CN1047016A - High oilness drug-resistance-extincted dimethylcyclopropanecarboxylate - Google Patents
High oilness drug-resistance-extincted dimethylcyclopropanecarboxylate Download PDFInfo
- Publication number
- CN1047016A CN1047016A CN 90105265 CN90105265A CN1047016A CN 1047016 A CN1047016 A CN 1047016A CN 90105265 CN90105265 CN 90105265 CN 90105265 A CN90105265 A CN 90105265A CN 1047016 A CN1047016 A CN 1047016A
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- China
- Prior art keywords
- agricultural chemicals
- resistance
- drug
- extincted
- dimethylcyclopropanecarboxylate
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- 206010059866 Drug resistance Diseases 0.000 title claims abstract description 26
- VEQMUQZKBLIXLT-UHFFFAOYSA-N 2,3-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1C(C)C1C(O)=O VEQMUQZKBLIXLT-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 239000003905 agrochemical Substances 0.000 claims abstract description 56
- 241000238631 Hexapoda Species 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 16
- 239000002283 diesel fuel Substances 0.000 claims description 10
- 239000005949 Malathion Substances 0.000 claims description 9
- 239000005916 Methomyl Substances 0.000 claims description 9
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 9
- 229960000453 malathion Drugs 0.000 claims description 9
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims description 9
- 150000002894 organic compounds Chemical class 0.000 claims description 9
- 239000010721 machine oil Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 241000723353 Chrysanthemum Species 0.000 claims description 7
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 7
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 239000005946 Cypermethrin Substances 0.000 claims description 2
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 2
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 claims description 2
- 229960005424 cypermethrin Drugs 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000000241 respiratory effect Effects 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 25
- 230000000749 insecticidal effect Effects 0.000 abstract description 11
- 241000607479 Yersinia pestis Species 0.000 abstract description 9
- 206010034133 Pathogen resistance Diseases 0.000 abstract description 8
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000000857 drug effect Effects 0.000 abstract description 5
- 230000000895 acaricidal effect Effects 0.000 abstract description 2
- 239000002917 insecticide Substances 0.000 abstract description 2
- 244000144977 poultry Species 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 13
- 108090000623 proteins and genes Proteins 0.000 description 7
- 230000007246 mechanism Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 241000449794 Alabama argillacea Species 0.000 description 3
- 241000255967 Helicoverpa zea Species 0.000 description 3
- -1 decises Chemical class 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 description 2
- 210000000653 nervous system Anatomy 0.000 description 2
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 2
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 2
- 241001600408 Aphis gossypii Species 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000176086 Sogatella furcifera Species 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007614 genetic variation Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention is a kind of agricultural chemicals that overcomes pest resistance to insecticide a---high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate.It belongs to the insecticidal/acaricidal agent of technical field of pesticide.This agricultural chemicals has utilized synergistic effect and the negative cross resistance relation between some agricultural chemicals, adopts the means of the physics of chemistry to overcome the pesticide resistance of insect to this agricultural chemicals.This agricultural chemicals discloses the series of effective prescription, makes that each composition plays one's part to the full in the agricultural chemicals, has the drug effect height, low to the person poultry toxicity, low-residual, pollution-free, characteristics safe in utilization are used this agricultural chemicals, are particularly suited for control and have produced serious drug-fast each class pest.
Description
The present invention relates to the biocide of crop pests, especially a kind ofly overcome drug-fast agricultural chemicals-high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate.It belongs to the insecticidal/acaricidal agent of technical field of pesticide.
Current, the pesticide variety of crops is various, and organophosphorus insecticide is arranged, chrysanthemum ester class, series pesticide agent such as carbamates.These agricultural chemicals have played important function over a period to come to kill pests protection crops; yet long-term use along with these agricultural chemicals; the primary pest of some crops; as: cotton aphid; cotton bollworm; European red mite; rice fulgorids etc. have all produced serious pesticide resistance to above-mentioned agricultural chemicals; especially (be often referred to: cotten aphid and cotton bollworm with cotton-plant pest-insects; hereinafter to be referred as " cotton worm ") show as more very; its pesticide resistance degree does not almost have the agent of a kind of agricultural chemicals list can prevent and treat drug-fast cotton worm preferably up to thousands of times.The insecticidal mechanism of above-mentioned agricultural chemicals nearly all is that the nervous system to insect suppresses, and then kill pests.The pesticide resistance of insect may be because the resistant gene of insect is selected by a certain agricultural chemicals or variation of drug resistance taken place.This is because all biological forms or physiological status all are the results of long-term variation and heredity.Therefore, use a certain single agent agricultural chemicals for a long time, must make the gene of insect produce variation and have the pesticide resistance of the effective fatal gene action that adapts to a certain single agent agricultural chemicals.This have drug-fast mutant gene and must form similar multiple choices to almost consistent insecticidal mechanism, resists or avoid the effective fatal gene of above-mentioned a certain agricultural chemicals with this.Thereby insect can also be to producing cross resistance relation (that is: the intersection of the pesticide resistance between two or more agricultural chemicals improves its drug-fast relation mutually) between above-mentioned several agricultural chemicals, thereby facilitate the pesticide resistance surge of insect, imitate and deposited the use to cause most agricultural chemicals to fall to above-mentioned agricultural chemicals.
