CN104663670A - Synergistic miticidal composition - Google Patents
Synergistic miticidal composition Download PDFInfo
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- CN104663670A CN104663670A CN201310627341.7A CN201310627341A CN104663670A CN 104663670 A CN104663670 A CN 104663670A CN 201310627341 A CN201310627341 A CN 201310627341A CN 104663670 A CN104663670 A CN 104663670A
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- 230000002195 synergetic effect Effects 0.000 title abstract description 9
- 230000003129 miticidal effect Effects 0.000 title abstract 2
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- -1 phenolic ester Chemical class 0.000 claims description 51
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- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
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- 239000005667 attractant Substances 0.000 description 1
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- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical class C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 1
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- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
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- APJLTUBHYCOZJI-VZCXRCSSSA-N cyenopyrafen Chemical compound CC1=NN(C)C(\C(OC(=O)C(C)(C)C)=C(/C#N)C=2C=CC(=CC=2)C(C)(C)C)=C1C APJLTUBHYCOZJI-VZCXRCSSSA-N 0.000 description 1
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- AQEFLFZSWDEAIP-UHFFFAOYSA-N di-tert-butyl ether Chemical compound CC(C)(C)OC(C)(C)C AQEFLFZSWDEAIP-UHFFFAOYSA-N 0.000 description 1
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- 238000007598 dipping method Methods 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
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- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
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- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 1
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229960000829 kaolin Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
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- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
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- 239000005011 phenolic resin Substances 0.000 description 1
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- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
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- 238000003672 processing method Methods 0.000 description 1
- ARENMZZMCSLORU-UHFFFAOYSA-N propan-2-yl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)OC(C)C)=CC=CC2=C1 ARENMZZMCSLORU-UHFFFAOYSA-N 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
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- 235000009566 rice Nutrition 0.000 description 1
- 235000021003 saturated fats Nutrition 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
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- 238000005507 spraying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
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- XOAAWQZATWQOTB-UHFFFAOYSA-N taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- WPALTCMYPARVNV-UHFFFAOYSA-N tolfenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(OC=3C=CC(C)=CC=3)=CC=2)=C1Cl WPALTCMYPARVNV-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the field of insecticides and relates to a synergistic miticidal composition containing two active ingredients A and B, wherein the ratio of the parts by weight of the ingredient A and the ingredient B is (1:100)-(100:1); and the active ingredient A is selected from a compound I shown by a structural formula in the specification, the active ingredient B is selected from an insecticide/acaricide, and the structure of the active ingredient A is as shown in the specification. The composition provided by the invention has the advantages of obvious synergistic effect, capability of delaying resistance and the like, and can be used for controlling various harmful insects.
Description
Technical field
The invention belongs to field of pesticides, relate to a kind of collaborative miticide composition.
Background technology
Insecticide has obvious effect in control agriculture and forestry injurious insect or urban health insect.
Chinese invention patent CN101875633 discloses a kind of pyrazolyl acrylonitrile compound and controls the purposes of insect pest and mite evil, wherein compound 5(is hereinafter referred to as chemical compounds I) can be used for preventing and treating various pests, evil mite, especially to evil mite, there is outstanding control efficiency.。
Insecticide containing single-activity component, control of insect uses continuously, easily makes insect develop immunity to drugs.By the insecticide of two kinds of active components by a certain percentage mixture become blending ingredients, often can improve preventive effect, reduce the consumption of active ingredient, cost-saving, the generation of pest resistance to insecticide can be delayed simultaneously.
Although disclose chemical compounds I general in prior art or its homologue can produce additional advantage and effect with other Mixture Use of Insecticides, the technical scheme of the binary pesticide composition containing chemical compounds I has no concrete open.
Summary of the invention
The object of the invention is a kind of collaborative miticide composition of exploitation, to meet the demand that agricultural and pest control aspect, urban health field day by day improve insecticide effect and kind is constantly updated.
