CN1047014A - Eliminating and resisting phosphorus - Google Patents
Eliminating and resisting phosphorus Download PDFInfo
- Publication number
- CN1047014A CN1047014A CN90105266.3A CN90105266A CN1047014A CN 1047014 A CN1047014 A CN 1047014A CN 90105266 A CN90105266 A CN 90105266A CN 1047014 A CN1047014 A CN 1047014A
- Authority
- CN
- China
- Prior art keywords
- agricultural chemicals
- benzene
- eliminating
- missible oil
- drug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 23
- 239000011574 phosphorus Substances 0.000 title claims abstract description 23
- 239000003905 agrochemical Substances 0.000 claims abstract description 63
- 239000000203 mixture Substances 0.000 claims abstract description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 57
- 239000003814 drug Substances 0.000 claims description 14
- 239000002904 solvent Substances 0.000 claims description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 12
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000005949 Malathion Substances 0.000 claims description 9
- JXSJBGJIGXNWCI-UHFFFAOYSA-N diethyl 2-[(dimethoxyphosphorothioyl)thio]succinate Chemical compound CCOC(=O)CC(SP(=S)(OC)OC)C(=O)OCC JXSJBGJIGXNWCI-UHFFFAOYSA-N 0.000 claims description 9
- 229960000453 malathion Drugs 0.000 claims description 9
- 239000005916 Methomyl Substances 0.000 claims description 8
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 6
- 239000008267 milk Substances 0.000 claims description 6
- 210000004080 milk Anatomy 0.000 claims description 6
- 235000013336 milk Nutrition 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 150000001298 alcohols Chemical class 0.000 claims description 5
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 229940079593 drug Drugs 0.000 claims 1
- 239000000575 pesticide Substances 0.000 abstract description 21
- 241000238631 Hexapoda Species 0.000 abstract description 16
- 206010034133 Pathogen resistance Diseases 0.000 abstract description 8
- 230000000749 insecticidal effect Effects 0.000 abstract description 8
- 230000000857 drug effect Effects 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 230000002195 synergetic effect Effects 0.000 abstract description 6
- 230000000895 acaricidal effect Effects 0.000 abstract description 2
- 244000144977 poultry Species 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 description 5
- 241000255967 Helicoverpa zea Species 0.000 description 4
- 241000449794 Alabama argillacea Species 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- VEQMUQZKBLIXLT-UHFFFAOYSA-N 2,3-dimethylcyclopropane-1-carboxylic acid Chemical compound CC1C(C)C1C(O)=O VEQMUQZKBLIXLT-UHFFFAOYSA-N 0.000 description 1
- 241001600408 Aphis gossypii Species 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 241000176086 Sogatella furcifera Species 0.000 description 1
- -1 benzene alcohols Chemical class 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003986 organophosphate insecticide Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention is a kind of drug-fast agricultural chemicals of crop pests---eliminating and resisting phosphorus that overcomes.It belongs to the insecticidal/acaricidal agent of technical field of pesticide.This agricultural chemicals has utilized synergistic effect and the negative cross resistance relation between some agricultural chemicals, overcomes the pesticide resistance of insect to agricultural chemicals.Each composition of this agricultural chemicals can be worked in coordination with in using and be played a role, and makes its drug effect height, and is low to the person poultry toxicity, and low-residual is pollution-free, safe in utilization.Use this agricultural chemicals to be particularly suited for control and produced serious drug-fast each class pest.
Description
The present invention relates to the biocide of crop pests, especially a kind ofly overcome drug-fast agricultural chemicals-eliminating and resisting phosphorus.It belongs to the insecticidal/acaricidal agent of technical field of pesticide.
Current, the pesticide variety of crops is various, and organophosphorus insecticide is arranged, chrysanthemum ester class, series pesticide agent such as carbamates.These agricultural chemicals have played important function over a period to come to kill pests protection crops; yet long-term use along with these agricultural chemicals; the primary pest of some crops; as: cotton aphid; cotton bollworm; European red mite; rice fulgorids etc. have all produced serious pesticide resistance to above-mentioned agricultural chemicals; especially (be often referred to: cotten aphid and cotton bollworm with cotton-plant pest-insects; hereinafter to be referred as " cotton worm ") show as more very; its pesticide resistance degree does not almost have the agent of a kind of agricultural chemicals list can prevent and treat drug-fast cotton worm preferably up to thousands of times.The insecticidal mechanism of above-mentioned agricultural chemicals nearly all is that the nervous system to insect suppresses, and then kill pests.The pesticide resistance of insect may be because the resistant gene of insect is selected by a certain agricultural chemicals or variation of drug resistance taken place.This is because all biological forms or physiological status all are the results of long-term variation and heredity.Therefore, use a certain single agent agricultural chemicals for a long time, must make the gene of insect produce variation and have the pesticide resistance of the effective fatal gene action that adapts to a certain single agent agricultural chemicals.This have drug-fast mutant gene and must form similar multiple choices to almost consistent insecticidal mechanism, resists or avoid the effective fatal gene of above-mentioned a certain agricultural chemicals with this.Thereby insect can also be to producing cross resistance relation (that is: the intersection of the pesticide resistance between two or more agricultural chemicals improves its drug-fast relation mutually) between above-mentioned several agricultural chemicals, thereby facilitate the pesticide resistance surge of insect, imitate and deposited the use to cause most agricultural chemicals to fall to above-mentioned agricultural chemicals.
