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CN104642340B - Mixed herbicide containing aminopyralid and bentazone - Google Patents

Mixed herbicide containing aminopyralid and bentazone Download PDF

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Publication number
CN104642340B
CN104642340B CN201310577113.3A CN201310577113A CN104642340B CN 104642340 B CN104642340 B CN 104642340B CN 201310577113 A CN201310577113 A CN 201310577113A CN 104642340 B CN104642340 B CN 104642340B
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China
Prior art keywords
bentazone
acid
salt
herbicide
fampridine
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CN104642340A (en
Inventor
邢刚
高瑞花
甘华军
芮裕健
郭崇友
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Jiangsu Ouyue Biotechnology Co., Ltd
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Nanjing Huazhou Pharmaceutical Co Ltd
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Abstract

The invention discloses a mixed herbicide containing aminopyralid and bentazone, which belongs to the technical field of pesticide. The herbicide uses aminopyralid and bentazone as main effective components, wherein the mass ratio of aminopyralid to bentazone is 0.1-80: 0.1-80. The mixed herbicide provided by the invention is applied to non-cultivated land, orchards, woodland, pasture, lawn and corn fields for weeding, has the advantages of fast action, a wide weed control spectrum, long lasting time of efficiency, thorough weeding, low residue, low toxicity, safety, environment friendliness and the like, and is a high-quality chemical herbicide for non-cultivated land, orchards, woodland, pasture, lawn and corn fields.

