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CN104654312A - Flameless incineration process of solid waste - Google Patents

Flameless incineration process of solid waste Download PDF

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Publication number
CN104654312A
CN104654312A CN201510089325.6A CN201510089325A CN104654312A CN 104654312 A CN104654312 A CN 104654312A CN 201510089325 A CN201510089325 A CN 201510089325A CN 104654312 A CN104654312 A CN 104654312A
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solid waste
burning
sorting
nonflame
anaerobic fermentation
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CN104654312B (en
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王鑫
王宇锋
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Sichuan Yingchuang Environmental Protection Technology Co ltd
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Sichuan Xin Yuanlv Environmental Protection Technology Co Ltd
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M1/00Apparatus for enzymology or microbiology
    • C12M1/107Apparatus for enzymology or microbiology with means for collecting fermentation gases, e.g. methane
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2201/00Pretreatment

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Biotechnology (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Biomedical Technology (AREA)
  • Sustainable Development (AREA)
  • Microbiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a flameless incineration process of solid waste. The flameless incineration process of the solid waste comprises the steps of sorting treatment, anaerobic fermentation, flameless incineration and combustible gas recovery. The process provided by the invention is high in treatment efficiency, good in comprehensive efficiency, thoroughly clean in treatment, high in flameless incineration temperature and quick to carbonize; the combustible gas is sufficient to be converted, so that the self-sufficiency of energy during the incineration process is realized, and the weight of the produced coke residues is light; the bubbles are rich; the water permeability is good; the carbon content is high, and the ultra-low emission of hazardous materials is realized.

