CN104770481A - Red pine nut blending oil and preparation technology - Google Patents
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Abstract
Description
技术领域technical field
本发明涉及一种调配油及制备工艺,特别涉及一种红松籽调配油及制备工艺。The invention relates to a blended oil and a preparation process, in particular to a Korean pine nut blended oil and a preparation process.
背景技术Background technique
调配油是适应现代人对健康饮食的需求,形成的一种时尚食用油品种。油脂是人类食品三大主要成分之一,它不仅具有供给热量,组成机体细胞,溶解营养素,调节生理机能等特点,而且是一些人体不能合成,必须要靠摄取食物以维持健康的必需脂肪酸的主要来源(如亚油酸、亚麻酸等)。随着科学技术的进步,人们生活水平的提高,饮食营养逐步引起人们重视,目前在提倡要多食用植物油外,还要求人们改变长期只食用一种油脂的习惯,把两种以上油脂混合起来取长补短调和食用,从而获得一种脂肪酸组成较平衡,营养价值更高的油脂。Blended oil is a fashionable edible oil variety formed to meet the needs of modern people for a healthy diet. Fat is one of the three main components of human food. It not only has the characteristics of supplying heat, forming body cells, dissolving nutrients, and regulating physiological functions, but also is the main source of essential fatty acids that cannot be synthesized by the human body and must be ingested to maintain health. Sources (such as linoleic acid, linolenic acid, etc.). With the advancement of science and technology and the improvement of people's living standards, dietary nutrition has gradually attracted people's attention. At present, in addition to advocating the consumption of more vegetable oil, people are also required to change the long-term habit of only eating one kind of oil, and mix more than two kinds of oil to learn from each other. Reconcile and eat, so as to obtain a kind of oil with more balanced fatty acid composition and higher nutritional value.
20世纪90年代以来,国内外油脂营养学者对各种脂肪酸在人体内的生理代谢进行了大量的研究,西方发达国家、联合国粮农组织和世界卫生组织对人体摄入各种脂肪酸的比例都提出了相应的标准。虽说,日常人们饮食中的蔬菜、蛋奶等食品中也含有少量的脂肪酸,但相对人体摄入各种脂肪酸的总量来说比例还很低。我国绝大多数居民动物性食物的消费是以猪牛羊肉为主,占人体脂肪摄取总量的30%左右。动物脂肪含有较多的饱和脂肪酸,居民日摄入量差异较大,摄入量的控制和均衡摄入等都是较难解决的。因此,研制和开发适合人体代谢需求的脂肪酸配比合理的调和油,关键是在占人体脂肪摄取总量70%左右的植物油调配中,解决不饱和脂肪酸(UFA)中的单不饱和脂肪酸(MUFA)与多不饱和脂肪酸(PUFA)的比例为l:1和PUFA中ω-6脂肪酸与ω-3脂肪酸的比例为4-6:1的问题。研究满足中国营养学会提出的脂肪酸配比标准、适合人体代谢需求配比合理的新型调和油,具有非常重要的意义。Since the 1990s, scholars at home and abroad have done a lot of research on the physiological metabolism of various fatty acids in the human body. Western developed countries, the Food and Agriculture Organization of the United Nations and the World Health Organization have all proposed the proportion of various fatty acids in the human body. corresponding standard. Although vegetables, eggs, milk and other foods in people's daily diet also contain a small amount of fatty acids, the proportion is still very low compared to the total amount of various fatty acids ingested by the human body. The consumption of animal food by the vast majority of residents in my country is mainly pork, beef and mutton, accounting for about 30% of the total body fat intake. Animal fat contains more saturated fatty acids, and the daily intake of residents varies greatly, so it is difficult to control and balance the intake. Therefore, to develop and develop a blended oil with a reasonable ratio of fatty acids suitable for human metabolism, the key is to solve the problems of monounsaturated fatty acids (MUFAs) in unsaturated fatty acids (UFAs) in the deployment of vegetable oils that account for about 70% of the total body fat intake. ) to polyunsaturated fatty acids (PUFA) in a ratio of 1:1 and PUFA in a ratio of omega-6 fatty acids to omega-3 fatty acids of 4-6:1. It is of great significance to study new blended oils that meet the fatty acid ratio standards proposed by the Chinese Nutrition Society and are suitable for human metabolism.