Description

A kind of chloride Fampridine acid and the mixed herbicide of bentazone
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, it is related to the binary of the acid of chlorine Fampridine and bentazone Built agent.This herbicidal composition can be applicable to bare place, orchard, forest land, pasture, lawn and corn field postemergence weed control.
Background technology
Chlorine Fampridine acid (aminopyralid), chemical name: 4- amino -3,6- dichloropyridine -2- carboxylic acid, chlorine Fampridine Acid is a kind of pyridines herbicide, is widely used in the control of weeds of mountain region, grassland, lawn, plantation and bare place.Can prevent and treat Annual or perennial broadleaf weed.
Bentazone (bentazone), a kind of carbamide herbicides, chemical name: 3- isopropyl (1h)-benzo -2,1,3- thiophene Diazine -4- (3h) -one 2,2 dioxide, bentazone is that contact killing type has selective herbicide after seedling, at seedling stage stem and leaf Reason, is worked by blade contact.Dry land uses, and first passes through blade face infiltration and is transmitted to inhibited photosynthesis in chloroplast.Have Effect composition detoxifies to the weak glycoconjugates metabolism of activity in tolerable crop body, and to crop safety, after dispenser, 6~18 weeks benzene reaches Pine can be decomposed by the microorganisms in soil.Prevent and kill off Herba Galii Teneri in wheat paddock, European lapsana apogonoides and Herba stellariae mediae etc..
The residue problem of chlorine Fampridine acid at present is serious, has been strictly limited usage amount and use in a lot of countries and regions Method.In order to while reducing herbicide carryover it is ensured that the herbicidal effect of medicament, the present invention select can weed control spectrum different, excellent lack It is made into mixture use after the complementary chlorine Fampridine acid of point and the suitable decrement of two kinds of herbicides of bentazone, so both expanded herbicide Spectrum, hence it is evident that improve herbicidal effect, it also avoid succession crop is produced with the probability of residual hazard.
Content of the invention
It is an object of the invention to provide the mixed herbicide of a kind of chloride Fampridine acid and bentazone.
It is a further object of the present invention to provide this herbicide removes in bare place, orchard, forest land, pasture, lawn and corn field Application in grass.
A kind of mixed herbicide of chloride Fampridine acid and bentazone it is characterised in that this herbicide with the acid of chlorine Fampridine with Bentazone is principle active component, and the acid of chlorine Fampridine is 0.1~80:0.1~80 with the mass ratio of bentazone, preferably chlorine Fampridine Acid is 1~60:1~60 with the mass ratio of bentazone, and most preferably the acid of chlorine Fampridine and the mass ratio of bentazone are 1~7.5:5.
In mixed herbicide, chlorine Fampridine acid with weight/mass percentage composition in herbicide for both bentazones be 1~ 85%, preferred mass percentage composition is 10~75%.
The acid of the mixed herbicide of the present invention, wherein chlorine Fampridine presented in water soluble salt, described chlorine Fampridine Acid water soluble salt include sodium salt, potassium salt, ammonium salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, The water soluble salts such as triisopropanolamine salt.
In the binary built preparation of the chlorine Fampridine acid of the present invention and bentazone, except the acid of chlorine Fampridine is effective with bentazone Outside composition, the auxiliary agents such as the conventional surfactants allowing, thickening agent, solvent or solid packing can also be added on pesticidal preparations and join Any one dosage form allowing is made on pesticide.Preferably be processed into water preparation, wettable powder, soluble powder, water-soluble granule, Water dispersible granules.
" % " of the present invention is weight/mass percentage composition.
The mixed herbicide of chloride Fampridine acid of the present invention and bentazone bare place, orchard, forest land, pasture, Application in lawn and cornfield weeding, in preventing and kill off bare place, orchard, forest land, pasture, lawn and corn field, various broad-leaveds are miscellaneous Application in grass has remarkable result.
Compared to the prior art, beneficial effects of the present invention:
The mixed herbicide of the present invention, has instant effect, a herbicide spectrum width, lasting period length, weeding are thoroughly, residual is low, low toxicity, The advantages of safety and environmental protection, be bare place, orchard, forest land, pasture, lawn and the Chemical Weeding in Maize Field agent of high-quality.
Specific embodiments
Embodiment 1
Bentazone 25%, chlorine Fampridine acid 5%, dodecylbenzene sodium sulfonate 5%, alkylphenol polyoxyethylene 3%, water is extremely 100%, it is configured to, according to conventional formulation method, the water preparation that weight/mass percentage composition is 30%.Wherein chloramines pyridine acid is with sodium salt shape Formula exists.
Embodiment 2
Bentazone 20%, chlorine Fampridine acid 30%, dodecylbenzene sodium sulfonate 5%, lauryl sulfate 2%, sulphuric acid Ammonium, to 100%, is configured to, according to conventional formulation method, the water solube powder that weight/mass percentage composition is 35%.Wherein chloramines pyridine Acid is existed with sodium-salt form.
Embodiment 3
Bentazone 15%, chlorine Fampridine acid 15%, dodecylbenzene sodium sulfonate 5%, alkylphenol polyoxyethylene 3%, water To 100%, it is configured to, according to conventional formulation method, the water preparation that weight/mass percentage composition is 30%.Wherein chloramines pyridine acid is different with three Propanolamine salt form exists.
Embodiment 4
Bentazone 45%, chlorine Fampridine acid 30%, nno (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 5%, lauryl sulfate 2%, Ammonium sulfate, to 100%, is configured to, according to conventional formulation method, the water-soluble granule that weight/mass percentage composition is 75%.Wherein chloramines Pyridine acid is existed with sodium-salt form.
Embodiment 5
Bentazone 20%, chlorine Fampridine acid 30%, dodecylbenzene sodium sulfonate 5%, alkylphenol polyoxyethylene 3%, sulfur Sour ammonium, to 100%, is configured to, according to conventional formulation method, the water solube powder that weight/mass percentage composition is 50%.Wherein chloramines pyrrole Pyridine acid is existed with ammonium salts.
Embodiment 6
Bentazone 15%, chlorine Fampridine acid 60%, nno (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) wetting agent 5%, ammonium sulfate 3%, gather Vinyl alcohol 2%, Kaolin to 100%, it is configured to, according to conventional formulation method, the water-dispersible grain that weight/mass percentage composition is 75% Agent.Wherein chloramines pyridine acid is existed with sodium-salt form.
Embodiment 7
Bentazone 60%, chlorine Fampridine acid 10%, nno (di-2-ethylhexylphosphine oxide bitter edible plant sodium sulfonate) 6%, sodium lignin sulfonate 5% is high Ridge soil, to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 70%.Wherein chloramines pyrrole Pyridine acid is existed with potassium salt form.
Embodiment 8
Bentazone 9%, chlorine Fampridine acid 1%, dodecylbenzene sodium sulfonate 5%, alkyl polyglucoside 5%, water to 100%, press The formulation method of more solito is configured to the water preparation that weight/mass percentage composition is 10%.Wherein chloramines pyridine acid is with triisopropanolamine salt shape Formula exists.
Embodiment 9
Bentazone 1%, chlorine Fampridine acid 9%, dodecylbenzene sodium sulfonate 5%, alkyl polyglucoside 5%, water to 100%, press The formulation method of more solito is configured to the water preparation that weight/mass percentage composition is 10%.Wherein chloramines pyridine acid is deposited with alcohol salt form ?.
Embodiment 10
Field control effectiveness test
Reagent agent: 4 kinds of re-compounded binary herbicides in embodiment 1~4.
Comparison medicament: 48% bentazone water preparation (commercially available), 30% chlorine Fampridine sour water agent (commercially available).
Preventing and treating crop: Semen Maydiss.
Prevent and kill off object: the weeds such as Herba Commelinae, Herba Galii Teneri, Herba Capsellae, Herba Portulacae.
Test method: according to the area of experimental plot, good various medicaments of precise, and after being watered dilution, using bearing Formula aerosol apparatus, carry out even spraying, the special Fan spray head of sprinkler selection herbicide.It should be noted that uniformly spraying medicinal liquid during spraying It is applied in experimental plot, accomplish do not have drain spray, the phenomenon of many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and compare the activity of weeding of various medicaments.
Embodiments of the invention preparation Herbicidal Testing Trials effect see table 1 (20d after medicine) and table 2 (40d after medicine)
1 test of pesticide effectiveness result of table (20d after medicine)
Table 2 field control effectiveness test result (40d after medicine)
As can be seen from Table 1 and Table 2, the present invention has significant preventive effect to broad leaved weed, building performance notable, and Instant effect, lasting period are long.