On nearest agricultural chemicals market, a kind of " mite-killing pesticide " agricultural chemicals has appearred, its mechanism of action separately (actual is the mutual synergistic effect of two kinds of agricultural chemicals) that utilizes two kinds of agricultural chemicals is different with desinsection worm spectrum, is equipped with " synergist " again and reaches and overcome drug-fast purpose.Itself no insecticidal action of used " synergist " of this mixture just can play synergistic effect to aforementioned two agricultural chemicals.But after in a single day aforementioned two kinds of agricultural chemicals are produced high anti-medicine by insect (having produced pesticide resistance now), the synergistic effect of being somebody's turn to do " synergist " is also just not obvious.Therefore the pesticide resistance of " mite-killing pesticide " agricultural chemicals is anxious to be solved.
Task of the present invention is exactly the cross resistance relation that will overcome between agricultural chemicals, find the medicament of more synergy mutually and negative cross resistance relation (promptly two kinds of agricultural chemicals intersect the reduction pesticide resistance each other to insect), increase the physics insecticidal mechanism again, make the insecticidal mechanism of Multiple Pesticides cooperate jointly, reach and both can prevent and treat existing high drug-resistance insect, can prevent that again insect from producing new drug-fast purpose.
The objective of the invention is following realization:
The experiment proved that: except the malathion has the mutual synergistic effect chrysanthemum esters such as decises, the agricultural chemicals Methomyl also has the negative cross resistance relation to chrysanthemum esters such as decises.And do not have cross resistance to concern between malathion and the Methomyl.Common cooperation relation with three kinds of agricultural chemicals is equipped with other insecticidal mechanism again, just can solve the pesticide resistance problem.The present invention is exactly to be mixed effectively with pyrethrin pesticide and malathion and Methomyl, auxiliary tone is gone into a large amount of having and is made insect breathe the diesel oil of smothering action or machine oil as active solvent again, call in effective organic compound emulsifying agent of effective dose again, can constitute the novel drug-fast agricultural chemicals-high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate that overcomes.
The material proportion of this high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals is as follows:
Material content %(weight per volume)
Chrysanthemum ester 0.1～0.5
Malathion 3～30
Methomyl 1～20
Diesel oil or machine oil 40～90
Organic compound emulsifying agent 3～10
Above-mentioned five kinds of materials by certain proportioning, are dropped in the modulation kettle successively, fully stir, mixing and emulsifying is even, promptly gets the tan high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals of clarifying.
In order to make in the above-mentioned prescription preceding four kinds of materials can mixing and emulsifying even, used emulsifier be effective organic compound emulsifying agent.This agent can be the compound emulsifying agent of the Different Weight ratio of ester emulsifying agent (as: polyoxyethylene carboxylate etc.) and ethers emulsifier (as: alkylphenol polyoxyethylene etc.).Its weight ratio is: 1: 1, and 3: 7,4: 6,6: 4,7: 3.Effective emulsifier like this can make preceding four kinds of raw materials in the above-mentioned prescription under abundant stirring action, fully emulsified, with static permanent and not stratified after reaching emulsification and finishing, but make both long term storage of this agricultural chemicals-high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate, again thin up several times and be used for the farmland in use.
The described pyrethrin pesticide of this agricultural chemicals can be a decis, or cypermethrin, or cyhalothrin, or comes the good fortune spirit, or Uranus, or goes out and sweep profit.
This agricultural chemicals makes it overcome the agricultural chemicals pesticide resistance and increases owing to the synergistic effect and the negative cross resistance relation that have made full use of between some agricultural chemicals.Various compositions nearly all have insecticidal action in this agricultural chemicals, and have saved " the synergy phosphorus " of no insecticidal action own.The effective insect of the heavy dose that increases breathes asphyxiant-diesel oil or machine oil, this insecticidal action with physicochemical characteristic, it makes outside its death by suffocation except stopping up the breathing duct of insect, can also assist molten above-mentioned agricultural chemicals infiltrate in the insect body.This is because the wax on this effective diesel oil or machine oil and pest body surface is the matter of dissolving each other.Effectively heavy dose of mineral hydrocarbon oils portability emulsifications such as diesel oil above-mentioned three kinds of main insecticides, go deep into the insect body everywhere, not only to nervous system, and insect blood circulation system, respiratory system, digestive system etc. are all had suppress or destruction, make the position expanded range of insect exposed to pesticides, that is: make the drug resistance gene of its genetic variation, when having little time to duplicate or modify, just destroyed, destroyed the drug resistance gene of insect like this, overcome the drug-fast purpose of insect agricultural chemicals thereby reached.
