CN1046553A - Hard Surface Cleaning Composition - Google Patents
Hard Surface Cleaning Composition Download PDFInfo
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- CN1046553A CN1046553A CN90102261A CN90102261A CN1046553A CN 1046553 A CN1046553 A CN 1046553A CN 90102261 A CN90102261 A CN 90102261A CN 90102261 A CN90102261 A CN 90102261A CN 1046553 A CN1046553 A CN 1046553A
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- surface cleaning
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- 239000000203 mixture Substances 0.000 title claims abstract description 74
- 238000004140 cleaning Methods 0.000 title claims abstract description 18
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 150000003863 ammonium salts Chemical class 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 claims description 6
- NTKBNCABAMQDIG-UHFFFAOYSA-N trimethylene glycol-monobutyl ether Natural products CCCCOCCCO NTKBNCABAMQDIG-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical group NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000011877 solvent mixture Substances 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- -1 alkylbenzene sulfonates Chemical class 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 3
- 239000005357 flat glass Substances 0.000 description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 2
- GZMAAYIALGURDQ-UHFFFAOYSA-N 2-(2-hexoxyethoxy)ethanol Chemical compound CCCCCCOCCOCCO GZMAAYIALGURDQ-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 150000004996 alkyl benzenes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 150000008051 alkyl sulfates Chemical class 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- LNFLHXZJCVGTSO-UHFFFAOYSA-N 1-(3-butoxypropoxy)propan-1-ol Chemical compound CCCCOCCCOC(O)CC LNFLHXZJCVGTSO-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001074085 Scophthalmus aquosus Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008162 cooking oil Substances 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- SATVIFGJTRRDQU-UHFFFAOYSA-N potassium hypochlorite Chemical compound [K+].Cl[O-] SATVIFGJTRRDQU-UHFFFAOYSA-N 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0043—For use with aerosol devices
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
公开了硬表面清洗组合物，它含有阴离子表面活性剂铵盐，单乙醇铵、二乙醇铵或三乙醇铵或它们的混合物，以及一种溶剂体系；该组合物呈碱性pH。A hard surface cleaning composition is disclosed comprising an anionic surfactant ammonium salt, monoethanolammonium, diethanolammonium or triethanolammonium, or mixtures thereof, and a solvent system; the composition has an alkaline pH.
Description
本发明涉及能同时提供良好的清洗效能与光亮效果的硬表面清洗组合物。The present invention relates to hard surface cleaning compositions which provide both good cleaning performance and gloss.
硬表面清洗组合物在工艺上已众所周知，多年来其清洗效能已大有改进。但是在集中注意清洗效能的同时遇到了一个新问题，即，用这些组合物时除非对已清洗过的表面再进行淋洗，否则其光亮效果不好。也就是说，用一种不淋洗型的硬表面清洗剂，良好的光亮效果与优良的清洗性能不能兼得。确实，大多数组合物在使用时在清洗过的表面上留下条纹和/或残留膜，结果所清洗过的表面外观不好。Hard surface cleaning compositions are well known in the art and their cleaning performance has improved considerably over the years. But while focusing on cleaning performance, a new problem has been encountered, namely, the poor gloss effect of these compositions unless the cleaned surface is rinsed again. That is to say, with a non-rinse type hard surface cleaner, good gloss effect and excellent cleaning performance cannot be combined. Indeed, most compositions leave streaks and/or a residual film on the cleaned surface upon use, resulting in an unappealing appearance of the cleaned surface.
在用硬表面清洗剂清洗窗玻璃或镜子时上述问题尤其讨厌，因为残留膜更为明显。This problem is especially annoying when cleaning windowpanes or mirrors with hard surface cleaners, since the residual film is more pronounced.
就窗玻璃而言，曾配制了形成“挥发性”清洗剂的组合物，它有效地解决了这一问题;但是，不是所有表面都能用这类组合物清洗，因为它们常常含有会溶解某些物质的溶剂。另外，这些组合物还有其它缺点，例如易燃性和有害的气味。In the case of window panes, compositions which form "volatile" cleaners have been formulated which effectively address this problem; however, not all surfaces can be cleaned with such compositions as they often contain certain solvents for these substances. Additionally, these compositions have other disadvantages such as flammability and noxious odour.
