

1】将水溶性的硅酸盐溶解于水中形成硅酸盐水溶液,将聚磷酸铵溶解于另一份水中,形成聚磷酸铵水溶液;1) Dissolving water-soluble silicate in water to form silicate aqueous solution, dissolving ammonium polyphosphate in another part of water to form ammonium polyphosphate aqueous solution;

2】将两份水溶液分别加入到有机质载体中,混合均匀。2] Add the two aqueous solutions to the organic carrier respectively, and mix well.

为了方便使用,进行造粒,控制含水量15-25%。For the convenience of use, it is granulated and the water content is controlled to 15-25%.

上述弱碱性缓释复混肥的制备方法的步骤1】还包括,将含N元素的质量分数在30%以上的化合物加入到硅酸盐水溶液和/或聚磷酸铵水溶液溶解;The step 1] of the preparation method of the above-mentioned weak alkaline slow-release compound fertilizer also includes adding the compound containing more than 30% of the mass fraction of N element to the silicate aqueous solution and/or the ammonium polyphosphate aqueous solution to dissolve;

上述弱碱性缓释复混肥的制备方法,当原料中还含有辅料时,还包括步骤3】:向有机质载体中添加辅料,混合均匀。The preparation method of the above-mentioned weak alkaline slow-release compound fertilizer, when the raw materials also contain auxiliary materials, also includes step 3]: add auxiliary materials to the organic carrier, and mix evenly.

一种硅基弱碱性缓释复合微生物肥的制备方法,其特殊之处在于:包括以下步骤:在弱碱性缓释复混肥的制备方法的基础上,即在步骤2】之后,有辅料时在步骤3】之后,向有机质载体中均匀喷洒有益菌母料,有淀粉时,再添加淀粉,搅拌均匀,造粒,控制水分15-25%。A method for preparing a silicon-based weakly alkaline slow-release compound microbial fertilizer, which is special in that it includes the following steps: on the basis of the preparation method of the weakly alkaline slow-release compound fertilizer, that is, after step 2], there is For auxiliary materials, after step 3], spray the beneficial bacteria masterbatch evenly into the organic carrier. If there is starch, add starch, stir evenly, granulate, and control the water content by 15-25%.

本发明的目标试验作物:水稻、苹果、蔬菜等喜硅作物。The target test crops of the present invention: rice, apples, vegetables and other silicon-loving crops.

本发明的优点是:The advantages of the present invention are:

(1)本发明的弱碱性缓释复混肥以及硅基弱碱性缓释复合微生物肥加入水溶性硅酸盐,硅素能够增产增收水稻等喜硅作物,增强作物表皮硬度和亮度,与各类重金属结合产生絮凝,抑制作物在酸性环境中对重金属的吸收,避免进入植物食品链,形成单硅酸后又有超强的渗透性,使作物更易吸收养分;起效迅速;水溶性硅酸盐中的有效硅含量比较高,易溶性好,使硅的吸收利用率高;(1) The weak alkaline slow-release compound fertilizer of the present invention and the silicon-based weak alkaline slow-release compound microbial fertilizer are added with water-soluble silicate, silicon can increase production and income of silicon-loving crops such as rice, and enhance the hardness and brightness of the crop epidermis. The combination of various heavy metals produces flocculation, which inhibits the absorption of heavy metals by crops in acidic environments and avoids entering the plant food chain. After forming monosilicic acid, it has super permeability, making it easier for crops to absorb nutrients; it works quickly; water-soluble silicon The effective silicon content in the acid salt is relatively high, and the solubility is good, so that the absorption and utilization rate of silicon is high;