The cooperation that cooperatively interacts between each composition in the agricultural chemicals of this invention promotes drug effect performance effect more fully separately.Therefore this agricultural chemicals is also toxic low, drug effect height, low-residual, pollution-free, safe in utilization characteristics.Especially this agricultural chemicals has utilized the effect of " negative cross resistance relation " and " insect breathes asphyxiant ", makes this agricultural chemicals to having drug-fast insect outstanding control efficiency be arranged.This agricultural chemicals can prevent that also insect from producing new pesticide resistance.Simultaneously, this agricultural chemicals is easy to use, and spraying times and dosage all are significantly smaller than single agent pesticide dosage, thereby has reduced the use cost of agricultural chemicals.This agricultural chemicals can be widely used in the cotton worm of control, grain worm, fruit tree pest insect, hundreds of insects such as forestry pest if use with spray-on process.
Embodiments of the invention are as follows:
Example one: produce 15.15% high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate
Press following prescription: (weight per volume)
Decis (former medicine 99%): 0.15%, malathion (former medicine 85%): 10%, Methomyl (former medicine 95%): 5%, diesel oil: 80%, organic compound emulsifying agent: 4.85%.
Example two: produce 30.25% high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate
Press following prescription: (weight per volume)
Come good fortune spirit (former medicine 99%): 0.25%, malathion (former medicine 85%): 20%, Methomyl (former medicine 95%): 10%, diesel oil or machine oil: 65%, organic compound emulsifying agent: 4.75%.
Example three: produce 45.45% high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate
Press following prescription: (weight per volume)
Go out and sweep profit (former medicine 45.45%): 0.45%, malathion (former medicine 85%): 25%, Methomyl (former medicine 95%): 15%, diesel oil or machine oil: 56%, organic compound emulsifying agent: 3.55%.
Material with above each prescription drops into respectively in the modulation kettle successively, and mixing and stirring after check, promptly gets the tan high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate series missible oil of clarifying.
Example four:
Serial any missible oil of high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals of above-mentioned production is diluted 1,000 times.Again with decis, the contrast of nuvacron agricultural chemicals.In the effect experiment of preventing and treating the resistance cotten aphid, the result: the drug effect of high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate is: 100%, and the contrast medicine all is worse than high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate.See attached list 1.
Example five:
Serial any missible oil of high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals with above-mentioned production dilutes 1,000 times, again with nuvacron, deltamethrin pesticide contrast.In the effect experiment of control resistant bollworm, the result: the drug effect of high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate is: 100%, and the contrast medicine all is worse than high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate.See attached list 2.
Claims (3)
1, a kind of high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals, it is except containing the chrysanthemum ester, the malathion, outside the Methomyl, also contain and be characterized as: the diesel oil of respiratory of insect asphyxiant or machine oil are as active solvent, and effective organic compound emulsifying agent; This agricultural chemicals material proportion is as follows:
Material content % (weight per volume)
Chrysanthemum ester 0.1～20
Malathion 3～30
Methomyl 1～20
Diesel oil or machine oil 40～90
Organic compound emulsifying agent 3～10
Above-mentioned five kinds of materials by proportioning, are dropped in the modulation kettle successively, fully stir, mixing and emulsifying is even, promptly gets the tan high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals of clarifying.
2, according to the described high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals of claim 1, it is characterized in that: the mixture that described effective organic compound emulsifying agent can be ester emulsifying agent and ethers emulsifier, its weight proportion is: 1: 1,3: 7,4: 6,6: 4,7: 3.
3, according to the described high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals of claim 1, it is characterized in that: the described the most handy decis of chrysanthemum ester or cypermethrin or cyhalothrin or come the good fortune spirit or Uranus or go out and sweep profit.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90105265 CN1047016A (en) | 1990-04-13 | 1990-04-13 | High oilness drug-resistance-extincted dimethylcyclopropanecarboxylate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90105265 CN1047016A (en) | 1990-04-13 | 1990-04-13 | High oilness drug-resistance-extincted dimethylcyclopropanecarboxylate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1047016A true CN1047016A (en) | 1990-11-21 |
Family
ID=4879092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 90105265 Pending CN1047016A (en) | 1990-04-13 | 1990-04-13 | High oilness drug-resistance-extincted dimethylcyclopropanecarboxylate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1047016A (en) |
-
1990
- 1990-04-13 CN CN 90105265 patent/CN1047016A/en active Pending
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |