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CN104761999A - High-strength wear-resistant water-based mixed coating - Google Patents

High-strength wear-resistant water-based mixed coating Download PDF

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Publication number
CN104761999A
CN104761999A CN201510178323.4A CN201510178323A CN104761999A CN 104761999 A CN104761999 A CN 104761999A CN 201510178323 A CN201510178323 A CN 201510178323A CN 104761999 A CN104761999 A CN 104761999A
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CN
China
Prior art keywords
parts
water
compo
silicon carbide
resin
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510178323.4A
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Chinese (zh)
Inventor
许汉池
佘三先
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Individual
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Individual
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Priority to CN201510178323.4A priority Critical patent/CN104761999A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a high-strength wear-resistant water-based mixed coating. The water-based mixed coating at least comprises 30-60 parts of silicon carbide and also comprises 13-80 parts of water-base resin, 1-3 parts of a water-base adjuvant agent, 0-30 parts of environmentally-friendly pigments and 10-50 parts of water. The hardness and the abrasive resistance of the water-based mixed coating or paint can be greatly increased with low cost and without pollution and the high-strength wear-resistant water-based mixed coating has the advantage of ageing resistance.

Description

A kind of high-strength abrasion-proof water-based compo
Technical field
The present invention relates to a kind of high-strength abrasion-proof water-based compo.
Background technology
At present, various types of coating, compo, paint on market, especially, there is the deficiency that hardness is low, wear no resistance in water-borne coatings, compo, water-miscible paint etc.How low cost, contamination-freely to solve the problem be the urgent target extensively pursued.
Summary of the invention
The object of this invention is to provide a kind of high-strength abrasion-proof water-based compo, can with lower cost, pollution-free, to improve water-based compo or paint class significantly hardness and wear resistance, also have the advantage of resistance to deterioration.
For this reason, the silicon carbide accounting for its overall weight 30 parts ~ 60 parts is at least comprised in water-based compo of the present invention.The water of the water-base resin accounting for its overall weight 13 parts ~ 80 parts, the aqueous promoter of 1 part ~ 3 parts, the environmental-friendly pigment of 0 part ~ 30 parts and 10 parts ~ 50 parts is also comprised in described water-based compo.Described water-base resin is one or several in aqueous epoxy resins, water-borne acrylic resin, the close ammonia resin of water-based, water-based fluorocarbon resin, synthesis water-base resin.In described compo, the weight proportion of each feed composition is: aqueous epoxy resins 45 parts ~ 80 parts, aqueous promoter 2 parts ~ 3 parts, film coalescence aid 3 parts ~ 5 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide and 25 parts ~ 45 parts, water.In described compo, the weight proportion of each feed composition is: aqueous epoxy resins 13 parts ~ 15 parts, aqueous promoter 1 part ~ 2 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 40 parts, silicon carbide, ethylene glycol 0 part ~ 2 parts and 15 parts ~ 30 parts, water.In described compo, the weight proportion of each feed composition is: synthesis water-base resin 45 parts ~ 60 parts, aqueous promoter 2 parts ~ 5 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 50 parts, silicon carbide, butyl glycol ether 0 part ~ 2 parts and 15 parts ~ 35 parts, water.In described compo, the weight proportion of each feed composition is: water-borne acrylic resin 45 parts ~ 60 parts, aqueous promoter 1 part ~ 3 parts, the close ammonia resin of water-based 10 parts ~ 15 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide, butyl 3 parts ~ 5 parts, ethanol 5 parts ~ 10 parts and 10 parts ~ 25 parts, water.Water-based fluorocarbon resin 40 parts ~ 60 parts, aqueous promoter 1 part ~ 2 parts, the close ammonia resin of water-based 8 parts ~ 10 parts, environmental-friendly pigment 10 parts ~ 30 parts, 45 parts ~ 55 parts, silicon carbide, butyl 5 parts ~ 8 parts, ethanol 8 parts ~ 15 parts and 10 parts ~ 20 parts, water.The particle diameter of described silicon carbide is 1 ~ 10 μm.