作为一种可采用的方法，曾经配制了一些氨含量较高的组合物。就成膜/条纹问题而言，用氨是含人满意的，但是从安全及产品的审美角度来看，则很不理想。确实，氨的存在使产品的气味难闻。As an alternative, some compositions having a higher ammonia content have been formulated. The use of ammonia is satisfactory in terms of filming/streaking, but far from ideal from a safety and product aesthetic standpoint. Indeed, the presence of ammonia makes the product smell bad.
美国专利3，591，510号公开的硬表面清洗剂含有可能是铵盐形 式的表面活性剂、一种混合溶剂、和一种水溶性助洗剂。U.S. Patent No. 3,591,510 discloses hard surface cleaners containing surfactants, possibly in the form of ammonium salts, a mixed solvent, and a water-soluble builder.
美国专利3，591，509号公开的组合物含有可能是铵盐形式的表面活性剂、一种混合溶剂、一种水溶性助洗剂和一种水溶性羧甲基纤维素。U.S. Patent No. 3,591,509 discloses compositions comprising a surfactant, possibly in the form of an ammonium salt, a mixed solvent, a water-soluble builder and a water-soluble carboxymethylcellulose.
英国专利2160887号公开了一种组合物，它含有一种阴离子表面活性剂，水溶性与水不溶性醇以及一种有机溶剂。British Patent No. 2160887 discloses a composition comprising an anionic surfactant, water-soluble and water-insoluble alcohols and an organic solvent.
日本专利62034998公开的组合物含有一种阴离子表面活性剂盐，一种水溶性溶剂，氯氧化钠或钾，以及单乙醇胺。Japanese Patent No. 62034998 discloses a composition containing an anionic surfactant salt, a water-soluble solvent, sodium or potassium oxychloride, and monoethanolamine.
日本专利58101198号公开的组合物含有链烷醇胺、一种阴离子与非离子表面活性剂的混合物和聚丙二醇。Japanese Patent No. 58101198 discloses compositions comprising alkanolamines, a mixture of anionic and nonionic surfactants and polypropylene glycol.
本发明的目的之一是提供液态的硬表面清洗组合物，即使在不淋洗的情况下使用时，它们也具有优良的清洗效能和良好的光亮效果。It is an object of the present invention to provide liquid hard surface cleaning compositions which have good cleaning performance and good shine even when used without rinsing.
本发明的另一目的是提供液态的硬表面清洗组合物，它能用于任何表面，对玻璃尤其有效。Another object of the present invention is to provide liquid hard surface cleaning compositions which can be used on any surface and are especially effective on glass.
本发明的另一目的是提供一种适用于任何分散装置、尤其是适用于喷雾分散器的硬表面清洗剂。Another object of the present invention is to provide a hard surface cleaner suitable for use in any dispensing device, especially in spray dispensers.
本发明还有一个目的，即，提供不含氨、因此没有有害气味的组合物。It is also an object of the present invention to provide compositions which are free of ammonia and therefore have no harmful odour.
由下面的叙述可以看出本发明的其它目的和优点。Other objects and advantages of this invention will appear from the following description.
本发明提供了硬表面清洗组合物，其pH至少为8.5，含有：The present invention provides hard surface cleaning compositions having a pH of at least 8.5 comprising:
-占组合物总重量0.04%至0.6%的阴离子表面活性剂铵盐，- from 0.04% to 0.6% by weight of the total composition of ammonium salts of anionic surfactants,
-占组合物总重量0.2%至2.0%的单乙醇胺、二乙醇胺或三乙醇胺，或它们的混合物，- from 0.2% to 2.0% by weight of the total composition of monoethanolamine, diethanolamine or triethanolamine, or mixtures thereof,
-占组合物总重量3%至14%的溶剂体系。- A solvent system comprising from 3% to 14% by weight of the total composition.
本发明的组合物含有阴离子表面活性剂铵盐，其含量为组合物总重量的0.04%至0.6%，最好是从0.07%至0.45%。The compositions of the present invention contain anionic surfactant ammonium salts in an amount of from 0.04% to 0.6%, preferably from 0.07% to 0.45%, by weight of the total composition.