(2)本发明的弱碱性缓释复混肥以及硅基弱碱性缓释复合微生物肥选用聚磷酸铵,自身不但含有较高含量的N和P,而且聚磷酸铵的特有聚合度和超强的络合金属阳离子的功能,使其具备突出的长效缓释性和螯合土壤中的中微量元素的能力,磷和铵的释放速度慢,因此作用持久;(2) ammonium polyphosphate is selected for the weak alkaline slow-release compound fertilizer of the present invention and the silicon-based weak alkaline slow-release compound microbial fertilizer, which not only contains higher content of N and P, but also has the unique degree of polymerization and the specific polymerization degree of ammonium polyphosphate. The super strong function of complexing metal cations makes it have outstanding long-term slow-release ability and the ability to chelate medium and trace elements in soil. The release speed of phosphorus and ammonium is slow, so the effect is long-lasting;

(3)本发明的硅基弱碱性缓释复合微生物肥,肥菌结合,有益菌分泌吲哚乙酸,抗生素等物质,生根壮势,抗击病毒;硅元素可以印制重金属被植物吸收;(3) The silicon-based weakly alkaline slow-release compound microbial fertilizer of the present invention combines fertilizer and bacteria, beneficial bacteria secrete indole acetic acid, antibiotics and other substances, takes root and strengthens, and fights viruses; silicon elements can print heavy metals and be absorbed by plants;

(4)本发明的弱碱性缓释复混肥以及硅基弱碱性缓释复合微生物肥呈弱碱性,PH值为7-8.5,有利于土壤改良。(4) The weakly alkaline slow-release compound fertilizer and the silicon-based weakly alkaline slow-release compound microbial fertilizer of the present invention are weakly alkaline and have a pH value of 7-8.5, which is beneficial to soil improvement.

(5)本发明的硅基弱碱性缓释复合微生物肥,发酵烟沫与食用淀粉的结合既保证了有机质的良好补充,又特别加强了有益菌的快速繁殖与活性。(5) In the silicon-based weak alkaline slow-release compound microbial fertilizer of the present invention, the combination of fermented smoke foam and edible starch not only ensures good supplementation of organic matter, but also particularly strengthens the rapid reproduction and activity of beneficial bacteria.

具体实施方式detailed description

按下表配方生产肥料:Produce fertilizer according to the formula in the table:

备注:聚磷酸铵的聚合度为20和50,重量比为4∶0.5。Note: The degree of polymerization of ammonium polyphosphate is 20 and 50, and the weight ratio is 4:0.5.

例1.1、2.1、3.1、4.1、5.1制备的是弱碱性缓释复混肥,其制备方法:Examples 1.1, 2.1, 3.1, 4.1, and 5.1 prepared weakly alkaline slow-release compound fertilizers, and their preparation methods:

1】在30℃温度下,将粉体速溶硅酸钾溶解于水中形成硅酸钾水溶液,将聚磷酸铵溶解于另一份水中,形成聚磷酸铵水溶液;1) Dissolve powdered instant potassium silicate in water to form an aqueous solution of potassium silicate at a temperature of 30°C, and dissolve ammonium polyphosphate in another portion of water to form an aqueous solution of ammonium polyphosphate;

2】将两份水溶液分别加入到有机质载体(硝化腐殖酸铵、或者发酵烟沫与硝化腐殖酸铵的混合物)中,混合均匀;2) Add two parts of the aqueous solution to the organic carrier (nitrated ammonium humate, or a mixture of fermented smoke and nitrated ammonium humate), and mix well;

3】送入造粒机进行造粒,控制含水量25%。3] Send it to a granulator for granulation, and control the water content to 25%.

制备得到的弱碱性缓释复混肥中含有氮、磷、钾、硅元素及有机质,PH值为8。The prepared weak alkaline slow-release compound fertilizer contains nitrogen, phosphorus, potassium, silicon and organic matter, and has a pH value of 8.

