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CN104722957B - A kind of environment-friendly spray coating type splash-proof welding agent and preparation method thereof - Google Patents

A kind of environment-friendly spray coating type splash-proof welding agent and preparation method thereof Download PDF

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CN104722957B
CN104722957B CN201510164570.9A CN201510164570A CN104722957B CN 104722957 B CN104722957 B CN 104722957B CN 201510164570 A CN201510164570 A CN 201510164570A CN 104722957 B CN104722957 B CN 104722957B
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agent
solvent
petroleum resin
splash
welding anti
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CN104722957A (en
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陈得军
朱安莲
李凌君
裴渊超
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Henan Normal University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/40Making wire or rods for soldering or welding

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

本发明公开了一种环保喷涂型焊接防飞溅剂及其制备方法,属于金属焊接防飞溅化学助剂技术领域。本发明的技术方案要点为:一种环保喷涂型焊接防飞溅剂,是由以下重量百分配比的原料制备而成的:成膜剂碳五石油树脂或碳九石油树脂5‑30%、剥离剂氯化聚乙烯树脂5‑30%、分散剂气相白炭黑5‑20%、溶剂脱芳烃溶剂油D4050‑70%和助溶剂环己醇1‑15%。本发明还公开了该环保喷涂型焊接防飞溅剂的制备方法。本发明制得的环保喷涂型焊接防飞溅剂所用的原料成本低廉,具有较好的均一性,因此在使用过程中可以使用喷枪喷涂,省时省力。The invention discloses an environment-friendly spraying type welding anti-splash agent and a preparation method thereof, belonging to the technical field of metal welding anti-splash chemical additives. The key points of the technical scheme of the present invention are: an environmentally friendly spraying type welding anti-splash agent, which is prepared from the following raw materials in proportion by weight: film-forming agent C5 petroleum resin or C9 petroleum resin 5-30%, stripping Agent chlorinated polyethylene resin 5-30%, dispersant fumed silica 5-20%, solvent dearomatization solvent oil D4050-70% and co-solvent cyclohexanol 1-15%. The invention also discloses a preparation method of the environment-friendly spraying welding anti-splash agent. The raw materials used in the environment-friendly spraying type welding anti-spatter agent prepared by the invention have low cost and good uniformity, so it can be sprayed with a spray gun during use, saving time and effort.

Description

一种环保喷涂型焊接防飞溅剂及其制备方法A kind of environmental protection spray type welding anti-splash agent and preparation method thereof

技术领域technical field

本发明属于金属焊接防飞溅化学助剂技术领域,具体涉及一种环保喷涂型焊接防飞溅剂及其制备方法.The invention belongs to the technical field of anti-splash chemical additives for metal welding, and specifically relates to an environmentally friendly spray-type welding anti-splash agent and a preparation method thereof.

背景技术Background technique

金属的焊接工艺是现代工业中应用非常广泛的金属加工过程,包括海洋船舶、航天航空、铁道交通、石油化工、五金建筑等各行各业。焊接时,需要使焊接材料与金属母材在高温高压的条件下将其连接成一个整体。在焊接过程中混合体中由于有外界气体的加入,从而使大电流产生弧光高温,而温度在急剧上升的时候会产生很多飞溅物,这些飞溅物很容易落在焊缝附近的金属表面,冷却后就粘连在金属母材的表面,也就是所说的焊渣。实际工作中,为保证焊接的质量,必须对焊渣进行处理,通常人们是通过铲除来打磨去掉焊渣,但是这会占用大量的时间,增加制作成本。The metal welding process is a very widely used metal processing process in modern industry, including marine ships, aerospace, railway transportation, petrochemical industry, hardware construction and other industries. When welding, it is necessary to connect the welding material and the metal base material into a whole under high temperature and high pressure conditions. During the welding process, due to the addition of external gas in the mixture, the high current generates arc light and high temperature, and when the temperature rises sharply, a lot of spatter will be generated. These spatters are easy to fall on the metal surface near the weld and cool down. After that, it sticks to the surface of the metal base metal, which is the so-called welding slag. In actual work, in order to ensure the quality of welding, the welding slag must be processed. Usually, people remove the welding slag by grinding and removing it, but this will take a lot of time and increase the production cost.