天然膳食中的脂肪酸分为SFA、MUFA和PUFA,由于它们具有不同的化学结构和物理性状,对健康亦产生不同的影响。不同的脂肪酸具有不同的营养功能,某一类脂肪酸摄取过量或不足,都会导致人体的代谢紊乱,引发疾病。调和油中脂肪酸合理的比例对人体生长、发育及疾病防治至关重要,尤其对于降低血浆中胆固醇和血糖含量,预防高脂血症、动脉粥样硬化、心血管疾病以及肿瘤,增强免疫力等具有重要的意义。The fatty acids in the natural diet are divided into SFA, MUFA and PUFA, and because of their different chemical structures and physical properties, they also have different effects on health. Different fatty acids have different nutritional functions. Excessive or insufficient intake of a certain type of fatty acid will lead to metabolic disorders in the human body and cause diseases. A reasonable proportion of fatty acids in blended oil is crucial to human growth, development and disease prevention, especially for reducing plasma cholesterol and blood sugar levels, preventing hyperlipidemia, atherosclerosis, cardiovascular diseases and tumors, and enhancing immunity, etc. is of great significance.
发明内容Contents of the invention
本发明的目的是为了解决目前单一的油脂成分单一,不能满足人们营养需求的问题而提供的一种红松籽调配油及制备工艺。The purpose of the present invention is to provide a kind of Korean pine nut blended oil and its preparation process in order to solve the problem that the current single oil has a single component and cannot meet people's nutritional needs.
本发明提供的红松籽调配油按重量份包括红松籽油10-20份,玉米油10-30份,花生油50-80份,按重量份同时添加维生素E 0.04-0.05份,特丁基对苯二酚(TBHQ)0.01-0.02份。The Korean pine nut blend oil provided by the invention comprises 10-20 parts of Korean pine nut oil, 10-30 parts of corn oil, 50-80 parts of peanut oil, 0.04-0.05 parts of vitamin E, tert-butyl Hydroquinone (TBHQ) 0.01-0.02 parts.
本发明提供的红松籽调配油的制备工艺,其具体工艺如下所述:The preparation technology of the Korean pine nut deployment oil provided by the invention, its concrete technology is as follows:
第一步、主要原料制备:按重量份取红松籽油10-20份,玉米油10-30份,花生油50-80份,原料质量要符合GB2716-2005标准要求;The first step, preparation of main raw materials: take 10-20 parts of Korean pine nut oil, 10-30 parts of corn oil, and 50-80 parts of peanut oil by weight, and the quality of raw materials will meet the requirements of GB2716-2005 standard;
第二步、调配:把第一步中的红松籽油、玉米油和花生油进行调配,调配油中按重量份的调配标准为:饱和脂肪酸(SFA)含量为10-20份,单不饱和脂肪酸(MUFA)含量为25-45份,多不饱和脂肪酸(PUFA)含量为40-55份,单不饱和脂肪酸(MUFA)与多不饱和脂肪酸(PUFA)的重量比为1:(1-1.5),ω-6多不饱和脂肪酸与ω-3多不饱和脂肪酸的重量比为(4.5-5.2):1;The second step, deployment: deploy the Korean pine nut oil, corn oil and peanut oil in the first step, the deployment standard by weight in the deployment oil is: saturated fatty acid (SFA) content is 10-20 parts, monounsaturated The fatty acid (MUFA) content is 25-45 parts, the polyunsaturated fatty acid (PUFA) content is 40-55 parts, and the weight ratio of monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA) is 1:(1-1.5 ), the weight ratio of ω-6 polyunsaturated fatty acid to ω-3 polyunsaturated fatty acid is (4.5-5.2): 1;
第三步、将第二步中配制好的调配油按重量份加入维生素E 0.04-0.05份,特丁基对苯二酚(TBHQ)0.01-0.02份,在温度为40-45℃的条件下,设定调配罐转速为100-150rpm的状态下搅拌20-30min,待搅拌均匀充分溶解后,进行包装,得到成品。In the third step, add 0.04-0.05 parts of vitamin E and 0.01-0.02 parts of tertiary butyl hydroquinone (TBHQ) to the blended oil prepared in the second step by weight, at a temperature of 40-45°C , set the speed of the blending tank at 100-150rpm and stir for 20-30min, after stirring evenly and fully dissolving, pack to obtain the finished product.