The present invention can with lower cost, and pollution-free, to improve water-based compo or paint class significantly hardness and wear resistance, also have the advantage of resistance to deterioration.
Cost of the present invention is only than the increase by 0.5 ~ 1% of traditional like product cost, but hardness >=4H; Shock strength (kg.cm) >=50; Resistance to neutral salt spray: 4000h plate face without getting rusty, bubble, variable color; Water boiling resistance > 1h: not softening, non-foaming, non-whitening, wet adhesion excellence without exception; Artificial accelerated aging (cladding, Lacquer finish): 600h is without considerable change; Heavy metal content meets International Toy Safety standard, meets Consumer Product Safety Commission CPSC standard, meets European ROHS instruction standard: etc. index be all better than existing procucts.
Embodiment
A kind of high-strength abrasion-proof water-based compo, at least comprises the silicon carbide accounting for its overall weight 30 parts ~ 60 parts in this water-based compo.
The water of the water-base resin accounting for its overall weight 13 parts ~ 80 parts, the aqueous promoter of 1 part ~ 3 parts, the environmental-friendly pigment of 0 part ~ 30 parts and 10 parts ~ 50 parts is also comprised in described water-based compo.
Described water-base resin is one or several in aqueous epoxy resins, water-borne acrylic resin, the close ammonia resin of water-based, water-based fluorocarbon resin, synthesis water-base resin.
The particle diameter of described silicon carbide is 1 ~ 10 μm.
Embodiment 1: in described compo, the weight proportion of each feed composition is: aqueous epoxy resins 45 parts ~ 80 parts, aqueous promoter 2 parts ~ 3 parts, film coalescence aid 3 parts ~ 5 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide and 25 parts ~ 45 parts, water.The particle diameter of described silicon carbide is 1 ~ 10 μm.
The product of this component is called: water-base epoxy amine coating.Its salient features is as follows:
Embodiment 2: in described compo, the weight proportion of each feed composition is: aqueous epoxy resins 13 parts ~ 15 parts, aqueous promoter 1 part ~ 2 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 40 parts, silicon carbide, ethylene glycol 0 part ~ 2 parts and 15 parts ~ 30 parts, water.
The product of this component is called: water-base epoxy amine coating.Its salient features is as follows:
Embodiment 3: in described compo, the weight proportion of each feed composition is: synthesis water-base resin 45 parts ~ 60 parts, aqueous promoter 2 parts ~ 5 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 50 parts, silicon carbide, butyl glycol ether 0 part ~ 2 parts and 15 parts ~ 35 parts, water.
The product of this component is called: water-based plastic paint.Its salient features is as follows:
Embodiment 4: in described compo, the weight proportion of each feed composition is: water-borne acrylic resin 45 parts ~ 60 parts, aqueous promoter 1 part ~ 3 parts, the close ammonia resin of water-based 10 parts ~ 15 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide, butyl 3 parts ~ 5 parts, ethanol 5 parts ~ 10 parts and 10 parts ~ 25 parts, water.
The product of this component is called: water soluble acrylic acid baking vanish.Its salient features is as follows:
Embodiment 5: in described compo, the weight proportion of each feed composition is: water-based fluorocarbon resin 40 parts ~ 60 parts, aqueous promoter 1 part ~ 2 parts, the close ammonia resin of water-based 8 parts ~ 10 parts, environmental-friendly pigment 10 parts ~ 30 parts, 45 parts ~ 55 parts, silicon carbide, butyl 5 parts ~ 8 parts, ethanol 8 parts ~ 15 parts and 10 parts ~ 20 parts, water.
The product of this component is called: aqueous fluorine-carbon paint.Its salient features is as follows:
In a word, the present invention can with lower cost, and pollution-free, to improve water-based compo or paint class significantly hardness and wear resistance, also have the advantage of resistance to deterioration.

Claims (9)