例1.2、2.2、3.2制备的是弱碱性缓释复混肥,其制备方法:Examples 1.2, 2.2, and 3.2 prepared weakly alkaline slow-release compound fertilizers, and their preparation methods:

1】在30℃温度下,将粉体速溶硅酸钾溶解于水中形成硅酸钾水溶液,将聚磷酸铵溶解于另一份水中,形成聚磷酸铵水溶液;将尿素加入到硅酸盐水溶液和/或聚磷酸铵水溶液溶解;1] Dissolve powdered instant potassium silicate in water to form an aqueous solution of potassium silicate at a temperature of 30°C, and dissolve ammonium polyphosphate in another part of water to form an aqueous solution of ammonium polyphosphate; add urea to the aqueous silicate solution and / or ammonium polyphosphate aqueous solution is dissolved;

2】将两份水溶液分别加入到有机质载体(硝化腐殖酸铵、或者发酵烟沫与硝化腐殖酸铵的混合物)中,混合均匀;2) Add two parts of the aqueous solution to the organic carrier (nitrated ammonium humate, or a mixture of fermented smoke and nitrated ammonium humate), and mix well;

3】送入造粒机进行造粒,控制含水量15%。3) Send it to a granulator for granulation, and control the water content to 15%.

制备得到的弱碱性缓释复混肥中含有氮、磷、钾、硅元素及有机质,PH值为7.5。The prepared weak alkaline slow-release compound fertilizer contains nitrogen, phosphorus, potassium, silicon and organic matter, and has a pH value of 7.5.

例2.3、4.2、5.2制备的是弱碱性缓释复混肥,其制备方法:Examples 2.3, 4.2, and 5.2 prepared weakly alkaline slow-release compound fertilizers, and their preparation methods:

1】在30℃温度下,将粉体速溶硅酸钾溶解于水中形成硅酸钾水溶液,将聚磷酸铵溶解于另一份水中,形成聚磷酸铵水溶液;将尿素加入到硅酸盐水溶液和/或聚磷酸铵水溶液溶解;1] Dissolve powdered instant potassium silicate in water to form an aqueous solution of potassium silicate at a temperature of 30°C, and dissolve ammonium polyphosphate in another part of water to form an aqueous solution of ammonium polyphosphate; add urea to the aqueous silicate solution and / or ammonium polyphosphate aqueous solution is dissolved;

2】将两份水溶液分别加入到有机质载体(硝化腐殖酸铵、或者发酵烟沫、或者发酵烟沫与硝化腐殖酸铵的混合物)中,混合均匀;2) Add the two aqueous solutions to the organic carrier (nitrated ammonium humate, or fermented smoke, or a mixture of fermented smoke and nitrified ammonium humate), and mix well;

3】向有机质载体中添加辅料(硫酸镁、硝酸锌、四水八硼酸钠、仲钼酸铵),混合均匀;3) Add auxiliary materials (magnesium sulfate, zinc nitrate, sodium octaborate tetrahydrate, ammonium paramolybdate) to the organic carrier, and mix well;

4】送入造粒机进行造粒,控制含水量20%。4] Send it to the granulator for granulation, and control the water content to 20%.

制备得到的弱碱性缓释复混肥中含有氮、磷、钾、硅、镁、锌、硼、钼元素及有机质,PH值为7.5。The prepared weak alkaline slow-release compound fertilizer contains nitrogen, phosphorus, potassium, silicon, magnesium, zinc, boron, molybdenum and organic matter, and has a pH value of 7.5.

例1.3、2.4、3.3、4.3、5.3制备的是硅基弱碱性缓释复合微生物肥,其制备方法是:Example 1.3, 2.4, 3.3, 4.3, 5.3 prepared silicon-based weakly alkaline slow-release compound microbial fertilizer, and its preparation method is:

1】在30℃温度下,将粉体速溶硅酸钾溶解于水中形成硅酸钾水溶液,将聚磷酸铵溶解于另一份水中,形成聚磷酸铵水溶液;将尿素加入到硅酸盐水溶液和/或聚磷酸铵水溶液溶解;1] Dissolve powdered instant potassium silicate in water to form an aqueous solution of potassium silicate at a temperature of 30°C, and dissolve ammonium polyphosphate in another part of water to form an aqueous solution of ammonium polyphosphate; add urea to the aqueous silicate solution and / or ammonium polyphosphate aqueous solution is dissolved;