这里所用的阴离子表面活性剂包括烷基苯磺酸盐或硫酸盐、链烷烃磺酸盐、烯属磺酸盐、脂肪酸磺酸盐和脂肪酸酯磺酸盐，以及在洗涤剂工业、中所熟知的类似物质。乙氧基化的品种也适用，例如烷基聚乙氧基硫酸盐和磺化琥珀酸盐。Anionic surfactants used herein include alkylbenzene sulfonates or sulfates, paraffin sulfonates, olefin sulfonates, fatty acid sulfonates and fatty acid ester sulfonates, as well as those used in the detergent industry, Well known similar substances. Ethoxylated varieties are also suitable, such as alkyl polyethoxy sulfates and sulfosuccinates.
适用于本明的较好的表面活性剂是C8-C18烷基苯磺酸盐和C8-C18烷基聚乙氧基硫酸盐。Preferred surfactants for use in the present invention are C 8 -C 18 alkyl benzene sulfonates and C 8 -C 18 alkyl polyethoxy sulfates.
用于实施本发明的最好是C8-C18直链烷基苯磺酸盐和3倍乙氧基化C8-C18烷基硫酸盐的混合物。Most preferred for use in the practice of this invention are mixtures of C 8 -C 18 linear alkyl benzene sulfonates and 3 times ethoxylated C 8 -C 18 alkyl sulfates.
组合物中的所有的阴离子表面活性剂均以其铵盐形式存在。All anionic surfactants in the composition are present in the form of their ammonium salts.
本发明的组合物还含有占组合物总重量0.2%至2.0%的单乙醇胺、二乙醇胺或三乙醇胺、或它们的混合物，最好是从0.35%至0.75%。组合物最好是含有上述含量的单乙醇胺。The compositions of the present invention also contain from 0.2% to 2.0% by weight of the total composition of monoethanolamine, diethanolamine or triethanolamine, or mixtures thereof, preferably from 0.35% to 0.75%. The composition preferably contains monoethanolamine in the above-mentioned levels.
重要的是，本发明的组合物的pH至少为8.5，最好是10.5。It is important that the compositions of the present invention have a pH of at least 8.5, preferably 10.5.
组合物的碱度基本上由单、二、三乙醇胺或其混合物的数量决定;这些化合物起缓冲体系的作用，使得可以提高组合物的碱度而不与表面活性剂的铵盐起反应。结果没有氨释放出来，因此本组合物无有害气味。The basicity of the composition is essentially determined by the amount of mono-, di-, triethanolamine or mixtures thereof; these compounds act as a buffer system allowing the basicity of the composition to be increased without reacting with the ammonium salt of the surfactant. As a result, no ammonia is released and therefore the composition has no harmful odour.
本发明的组合物还含有溶剂体系，其含量为组合物总重量的3%至14%，最好是5%至11%。The compositions of the present invention also contain a solvent system at a level of from 3% to 14%, preferably from 5% to 11%, by weight of the total composition.
适用的溶剂有正丁氧基丙醇，乙醇，异丙醇，正丁氧基丙氧基丙醇，丁基卡必醇（即2-（2-丁氧基乙氧基）乙醇），己二醇，己基卡必醇（即2-（2-己氧基乙氧基）乙醇），及它们的混合物。Suitable solvents are n-butoxypropanol, ethanol, isopropanol, n-butoxypropoxypropanol, butyl carbitol (i.e. 2-(2-butoxyethoxy)ethanol), hexyl Glycols, hexyl carbitol (i.e. 2-(2-hexyloxyethoxy) ethanol), and mixtures thereof.
优选的溶剂体系由正丁氧基丙醇与乙醇或异丙醇的混合物构成，其比例为1∶20至1∶2。最佳溶剂体系由正丁氧基丙醇和乙醇的1∶3混合物构成。A preferred solvent system consists of a mixture of n-butoxypropanol and ethanol or isopropanol in a ratio of 1:20 to 1:2. The optimal solvent system consisted of a 1:3 mixture of n-butoxypropanol and ethanol.
此外，组合物可以含有少量的助洗剂，例如次氮基三乙酸酯，聚羧酸酯，硝酸盐，水溶性磷酸盐，硅酸盐，乙二胺四乙酸盐（EDTA），氨基聚膦酸酯，磷酸酯，及它们的混合物。In addition, the composition may contain minor amounts of builders such as nitrilotriacetate, polycarboxylates, nitrates, water-soluble phosphates, silicates, ethylenediaminetetraacetate (EDTA), amino Polyphosphonates, phosphates, and mixtures thereof.