目前,为解决这个问题,相关研究人员发明了一些金属焊接用防飞溅剂,比如公开号为CN 102061110A的专利公开了一种金属焊接用防飞溅液,但是原料中含有硝酸钙等,在实际操作过程中将防飞溅液刷涂在母材的表面,这给实际操作过程带来很大的不便,而且效率低,最重要的是在刷涂的过程中会造成刷涂的不均匀,导致实际使用的效果差。At present, in order to solve this problem, relevant researchers have invented some anti-splash agents for metal welding. For example, the patent with the publication number of CN 102061110A discloses an anti-splash liquid for metal welding, but the raw materials contain calcium nitrate, etc., in actual operation During the process, the anti-splash liquid is brushed on the surface of the base material, which brings great inconvenience to the actual operation process, and the efficiency is low. The effect of use is poor.

因此,喷涂型的金属焊接防飞溅剂有很大的优势。比如公开号为CN 103612028A的专利公开了一种金属焊接防飞溅剂,但是试剂中含有聚醚、三乙醇胺和亚硝酸钠,三乙醇胺分解会产生强烈的刺激性氨气味,这在实际的操作过程中污染空气,特别是在某些密闭场合(比如某些大型的反应釜内部),另外亚硝酸钠为强致癌性物质,对人的身体有害,所以开发出一种无污染环保喷涂型焊接防飞溅剂就显得特别重要。Therefore, the spray type metal welding anti-spatter has great advantages. For example, the patent with the publication number CN 103612028A discloses a metal welding anti-splash agent, but the reagent contains polyether, triethanolamine and sodium nitrite, and the decomposition of triethanolamine will produce a strong pungent ammonia smell, which is difficult to obtain in the actual operation process. In addition, sodium nitrite is a strong carcinogen and harmful to human body, especially in some closed places (such as inside some large reactors), so a non-polluting and environmentally friendly spray welding anti The splash agent is particularly important.

发明内容Contents of the invention

本发明为克服现有技术的不足而提供了一种环保喷涂型焊接防飞溅剂及其制备方法,该焊接防飞溅剂有效地解决了焊接过程中焊花飞溅所造成的飞溅物粘连在母材表面的技术问题。In order to overcome the deficiencies of the prior art, the present invention provides an environmentally friendly spray-coated welding anti-spatter agent and its preparation method. superficial technical problems.

本发明的技术方案为:一种环保喷涂型焊接防飞溅剂,其特征在于是由以下重量百分配比的原料制备而成的:The technical solution of the present invention is: an environmentally friendly spray-type welding anti-spatter agent, which is characterized in that it is prepared from the following raw materials in the proportion by weight:

成膜剂:碳五石油树脂或碳九石油树脂5-30%Film-forming agent: C5 petroleum resin or C9 petroleum resin 5-30%

剥离剂:氯化聚乙烯树脂5-30%Stripping agent: Chlorinated polyethylene resin 5-30%

分散剂:气相白炭黑5-20%Dispersant: fumed silica 5-20%

溶剂:脱芳烃溶剂油D40 50-70%Solvent: Dearomatized solvent oil D40 50-70%

助溶剂:环己醇1-15%。Co-solvent: cyclohexanol 1-15%.

作为优选的,所述的环保喷涂型焊接防飞溅剂是由以下重量百分配比的原料制备而成的:As preferably, described environment-friendly spray type welding anti-spatter agent is prepared from the raw material of following weight percent ratio:

成膜剂:碳五石油树脂10%Film-forming agent: C5 petroleum resin 10%

剥离剂:氯化聚乙烯树脂10%Release agent: Chlorinated polyethylene resin 10%

分散剂:气相白炭黑10%Dispersant: fumed silica 10%

溶剂:脱芳烃溶剂油D40 65%Solvent: Dearomatized solvent oil D40 65%

助溶剂:环己醇5%。Co-solvent: 5% cyclohexanol.