2.1】每吨腐殖酸中,加入溶质质量分数为20%的稀硝酸50-100公斤的,拌匀送入硝化池进行硝化反应,生成硝化腐植酸铵,备用;2.1] For each ton of humic acid, add 50-100 kg of dilute nitric acid with a solute mass fraction of 20%, mix well and send it to the nitrification tank for nitrification reaction to generate nitrified humic acid ammonium for later use;

2.2】烟沫加水,水的重量为烟沫重量20%至30%,与枯草芽孢杆菌、地衣芽孢杆菌、黑曲霉菌等复合菌母液拌匀发酵10-30天,备用;2.2] Add water to the smoke foam, the weight of the water is 20% to 30% of the smoke foam weight, mix well with the mother liquor of complex bacteria such as Bacillus subtilis, Bacillus licheniformis, Aspergillus niger, etc., and ferment for 10-30 days, and set aside;

2.3】将两份水溶液分别加入到步骤2.1】和步骤2.2】的混合物中,混合均匀;2.3] Add two parts of aqueous solution to the mixture of step 2.1] and step 2.2] respectively, and mix well;

3】向步骤2.3】所得物料中添加辅料(硫酸镁、硝酸锌、四水八硼酸钠、仲钼酸铵),混合均匀;3) Add auxiliary materials (magnesium sulfate, zinc nitrate, sodium octaborate tetrahydrate, ammonium paramolybdate) to the material obtained in step 2.3], and mix well;

4】向步骤3】所得物料中均匀喷洒有益菌母料,再添加淀粉,搅拌均匀,造粒,造粒温度控制在80-120摄氏度,控制水分15-25%,成品料出料口温度控制在摄氏60度,冷却晾晒,计量装包。有益菌母料为枯草芽孢杆菌、胶冻样芽胞杆菌、巨大芽孢杆菌、侧孢芽孢杆菌、地衣芽孢杆菌中的至少一种。4) Spray the beneficial bacteria masterbatch evenly on the material obtained in step 3], then add starch, stir evenly, and granulate. The granulation temperature is controlled at 80-120 degrees Celsius, the water content is controlled at 15-25%, and the temperature of the finished material outlet is controlled. At 60 degrees Celsius, cool and dry, measure and pack. The beneficial bacteria masterbatch is at least one of Bacillus subtilis, Bacillus jelly-like, Bacillus megaterium, Bacillus lateral sporosum, and Bacillus licheniformis.

制备得到的弱碱性缓释复混肥中含有氮、磷、钾、硅、镁、锌、硼、钼元素以及丰富的有益菌和有机质,PH值为8。The prepared weak alkaline slow-release compound fertilizer contains nitrogen, phosphorus, potassium, silicon, magnesium, zinc, boron, molybdenum, rich beneficial bacteria and organic matter, and has a pH value of 8.

例5.3的硅基弱碱性缓释复合微生物肥效果实验Example 5.3 Effect experiment of silicon-based weak alkaline slow-release compound microbial fertilizer

1.硅基弱碱性缓释复合微生物肥提高酸性土壤pH值的作用1. The effect of silicon-based weak alkaline slow-release compound microbial fertilizer on improving the pH value of acidic soil

试验对象:山东省烟台市牟平区观水镇苹果田;土壤初始pH值3.2-5。Test object: Apple field in Guanshui Town, Muping District, Yantai City, Shandong Province; the initial pH value of the soil is 3.2-5.