本发明的组合物是将所有组分混在一起而得到的;这样得到的硬表面清洗剂适用于目前用于该技术领域中的任何分散装置，但最好是以喷雾清洗剂的方式使用。这些组合物适用于任何表面，尤其是窗玻璃或任何玻璃材料。The compositions of the present invention are obtained by mixing all the components together; the resulting hard surface cleaner is suitable for use in any dispensing device currently used in the art, but is preferably used as a spray cleaner. These compositions are suitable for use on any surface, especially window glass or any glass material.
本发明的组合物也可以含有其它的任选物质，例如香料、染料、荧光增白剂、污垢悬浮剂、酶、冰冻-熔化稳定剂、杀菌剂和防腐剂。The compositions of the present invention may also contain other optional materials such as perfumes, dyes, optical brighteners, soil suspending agents, enzymes, freeze-thaw stabilizers, bactericides and preservatives.
实例example
下述本发明组合物通过将所有组分（百分数为占组合物总重的百分数）相混合而制得：The following compositions of the present invention are prepared by mixing all components (percentages are based on the total weight of the composition):
0.07%直链烷基苯磺酸铵盐0.07% ammonium linear alkylbenzene sulfonate
0.10%三倍乙氧基化烷基硫酸铵盐0.10% Triple Ethoxylated Alkyl Ammonium Sulfate
2%正丁氧基丙醇2% n-butoxypropanol
6%乙醇6% ethanol
0.5%单乙醇铵0.5% monoethanolammonium
直到100%的水和其它物质up to 100% water and other substances
本发明组合物的pH为10.5The pH of the composition of the present invention is 10.5
本组合物与作为先有技术代表的、配方如下的参照组合物相比较：This composition is compared with the reference composition of following formula as prior art representative:
0.013%三倍乙氧基化烷基硫酸钠盐0.013% Triple Ethoxylated Alkyl Sulfate Sodium Salt
9.0%丁基溶纤素9.0% Butyl Cellosolve
0.2%氨0.2% ammonia
直到100%的水和其它物质up to 100% water and other substances
此组合物的pH为11The pH of this composition is 11
比较两种组合物的光亮效果（在镜子和窗玻璃上）以及它们的清洗效能。The gloss effect (on mirrors and window panes) of the two compositions was compared as well as their cleaning performance.
清洗效能按下述对合成污垢作评价：Cleaning performance was evaluated on synthetic soils as follows:
HBTS污垢：由250毫升异丙醇、75克硬脂酸钙粉末和0.5克碳黑组成。用油漆滚筒将它涂敷在一块涂着搪瓷的金属板（先用洗涤剂、后用醇洗）上，将板在180℃烤20分钟。HBTS soil: Consists of 250 ml of isopropanol, 75 g of calcium stearate powder and 0.5 g of carbon black. Apply it with a paint roller to an enamel-coated metal plate (washed with detergent first, then alcohol), and bake the plate at 180°C for 20 minutes.
KD污垢：由25%的HSW
注：（1）Procter&Gamble公司销售的商品烹调油Note: (1) Commercial cooking oil sold by Procter & Gamble
（2）美国Chem Pack Inc.销售的商品污垢。(2) Commodity dirt sold by Chem Pack Inc., USA.
试验条件如下：The test conditions are as follows:
所有试验都通过一个Erichsen可洗性试验机进行。使用一块尺寸约为9.5×5×4厘米的海绵，事先将它在流动的热水下仔细清洗并用干燥的滚筒挤干。将5克欲试验的未经稀释的清洗剂复盖在海绵的一面上。记下清洗机为洗净板面所需要动作的次数。All tests were performed with an Erichsen washability tester. Use a sponge measuring approximately 9.5 x 5 x 4 cm, which you have previously washed carefully under running hot water and squeezed dry with a dry roller. 5 g of the undiluted cleanser to be tested is covered on one side of the sponge. Make a note of the number of times the washer takes to clean the deck.
光亮效果在干净的镜子或窗玻璃（户内和户外）上评价;由三名鉴定人独立地用0-4记分法目测评价成膜/条纹的程度，其中0＝无差别，4＝很大差别。Gloss effect was evaluated on a clean mirror or window glass (indoor and outdoor); degree of filming/streaking was visually evaluated by three judges independently on a 0-4 scale, where 0=no difference, 4=very much difference .