For achieving the above object, the technical solution used in the present invention is:
A kind of collaborative miticide composition, composition contains A, B two kinds of active components, and the ratio of weight and number between component A and B component two component is 1:100-100:1; Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from desinsection/mite agent,
Described active component A structure is as follows:
chemical compounds I;
Described desinsection/mite agent is selected from Citrazon (Benzoximate), fenisobromolate (Bromopropylate), dicofol (Dicofol), second mite ester, dinobuton (Dinobuton), dinitro crotons phenolic ester (Dinocap), Dinocap-4, Dinocap-6, 4,6-Dinitro-O-Cresol (DNOC), chinomethionat (Chinomethionat), Thioquinox, Zo insect amide (Tolfenpyrad), sulfanilamide (SN) mite ester (Amidoflument), Arsenousoxide, dichlofluanid (Dichlofluanid), Sulfur (Sulfur), phonetic mite amine, fluacrypyrim (Fluacrypyrim), acequinocyl (Acequinocyl), hydramethylnon (Hydramethylnon), cyflumetofen (Cyflumetofen), nitrile pyrrole mite ester (Cyenopyrafen) or SYP-10898(SYP-10898, see " world pesticide is complete works of " insecticide volume, Chemical Industry Press, 2012.2 first editions: P768-769).
Described active component A is chemical compounds I, and active component B is preferably phonetic mite amine; The ratio of weight and number of two kinds of active components is optimized for 1:20-100:1;
Described active component A is chemical compounds I, and active component B is preferably dicofol; The ratio of weight and number of two kinds of active components is optimized for 1:1-20:1;
Described active component A is chemical compounds I, and active component B is preferably SYP-10898; The ratio of weight and number of two kinds of active components is optimized for 1:10-10:1.
Synergistic effect composition of the present invention can provide in finished product preparation form.Therefore, the present invention also comprises a kind of insecticides of dosage form.Take composition as active component, make missible oil, suspending agent, water-dispersible granules, aqueous emulsion, soluble concentrate, wetting powder, water dispersible oil suspending agent etc. as required.In preparation, the cumulative amount of the active component of composition is between 0.5% ~ 95%, and preferred cumulative amount is between 1%-85%.In composition of the present invention, the content of active component depends on amount of application when being used alone, and also depends on mixed ratio and synergistic effect degree.The optimum range of active component content is different according to the preparation type of composition.
The preparation of composition finished product preparation of the present invention can be prepared by common processing method, after mixing with liquid-carrier (solvent) or solid carrier by active substance, add one or more surfactants as emulsifier, dispersant, wetting agent, adhesive, stabilizing agent and defoamer etc.Containing at least one carrier and at least one surfactant in usual composition.In all cases, should guarantee that present composition active component is uniformly distributed.
Missible oil contains the active component of 10 ~ 50% usually, 2 ~ 20% emulsifier, other additive such as stabilizing agent, the bleeding agent etc. of 0 ~ 20%, and solvent (if desired also containing cosolvent).
Suspending agent needs sand milling usually, to obtain stable non-deposited flowable product.Usually containing 5 ~ 75% active components in suspending agent, 5 ~ 15% dispersants, 4 ~ 10% antifreezing agents, other additive of 0 ~ 10% is as defoamer, preservative, stabilizing agent, bleeding agent and thickener, and liquid-carrier surplus.
Water-dispersible granules makes 10 ~ 100 international standard sieve mesh (1.676 ~ 0.152mm) particles usually, can by extruding, dipping or Spray granulation method preparation.Usual water-dispersible granules contains the active component of 0.5 ~ 75% and surfactant such as stabilizing agent, wetting dispersing agent, disintegrant and the adhesive of 5 ~ 20%, and inert carrier surplus.
Wetting powder contains the active component of 10 ~ 85% usually, except solid inert carrier, usually contains the dispersant of 3 ~ 10%, can also contain stabilizing agent and (or) other additive of 0 ~ 10%, such as bleeding agent or sticker.
Aqueous emulsion is that former medicine, organic solvent, surfactant mixing are formed oil phase; Water, antifreezing agent are mixed, becomes transparent and homogeneous aqueous phase.With high-shear emulsion machine high speed shear oil phase, slowly aqueous phase is added oil phase, usual active ingredient 1 ~ 60%, surfactant 5 ~ 20%, antifreezing agent 2 ~ 10%, water surplus simultaneously.