On nearest agricultural chemicals market, a kind of " mite-killing pesticide " agricultural chemicals has appearred, its mechanism of action separately (actual is the mutual synergistic effect of two kinds of agricultural chemicals) that utilizes two kinds of agricultural chemicals is different with desinsection worm spectrum, is equipped with " synergist " again and reaches and overcome drug-fast purpose.Itself no insecticidal action of used " synergist " of this mixture just can play synergistic effect to aforementioned two agricultural chemicals.But the synergistic effect of (having produced pesticide resistance now) this " synergist " is also just not obvious after in a single day aforementioned two kinds of agricultural chemicals are produced high anti-medicine by insect.Therefore the pesticide resistance of " mite-killing pesticide " agricultural chemicals is anxious to be solved.
Task of the present invention is exactly the cross resistance relation that will overcome between agricultural chemicals, find the medicament of more synergy mutually and negative cross resistance relation (promptly two kinds of agricultural chemicals intersect the reduction pesticide resistance each other to insect), make the insecticidal mechanism of Multiple Pesticides cooperate jointly, reach and both can prevent and treat existing high drug-resistance insect, can prevent that again insect from producing new drug-fast purpose.
The objective of the invention is following realization:
The experiment proved that: the malathion agricultural chemicals has mutual synergistic effect to nuvacron, and 'Miduowei ' agricultural chemical has the negative cross resistance relation to nuvacron again.And do not have cross resistance to concern between malathion and the Methomyl.Utilize the common cooperation relation of above-mentioned three kinds of agricultural chemicals, can solve the pesticide resistance problem of insect agricultural chemicals.The present invention is exactly to be mixed effectively with nuvacron and malathion and Methomyl, allocates the benzene class organic solvent of effective dose or benzene, alcohol organic solvent again into, can constitute the novel drug-fast agricultural chemicals-eliminating and resisting phosphorus that overcomes.
The material proportion of this eliminating and resisting phosphorus agricultural chemicals is as follows:
Material content %(weight per volume)
Nuvacron missible oil 6～45
Malathion missible oil 7～50
Methomyl milk oil 2～40
Benzene kind solvent or benzene, alcohols solvent 20～80
With above-mentioned first three plant material by prescription, drop into successively in the modulation kettle, after fully stirring, add the benzene kind solvent of effective dose or benzene, alcohols solvent again, can mixing and emulsifying more even, through stirring the tan missible oil-eliminating and resisting phosphorus agricultural chemicals that can clarify.
This agricultural chemicals is to be mixed with above-mentioned first three missible oil of planting agricultural chemicals, is equipped with hydrotropy, assistant for emulsifying agent-benzene kind solvent (as dimethylbenzene, benzene etc.) or benzene alcohols solvent (as benzene, ethanol mixture, dimethylbenzene, ethanol mixture) again.
This agricultural chemicals increases its gram agricultural chemicals pesticide resistance owing to the synergistic effect and the negative cross resistance relation that have made full use of between some agricultural chemicals.This agricultural chemicals has saved no insecticidal action " synergy phosphorus " organic matter, and the benzene class solution or the benzene alcohol solution of the effective dose of increase mainly are hydrotropy, assistant for emulsifying agent, prevents that occurring oil, water stratification or precipitation after ten minutes at the agricultural chemicals thin up takes place and establish.This agricultural chemicals mainly is that first three plants the component synergy, and cotten aphid, cotton bollworm are all had insecticidal effect.According to crops land for growing field crops insect the pesticide resistance rule taking place: general 3 years left and right sides time, the pesticide resistance to a certain agricultural chemicals occurs once.Use above-mentioned this agricultural chemicals-eliminating and resisting phosphorus and another kind of high oily eliminating and resisting phosphorus thus by turns, or chrysanthemic ester for perishing/resisting of insect pests and plant disease, or the high oilness drug-resistance-extincted dimethylcyclopropanecarboxylate agricultural chemicals.