结果如下：The result is as follows:
HBTS KD 干净镜面 窗玻璃HBTS KD clean mirror window glass
( 动作次数) (PSU) 户内 户外(Number of action) (PSU) Outdoor outdoor
(PSU)(PSU)
参照样品 ＞200 10 0（参照） 0(参照） 0(参照）Reference sample ＞200 10 0 (reference) 0 (reference) 0 (reference)
本发明样品 ＞200 16 ＋1.8 +1.1 0Samples of the present invention
此鉴定小组表明，本发明的组合物具有和参照组合物同样好的清洗效能和更好的光亮效果。This panel showed that the compositions of the invention had as good cleaning performance and better shine as the reference compositions.
Claims (7)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB898909157A GB8909157D0 (en) | 1989-04-21 | 1989-04-21 | Hard-surface cleaning compositions |
| GB8909157.3 | 1989-04-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1046553A true CN1046553A (en) | 1990-10-31 |
| CN1025349C CN1025349C (en) | 1994-07-06 |
Family
ID=10655508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN90102261A Expired - Lifetime CN1025349C (en) | 1989-04-21 | 1990-04-21 | Hard Surface Cleaning Composition |
Country Status (13)
| Country | Link |
|---|---|
| EP (1) | EP0393772A3 (en) |
| JP (1) | JPH0341200A (en) |
| CN (1) | CN1025349C (en) |
| AR (1) | AR245496A1 (en) |
| AU (1) | AU641643B2 (en) |
| BR (1) | BR9001845A (en) |
| CA (1) | CA2013976A1 (en) |
| GB (1) | GB8909157D0 (en) |
| IE (1) | IE901423L (en) |
| MX (1) | MX171350B (en) |
| MY (1) | MY106340A (en) |
| NZ (1) | NZ233397A (en) |
| PE (1) | PE27691A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046137C (en) * | 1994-06-29 | 1999-11-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN103060824A (en) * | 2013-01-21 | 2013-04-24 | 上海艳紫化工科技有限公司 | Universal metal surface cleaning agent |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0503219A1 (en) * | 1991-03-11 | 1992-09-16 | THE PROCTER & GAMBLE COMPANY | Method and diluted cleaning composition for the cleaning of hard surfaces |
| EP0623166B1 (en) * | 1992-01-23 | 1996-06-05 | The Procter & Gamble Company | Liquid hard surface detergent compositions containing zwitterionic and cationic detergent surfactants and monoethanolamine and/or beta-aminoalkanol |
| US5252245A (en) * | 1992-02-07 | 1993-10-12 | The Clorox Company | Reduced residue hard surface cleaner |
| US5523024A (en) * | 1992-02-07 | 1996-06-04 | The Clorox Company | Reduced residue hard surface cleaner |
| US5585342A (en) * | 1995-03-24 | 1996-12-17 | The Clorox Company | Reduced residue hard surface cleaner |
| US5817615A (en) * | 1992-02-07 | 1998-10-06 | The Clorox Company | Reduced residue hard surface cleaner |
| US5468423A (en) * | 1992-02-07 | 1995-11-21 | The Clorox Company | Reduced residue hard surface cleaner |
| DE4210364B4 (en) * | 1992-03-30 | 2006-05-18 | Henkel Kgaa | Cleaning agents for hard surfaces, in particular glass |
| DE69405563T2 (en) * | 1993-06-01 | 1998-01-22 | Ecolab Inc | FOAM CLEANER |
| EP0691397B1 (en) | 1994-07-07 | 2004-10-06 | The Clorox Company | Antimicrobial hard surface cleaner |
| US6399553B1 (en) * | 1997-06-05 | 2002-06-04 | The Clorox Company | Reduced residue hard surface cleaner |
| US6432897B1 (en) * | 1997-06-05 | 2002-08-13 | The Clorox Company | Reduced residue hard surface cleaner |
| DE19811387A1 (en) | 1998-03-16 | 1999-09-23 | Henkel Kgaa | Liquid, multiphase, chlorofluorocarbon-free detergent forming temporary emulsion on shaking and used especially on glass |