Microemulsion is mixed former medicine, organic solvent, surfactant, water, becomes transparent and homogeneous aqueous phase.Usual active ingredient 1 ~ 50%, surfactant 10 ~ 40%, antifreezing agent 2 ~ 10%, water surplus.
Soluble liquid is mixed active component, organic solvent, surfactant, becomes transparent and homogeneous liquid.Usual active ingredient 1 ~ 50%, surfactant 6 ~ 20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added sand milling in sand mill, until particle diameter is qualified, and usual active ingredient 2 ~ 60%, surfactant 6 ~ 20%, oil based vehicle surplus.
Moisture dispersion liquid and emulsion (composition that missible oil as of the present invention in dilute with water, wetting powder or concentrate obtain) are also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have dense thick paste-like consistency.
The preparation of composition finished product preparation of the present invention can adopt known (liquid or solid) carrier of those skilled in the art and various auxiliary agent.Such as include but not limited to following all kinds of material.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., as one or more in toluene, dimethylbenzene, acetone, cyclohexanone, acetonitrile, benzene, cyclohexane, isopropyl alcohol, ethylene glycol, sorbierite, methyl alcohol, ethanol, butanols, dimethyl formamide, dimethyl sulfoxide (DMSO), N-methyl-pyrrolidon, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, benzinum, methyl oleate, methylated soya oil or the molten fiber of methyl etc.The mixture of different liquids is often applicable.
Suitable solid carrier comprises clay that is natural or synthesis and silicate, and the solid carrier being applicable to pulvis comprises the mineral matter (as microdispersed silicic acid or aluminium oxide) ground of the White Carbon black of natural formation, rock dust, chalk, quartz, clay, imvite, sodium sulphate, white carbon, silica, diatomite, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, potter's clay and synthesis.The particulate vector be applicable to comprises the broken synthesis particle made with natural rock such as calcite, marble, float stone, sepiolite and dolomite of classification and by the powder of organic matter and inorganic matter.
Suitable co-solvents is one or more in methyl alcohol, phenol, isoamyl alcohol, dimethyl sulfoxide (DMSO), tributyl phosphate, ethyl acetate, butanone, dimethyl formamide, dimethyl sulfoxide (DMSO), N-methyl-pyrrolidon, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether (YUS-SC3), diphenyl phenolic group polyoxyethylene (n
18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, agriculture breast YUS-D935, agriculture breast YUS-CP120, agriculture breast YUS-A41B, agriculture breast YUS-D3020, agriculture breast NP-10, agriculture breast NP-15 etc.
Suitable dispersant can be sodium lignin sulfonate, calcium lignosulfonate, the sodium salt of alkyl naphthalene sulfonic acid condensation polymer, polycarboxylate salt dispersant GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalenesulfonic acid-formaldehyde condensate, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N-methyl-oleoyl-sodium taurocholate, detergent LS, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, dispersant SP-28F, dispersant SP-SC3, reach profit dispersant D909S, alkylaryl APEO, alkylpolyoxyethylene phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkyl amide taurate, alkylnaphthalene sulfonate formaldehyde condensation products (NNO), ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products, N-methyl-fatty acyl group-sodium taurocholate, alkylphenol polyoxyethylene formaldehyde condensation products, nekal (Nekal BX), dibutyl naphthalenesulfonic acid formaldehyde condensation products, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, alkylphenol-polyethenoxy based phosphates, dispersant YUS-NV1203, dispersant YUS-NV1420, dispersant YUS-WG4, dispersant YUS-TG285, dispersant YUS-WP1, dispersant YUS-110, dispersant YUS-EP60P, dispersant YUS-CH1100, Deng.
Suitable wetting agent can be lauryl sodium sulfate, sodium sulphate, Morwet EFW, wetting agent SP-SC3266, wetting agent YUS-LXC, wetting agent YUS-204, isopropyl naphthalene sulfonate, alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sldium lauryl sulfate, neopelex, calcium dodecyl benzene sulfonate, Negel aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether etc.
