CN104621177A - Mixed herbicide containing picloram and glufosinate - Google Patents
Mixed herbicide containing picloram and glufosinate Download PDFInfo
- Publication number
- CN104621177A CN104621177A CN201310573155.XA CN201310573155A CN104621177A CN 104621177 A CN104621177 A CN 104621177A CN 201310573155 A CN201310573155 A CN 201310573155A CN 104621177 A CN104621177 A CN 104621177A
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- Prior art keywords
- acid
- fampridine
- ammonium phosphine
- herbicide
- careless ammonium
- Prior art date
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- Pending
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- 239000004009 herbicide Substances 0.000 title claims abstract description 55
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 43
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 title abstract 4
- 239000005561 Glufosinate Substances 0.000 title abstract 4
- 239000005595 Picloram Substances 0.000 title abstract 4
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 title abstract 4
- 241000209140 Triticum Species 0.000 claims abstract description 10
- 235000021307 Triticum Nutrition 0.000 claims abstract description 10
- 238000009333 weeding Methods 0.000 claims abstract description 9
- NUKYPUAOHBNCPY-UHFFFAOYSA-N 4-aminopyridine Chemical compound NC1=CC=NC=C1 NUKYPUAOHBNCPY-UHFFFAOYSA-N 0.000 claims description 46
- 229960004979 fampridine Drugs 0.000 claims description 46
- 239000002253 acid Substances 0.000 claims description 45
- QLULGSLAHXLKSR-UHFFFAOYSA-N azane;phosphane Chemical compound N.P QLULGSLAHXLKSR-UHFFFAOYSA-N 0.000 claims description 36
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 32
- 239000000460 chlorine Substances 0.000 claims description 32
- 229910052801 chlorine Inorganic materials 0.000 claims description 32
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 14
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical class [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 241000196324 Embryophyta Species 0.000 claims description 10
- 239000002420 orchard Substances 0.000 claims description 8
- 238000009472 formulation Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical class CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 239000004562 water dispersible granule Substances 0.000 claims description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 2
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical class CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 claims description 2
- 239000003905 agrochemical Substances 0.000 claims description 2
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 150000004656 dimethylamines Chemical class 0.000 claims description 2
- 150000003956 methylamines Chemical class 0.000 claims description 2
- 239000001103 potassium chloride Substances 0.000 claims description 2
- 235000011164 potassium chloride Nutrition 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 5
- 239000000126 substance Substances 0.000 abstract description 4
- 238000001228 spectrum Methods 0.000 abstract description 3
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 230000005923 long-lasting effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000003814 drug Substances 0.000 description 9
- 244000025254 Cannabis sativa Species 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 5
- 241001060350 Acalypha Species 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 240000001592 Amaranthus caudatus Species 0.000 description 2
- 235000009328 Amaranthus caudatus Nutrition 0.000 description 2
- 235000011305 Capsella bursa pastoris Nutrition 0.000 description 2
- 240000008867 Capsella bursa-pastoris Species 0.000 description 2
- 241000233838 Commelina Species 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 229930182470 glycoside Natural products 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- ZBMRKNMTMPPMMK-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid;azane Chemical compound [NH4+].CP(O)(=O)CCC(N)C([O-])=O ZBMRKNMTMPPMMK-UHFFFAOYSA-N 0.000 description 1
- 239000005468 Aminopyralid Substances 0.000 description 1
- 244000075634 Cyperus rotundus Species 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- NIXXQNOQHKNPEJ-UHFFFAOYSA-N aminopyralid Chemical compound NC1=CC(Cl)=NC(C(O)=O)=C1Cl NIXXQNOQHKNPEJ-UHFFFAOYSA-N 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 102000005396 glutamine synthetase Human genes 0.000 description 1
- 108020002326 glutamine synthetase Proteins 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 125000002467 phosphate group Chemical class [H]OP(=O)(O[H])O[*] 0.000 description 1
- 125000001476 phosphono group Chemical group [H]OP(*)(=O)O[H] 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a mixed herbicide containing picloram and glufosinate, belonging to the technical field of herbicides. The herbicide is prepared by taking picloram and glufosinate as main effective components, wherein the mass ratio of picloram to glufosinate is (0.1-80): (0.1-80). The mixed herbicide disclosed by the invention is applied to weeding in uncultivated areas, gardens, forest lands and wheat paddocks, has the advantages of high effect taking speed, wide herbicide control spectrum, long lasting period, weeding thoroughness, low residual quantity, low toxicity, safety, environment friendliness and the like, and is a chemical herbicide for the uncultivated areas, the gardens, the forest lands and the wheat paddocks.
Description
Technical field
The invention belongs to technical field of pesticide, especially weed killer herbicide field, relate to the binary built agent of the acid of chlorine Fampridine and careless ammonium phosphine.This herbicidal composition can be applicable to uncultivated area, orchard, forest land and wheat paddock weeding.
Background technology
Chlorine Fampridine acid (aminopyralid), amino-3, the 6-dichloropyridine-2-carboxylic acids of chemical name: 4-, the acid of chlorine Fampridine is a kind of pyridines weed killer herbicide, is widely used in the control of weeds of mountain region, grassland, lawn, plantation and uncultivated area.Annual or perennial broadleaf weed can be prevented and treated.
Grass ammonium phosphine (glufosinate-ammonium), organic phosphates weed killer herbicide, chemical name: 4-[hydroxyl (methyl) phosphono]-DL-high lactamine is a kind of glutamine synthetase inhibitor, non-selective contact weedicide.There is certain systemic action, can be used for orchard, vineyard, uncultivated area weeding, prevent and kill off annual or perennial dicotyledonous and grassy weed and nutgrass flatsedge etc. with also can be used for potato.
Because current chlorine Fampridine acid residue problem is serious, usage amount and using method are strictly limited in a lot of countries and regions.In order to while minimizing herbicide carryover, guarantee the herbicidal effect of medicament, using being made into mixture after the acid of chlorine Fampridine and careless ammonium phosphine two kinds of suitable decrements of weed killer herbicide, can dosing be reduced like this, both expand herbicide spectrum, it also avoid possibility succession crop being produced to residual hazard.
Summary of the invention
The object of this invention is to provide the mixed herbicide of a kind of chloride Fampridine acid and careless ammonium phosphine.
Another object of the present invention is to provide the application of this weed killer herbicide in uncultivated area, orchard, forest land and wheat paddock weeding.
The mixed herbicide of a kind of chloride Fampridine acid and careless ammonium phosphine, it is characterized in that this weed killer herbicide with chlorine Fampridine acid with careless ammonium phosphine for principle active component, the acid of chlorine Fampridine is 0.1 ~ 80:0.1 ~ 80 with the mass ratio of careless ammonium phosphine, preferred chlorine Fampridine acid is 1 ~ 60:1 ~ 60 with the mass ratio of careless ammonium phosphine, and most preferably the acid of chlorine Fampridine is 0.5 ~ 1.5:1 with the mass ratio of careless ammonium phosphine.
In mixed herbicide, the acid of chlorine Fampridine is 1 ~ 85% with the mass percentage of careless both ammonium phosphines in weed killer herbicide, and preferred mass percentage composition is 10 ~ 75%.
Mixed herbicide of the present invention, wherein the acid of chlorine Fampridine exists with the form of water soluble salt, and the water soluble salt of described chlorine Fampridine acid comprises the water soluble salts such as sodium salt, sylvite, ammonium salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, triisopropanolamine salt.
Chlorine Fampridine acid of the present invention is with the binary built preparation of careless ammonium phosphine, except the acid of chlorine Fampridine is with except careless ammonium phosphine active ingredient, the auxiliary agents such as conventional surfactants, thickener, solvent or the solid packing that pesticidal preparations allows can also be added and be mixed with any one formulation that agricultural chemicals allows.Preferably be processed into water dispersible granules, water solube powder, soluble liquid, aqua.
" % " of the present invention is mass percentage.
The application of mixed herbicide in uncultivated area, orchard, forest land and wheat paddock weeding of chloride Fampridine acid of the present invention and careless ammonium phosphine, has remarkable result preventing and kill off the application in uncultivated area, orchard, forest land and wheat paddock in various broad leaved weed.