本发明的有益效果:Beneficial effects of the present invention:
本发明是在中国营养学会对中国居民脂肪及脂肪酸的推荐摄入量和推荐比例的基础上,考虑到植物中其它营养成分均衡,选择以红松籽油为主,并加入其它植物油进行调和,控制饱和脂肪酸(SFA)含量为9-15份,单不饱和脂肪酸(MUFA)含量为25-45份,多不饱和脂肪酸(PUFA)含量为40-50份,多不饱和脂肪酸(PUFA)与单不饱和脂肪酸(MUFA)的比例为1:(1-1.5),ω-6多不饱和脂肪酸与ω-3多不饱和脂肪酸的重量比为(4.7-5.2):1。这样脂肪酸组成的油不仅可以调配膳食脂肪中的各种脂肪酸达到较理想的比值,有利于人体消化和吸收,长期食用可预防营养缺乏症,同时还能有效地抑制胆固醇,高血压等心血管疾病。The present invention is based on the recommended intake and ratio of fats and fatty acids for Chinese residents by the Chinese Nutrition Society, and in consideration of the balance of other nutritional components in plants, chooses Korean pine seed oil as the main ingredient, and adds other vegetable oils for blending. Control saturated fatty acid (SFA) content to 9-15 parts, monounsaturated fatty acid (MUFA) content to 25-45 parts, polyunsaturated fatty acid (PUFA) content to 40-50 parts, polyunsaturated fatty acid (PUFA) and monounsaturated fatty acid (PUFA) The ratio of unsaturated fatty acid (MUFA) is 1:(1-1.5), and the weight ratio of omega-6 polyunsaturated fatty acid to omega-3 polyunsaturated fatty acid is (4.7-5.2):1. The oil composed of such fatty acids can not only adjust the various fatty acids in the dietary fat to achieve an ideal ratio, which is beneficial to the digestion and absorption of the human body. Long-term consumption can prevent nutritional deficiencies, and at the same time, it can effectively inhibit cardiovascular diseases such as cholesterol and high blood pressure. .
具体实施方式Detailed ways
实施方案1:Implementation 1:
配料前,根据红松籽油、玉米油和花生油中的脂肪酸含量,按重量份确定的标准为:饱和脂肪酸(SFA)含量为10-20份,单不饱和脂肪酸(MUFA)含量为25-45份,多不饱和脂肪酸(PUFA)含量为40-55份,单不饱和脂肪酸(MUFA)与多不饱和脂肪酸(PUFA)的重量比为1:(1-1.5),ω-6多不饱和脂肪酸与ω-3多不饱和脂肪酸的重量比为(4.5-5.2):1,经实验得到:按重量份红松籽油15份,玉米油25份,花生油60份。调配罐搅拌的同时,按重量份添加维生素E 0.04-0.05份,特丁基对苯二酚(TBHQ)0.01-0.02份,温度为40-45℃,转速100-150rpm,搅拌20-30min。Before batching, according to the fatty acid content in Korean pine seed oil, corn oil and peanut oil, the standard determined by weight is: saturated fatty acid (SFA) content is 10-20 parts, and monounsaturated fatty acid (MUFA) content is 25-45 parts. Parts, polyunsaturated fatty acid (PUFA) content is 40-55 parts, the weight ratio of monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA) is 1:(1-1.5), omega-6 polyunsaturated fatty acid The weight ratio to the omega-3 polyunsaturated fatty acid is (4.5-5.2): 1, obtained through experiments: 15 parts by weight of Korean pine seed oil, 25 parts of corn oil, and 60 parts of peanut oil. While stirring in the blending tank, add 0.04-0.05 parts of vitamin E and 0.01-0.02 parts of tertiary butyl hydroquinone (TBHQ) by weight, at a temperature of 40-45 °C, at a speed of 100-150 rpm, and stir for 20-30 minutes.