试验方法:对苹果田施用例5.3制备的含硅基弱碱性缓释复合微生物肥,施用量分别为0(不施用本发明硅基弱碱性缓释复合微生物肥,继续按常规使用普通复合肥,作为空白对照)、50Kg/hm2、100Kg/hm2,施用后分别取0-60cm土壤进行pH测定,结果见表1。Test method: the silicon-based weak-alkaline slow-release compound microbial fertilizer prepared by Example 5.3 is used in the apple field, and the application rate is 0 (do not use the silicon-based weak-alkaline slow-release compound microbial fertilizer of the present invention, continue to use the common compound fertilizer as usual) Fertilizer, as a blank control), 50Kg/hm 2 , 100Kg/hm 2 , 0-60cm soil was taken for pH measurement after application, and the results are shown in Table 1.

表1土壤pH值检测Table 1 Soil pH value detection

由表1可知,随着硅基弱碱性缓释复合微生物肥施用量的增加,土壤pH值呈不断上升的趋势;并且表层土壤改良效果较好,深层土壤(60cm)也实现的土壤pH值的改良和优化。It can be seen from Table 1 that with the increase in the application rate of silicon-based weak alkaline slow-release compound microbial fertilizer, the soil pH value is on the rise; and the improvement effect of the surface soil is better, and the soil pH value of the deep soil (60cm) is also achieved. improvement and optimization.

2.硅基弱碱性缓释复合微生物肥对土壤养分的作用2. The effect of silicon-based weak alkaline slow-release compound microbial fertilizer on soil nutrients

试验田同上,采用常规施肥(CK)作为对照,在常规施肥的基础上,增施例5.3制备的含硅基弱碱性缓释复合微生物肥料100Kg/hm2进行土壤调理。The test field is the same as above, using conventional fertilization (CK) as a control, on the basis of conventional fertilization, add 100Kg/hm of the silicon - based weak alkaline slow-release compound microbial fertilizer prepared in Example 5.3 for soil conditioning.

试验结束后采取各处理小区的耕层土壤(0-20cm)进行土壤中全氮、有效磷、有效钾、有效硅、有效硼、有效锌、交换性钙、交换性镁含量的测定。土壤养分检测结果见下表2:After the test, the plow layer soil (0-20cm) of each treatment plot was taken to measure the content of total nitrogen, available phosphorus, available potassium, available silicon, available boron, available zinc, exchangeable calcium and exchangeable magnesium in the soil. The soil nutrient test results are shown in Table 2 below:

表2土壤中有效元素养分含量Table 2 The effective element nutrient content in the soil

由表2可知,在常规施肥的基础上施加本发明的硅基弱碱性缓释复合微生物肥,土壤中全氮、有效磷、有效钾、有效硅、有效硼、有效锌、交换性钙、交换性镁含量均有显著提高。As can be seen from Table 2, on the basis of conventional fertilization, the silicon-based weakly alkaline slow-release compound microbial fertilizer of the present invention is applied, and in the soil, total nitrogen, available phosphorus, available potassium, available silicon, available boron, available zinc, exchangeable calcium, The content of exchangeable magnesium was significantly increased.

3.硅基弱碱性缓释复合微生物肥对土壤调理的增产作用3. Yield-increasing effect of silicon-based weak alkaline slow-release compound microbial fertilizer on soil conditioning

3.1试验田:山东省烟台市牟平区观水镇苹果田;土壤初始pH值3.2-4.5。3.1 Test field: Apple field in Guanshui Town, Muping District, Yantai City, Shandong Province; the initial pH value of the soil is 3.2-4.5.