本发明所述的环保喷涂型焊接防飞溅剂的制备方法,其特征在于具体步骤为:按照如下重量百分配比分别称取原料成膜剂碳五石油树脂或碳九石油树脂5-30%、剥离剂氯化聚乙烯树脂5-30%、分散剂气相白炭黑5-20%、溶剂脱芳烃溶剂油D40 50-70%和助溶剂环己醇 1-15%,将称取的成膜剂碳五石油树脂或碳九石油树脂和剥离剂氯化聚乙烯树脂加入溶剂脱芳烃溶剂油D40中,待完全溶解后依次加入分散剂气相白炭黑和助溶剂环己醇并调节到成均相即制得环保喷涂型焊接防飞溅剂。The preparation method of the environmental protection spraying type welding anti-splash agent according to the present invention is characterized in that the specific steps are: according to the following weight percentage ratio, take respectively 5-30% of raw material film-forming agent C5 petroleum resin or C9 petroleum resin, Stripping agent chlorinated polyethylene resin 5-30%, dispersant fumed silica 5-20%, solvent dearomatization solvent oil D40 50-70% and co-solvent cyclohexanol 1-15%, weigh the film-forming C5 petroleum resin or C9 petroleum resin and stripping agent chlorinated polyethylene resin are added to solvent dearomatization solvent oil D40, and after complete dissolution, add dispersant fumed silica and cosolvent cyclohexanol in sequence and adjust to the average Then the environment-friendly spray-type welding anti-spatter agent can be obtained.

作为优选的,所述的环保喷涂型焊接防飞溅剂的制备方法的具体步骤为:按照如下重量百分配比分别称取原料成膜剂碳五石油树脂10%、剥离剂氯化聚乙烯树脂10%、分散剂气相白炭黑10%、溶剂脱芳烃溶剂油D40 65%和助溶剂环己醇 5%,将称取的成膜剂碳五石油树脂和剥离剂氯化聚乙烯树脂加入溶剂脱芳烃溶剂油D40中,待完全溶解后依次加入分散剂气相白炭黑和助溶剂环己醇并调节到成均相即制得环保喷涂型焊接防飞溅剂。As preferably, the specific steps of the preparation method of the environmental protection spraying type welding anti-spatter agent are: according to the following weight percentage proportions, respectively weigh 10% of the raw material film-forming agent C5 petroleum resin and 10% of the stripping agent chlorinated polyethylene resin. %, dispersant fumed silica 10%, solvent dearomatized solvent oil D40 65% and cosolvent cyclohexanol 5%, the film-forming agent C5 petroleum resin and stripping agent chlorinated polyethylene resin were added to solvent de-aromatization In the aromatic hydrocarbon solvent oil D40, after being completely dissolved, add the dispersant fumed silica and the cosolvent cyclohexanol in sequence and adjust to a homogeneous phase to obtain an environmentally friendly spray-type welding anti-spatter agent.

本发明制得的环保喷涂型焊接防飞溅剂所用的原料成本低廉,具有较好的均一性,因此在使用过程中可以使用喷枪喷涂,省时省力,使用时将本品刷涂或喷涂于工件的表面,再进行焊接操作,可以有效地防止工件与焊渣粘连,焊接完毕后,焊渣经过水洗或清扫即可轻松去除。The raw materials used in the environmentally friendly spray-type welding anti-spatter agent prepared by the present invention are low in cost and have good uniformity, so it can be sprayed with a spray gun during use, saving time and effort, and brushing or spraying this product on the workpiece during use The welding operation can effectively prevent the workpiece from sticking to the welding slag. After welding, the welding slag can be easily removed by washing or cleaning.

具体实施方式detailed description

以下通过实施例对本发明的上述内容做进一步详细说明,但不应该将此理解为本发明上述主题的范围仅限于以下的实施例,凡基于本发明上述内容实现的技术均属于本发明的范围。The above-mentioned contents of the present invention are described in further detail below through the embodiments, but this should not be interpreted as the scope of the above-mentioned themes of the present invention being limited to the following embodiments, and all technologies realized based on the above-mentioned contents of the present invention all belong to the scope of the present invention.