Suitable thickener can be synthesis (as carbonyl methylol, polyvinyl alcohol, polyvinyl acetate) or natural water-soluble polymer (as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, PEG 8000, phenolic resins, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), adds in preparation with powder, particle or latex form.
Suitable defoamer is bubble enemy, silicone, C8-10 fatty alcohol, phosphoric acid ester, C10-20 saturated fat acids (as capric acid) and acid amides etc.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, carboxymethyl cellulose and sodium alginate etc.
Aerosol can be made during for preventing and treating city insect, need to add propellant wherein, also bait formulation composition be can make, except containing except active component, also the foodstuff of insect's food-taking, optional attractant and optional wetting agent are suitable for containing one or more.
The present invention also comprises the present composition and is prepared into the purposes that Insecticiding-miticiding preparation controls agriculture and forestry injurious insect or urban health insect.Specifically be suitable for the multiple important pest of control as blister mite, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, panonychus citri, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite etc., city insect is as termite, blattaria, ant, fly class, mosquito class etc.For fruit tree as apple, pears, citrus, lichee etc., Cereal is as wheat, paddy rice etc., and beans is as soybean, Kidney bean etc., and cotton, vegetables are as wild cabbage, cauliflower, Chinese cabbage, rape, tomato, capsicum and flowers.During for preventing and treating city insect, may be used for family, various public place, office space and trees etc.
The present invention also comprises a kind of method controlling insect pest, the present composition can be imposed on the medium of insect or its growth needing to control with effective dose.The comparatively suitable effective dose of usual selection is per hectare 10 grams to 500 grams, and preferred effective dose is per hectare 15 grams to 100 grams.
Separately, demonstrate composition of the present invention through indoor biological determination of activity and there is synergistic effect.Such as, chemical compounds I and dicofol, within the scope of 1:1-20:1, with phonetic mite amine within the scope of 1:20-100:1, with SYP-10898 within the scope of 1:10-10:1, show certain synergistic effect to Tetranychus cinnabarinus.
Tool of the present invention has the following advantages:
1. composition of the present invention shows obvious synergistic effect in certain ratio range, improves the control efficiency of this compound to insect.
2. the present composition reduces the using dosage of compound in the application, thus reduces use cost, reduces environmental pollution.
3. in the present composition, the mechanism of action of each active ingredient is different, there is not the problem of cross resistance, can delay the generation of pest resistance to insecticide with its pest control, and improve the control efficiency of antagonism population.
Embodiment
Following specific embodiment is for further describing the present invention, but the present invention is only limitted to absolutely not these examples.In embodiment, each component percentages or proportioning are all by weight.Active component in each formula calculates with effective content, and each material of combination species all prepares by usual manner.
Formulation Example
The preparation of embodiment 1,21% dicofol chemical compounds I missible oil
By recipe requirements, add 1 part of dicofol respectively, 20 parts of chemical compounds Is, 5 parts of agriculture breast 0201B, 5 parts of agriculture breast 507#, 2 parts of agriculture breast 1601#, 8 parts of methyl alcohol, dimethylbenzene complement to 100% and add in mixing kettle, be uniformly mixed, use hot bath heating for dissolving if desired, 21% dicofol chemical compounds I missible oil can be obtained.
Can also by the Citrazon described by dicofol alternative costs specification, fenisobromolate, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 21% new active component B chemical compounds I missible oil.The preparation of embodiment 2,21% Citrazon chemical compounds I wetting powder
By recipe requirements, 1 part of Citrazon, 20 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 4 parts of naphtholsulfonic acid formaldehyde condensation products sodium salts, 4 parts of dispersant YUS-WP1,5 parts of White Carbon blacks, precipitated calcium carbonates are complemented to 100% and fully mix, after ultra-fine pulverizer disintegrating, 21% Citrazon chemical compounds I wetting powder can be obtained.
Can also by the fenisobromolate described by Citrazon alternative costs specification, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 21% new active component B chemical compounds I wetting powder.