在同等使用有机肥底肥的情况下,对照田全年使用普通氮磷钾复合肥亩用量为250公斤,而在试验田中,普通氮磷钾复合肥全年用量减为100公斤,另外增施本发明实施例5.3制备的硅基弱碱性缓释复合微生物肥施用量200Kg/hm2,在11月份采收后,测定苹果的亩产量:施用本发明硅基弱碱性缓释复合微生物肥的农田苹果的亩产量为7750Kg/hm2,对照田苹果的亩产量为5790Kg/hm2,产量增加达33%,而且试验田果树的痘斑病,黄化病,裂纹病,花叶病和病毒性缩果病当年都没有发生,果品的色度,糖度均高于对照田两个百分点,商品价值明显提高.同时可以明显看出本产品的使用可以明显降低复合肥的使用量60%,有效减轻因过度使用普通复合肥而造成土地的残留污染。尤其是在果树的生长后期,试验田果树生命体征明显优于对照田,在10月15号和11月25号分两次对两组的叶片和地下根系进行了对比查看,试验田果树的叶片功能退化程度(如叶片黄化,落叶量)明显没有对照田多,地下根系毛根明显处于旺盛生长状态,比对照田的果树根系毛根多而且长。充分说明试验田果树后期没有脱肥现象出现,也体现了本产品的养分缓释性。In the case of the same use of organic fertilizer base fertilizer, the annual amount of ordinary nitrogen, phosphorus and potassium compound fertilizer used in the control field was 250 kg per mu, while in the test field, the annual amount of ordinary nitrogen, phosphorus and potassium compound fertilizer was reduced to 100 kg, and additionally applied The application rate of the silicon-based weak alkaline slow-release compound microbial fertilizer prepared in Example 5.3 of the invention was 200Kg/hm 2 . After harvesting in November, the yield per mu of apples was measured: The yield per mu of apples in the farmland was 7750Kg/hm 2 , and the yield per mu of apples in the control field was 5790Kg/hm 2 . Fruit shrinkage disease did not occur that year, and the color and sugar content of the fruit were two percentage points higher than those of the control field, and the commodity value was significantly increased. At the same time, it can be clearly seen that the use of this product can significantly reduce the use of compound fertilizers by 60%, effectively reducing Residual pollution of land caused by excessive use of common compound fertilizers. Especially in the late growth period of the fruit trees, the vital signs of the fruit trees in the experimental field were significantly better than those in the control field. The leaves and underground root systems of the two groups were compared twice on October 15 and November 25. The leaf function of the fruit trees in the experimental field was degraded. The degree (such as yellowing of leaves, amount of fallen leaves) is obviously not as much as that in the control field, and the hairy roots of the underground root system are obviously in a vigorous growth state, which is more and longer than that of the fruit tree root system in the control field. It fully shows that there is no defertilization phenomenon in the later stage of the fruit trees in the test field, and it also reflects the slow release of nutrients of this product.

3.2试验田:湖南省某工业城市市郊水稻田,土壤基本化学性质为:有机质17.79g/kg,阳离子交换量为3.07cmol/kg,初始pH值3.4-4.2,为严重酸性土壤。3.2 Experimental field: a paddy field in the outskirts of an industrial city in Hunan Province. The basic chemical properties of the soil are: organic matter 17.79g/kg, cation exchange capacity 3.07cmol/kg, initial pH value 3.4-4.2, which is severely acidic soil.