实施例Example

按照如下配比分别称取原料(千克):Weigh the raw materials (kg) according to the following proportions:

1、成膜剂碳五石油树脂10、剥离剂氯化聚乙烯树脂10、分散剂气相白炭黑10、溶剂脱芳烃溶剂油D40 65和助溶剂环己醇5;1. Film-forming agent C5 petroleum resin 10, stripping agent chlorinated polyethylene resin 10, dispersant fumed silica 10, solvent dearomatization solvent oil D40 65 and co-solvent cyclohexanol 5;

2、成膜剂碳九石油树脂5、剥离剂氯化聚乙烯树脂30、分散剂气相白炭黑5、溶剂脱芳烃溶剂油D40 59和助溶剂环己醇1;2. Film-forming agent C9 petroleum resin 5, stripping agent chlorinated polyethylene resin 30, dispersant fumed silica 5, solvent dearomatization solvent oil D40 59 and co-solvent cyclohexanol 1;

3、成膜剂碳五石油树脂30、剥离剂氯化聚乙烯树脂5、分散剂气相白炭黑5、溶剂脱芳烃溶剂油D40 59和助溶剂环己醇1;3. Film-forming agent C5 petroleum resin 30, stripping agent chlorinated polyethylene resin 5, dispersant fumed silica 5, solvent dearomatization solvent oil D40 59 and co-solvent cyclohexanol 1;

4、成膜剂碳九石油树脂5、剥离剂氯化聚乙烯树脂5、分散剂气相白炭黑20、溶剂脱芳烃溶剂油D40 55和助溶剂环己醇15;4. Film forming agent C9 petroleum resin 5, stripping agent chlorinated polyethylene resin 5, dispersant fumed silica 20, solvent dearomatization solvent oil D40 55 and cosolvent cyclohexanol 15;

5、成膜剂碳五石油树脂15、剥离剂氯化聚乙烯树脂15、分散剂气相白炭黑10、溶剂脱芳烃溶剂油D40 50和助溶剂环己醇10;5. Film-forming agent C5 petroleum resin 15, stripping agent chlorinated polyethylene resin 15, dispersant fumed silica 10, solvent dearomatization solvent oil D40 50 and co-solvent cyclohexanol 10;

6、成膜剂碳九石油树脂5、剥离剂氯化聚乙烯树脂5、分散剂气相白炭黑5、溶剂脱芳烃溶剂油D40 70和助溶剂环己醇15。6. Film-forming agent C9 petroleum resin 5, stripping agent chlorinated polyethylene resin 5, dispersant fumed silica 5, solvent dearomatization solvent oil D40 70 and co-solvent cyclohexanol 15.

制备方法为:The preparation method is:

将按上述配比称取的成膜剂碳五石油树脂或碳九石油树脂和剥离剂氯化聚乙烯树脂加入溶剂脱芳烃溶剂油D40中,待完全溶解后依次加入分散剂气相白炭黑和助溶剂环己醇并调节到成均相即制得环保喷涂型焊接防飞溅剂。Add the film-forming agent C5 petroleum resin or C9 petroleum resin and the stripping agent chlorinated polyethylene resin weighed according to the above ratio into the solvent dearomatization solvent oil D40, and then add the dispersant gas phase white carbon black and The co-solvent cyclohexanol is adjusted to form a homogeneous phase to prepare an environmentally friendly spray-type welding anti-spatter agent.

使用方法为:The method of use is:

使用时将上述制备的环保喷涂型焊接防飞溅剂刷涂或喷涂于工件的表面,再进行焊接操作,可以有效地防止工件与焊渣粘连,焊接完毕后,焊渣经过水洗或清扫即可轻松去除。When in use, brush or spray the above-mentioned environmentally friendly spray-type welding anti-spatter agent on the surface of the workpiece, and then perform welding operation, which can effectively prevent the workpiece from sticking to the welding slag. After welding, the welding slag can be washed or cleaned easily. remove.