The preparation (1:1) of embodiment 3,40% chinomethionat chemical compounds I wetting powder
By recipe requirements; 20 parts of chinomethionats, 20 parts of chemical compounds Is, 2 parts of lauryl sodium sulfate, 3 parts of N-methyl-oleoyl-sodium taurocholates, 2 parts of methanonaphthalene sodium sulfonates, 4 parts of naphthalenesulfonic acid-formaldehyde condensates, 2 parts of detergent LS, 10 parts of White Carbon blacks, bentonites are complemented to 100% and fully mix; after ultra-fine pulverizer disintegrating, 40% chinomethionat chemical compounds I wetting powder can be obtained.
Can also by the Citrazon described by chinomethionat alternative costs specification, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 40% new active component B chemical compounds I wetting powder.
The preparation of embodiment 4,22% fenisobromolate chemical compounds I aqueous emulsion
By recipe requirements, by 2 parts of fenisobromolates, 20 parts of chemical compounds Is, 4 parts of polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, 6 parts of agricultures breast OX-2681,2 parts of agriculture breast 1601#, 8 parts of dimethylbenzene, 5 parts of tributyl phosphates add in mixing kettle, be uniformly mixed, make to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is joined oil phase, 22% fenisobromolate chemical compounds I aqueous emulsion of favorable dispersibility can be obtained.
Can also by the Citrazon described by fenisobromolate alternative costs specification, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 22% new active component B chemical compounds I aqueous emulsion.
The preparation (1:1) of embodiment 5,40% dicofol chemical compounds I aqueous emulsion
By recipe requirements, by 20 parts of dicofols, 20 parts of chemical compounds Is, 5 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 8 parts of agricultures breast 2201#, 5 parts of agriculture breast 0201B, 10 parts of cyclohexanone, 10 parts of dimethylbenzene add in mixing kettle, be uniformly mixed, make to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is joined oil phase, 40% dicofol chemical compounds I aqueous emulsion of favorable dispersibility can be obtained.
Can also by the Citrazon described by dicofol alternative costs specification, fenisobromolate, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 40% new active component B chemical compounds I aqueous emulsion.
Embodiment 6,60% Citrazon chemical compounds I water-dispersible granules (1:1)
By recipe requirements; 30 parts of Citrazons, 30 parts of chemical compounds Is, 3 parts of alkyl-diethylene glycol ether-sodium sulfonates, 5 parts of dispersant YUS-WG4,3 parts of naphtholsulfonic acid formaldehyde condensation products, 8 parts of sodium sulphate, 5 parts of soluble starches, diatomite are complemented to 100% and are added together; carry out co-grinding; again after adding water and mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope), 60% Citrazon chemical compounds I water-dispersible granules can be obtained.
Can also by the fenisobromolate described by Citrazon alternative costs specification, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 60% new active component B chemical compounds I water-dispersible granules (1:1).
Embodiment 7,44% chinomethionat chemical compounds I water-dispersible granules
By recipe requirements; 4 parts of chinomethionats, 40 parts of chemical compounds Is, 4 parts of methyl naphthalene sulfonate formaldehyde condensates, 5 parts of dispersant YUS-TG285,1 part of Morwet EFW, 5 parts of PEG 8000s, 10 parts of sodium sulphate, attapulgites are complemented to 100% and are added together; carry out co-grinding; again after adding water and mediating, add in the comminutor that certain specification screen cloth is housed and carry out granulation.And then drying, screening (by screen cloth scope), 44% chinomethionat chemical compounds I water-dispersible granules can be obtained.
Can also by the Citrazon described by chinomethionat alternative costs specification, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 44% new active component B chemical compounds I water-dispersible granules.
Embodiment 8,12%SYP-10898 chemical compounds I suspending agent
By recipe requirements, by 2 parts of SYP-10898,10 parts of chemical compounds Is, 4 parts of polycarboxylate salt dispersant GY-D04,2 parts of methanonaphthalene sodium sulfonates, 2 parts of agriculture breast 1601#, 4 parts of agriculture breast 0201B, 0.1 part of xanthans, 0.5 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water, join in blending tank successively and mix, first carry out coarse crushing, homogenize through high shear, then be pumped in sand mill and carry out fine grinding, the granularity of sand milling material is detected with particles distribution instrument, after particle diameter reaches standard-required, filter, 12%SYP-10898 chemical compounds I suspending agent can be obtained.