Compared to the prior art, beneficial effect of the present invention:
Mixed herbicide of the present invention, has instant effect, herbicide spectrum width, and the advantages such as the lasting period is long, weeding is thorough, it is low to remain, low toxicity, safety and environmental protection are the uncultivated area of high-quality, orchard, forest land and wheat paddock chemical herbicide.
Specific embodiments
Embodiment 1
Grass ammonium phosphine 50%, chlorine Fampridine acid 25%, dodecyl pump sodium sulfonate 5%, lauryl sulfate 2%, ammonium sulfate to 100%, formulation method is conveniently mixed with the water dispersible granules that mass percentage is 75%.Wherein the acid of chlorine Fampridine exists with sodium-salt form.
Embodiment 2
Grass ammonium phosphine 20%, chlorine Fampridine acid 30%, neopelex 5%, alkylphenol polyoxyethylene 3%, ammonium sulfate 100%, formulation method is conveniently mixed with the water solube powder that mass percentage is 50%.Wherein the acid of chlorine Fampridine exists with ammonium salts.
Embodiment 3
Grass ammonium phosphine 5%, chlorine Fampridine acid 5%, neopelex 5%, alkyl glycoside 5%, isopropyl alcohol 15%, ethylene glycol 5%, water to 100%, formulation method is conveniently mixed with the soluble liquid that mass percentage is 10%.Wherein the acid of chlorine Fampridine exists with isopropyl amine salt form.
Embodiment 4
Grass ammonium phosphine 20%, chlorine Fampridine acid 10%, neopelex 5%, alkyl glycoside 5%, water to 100%, formulation method is conveniently mixed with the aqua that mass percentage is 30%.Wherein the acid of chlorine Fampridine exists with sodium-salt form.
Embodiment 5
1, toxicity determination test
Utilize the preparation in embodiment 1 ~ 4, measure its co-toxicity coefficient to acalypha copperleaf.
Test method: be seeded in respectively in the Disposable paper cup of 9cm by the seed of quantitative acalypha copperleaf, sows 10 ~ 15 seeds in every glass, cultivates in illumination box, when acalypha copperleaf 3 ~ 6 leaf phase, does composition spray to carry out spraying process in crawler type.Continue in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, weighs the weeds fresh weight after each process after 30d, and the method proposed by nineteen sixties such as Sun Yunpei, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is greater than 100, and show that two kinds of active principles have synergistic effect, co-toxicity coefficient is less than 100, shows that two kinds of active principles have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As can be seen from Table 1, the co-toxicity coefficient after two kinds of active principles are composite is all greater than 100, illustrates that the present invention has obvious synergistic effect.
2, field control effectiveness test
Reagent agent: 4 kinds of re-compounded binary herbicides in embodiment 1 ~ 4.
Contrast medicament: 200g/L grass ammonium phosphine aqua (commercially available), 30% chlorine Fampridine sour water agent (commercially available).
Control crop: wheat.
Prevent and kill off object: the weeds such as dayflower, acalypha copperleaf, shepherd's purse, amur foxtail.
Test method: according to the area of experimental plot, the good various medicament of precise, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head that sprinkler selection weed killer herbicide is special.During spraying, liquid be noted evenly to spray application in experimental plot, accomplish the phenomenon not having drain spray, many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and the activity of weeding of more various medicament.
Embodiments of the invention preparation Herbicidal Testing Trials effect sees the following form 20d after 2(medicine) and table 3(medicine after 40d)
Table 2 field control effectiveness test result (after medicine 20d)
Table 3 field control effectiveness test result (after medicine 40d)
As can be seen from table 2 and table 3, the present invention has significant preventive effect to broad leaved weeds such as dayflower, clearvers, shepherd's purse, amur foxtails, significantly building performance, and instant effect, lasting period are long.
Claims (10)
1. a mixed herbicide for the acid of chloride Fampridine and careless ammonium phosphine, it is characterized in that this weed killer herbicide with the acid of chlorine Fampridine with careless ammonium phosphine for principle active component, the acid of chlorine Fampridine is 0.1 ~ 80:0.1 ~ 80 with the mass ratio of careless ammonium phosphine.