Description

A kind of nonflame burning process of solid waste
Technical field
The invention belongs to environmental protection technical field, relate to solid waste resource comprehensive utilization process, be specifically related to a kind of nonflame burning process of solid waste.
Background technology
Along with the raising of socioeconomic development and living standards of the people, the discharge capacity of solid waste increases sharply, and the annual newly-increased solid waste in the whole world reaches 10,000,000,000 tons, 0.6 ton per capita at present.And solid waste problem " the most seldom arrives process " with it, " most is comprehensive ", " most contaminative ", " coming into one's own the latest " and " most closeness to life " extremely people concern.
The processing method of solid waste mainly contains three kinds in the world at present: compost, landfill and burning electricity generation.Organic matter is sorted out by pretreatment by compost method, and because the Sorting Technique of developing country is also immature, compost method is seldom used in developing country, as just the supplementary means of solid waste process.Burying method is simple to operate, and front current cost is low, but needs to take a large amount of soils, and landfill yard stinks to high heaven after arriving during one's term of military service and closing, mosquitos and flies grows, percolate etc. becomes permanent pollution sources.The nucleus equipment of burning electricity generation method is incinerator, and incinerator technology is developed according to the solid waste feature after sorting based on external minority developed country.The combustion system of incinerator is naked light, and the powdery ashes of burning-out do not stop in stove directly discharges, and use value is low.Although above-mentioned solid waste treating technology respectively lays particular stress on, be all difficult to accomplish country-driven " three change ".
In addition, the domestic solid waste of China is by region, season, the restriction of economic situation, solid waste composition is diversity, complexity, anti-flammability is particularly outstanding, the water content of solid waste is generally higher than 40%, such solid waste enters incinerator and carries out burning disposal and will inevitably cause combustion instability, easily flame-out in stove, even if it is combustion-supporting to add supplementary energy, combustion conditions also cannot be steady, operation is made to become complicated, operation cost is high, bioxin is wayward, seriously polluted, collective of a mass character event in rapid succession, so the combustion system of incinerator is also not exclusively suitable for the current fixed-end forces of China.
Have at present and about solid waste sorting, valuable material is reclaimed, combustion value is improved by anaerobic ferment process, produce biogas and manufacture clean energy resource by thermal cracking, graininess combustibles are produced to not perishable organic matter, the report that the inorganic matter little to particle and organic matter are buried or burned, but really implement and still have certain gap.
Summary of the invention
The object of the invention is to the defect overcoming prior art, a kind of nonflame burning process of solid waste is provided, makes full use of the source material of solid, turn the foul and rotten into the rare and ethereal.
It is a kind of up-to-date combustion system that the international combustion field of Jin20Nian develops that nonflame burns, process for solid waste still belongs to the first, have that treatment effeciency is high, solid waste source material utilizes fully, profitable, process is thoroughly clean and the feature of nuisance minimum discharge.
The present invention is achieved through the following technical solutions: a kind of nonflame burning process of solid waste, and it comprises the following steps:
S1. sorting process: sub-elect plastics, rubber and heavy metal from solid waste;
S2. anaerobic fermentation: the solid waste after sorting is moved in anaerobic fermentation room and carries out fermentation process, the water content of solid waste is made to decline 5% ~ 15%, the height that the indoor solid waste of described anaerobic fermentation is stacked is 5 ~ 7m, and the time of fermentation process is 5 ~ 10 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 5 ~ 7m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 10 ~ 50m/s to air supply system, lighted a fire by ignition system, make it burning and enter design conditions, described design conditions are: coking layer, burning layer, carburization zone and baking zone, burning layer central temperature is 1450 ~ 1650 DEG C, and solid waste is converted into available cinder the most at last.
Further, described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.
Further, described sorting process adopts artificial separation, mechanical sorting and instrument to detect the mode combined.
Further, during nonflame described in step S3 burns, disposable extensive charging, disposablely slags tap on a large scale; What burn layer is 2%-15% containing oxygen, and burning layer is carbide, and incineration temperature is high, and the flue gas main component discharged is imflammable gas.
Further, a kind of nonflame burning process of solid waste also comprises the recovery of S4 fuel gas, and the removal process of described fuel gas comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process, anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, described incinerating kiln top arranges smoke evacuation system, by the fuel gas negative pressure sucking-off from smoke evacuation system produced in nonflame burning process, carries out bulk processing;
S43. mix in the lump as assisted gas using the flammable foul smell collected in step S41 with the fuel gas in step S42 after bulk processing, air supply system bottom incinerating kiln injects, and participates in combustion-supporting, achieves the self-sufficient of the energy in burning process.
Further, the production process of described fuel gas is: in nonflame burning process, and when solid waste more than burning layer experiences the heat radiation of more than 300 DEG C, in solid waste, hemicellulose starts pyrolysis carbonization, produces fuel gas.
Further, described solid waste RESEARCH OF PYROCARBON chemical industry condition is as follows: in kiln, solid waste is after ignition system fires, ignition temperature reaches 800 DEG C thereupon, burning and carbonization are almost carried out simultaneously, drying stage is in when the top heat radiation of burning layer is at 200 ~ 300 DEG C, when radiation temperature reaches more than 300 DEG C, half fiber in solid waste starts pyrolysis carburizing reagent, the volatile matter that pyrolysis carbonization is separated out mainly comprises steam, hydrogen, carbon monoxide, methane, tar and hydrocarbon, i.e. wood gas, wood tar and pyrolkigneous liquid, be referred to as " flue gas ", flue gas by air exhauster from the smoke evacuation system negative pressure sucking-off of kiln top, when the radiation temperature of burning layer reaches 500 DEG C, the living beings in solid waste are accelerated to decompose, and along with the quickening cracking process decomposed and product thereof are also accelerated thereupon, the flue gas of generation is more abundant, after ignition temperature reaches 1200 DEG C, burning layer and carburization zone mainly produce methane and namely hydrogen no longer produce vinegar liquid and tar, and just produce wood gas, and the calorific value of wood gas improves greatly, wood gas is fuel gas.
Living beings in solid waste, kitchen is remaining in pyrogenation and combustion process, tar can be produced, tar is 1000 ~ 1200 DEG C time, in short time, cleavage rate reaches more than 99%, can make full use of nonflame burn in the steam that contains react with composition in tar and produce carbon monoxide and hydrogen, the generation of minimizing carbon black, the production rate of fuel gas in raising flue gas.Catalytic pyrolysis as naphthalene in tar: C 10h 8+ 10H 20 → 10CO+14H 2, C 10h 8+ 20H 20 → 10CO 2+ 2H 2, C 10h 8+ 10H 20 → CO+4CO 2+ 6H 2+ 4CH 4; Steam is conducive to the generation of coke tar cracking and fuel gas, and the fuel gases calorific value of generation is 10 ~ 16MJ/Nm 3, hydrogen content is 30 ~ 60%.