Can also by the Citrazon described by SYP-10898 alternative costs specification, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, forms 12% new active component B chemical compounds I suspending agent.
Example 9,50% Sulfur chemical compounds I suspending agent (1:1)
By recipe requirements; by 25 parts of Sulfurs, 25 parts of chemical compounds Is, 3 parts of sodium lignin sulfonates, 5 parts of N-methyl-oleoyl-sodium taurocholates, 2 parts of dispersant SP-SC3, Nongru-700 #, 0.1 part of xanthans, 0.2 part of white carbon, 5 parts of ethylene glycol, complement to 100% with water; join in blending tank successively and mix; first carry out coarse crushing, homogenize through high shear; then be pumped in sand mill and carry out fine grinding; the granularity of sand milling material is detected with particles distribution instrument; after particle diameter reaches standard-required; filter, 50% Sulfur chemical compounds I suspending agent can be obtained.
Can also by the Citrazon described by Sulfur alternative costs specification, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 50% new active component B chemical compounds I suspending agent (1:1).
Embodiment 10,21% fenisobromolate chemical compounds I microemulsion
By recipe requirements, by 1 part of fenisobromolate, 20 parts of chemical compounds Is, 6 parts of triphenyl vinyl phenol polyoxyethylene (n
20) ether phosphoric acid triethanolamine salt, 4 parts of agricultures breast NP-15,3 parts of castor oil polyoxyethylene ethers, 6 parts of ethyl acetate, 5 parts of acetonitriles are added together, make to be dissolved into homogeneous oil phase, surplus water complements to 100%, under high velocity agitation, aqueous phase joined oil phase or oil phase is joined aqueous phase, forming 21% fenisobromolate chemical compounds I microemulsion of favorable dispersibility.
Can also by the Citrazon described by fenisobromolate alternative costs specification, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 21% new active component B chemical compounds I microemulsion.
Embodiment 11,21% dinobuton chemical compounds I soluble concentrate
By recipe requirements, by 1 part of dinobuton, 20 parts of chemical compounds Is, 15 parts of agriculture breast 507#, 5 parts of agriculture breast 1601#, 6 parts of agriculture breast 100#, 12 parts of dimethyl formamides, 10 parts of methyl alcohol, 20 parts of dimethyl sulfoxide (DMSO)s, 17 parts of molten fibers mixture of methyl are even, use hot bath heating for dissolving if desired, 15% avermectin compounds I soluble concentrate can be obtained, the molten fiber of methyl complements to 100% and mix, use hot bath heating for dissolving if desired, 21% dinobuton chemical compounds I soluble concentrate can be obtained.
Can also by the Citrazon described by dinobuton alternative costs specification, fenisobromolate, dicofol, second mite ester, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 21% new active component B chemical compounds I soluble concentrate.
The phonetic mite amines I water dispersible oil suspending agent of embodiment 12,21%
By recipe requirements, 1 part of phonetic mite amine, 20 parts of chemical compounds Is, 3 parts of agriculture breast 0201B, 4 parts of dispersant YUS-110,5 parts of agriculture breast S-80,3 parts of white carbons, 3 parts of agriculture breast 500#, methyl oleate are complemented to 100% to join in blending tank successively and mix, first carry out coarse crushing, homogenize through high shear, then be pumped in sand mill and carry out fine grinding, the granularity of sand milling material is detected with particles distribution instrument, after particle diameter reaches standard-required, filter, 21% phonetic mite amines I water dispersible oil suspending agent can be obtained.
Can also by the Citrazon described by phonetic mite amine alternative costs specification, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4, one in the desinsection/mite agent such as 6-Dinitro-O-Cresol, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester, SYP-10898, forms 21% new active component B chemical compounds I water dispersible oil suspending agent.