2. chloride Fampridine acid according to claim 1 and the mixed herbicide of careless ammonium phosphine, is characterized in that in this weed killer herbicide, the acid of chlorine Fampridine is 1 ~ 60:1 ~ 60 with the mass ratio of careless ammonium phosphine.
3. chloride Fampridine acid according to claim 2 and the mixed herbicide of careless ammonium phosphine, is characterized in that in this weed killer herbicide, the acid of chlorine Fampridine is 0.5 ~ 1.5:1 with the mass ratio of careless ammonium phosphine.
4. chloride Fampridine acid according to claim 1 and the mixed herbicide of careless ammonium phosphine, is characterized in that the acid of chlorine Fampridine is 1 ~ 85% with the mass percentage of careless both ammonium phosphines in weed killer herbicide.
5. chloride Fampridine acid according to claim 4 and the mixed herbicide of careless ammonium phosphine, is characterized in that the acid of chlorine Fampridine is 10 ~ 75% with the mass percentage of careless both ammonium phosphines in weed killer herbicide.
6. the chloride Fampridine acid according to arbitrary one of claim 1-5 and the mixed herbicide of careless ammonium phosphine, it is characterized in that the acid of described chlorine Fampridine exists with the form of water soluble salt, the water soluble salt of described chlorine Fampridine acid comprises sodium salt, sylvite, ammonium salt, isopropyl amine salt, methylamine salt, dimethylamine salt, alcohol salt, triethanolamine salt, triisopropanolamine salt.
7. the mixed herbicide of chloride Fampridine acid according to claim 1 and careless ammonium phosphine, it is characterized in that it with the acid of chlorine Fampridine with careless ammonium phosphine for the auxiliary agent that principle active component and agricultural chemicals allow is mixed with any one formulation.
8. chloride Fampridine acid according to claim 7 and the mixed herbicide of careless ammonium phosphine, is characterized in that described formulation is water dispersible granules, water solube powder, soluble liquid, aqua.
9. the application of mixed herbicide in uncultivated area, orchard, forest land and wheat paddock weeding of chloride Fampridine acid according to claim 1 and careless ammonium phosphine.
10. chloride Fampridine acid according to claim 1 is preventing and kill off the application in uncultivated area, orchard, forest land and wheat paddock in various broad leaved weed with the mixed herbicide of careless ammonium phosphine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310573155.XA CN104621177A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and glufosinate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310573155.XA CN104621177A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and glufosinate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104621177A true CN104621177A (en) | 2015-05-20 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310573155.XA Pending CN104621177A (en) | 2013-11-15 | 2013-11-15 | Mixed herbicide containing picloram and glufosinate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104621177A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110881474A (en) * | 2018-09-10 | 2020-03-17 | 四川利尔作物科学有限公司 | Herbicidal composition and use thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080114168A1 (en) * | 2004-06-21 | 2008-05-15 | Coret Joel M | Novel esters as useful broad spectrum herbicidal compounds |
| CN103053609A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Glufosinate-picolinic acid herbicide weeding composition |
-
2013
- 2013-11-15 CN CN201310573155.XA patent/CN104621177A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080114168A1 (en) * | 2004-06-21 | 2008-05-15 | Coret Joel M | Novel esters as useful broad spectrum herbicidal compounds |
| CN103053609A (en) * | 2012-12-29 | 2013-04-24 | 广东中迅农科股份有限公司 | Glufosinate-picolinic acid herbicide weeding composition |
Non-Patent Citations (2)
| Title |
|---|
| 张一宾: "含吡啶环的新的农药及医药品种", 《精细与专用化学品》, vol. 17, no. 17, 6 September 2009 (2009-09-06) * |
| 赵平: "新型除草剂Aminocyclopyrachlor", 《农药》, vol. 50, no. 11, 10 November 2011 (2011-11-10), pages 834 - 836 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110881474A (en) * | 2018-09-10 | 2020-03-17 | 四川利尔作物科学有限公司 | Herbicidal composition and use thereof |
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