采用例5.3制备的酸土改良型硅基弱碱性缓释复合微生物肥100Kg/hm2,在实验地块使用与前一年相同量的复合肥和尿素追肥,施用1年两季后,经测定水稻的单季亩产量较未使用本发明硅基弱碱性缓释复合微生物肥前一年单季亩产的561公斤和579公斤分别增产192公斤和205公斤,达到753公斤和784公斤,试验田千粒重分别为30.1g和30.7g,对照田千粒重分别为25.7g和25.8g水稻种植过程中倒伏较少,稻瘟病、胡麻斑病等生理病害发生也较对之前明显减少,尤其是二季晚稻的各类生理性病害基本没有发生。同时两季稻试验田都出现稻谷梗脱青较对照田晚,稻谷成熟试验田比对照田晚5-7天的情况,说明本产品的养分缓释性对水稻的产量提升起了很大的作用。这也是本实验产品养分缓释功能的优越性的良好体现。Using 100Kg/hm 2 of acid-soil-improved silicon-based weak-alkaline slow-release compound microbial fertilizer prepared in Example 5.3, the same amount of compound fertilizer and urea topdressing as in the previous year was used in the experimental plot. Measure the single-season yield of rice compared with 561 kilograms and 579 kilograms of single-season yield per mu in the previous year without using the silicon-based weak alkaline slow-release compound microbial fertilizer of the present invention. The thousand-grain weights were 30.1g and 30.7g respectively, and the thousand-grain weights in the control fields were 25.7g and 25.8g respectively. During the rice planting process, there was less lodging, and the occurrence of physiological diseases such as rice blast and flax spot was also significantly reduced compared with the previous ones. Physiological diseases basically did not occur. At the same time, the rice stalks of the two rice test fields were degreened later than the control field, and the rice maturity test field was 5-7 days later than the control field, which shows that the slow release of nutrients of this product has played a great role in improving the yield of rice. This is also a good embodiment of the superiority of the nutrient slow release function of the experimental product.

Claims (8)

1. alkalescent slow-release compound fertilizer, it is characterised in that:Including water miscible silicate 20-200 parts by weight, APP 50- 400 parts by weight, organic matter carrier 200-700 parts by weight, the p H values of the APP are more than or equal to 7;The APP The degree of polymerization is that n1 and n2, n1 are not equal to n2,1≤polymerization degree n 1≤20,20≤polymerization degree n 2≤50.
2. alkalescent slow-release compound fertilizer according to claim 1, it is characterised in that:The alkalescent slow-release compound fertilizer is also wrapped Include compound 200-400 parts by weight of the mass fraction containing N element more than 30%, the mass fraction containing N element 30% with On compound be urea.
3. alkalescent slow-release compound fertilizer according to claim 1 or 2, it is characterised in that:The organic matter carrier is nitrification Ammonium humate, fermentation cigarette foam or powdered rice hulls or at least one of humic acid or mushroom residue.
4. alkalescent slow-release compound fertilizer according to claim 1 or 2, it is characterised in that:N1 and n2 mass ratio is 4: (0.5-1)。
5. alkalescent slow-release compound fertilizer according to claim 1 or 2, it is characterised in that:The water miscible silicate bag Include at least one of potassium silicate, sodium metasilicate, sodium potassium silicate;If necessary, in addition to following at least one auxiliary material, magnesium sulfate 10- 50 parts by weight, zinc nitrate 5-15 parts by weight, the Boratex 5-15 parts by weight of four water eight, ammonium paramolybdate 1-10 parts by weight.
6. alkalescent slow-release compound fertilizer according to claim 1 or 2, it is characterised in that:Also include beneficial bacterium masterbatch 30-50 Beneficial bacterium quantity hundred million/g of 100-200 in parts by weight, beneficial bacterium masterbatch, if necessary, in addition to starch 20-60 parts by weight.
7. the preparation method based on any described alkalescent slow-release compound fertilizer of claim 1 to 6, it is characterised in that:Including with Lower step:
1】Water miscible silicate is dissolved in the water to form aqueous silicate solution, APP is dissolved in another water, Form the APP aqueous solution;
2】Two parts of aqueous solution are added separately in organic matter carrier, are well mixed;
If necessary, step 1】Also include, it is water-soluble that compound of the mass fraction containing N element more than 30% is added into silicate Liquid and/or APP aqueous dissolution;
When also containing auxiliary material in raw material, in addition to step 3】, auxiliary material is added into organic matter carrier, is well mixed.
8. the preparation method of alkalescent slow-release compound fertilizer according to claim 7, it is characterised in that:Comprise the following steps:
In step 2】Afterwards, in step 3 when having an auxiliary material】Afterwards, the uniform sprinkling beneficial bacterium masterbatch into organic matter carrier, there is starch When, then starch is added, and stir, granulate, control moisture 15-25%.
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