1. a high-strength abrasion-proof water-based compo, is characterized in that: at least comprise the silicon carbide accounting for its overall weight 30 parts ~ 60 parts in this water-based compo.
2. a kind of high-strength abrasion-proof water-based compo according to claim 1, is characterized in that: the water also comprising the water-base resin accounting for its overall weight 13 parts ~ 80 parts, the aqueous promoter of 1 part ~ 3 parts, the environmental-friendly pigment of 0 part ~ 30 parts and 10 parts ~ 50 parts in described water-based compo.
3. a kind of high-strength abrasion-proof water-based compo according to claim 2, is characterized in that: described water-base resin is one or several in aqueous epoxy resins, water-borne acrylic resin, the close ammonia resin of water-based, water-based fluorocarbon resin, synthesis water-base resin.
4. a kind of high-strength abrasion-proof water-based compo according to claim 1 and 2 and 3, is characterized in that: in described compo, the weight proportion of each feed composition is: aqueous epoxy resins 45 parts ~ 80 parts, aqueous promoter 2 parts ~ 3 parts, film coalescence aid 3 parts ~ 5 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide and 25 parts ~ 45 parts, water.
5. a kind of high-strength abrasion-proof water-based compo according to claim 1 and 2 and 3, is characterized in that: in described compo, the weight proportion of each feed composition is: aqueous epoxy resins 13 parts ~ 15 parts, aqueous promoter 1 part ~ 2 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 40 parts, silicon carbide, ethylene glycol 0 part ~ 2 parts and 15 parts ~ 30 parts, water.
6. a kind of high-strength abrasion-proof water-based compo according to claim 1 and 2 and 3, is characterized in that: in described compo, the weight proportion of each feed composition is: synthesis water-base resin 45 parts ~ 60 parts, aqueous promoter 2 parts ~ 5 parts, environmental-friendly pigment 5 parts ~ 25 parts, 30 parts ~ 50 parts, silicon carbide, butyl glycol ether 0 part ~ 2 parts and 15 parts ~ 35 parts, water.
7. a kind of high-strength abrasion-proof water-based compo according to claim 1 and 2 and 3, is characterized in that: in described compo, the weight proportion of each feed composition is: water-borne acrylic resin 45 parts ~ 60 parts, aqueous promoter 1 part ~ 3 parts, the close ammonia resin of water-based 10 parts ~ 15 parts, environmental-friendly pigment 0 part ~ 25 parts, 40 parts ~ 60 parts, silicon carbide, butyl 3 parts ~ 5 parts, ethanol 5 parts ~ 10 parts and 10 parts ~ 25 parts, water.
8. a kind of high-strength abrasion-proof water-based compo according to claim 1 and 2 and 3, is characterized in that: in described compo, the weight proportion of each feed composition is: water-based fluorocarbon resin 40 parts ~ 60 parts, aqueous promoter 1 part ~ 2 parts, the close ammonia resin of water-based 8 parts ~ 10 parts, environmental-friendly pigment 10 parts ~ 30 parts, 45 parts ~ 55 parts, silicon carbide, butyl 5 parts ~ 8 parts, ethanol 8 parts ~ 15 parts and 10 parts ~ 20 parts, water.
9. according to a kind of high-strength abrasion-proof water-based compo described in claim 1 to 8, it is characterized in that: the particle diameter of described silicon carbide is 1 ~ 10 μm.
CN201510178323.4A 2015-04-16 2015-04-16 High-strength wear-resistant water-based mixed coating Pending CN104761999A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510178323.4A CN104761999A (en) 2015-04-16 2015-04-16 High-strength wear-resistant water-based mixed coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510178323.4A CN104761999A (en) 2015-04-16 2015-04-16 High-strength wear-resistant water-based mixed coating

Publications (1)

Publication Number Publication Date
CN104761999A true CN104761999A (en) 2015-07-08

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106046969A (en) * 2016-08-08 2016-10-26 许汉池 Aqueous fluorocarbon resin paint
CN111040576A (en) * 2019-12-28 2020-04-21 西安博尔新材料有限责任公司 Cubic silicon carbide anticorrosive wear-resistant coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101680193A (en) * 2007-04-20 2010-03-24 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 Anti abrasion layer
CN102627905A (en) * 2012-04-18 2012-08-08 天长市巨龙车船涂料有限公司 Waterborne epoxy anti-corrosive coating and preparation method thereof
CN102898904A (en) * 2012-09-12 2013-01-30 上海三银制漆有限公司 Waterborne fluorocarbon coating, and preparation method and application thereof
CN104263045A (en) * 2014-09-19 2015-01-07 江苏海晟涂料有限公司 Water-based epoxy anticorrosive paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101680193A (en) * 2007-04-20 2010-03-24 研磨剂与耐火品研究与开发中心C.A.R.R.D.有限公司 Anti abrasion layer
CN102627905A (en) * 2012-04-18 2012-08-08 天长市巨龙车船涂料有限公司 Waterborne epoxy anti-corrosive coating and preparation method thereof
CN102898904A (en) * 2012-09-12 2013-01-30 上海三银制漆有限公司 Waterborne fluorocarbon coating, and preparation method and application thereof
CN104263045A (en) * 2014-09-19 2015-01-07 江苏海晟涂料有限公司 Water-based epoxy anticorrosive paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106046969A (en) * 2016-08-08 2016-10-26 许汉池 Aqueous fluorocarbon resin paint
CN111040576A (en) * 2019-12-28 2020-04-21 西安博尔新材料有限责任公司 Cubic silicon carbide anticorrosive wear-resistant coating and preparation method thereof

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Application publication date: 20150708