实施方案2:Implementation 2:
配料前,根据红松籽油、玉米油和花生油中的脂肪酸含量,按重量份确定的标准为:饱和脂肪酸(SFA)含量为10-20份,单不饱和脂肪酸(MUFA)含量为25-45份,多不饱和脂肪酸(PUFA)含量为40-55份,单不饱和脂肪酸(MUFA)与多不饱和脂肪酸(PUFA)的重量比为1:(1-1.5),ω-6多不饱和脂肪酸与ω-3多不饱和脂肪酸的重量比为(4.5-5.2):1,经实验得到:按重量份红松籽油14份,玉米胚芽油12份,花生油74份。调配罐搅拌的同时,按重量份添加维生素E含量为0.04-0.05份,特丁基对苯二酚(TBHQ)含量为0.01-0.02份,温度为40-45℃,转速100-150rpm,搅拌20-30min。Before batching, according to the fatty acid content in Korean pine nut oil, corn oil and peanut oil, the standard determined by weight is: saturated fatty acid (SFA) content is 10-20 parts, monounsaturated fatty acid (MUFA) content is 25-45 parts Parts, polyunsaturated fatty acid (PUFA) content is 40-55 parts, the weight ratio of monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA) is 1:(1-1.5), omega-6 polyunsaturated fatty acid The weight ratio to the omega-3 polyunsaturated fatty acid is (4.5-5.2): 1, obtained through experiments: 14 parts by weight of Korean pine seed oil, 12 parts of corn germ oil, and 74 parts of peanut oil. While stirring in the blending tank, add 0.04-0.05 parts of vitamin E and 0.01-0.02 parts of tertiary butyl hydroquinone (TBHQ) by weight, at a temperature of 40-45 °C, at a speed of 100-150 rpm, and stir for 20 -30min.
以上实施方案中的试验方法及结果如下:The test method and results in the above embodiment are as follows:
1、原料的脂肪酸含量测定:1. Determination of fatty acid content of raw materials:
甲酯化方法:油样取0.05g,加入氢氧化钾甲醇溶液(0.5mol/L)5mL,由75℃烘箱中皂化10-15分钟,直到油完全溶解.再加入1mL的三氟化硼乙醚溶液(45%三氟化硼乙醚用甲醇稀释3倍)于75℃反应1小时,取10mL正已烷萃取,移出上层溶液待测。(再稀释10倍)Methylation method: take 0.05g of oil sample, add 5mL of potassium hydroxide methanol solution (0.5mol/L), saponify in a 75°C oven for 10-15 minutes, until the oil is completely dissolved, then add 1mL of boron trifluoride ether The solution (45% boron trifluoride diethyl ether diluted 3 times with methanol) was reacted at 75°C for 1 hour, extracted with 10 mL of n-hexane, and the upper layer solution was removed for testing. (re-diluted 10 times)
GC-MS条件:WAX色谱柱,60m*250um*0.25um。GC-MS conditions: WAX column, 60m*250um*0.25um.
80℃---(3min)---5℃/min升到250℃(保持10分钟)80°C---(3min)---5°C/min to 250°C (hold for 10 minutes)
表1、原料的脂肪酸含量测定百分比:Table 1, the fatty acid content determination percentage of raw material:
表2、原料的主要脂肪酸含量:Table 2, main fatty acid content of raw material:
2、成品的检测:2. Inspection of finished products:
(1)计算含量:(1) Calculate the content:
按重量份红松籽油15份,玉米胚芽油25份,花生油60份:15 parts by weight of Korean pine nut oil, 25 parts of corn germ oil, 60 parts of peanut oil:
按重量份红松籽油14份,玉米胚芽油12份,花生油74份:14 parts by weight of Korean pine nut oil, 12 parts of corn germ oil, 74 parts of peanut oil:
(2)、测定含量:(2), determination of content:
按重量份红松籽油15份,玉米胚芽油25份,花生油60份:15 parts by weight of Korean pine nut oil, 25 parts of corn germ oil, 60 parts of peanut oil:
按重量份红松籽油14份,玉米胚芽油12份,花生油74份:14 parts by weight of Korean pine nut oil, 12 parts of corn germ oil, 74 parts of peanut oil:
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