It is as follows that described solid waste nonflame burns mechanism: in incinerating kiln, stack solid waste reach 5 ~ 7m, initial burning produces naked light, and along with passing into combustion-supporting gas at the bottom of kiln, due to the relation of solid waste pressure and gravity, flame reduces gradually until small.The burning initial stage, burning, pyrolysis, carbonization almost completes simultaneously, the solid waste that gas permeation 5 ~ 7m that the flue gas produced in burning and pyrolysis carbonization produce is high, slow precipitation, heat, ash flies and impurity is retained by thick solid waste, take out the oxygen deprivation air-flow drawing low speed movement in kiln, after bulk processing, the fuel gas in flue gas is reclaimed, same sorting, the foul smell mixing that anaerobic fermentation process produces, burning layer is entered by the air supply system at the bottom of kiln by 4/5 ~ 6/7 of mixing foul smell, make Incineration circumstances by initial burning layer, carburization zone, baking zone is to coking layer, burn layer, carburization zone and baking zone transform, what burn is no longer the ortho states of solid waste, and be through the carburization zone of RESEARCH OF PYROCARBON, after carburization zone temperature reaches 1000 DEG C, the tar gasification and pyrolysis speed that solid waste produces is accelerated, separate out the Small molecular hydrocarbon gas being conducive to burning, along with the further lifting of carbonization heat, promote carbide second pyrolysis, the productive rate of fuel gas improves, along with the rising of carburizing temperature, the temperature that carbide catches fire also raises.Along with adding of high temperature incineration fuel gas and hypoxemia, burning flame volume increases exponentially, burning layer heats up evenly, mean temperature promotes greatly, achieve stable burning, progressively upwards pass with the form of nonflame, heat energy is piled up rapidly, the temperature of burning layer in the short time reaches 1450 ~ 1650 DEG C, finally makes solid waste form available cinder.
The present invention has following beneficial effect:
(1) the present invention is applicable to the process of domestic waste, Medical Solid Wastes and municipal sludge;
(2) the present invention has low-carbon (LC), environmental protection, and treatment effeciency is high, and decrement is thorough, the feature of nuisance minimum discharge;
(3) in the present invention, solid waste source material utilizes fully, and imflammable gas transforms sufficient, achieves the self-sufficient of the energy in burning process;
(4) the present invention can make the high-quality cinder that discarded object changes into light weight, bubble enriches, good water permeability, phosphorus content are high;
(5) cinder produced in the present invention is widely used, and can be used for precision agriculture, building materials and pollution treatment industry.
Accompanying drawing explanation
Fig. 1 is nonflame Incineration circumstances in the present invention;
Fig. 2 is nonflame Incineration circumstances curve in the present invention.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described, and protection scope of the present invention is not limited to the following stated.
Embodiment 1: a kind of nonflame burning process of solid waste, it comprises the following steps:
S1. sorting process: adopt artificial separation, mechanical sorting and instrument to detect the mode combined and sub-elect plastics, rubber and heavy metal from solid waste;
S2. anaerobic fermentation: the solid waste after sorting moved in anaerobic fermentation room and carry out fermentation process, makes the water content of solid waste decline 5%, and the height that the indoor solid waste of described anaerobic fermentation is stacked is 5m, and the time of fermentation process is 5 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 5m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 10m/s to air supply system, lighted a fire by ignition system, burn thereupon and enter design conditions, described design conditions are: coking layer, burning layer, carburization zone and baking zone, and burning layer central temperature is 1450 DEG C, and final solid waste is converted into available cinder;
S4. the recovery of fuel gas, it comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process and anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, there is smoke evacuation system on described incinerating kiln top, by the fuel gas negative pressure sucking-off from smoke evacuation system produced in nonflame burning process, carries out bulk processing;
S43. mixed with the fuel gas in step S42 after bulk processing by the flammable foul smell collected in step S41 and as assisted gas, the air supply system bottom incinerating kiln injects, and participates in combustion-supporting, achieves the self-sufficient of the energy in burning process.
Described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.
Embodiment 2: a kind of nonflame burning process of solid waste, it comprises the following steps:
S1. sorting process: the mode adopting artificial separation, mechanical sorting and instrument detection sorting to combine sub-elects plastics, rubber and heavy metal from solid waste;
S2. anaerobic fermentation: the solid waste after sorting moved in anaerobic fermentation room and carry out fermentation process, makes the water content of solid waste decline 15%, and the height that the indoor solid waste of described anaerobic fermentation is stacked is 7m, and the time of fermentation process is 10 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 7m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 50m/s to air supply system, lighted a fire by ignition system, burn thereupon and enter design conditions, described design conditions are: the operating mode of coking layer, burning layer, carburization zone and baking zone, and burning layer central temperature is 1650 DEG C, and final solid waste is converted into available cinder;
S4. the recovery of fuel gas, it comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process and anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, there is smoke evacuation system on described incinerating kiln top, by the fuel gas negative pressure sucking-off from smoke evacuation system produced in nonflame burning process, carries out bulk processing;
S43. mixed with the fuel gas in step S42 after bulk processing by the flammable foul smell collected in step S41 and as assisted gas, the air supply system bottom incinerating kiln injects, and participates in combustion-supporting, achieves the self-sufficient of the energy in burning process.
Described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.
Embodiment 3: a kind of nonflame burning process of solid waste, it comprises the following steps:
S1. sorting process: adopt artificial separation, mechanical sorting and instrument to detect the mode combined and sub-elect plastics, rubber and heavy metal from solid waste;
S2. anaerobic fermentation: the solid waste after sorting moved in anaerobic fermentation room and carry out fermentation process, makes the water content of solid waste decline 8%, and the height that the indoor solid waste of described anaerobic fermentation is stacked is 5.8m, and the time of fermentation process is 7 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 5.8m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 25m/s to air supply system, lighted a fire by ignition system, burn thereupon and enter design conditions, described design conditions are: the operating mode of coking layer, burning layer, carburization zone and baking zone, and burning layer central temperature is 1500 DEG C, and final solid waste is converted into available cinder;
S4. the recovery of fuel gas, it comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process and anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, there is smoke evacuation system on described incinerating kiln top, by the fuel gas negative pressure sucking-off from smoke evacuation system produced in nonflame burning process, carries out bulk processing;
S43. mixed with the fuel gas in step S42 after bulk processing by the flammable foul smell collected in step S41 and as assisted gas, the air supply system bottom incinerating kiln injects, and participates in combustion-supporting, achieves the self-sufficient of the energy in burning process.
Described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.
Embodiment 4: a kind of nonflame burning process of solid waste, it comprises the following steps:
S1. sorting process: the mode adopting artificial separation, mechanical sorting and instrument detection sorting to combine sub-elects plastics, rubber and heavy metal from solid waste;
S2. anaerobic fermentation: the solid waste after sorting moved in anaerobic fermentation room and carry out fermentation process, makes the water content of solid waste decline 12%, and the height that the indoor solid waste of described anaerobic fermentation is stacked is 6.5m, and the time of fermentation process is 9 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 6.5m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 40m/s to air supply system, lighted a fire by ignition system, burn thereupon and enter design conditions, described design conditions are: the operating mode of coking layer, burning layer, carburization zone and baking zone, and burning layer central temperature is 1600 DEG C, and final solid waste is converted into available cinder;
S4. the recovery of fuel gas, it comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process and anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, there is smoke evacuation system on described incinerating kiln top, by the fuel gas negative pressure sucking-off from smoke evacuation system produced in nonflame burning process, carries out bulk processing;
S43. mixed with the fuel gas in step S42 after bulk processing by the flammable foul smell collected in step S41 and as assisted gas, the air supply system bottom incinerating kiln injects, and participates in combustion-supporting, achieves the self-sufficient of the energy in burning process.
Described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.