以上实施例仅为说明本发明的技术思想,不能以此限定本发明的保护范围,凡是按照本发明提出的技术思想,在技术方案基础上所做的任何改动,均落入本发明保护范围之内。The above embodiments are only to illustrate the technical ideas of the present invention, and can not limit the protection scope of the present invention with this. All technical ideas proposed in accordance with the present invention, any changes made on the basis of technical solutions, all fall within the protection scope of the present invention. Inside.

Claims (3)

1.一种环保喷涂型焊接防飞溅剂, 其特征在于是由以下重量百分配比的原料制备而成的:1. An environment-friendly spraying type welding anti-splash agent is characterized in that it is prepared from the following raw materials in proportion by weight: 成膜剂:碳五石油树脂10%Film-forming agent: C5 petroleum resin 10% 剥离剂:氯化聚乙烯树脂10%Release agent: Chlorinated polyethylene resin 10% 分散剂:气相白炭黑10%Dispersant: fumed silica 10% 溶剂:脱芳烃溶剂油D40 65%Solvent: Dearomatized solvent oil D40 65% 助溶剂:环己醇5%。Co-solvent: 5% cyclohexanol. 2.一种环保喷涂型焊接防飞溅剂的制备方法,其特征在于具体步骤为:按照如下重量百分配比分别称取原料成膜剂碳五石油树脂或碳九石油树脂5-30%、剥离剂氯化聚乙烯树脂5-30%、分散剂气相白炭黑5-20%、溶剂脱芳烃溶剂油D40 50-70%和助溶剂环己醇 1-15%,将称取的成膜剂碳五石油树脂或碳九石油树脂和剥离剂氯化聚乙烯树脂加入溶剂脱芳烃溶剂油D40中,待完全溶解后依次加入分散剂气相白炭黑和助溶剂环己醇并调节至成均相即制得环保喷涂型焊接防飞溅剂。2. A preparation method of an environmental protection spraying type welding anti-splash agent, is characterized in that concrete steps are: take by weighing raw material film-forming agent C5 petroleum resin or C9 petroleum resin 5-30% respectively according to following weight percentage distribution ratio, peel off Agent chlorinated polyethylene resin 5-30%, dispersant fumed silica 5-20%, solvent dearomatization solvent oil D40 50-70% and co-solvent cyclohexanol 1-15%, the film-forming agent C5 petroleum resin or C9 petroleum resin and stripping agent chlorinated polyethylene resin are added to solvent dearomatization solvent oil D40, and after being completely dissolved, add dispersant fumed silica and cosolvent cyclohexanol in sequence and adjust to form a homogeneous phase. An environmentally friendly spray-type welding anti-splash agent is prepared. 3. 根据权利要求2所述的环保喷涂型焊接防飞溅剂的制备方法,其特征在于具体步骤为:按照如下重量百分配比分别称取原料成膜剂碳五石油树脂10%、剥离剂氯化聚乙烯树脂10%、分散剂气相白炭黑10%、溶剂脱芳烃溶剂油D40 65%和助溶剂环己醇 5%,将称取的成膜剂碳五石油树脂和剥离剂氯化聚乙烯树脂加入溶剂脱芳烃溶剂油D40中,待完全溶解后依次加入分散剂气相白炭黑和助溶剂环己醇并调节至成均相即制得环保喷涂型焊接防飞溅剂。3. the preparation method of environmental protection spraying type welding anti-splash agent according to claim 2, it is characterized in that concrete steps are: take by weighing respectively raw material film-forming agent C5 petroleum resin 10%, stripping agent chlorine according to following weight percentage distribution ratio Polyethylene resin 10%, dispersant fumed silica 10%, solvent dearomatization solvent oil D40 65% and cosolvent cyclohexanol 5%, the film-forming agent C5 petroleum resin and stripping agent chlorinated poly Vinyl resin is added to the solvent dearomatization solvent oil D40, and after being completely dissolved, the dispersant fumed silica and the cosolvent cyclohexanol are added in sequence and adjusted to form a homogeneous phase to obtain an environmentally friendly sprayable welding anti-spatter agent.
CN201510164570.9A 2015-04-09 2015-04-09 A kind of environment-friendly spray coating type splash-proof welding agent and preparation method thereof Expired - Fee Related CN104722957B (en)

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