Claims (7)

1. a kind of chloride Fampridine acid and the mixed herbicide of bentazone are it is characterised in that this herbicide is with the acid of chlorine Fampridine and benzene Reaching pine is effective ingredient, and the acid of chlorine Fampridine is 1.5:1,1:1.5 with the mass ratio of bentazone.
2. the mixed herbicide of chloride Fampridine acid according to claim 1 and bentazone is it is characterised in that chlorine Fampridine Acid and weight/mass percentage composition in herbicide for both bentazones are 1~85%.
3. the mixed herbicide of chloride Fampridine acid according to claim 2 and bentazone is it is characterised in that chlorine Fampridine Acid and weight/mass percentage composition in herbicide for both bentazones are 10~75%.
4. the mixed herbicide of the chloride Fampridine acid according to claim 1-3 any one and bentazone, its feature exists In the acid of described chlorine Fampridine presented in water soluble salt, the water soluble salt of described chlorine Fampridine acid is sodium salt, potassium salt, ammonium Salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, triisopropanolamine salt.
5. chloride Fampridine acid according to claim 1 and the mixed herbicide of bentazone are it is characterised in that it is with chlorine ammonia Pyridine acid and bentazone are that the auxiliary agent allowing on effective ingredient and pesticide is configured to any one dosage form;Described dosage form is water Agent, wettable powder, soluble powder, water-soluble granule, water dispersible granules.
6. the mixed herbicide of the chloride Fampridine acid described in claim 1 and bentazone orchard, forest land, pasture, lawn and Application in cornfield weeding.
7. the chloride Fampridine acid described in claim 1 and the mixed herbicide of bentazone are preventing and kill off orchard, forest land, pasture, grass Application in various broad leaved weeds in level ground and corn field.
CN201310577113.3A 2013-11-15 2013-11-15 Mixed herbicide containing aminopyralid and bentazone Active CN104642340B (en)

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CN104642340A CN104642340A (en) 2015-05-27
CN104642340B true CN104642340B (en) 2017-02-01

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009053061A2 (en) * 2007-10-24 2009-04-30 Bayer Cropscience Ag Herbicidal combination
CN101808520A (en) * 2007-08-27 2010-08-18 陶氏益农公司 Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides
CN104768381A (en) * 2012-09-13 2015-07-08 美国陶氏益农公司 Herbicidal compositions comprising aminopyralid and bentazon

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101808520A (en) * 2007-08-27 2010-08-18 陶氏益农公司 Synergistic herbicidal composition containing certain pyridine or pyrimidine carboxylic acids and certain cereal and rice herbicides
WO2009053061A2 (en) * 2007-10-24 2009-04-30 Bayer Cropscience Ag Herbicidal combination
CN104768381A (en) * 2012-09-13 2015-07-08 美国陶氏益农公司 Herbicidal compositions comprising aminopyralid and bentazon

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Patentee after: Nanjing Boland Biotechnology Co., Ltd

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Patentee before: Nanjing Huazhou Parmaceutical Co.,Ltd.

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Patentee after: Jiangsu Ouyue Biotechnology Co., Ltd

Address before: 210002 705, Xingye building, 15 Hubu street, Qinhuai District, Nanjing City, Jiangsu Province

Patentee before: Nanjing Boland Biotechnology Co., Ltd

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