Indoor biological determination of activity
The composition of embodiment 13 containing chemical compounds I is to the synergism determination of Tetranychus cinnabarinus
For examination object: Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), become mite, the sensitive strain of indoor feeding.
Test condition: temperature: 24 ~ 26 DEG C, humidity: RH60%, illumination: L:D=14:10
Test method: adopt pot-spraying method.The potted plant Kidney bean seedling of sizing (2 true leaves) of hot-house culture, stays a slice true leaf, is connected into mite 40-60 head thereon.Adopt Airbrush spray-on process liquid process examination material, naturally dry in the shade.First process blank, then repeat aforesaid operations from low to high according to experimental scheme dosage, often process 4 times and repeat.Be placed in observation ward by the examination worm after process, routine observation examination worm response situation, 72h " Invest, Then Investigate " is dead, borer population of living, and calculates lethality.
Evaluate and adopt Bliss method, the method is one of classical way evaluating mixture effect.The independent joint action concept that Bliss proposes according to it is thought, theoretical lethality P during Mixture Use of Insecticides can calculate with following formula:
P=P
m+P
n(1-P
m)
P
mit is the lethality (%) of the first active component target when concentration is m; P
nthe lethality (%) of target when be the second active component working concentration being n.
If two kinds of active components are being greater than theoretical lethality P with the actual of the rear target of finite concentration mixing, are then judging that two kinds of active components are used in combination under setting concentration and there is synergistic effect, otherwise be then antagonism.
The results are shown in Table 1.
Table 1 chemical compounds I uses with 3 compound such as dicofols synergism determination Tetranychus cinnabarinus being become to mite
Claims (10)
1. a collaborative miticide composition, is characterized in that: composition contains A, B two kinds of active components, and the ratio of weight and number between component A and B component two component is 1:100-100:1; Active component A is selected from the chemical compounds I shown in following structural formula, and active component B is selected from desinsection/mite agent,
Described active component A structure is as follows:
chemical compounds I.
2., according to composition according to claim 1, it is characterized in that:
Described desinsection/mite agent is selected from Citrazon, fenisobromolate, dicofol, second mite ester, dinobuton, dinitro crotons phenolic ester, Dinocap-4, Dinocap-6,4,6-Dinitro-O-Cresols, chinomethionat, Thioquinox, Zo insect amide, sulfanilamide (SN) mite ester, Arsenousoxide, dichlofluanid, Sulfur, phonetic mite amine, fluacrypyrim, acequinocyl, hydramethylnon, cyflumetofen, nitrile pyrrole mite ester or SYP-10898.
3. according to the composition described in claim 1 or 2, it is characterized in that: described active component A is chemical compounds I, active component B is selected from phonetic mite amine; The ratio of weight and number of two kinds of active components is 1:20-100:1.
4. according to the composition described in claim 1 or 2, it is characterized in that: described active component A is chemical compounds I, and active component B is selected from dicofol; The ratio of weight and number of two kinds of active components is 1:1-20:1.
5. according to the composition described in claim 1 or 2, it is characterized in that: described active component A is chemical compounds I, and active component B is selected from SYP-10898; The ratio of weight and number of two kinds of active components is 1:10-10:1.
6. according to composition according to claim 1, it is characterized in that: composition can be configured to missible oil, suspending agent, water-dispersible granules, aqueous emulsion, microemulsion, soluble concentrate, wetting powder or water dispersible oil suspending agent.
7. according to composition according to claim 6, it is characterized in that: in composition, the cumulative amount of active component is between 0.5%-95%.
8. according to composition according to claim 7, it is characterized in that: in composition, the cumulative amount of active component is between 1%-85%.
9. one kind according to collaborative miticide composition application according to claim 1, it is characterized in that: described composition for the preparation of insecticidal/acaricidal agent, for controlling pest or urban health insect.
10., according to collaborative miticide composition application according to claim 8, it is characterized in that: in effective dose, the described composition being prepared into insecticidal/acaricidal agent is imposed on the medium of insect or its growth needing to control.
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