| DE19856529A1 (en) * | 1998-12-08 | 2000-06-15 | Henkel Kgaa | Detergent for hard surfaces |
| DE19859808A1 (en) | 1998-12-23 | 2000-06-29 | Henkel Kgaa | Multi-phase cleaning agent with lignin sulfonate |
| DE19859640A1 (en) | 1998-12-23 | 2000-06-29 | Henkel Kgaa | Detergent for hard surfaces |
| DE19859778A1 (en) | 1998-12-23 | 2000-06-29 | Henkel Kgaa | Multi-phase cleaning agent with naphthalenesulfonic acid-formaldehyde condensate |
| JP2002226898A (en) * | 1999-01-13 | 2002-08-14 | Nisshin Kagaku Kk | Cleaning agent for spray |
| MXPA02012888A (en) | 2000-06-20 | 2003-05-14 | Procter & Gamble | Multi-phase fabric care composition for delivering multiple fabric care benefits. |
| CA3077837A1 (en) | 2020-04-03 | 2021-10-03 | Fluid Energy Group Ltd. | Hard surface cleaner |
| CA3113508A1 (en) | 2021-03-30 | 2022-09-30 | Fluid Energy Group Ltd. | Hard surface cleaning composition |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3839234A (en) * | 1973-01-26 | 1974-10-01 | C Roscoe | Multi-purpose cleaning concentrate |
| US4077896A (en) * | 1975-01-15 | 1978-03-07 | Minnesota Mining And Manufacturing Company | Wax-stripping cleaning composition |
| AU575399B2 (en) * | 1984-06-21 | 1988-07-28 | S.C. Johnson & Son, Inc. | Hard surface cleaning composition |
| JPS62252499A (en) * | 1986-04-25 | 1987-11-04 | ライオン株式会社 | Liquid detergent composition |
| NZ224148A (en) * | 1987-04-10 | 1991-02-26 | Colgate Palmolive Co | Pre-spotting composition for food residue removal |
| AU4702289A (en) * | 1989-01-19 | 1990-07-26 | Sterling Drug Inc. | Hard surface cleaning composition |
-
1989
- 1989-04-21 GB GB898909157A patent/GB8909157D0/en active Pending
-
1990
- 1990-04-05 CA CA002013976A patent/CA2013976A1/en not_active Abandoned
- 1990-04-13 EP EP19900200921 patent/EP0393772A3/en not_active Withdrawn
- 1990-04-19 AU AU53698/90A patent/AU641643B2/en not_active Ceased
- 1990-04-19 PE PE1990168027A patent/PE27691A1/en unknown
- 1990-04-19 MY MYPI90000645A patent/MY106340A/en unknown
- 1990-04-19 AR AR90316669A patent/AR245496A1/en active
- 1990-04-20 IE IE901423A patent/IE901423L/en unknown
- 1990-04-20 NZ NZ233397A patent/NZ233397A/en unknown
- 1990-04-20 BR BR909001845A patent/BR9001845A/en unknown
- 1990-04-20 JP JP2105150A patent/JPH0341200A/en active Pending
- 1990-04-20 MX MX020390A patent/MX171350B/en unknown
- 1990-04-21 CN CN90102261A patent/CN1025349C/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1046137C (en) * | 1994-06-29 | 1999-11-03 | 首钢总公司 | General-purpose hard surface detergent |
| CN103060824A (en) * | 2013-01-21 | 2013-04-24 | 上海艳紫化工科技有限公司 | Universal metal surface cleaning agent |
| CN103060824B (en) * | 2013-01-21 | 2015-06-03 | 陕西理工学院 | Universal metal surface cleaning agent |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ233397A (en) | 1993-05-26 |
| MY106340A (en) | 1995-05-30 |
| AU641643B2 (en) | 1993-09-30 |
| MX171350B (en) | 1993-10-20 |
| BR9001845A (en) | 1991-06-18 |
| IE901423L (en) | 1990-10-21 |
| CN1025349C (en) | 1994-07-06 |
| PE27691A1 (en) | 1991-09-27 |
| EP0393772A2 (en) | 1990-10-24 |
| AU5369890A (en) | 1990-10-25 |
| GB8909157D0 (en) | 1989-06-07 |
| EP0393772A3 (en) | 1991-09-11 |
| AR245496A1 (en) | 1994-01-31 |
| JPH0341200A (en) | 1991-02-21 |
| CA2013976A1 (en) | 1990-10-21 |
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