Claims (4)

1. a nonflame burning process for solid waste, it is characterized in that, it comprises the following steps:
S1. sorting process: go out plastics, rubber and heavy metal from solid waste sorting;
S2. anaerobic fermentation: the solid waste after sorting is moved in anaerobic fermentation room and carries out fermentation process, the water content of solid waste is made to decline 5% ~ 15%, the height that the indoor solid waste of described anaerobic fermentation is stacked is 5 ~ 7m, and the time of fermentation process is 5 ~ 10 days;
S3. nonflame burns: the solid waste after anaerobic fermentation piles up 5 ~ 7m in incinerating kiln, set-point ignition system and air supply system bottom described incinerating kiln, assisted gas is passed into the flow velocity of 10 ~ 50m/s to air supply system, lighted a fire by ignition system, burn thereupon and enter design conditions, described design conditions are: coking layer, burning layer, carburization zone and baking zone, burning layer central temperature is 1450 ~ 1650 DEG C, and solid waste is converted into available cinder the most at last.
2. the nonflame burning process of a kind of solid waste according to claim 1, is characterized in that, described solid waste comprises domestic waste, Medical Solid Wastes and municipal sludge.
3. the nonflame burning process of a kind of solid waste according to claim 1, is characterized in that, described sorting process adopts artificial separation, mechanical sorting and instrument to detect the mode combined.
4. the nonflame burning process of a kind of solid waste according to claim 1, is characterized in that, it also comprises S4 fuel gas and reclaims, and the removal process of described fuel gas comprises following sub-step:
S41. the flammable foul smell that solid waste produces in sorting process, anaerobic fermentation process is collected;
S42. outside incinerating kiln, arrange air exhauster, described incinerating kiln top arranges smoke evacuation system, and the fuel gas produced from nonflame burning process is negative pressure sucking-off from smoke evacuation system, carries out bulk processing;
S43. the flammable foul smell collected in step S41 to be mixed with the fuel gas in step S42 after bulk processing and as assisted gas, the air supply system bottom incinerating kiln passes into, participate in combustion-supporting.
CN201510089325.6A 2015-02-27 2015-02-27 A kind of nonflame burning process of solid waste Expired - Fee Related CN104654312B (en)

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CN107101206A (en) * 2017-05-09 2017-08-29 高承疆 Fuel gas wraps up the combustion method of flammable solid
CN110145742A (en) * 2019-05-27 2019-08-20 光大环保能源(沛县)有限公司 A kind of garbage power environmental protection equipment

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CN107101206A (en) * 2017-05-09 2017-08-29 高承疆 Fuel gas wraps up the combustion method of flammable solid
CN110145742A (en) * 2019-05-27 2019-08-20 光大环保能源(沛县)有限公司 A kind of garbage power environmental protection equipment

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