Act synergistically between each composition in the agricultural chemicals of this invention, promote drug effect performance effect more fully separately.Therefore also toxic low, the high and low characteristics residual, pollution-free, safe in utilization of drug effect of this agricultural chemicals have especially been utilized " negative cross resistance relation ", make this agricultural chemicals to having drug-fast insect outstanding control efficiency be arranged.This agricultural chemicals is easy to use, and spraying times and dosage all are significantly smaller than the single-dose consumption, thereby has reduced the use cost of agricultural chemicals.If use this agricultural chemicals, can be widely used in the cotton worm of control, grain worm, the hundreds of insects on the crops such as fruit tree, forestry with spray-on process.
Embodiments of the invention are as follows:
Example one: produce 27% eliminating and resisting phosphorus;
Press following prescription: (weight per volume)
Nuvacron missible oil (former medicine 50%): 15%, malathion missible oil (former medicine 50%): 10%, methomyl milk oil (former medicine 20%): 2%, dimethylbenzene: 73%.
Example two: produce 50% eliminating and resisting phosphorus;
Press following prescription: (weight per volume)
Nuvacron missible oil (former medicine 50%): 25%, malathion missible oil (former medicine 50%): 15%, methomyl milk oil (former medicine 20%): 10%, dimethylbenzene: 50%.
Example three: produce 34% eliminating and resisting phosphorus;
Press following prescription: (weight per volume)
Nuvacron missible oil (former medicine 50%): 10%, malathion missible oil (former medicine 50%): 20%, methomyl milk oil (former medicine 20%): 4%, benzene: 66%.
First three kind agricultural chemicals with in above-mentioned three examples drops in the modulation kettle successively, fully after the stirring, adds the benzene kind solvent in respectively filling a prescription again, through stirring, gets final product the even eliminating and resisting phosphorus agricultural chemicals of emulsification again, and the tan missible oil that can obtain clarifying.
Example four:
With 1,000 times of serial any missible oil dilute with waters of the eliminating and resisting phosphorus agricultural chemicals of above-mentioned production.Decis, the nuvacron agricultural chemicals also dilutes identical multiple, agricultural chemicals in contrast again.Antagonism cotten aphid spraying control respectively, the result: the eliminating and resisting phosphorus drug effect is 100%, and the drug effect of contrast medicine all is worse than eliminating and resisting phosphorus.See attached list 1.
Example five:
With 1,000 times of serial any missible oil dilute with waters of the eliminating and resisting phosphorus agricultural chemicals of above-mentioned production.Decis, the nuvacron agricultural chemicals also dilutes identical multiple, agricultural chemicals in contrast again.Antagonism cotton bollworm spraying control respectively, the result: the eliminating and resisting phosphorus drug effect is 100%, and the drug effect of contrast medicine is worse than eliminating and resisting phosphorus.See attached list 2.
Claims (2)
1, a kind of eliminating and resisting phosphorus agricultural chemicals.It is characterized in that: this agricultural chemicals contains nuvacron missible oil, former medicines such as malathion missible oil and methomyl milk oil; This agricultural chemicals material proportion is as follows:
Material content % (weight per volume)
Nuvacron missible oil 6～45
Malathion missible oil 7～50
Methomyl milk oil 2～40
Benzene kind solvent or benzene, alcohols solvent 20～50
With above-mentioned first three plant material by proportioning, drop into successively in the modulation kettle, after fully stirring, add the benzene kind solvent of effective dose or benzene, alcohols solvent again, can mixing and emulsifying more even, through stirring the tan missible oil-eliminating and resisting phosphorus agricultural chemicals that can clarify.
2, according to the described eliminating and resisting phosphorus agricultural chemicals of claim 1, it is characterized in that: described benzene kind solvent can be dimethylbenzene or benzene etc.; Described benzene, alcohols solvent can be benzene, ethanol mixture or dimethylbenzene, ethanol mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN90105266.3A CN1047014A (en) | 1990-04-13 | 1990-04-13 | Eliminating and resisting phosphorus |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN90105266.3A CN1047014A (en) | 1990-04-13 | 1990-04-13 | Eliminating and resisting phosphorus |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1047014A true CN1047014A (en) | 1990-11-21 |
Family
ID=4879093
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN90105266.3A Pending CN1047014A (en) | 1990-04-13 | 1990-04-13 | Eliminating and resisting phosphorus |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1047014A (en) |
-
1990
- 1990-04-13 CN CN90105266.3A patent/CN1047014A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |