CN104627542B - Volatilization container and medicine volatilizer - Google Patents
Volatilization container and medicine volatilizer Download PDFInfo
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- CN104627542B CN104627542B CN201410643813.2A CN201410643813A CN104627542B CN 104627542 B CN104627542 B CN 104627542B CN 201410643813 A CN201410643813 A CN 201410643813A CN 104627542 B CN104627542 B CN 104627542B
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Abstract
The present invention provides a kind of volatilization container of following composition, i.e. can effectively by volatile substances, even and if in the case where container is toppled over, carrier will not also overflow to outside container.The present invention is to make volatile materials to the volatilization of outside volatilization with container (100), is possessed：Container body (10), it has the opening portion (11) of carrier of the storage containing volatile materials；With lid (20), it is provided with the evaporation hole (21) that the volatile materials that will be volatilized from carrier is released to outside, container body (10) is installed in the way of with opening portion (11) discontiguous state coverage opening portion (11), limiting unit (22) is provided with the inside of lid, when lid (20) is installed on into container body (10), limiting unit (22) prevent carrier from opening portion (11) to container body (10) around overflow.
Description
Technical field
The present invention relates to making volatile materials to the volatilization container of outside volatilization and having used the volatilization container
Medicine volatilizer.
Background technology
For pest, commercially sale has has volatile insect-proof agent at normal temperatures.This kind of insect-proof agent is general
Peddled with following state, i.e. will be fitted into container body with volatile carrier, the opening portion of container body is sealed
Material etc. is sealed, and is closed the lid on container body.In container body or lid, in order that volatile ingredient can volatilize and
It is provided with multiple holes.When in use, temporarily lid container body is removed, peels off the sealing of the opening portion of covering container body
Material, lid is arranged on container body.Due to being this kind of composition, therefore it is defence container situation about toppling over, it is necessary to holding
Device main body, lid are designed so that insect-proof agent will not overflow.
In the past, on having received the container of volatile ingredient, have while volatile ingredient is effectively volatilized, avoid
The container for aromatics that the moisture isolated from gel aromatic outwards spills (for example, referring to patent document 1).According to patent
Document 1, discloses following container, i.e. the volatilization opening of aromatic is set in lid, and is provided with installation direction limitation machine
Structure, its top part and top part of the master face with lid and master so that the container body of the volatilization opening of aromatic will be formed with
The mode that side surface part is configured face to face, limitation aromatic case is to the installation direction on lid；And orientation maintaining means, it is by virtue
Pastil box is positioned at the overall inside of the top part of the container body of mounted aromatic case, side surface part.By so composition,
Just can effectively volatilize the volatile ingredient of aromatic, even if in the case where lid is placed vertically, can also avoid from gel
The moisture isolated in aromatic outwards spills.
On the other hand, it is designed as toppling over the container that its content will not also overflow even if having (referring for example to patent document 2).
According to patent document 2, constitute as shown below, i.e. installed with small hole in the outer container of funnelform mouth is provided with
Inner pressurd vessel, when powder is added in outer container, micro powder will enter in inner pressurd vessel through the small hole.Even if holding
Device is toppled over, and the powder into inner pressurd vessel is also very micro, further, since the mouth of outer container is funnel-form, therefore, it is difficult to the powder for sliding
End is parked in the way of funnel, so being the container that will not outwards overflow.
Prior art literature
Patent document
Patent document 1：No. 201240254 publications of Japanese Unexamined Patent Publication
Patent document 2：Japanese real public clear No. 5771042 publications
The content of the invention
Invent problem to be solved
For the container for receiving the carrier of the volatile materials containing insect-proof agent etc, first, it is desirable to be expeditiously simultaneously
And effectively make the composition of volatile substances.In addition, be set to the carrier in the case where container is toppled over will not be excessive to container
The composition for going out is also critically important.
At this point, according to patent document 1, it is intended that by the container and the container that design storage gel aromatic
The composition of lid avoids the moisture isolated from gel aromatic to overflowing outside container, and realizes volatilization efficiency
Improve.But, due to being overflowed to outside container without the estimated carrier of volatile materials that is supported with, once therefore container topple over, carry
Body is possible to be overflowed to outside container, it is believed that volatilization efficiency can be impacted.
On the other hand, according to patent document 2, constitute as shown below, i.e. the opening portion of outer container is funnel-form, therefore
In the case where container is toppled over, the powder of receiving is difficult to be slid on funnelform surface, thus stops on the way, will not be to container
Outer spilling.But, in the case that the powder in outer container, inner pressurd vessel enters in large quantities, would not stop in funnelform way
Only, it is possible to be overflowed to outside container.Further, since hole is not provided with above container, it can be said that being not suitable for
The container of the volatile materials such as storage insect-proof agent.
The present invention is to complete in view of the above problems, it is intended that for receiving waving containing insect-proof agent or the like
The container of the carrier of volatile material, there is provided even if with the feelings that volatile materials can be made effectively to volatilize and topple in container
The volatilization container that carrier will not also be constituted to the mode overflowed outside container under condition.Additionally, the present invention also aims to, there is provided
The medicine volatilizer of the volatilization container is used.
For the method for solve problem
The characteristic of the volatilization container of the invention for solving the above problems constitutes and is,
It is the volatilization container for making volatile materials to outside volatilization,
Possess：
Container body, it has the opening portion of carrier of the storage containing the volatile materials；With
Lid, it is provided with the volatile materials that will be volatilized from the carrier to the outside evaporation hole released, with
Be installed on the mode that the opening portion covers in the container body by the discontiguous state in opening portion,
Limiting unit is provided with the inside of the lid, when the lid is installed in the container body, the limit
Portion processed prevents the carrier from the opening portion to spilling around the container body.
In general, in the volatilization container of storage volatile materials, in order to be volatilized before using when starting
And opening portion encapsulant by container body etc. is sealed, lid is being installed using encapsulant etc. is peelled off when starting.This
When, in the case where the opening portion of container body is installed into lid with fully covering, due to can only be from being located at and opening portion
Face identical area and the volatilization in the evaporation hole above the lid of the surface in the face, therefore volatilization deterioration of efficiency,
It is difficult to give play to sufficiently volatilization effect.
But, according to the volatilization container that this is constituted, comprising top is for the container body of opening portion and is provided with for making to wave
The lid in the hole (evaporation hole) that volatile material volatilizees to outside, when the lid is installed on into container body, will be so that lid
With opening portion for the mode of contactless state is constituted.That is, lid is with opening portion and indirectly contacts, but at both
Between form gap.Further, since volatile materials can be released through the gap in the evaporation hole from located at lid, because
This volatilization efficiency is improved, and volatile materials can be made promptly to be full of and use space.
In addition, in the inner side of lid, being provided with for the carrier for preventing from being accommodated in container body to the limitation around overflowed
Portion.Thus, in the case where container is toppled over, even if carrier is moved near opening portion, limiting unit can also turn into block, stop load
Body and prevent from opening portion overflow.Additionally, when making container upright, the carrier for colliding limiting unit returns to container body
Inside.
Thus, if the volatilization container of this composition, so that it may so that the volatilization efficiency of volatile materials is well allowed to
Effectively volatilize, even and if in the case where container is toppled over, it is also possible to carrier is prevented to around overflowing.
In volatilization container of the invention,
It is preferred that inner crest face of the limiting unit located at the lid, forms than described with it between the opening portion
The mode in the small gap of the size of carrier is constituted as the cylindrical member extended downwards from the inner crest face.
According to the volatilization container that this is constituted, limiting unit is set in the inner crest face of lid, when lid is installed on into container
During main body, between the small size of size of carrier than being accommodated in container body will be formed between limiting unit and opening portion
Gap.Thus, even if in the case where container is toppled over, it is also possible to reliably stop the load moved near opening portion using limiting unit
Body, when making container upright, returns to the inside of container body.
In addition, limiting unit is the cylindrical member extended downwards from above lid, can be along being set around opening portion
Put.Thus, no matter which direction container swings to, and can prevent carrier to around overflowing.
Further, since be formed with gap between the whole periphery and limiting unit of opening portion, therefore volatile materials can be with
Volatilized from the whole periphery of opening portion.Thus, volatile materials would not produce inequality on the direction of volatilization, can be whole
Using volatilizing while good efficiency is allowed in space.
In volatilization container of the invention,
It is preferred that in the cylindrical member, it is provided for making the size of carrier described in the ratio of the volatile materials circulation small
Throughput.
According to the volatilization container that this is constituted, throughput is provided with the cylindrical member for be construed as limiting portion.Thus, add
The gap between above-mentioned limiting unit and opening portion is formed at, volatile materials just can be through the throughput from located at lid
In evaporation hole in release.Thus, volatilization efficiency is improved, and volatilization effect is more excellent.
Further, since constituted in the way of making throughput be the size smaller than the size of carrier, even if therefore inclining in container
In the case of, overflowed to outside container through the throughput without the carrier for worrying to be stopped from limiting unit.Thus, waved in raising
While hair efficiency and volatilization effect, carrier can be prevented to around overflowing.
In volatilization container of the invention,
It is preferred that close constituting the limiting unit to the upper end of the opening portion by making the inner crest face of the lid.
According to the volatilization container that this is constituted, it is possible to use lid itself is construed as limiting portion.If so constituted,
In the case that container is toppled over, because carrier is stopped by the periphery of above lid and opening portion, therefore will not oriented container it is excessive
Situation about going out.Further, since volatile materials can be formed through the gap between lid and opening portion, from lid
Evaporation hole in release, therefore volatilization efficiency can be improved.
Further, since lid itself is constituted as limiting unit, therefore need not use attached component, can be with low cost
Ground makes volatilization container, it is also possible to be supplied to consumer as cheap product.
In volatilization container of the invention,
It is preferred that constituting the limiting unit by making the inner side surface of the lid to being close to around the opening portion.
According to the volatilization container that this is constituted, it is possible to use lid itself is construed as limiting portion.If so constituted,
In the case that container is toppled over, because carrier is stopped around the inner side surface of lid and opening portion, therefore will not oriented container
The situation of outer spilling.Further, since volatile materials can be formed through the gap between lid and opening portion, from located at lid
Released in evaporation hole in body, therefore volatilization efficiency can be improved.
Further, since lid itself is constituted as limiting unit, therefore does not need attached component, can be with low-cost production
Volatilization container, it is also possible to be supplied to consumer as cheap product.
In volatilization container of the invention,
It is preferred that being constituted in the mode for making the evaporation hole in the lid smaller than the size of the carrier.
According to the volatilization container that this is constituted, with the mode structure for making the evaporation hole in lid smaller than the size of carrier
Into.Thus, even if container is toppled over, just in case overflowed in the opening portion of carrier container body, because the evaporation hole of lid is less than load
The size of body, therefore can also reliably prevent from being spilt into outside volatilization container through evaporation hole.
In addition, when making volatilization container upright, carrier is returned in container body, therefore can reuse.
Further, since by the size being dimensioned so as to less than carrier of evaporation hole, therefore evaporation hole can be located at lid
Multiple positions.Thus, it is possible to increase the number of evaporation hole and improve the volatilization efficiency of volatile materials, such that it is able to good
Ground plays volatilization effect.
The characteristic of the medicine volatilizer of the invention for solving the above problems constitutes and is,
The medicine volatilizer of the volatilization container being the use of described in above-mentioned any one,
As the carrier, the aqueous solution or water for water absorbent polymer is at least absorbed the volatile materials have been received
The microspheric medicament of aqueous gel of suspension.
According to the medicine volatilizer that this is constituted, due in volatilization container of the invention, being accommodated with aqueous gel micro-
The medicament of ball-type, therefore form security and the excellent medicine volatilizer of convenience.
In medicine volatilizer of the invention,
The volatile materials is preferably selected from flying pest repellent composition, flying pest repellent fragrance component, dress material to be prevented
At least one in worm repellent composition, dress material insect prevention fragrance component and fragrance component.
According to the medicine volatilizer that this is constituted, due to volatile materials be selected from each composition enumerated above at least
One kind, therefore optimal volatile materials can be selected according to the purposes application target of medicine volatilizer.Thus, Jiu Huiti
The convenience of medicine volatilizer high, realization is related to the use of many aspects.
Brief description of the drawings
Fig. 1 is the stereogram of the volatilization container of first embodiment, and (a) represents the exploded perspective of lid and container body
Figure, (b) represents stereogram when being mounted with lid of container body.
Fig. 2 is the profile of the volatilization container of first embodiment.
Fig. 3 is the profile of the volatilization container of second embodiment.
Fig. 4 is the profile of the volatilization container of the 3rd implementation method.
Fig. 5 is the profile of the volatilization container of the 4th implementation method.
Fig. 6 is the profile of the volatilization container of the 5th implementation method.
Fig. 7 is the use of the stereogram of the medicine volatilizer of the volatilization container of first embodiment.
Specific embodiment
Hereinafter, the implementation method of volatilization container for the present invention is illustrated based on Fig. 1~Fig. 6.For this hair
Bright medicine volatilizer, compactly illustrates while reference picture 7.But, be not intended to limit the invention to
Composition described in the implementation method of lower explanation, accompanying drawing.
<First embodiment>
Fig. 1 is the volatilization stereogram of container 100 of first embodiment of the invention.A () is volatilization container 100
Exploded perspective view, (b) is stereogram when lid is mounted with container body.Fig. 2 is first embodiment of the invention
The volatilization profile of container 100.Volatilization container 100 is in order that volatile materials described later is used to outside volatilization
Container, possesses container body 10 and lid 20.And, including the volatilization that including Fig. 2, the illustrates profile of container 100 later
It is the relation and the figure that illustrates that should be readily appreciated that container body 10 and lid 20, omissions of detail part.Thus, it is not necessarily essence
Thickly reflect the figure of the section of actual volatilization container 100.
As shown in Fig. 1 (a), container body 10 is the container with the end for possessing opening portion 11, is made the shape of ampuliform.Can be with
The carrier comprising volatile materials described later is received in the inside of main body 10.
As long as the material for constituting container body 10 will not become the volatile materials of the inside for being accommodated in container body 10
Matter and container body 10 will not be made itself to be deteriorated because of the volatile materials received, etch, corrosion etc. material i.e.
Can.As this kind of material, for example, can enumerate polyethylene terephthalate (PET), polybutylene terephthalate (PBT)
(PBT), polypropylene (PP), polyethylene (PE), polystyrene (PS), polymethyl methacrylate (PMMA), polyphenylene oxide (PPE),
Polyamide (PA), makrolon (PC), acrylonitrile butadient styrene (ABS), polyphenylene sulfide (PPS), polyethers
The thermoplastic resins such as ether ketone (PEEK), PEKK (PEKK) and polyformaldehyde (POM) or phenolic resin (PF), urea resin
(UF), the thermosetting resin such as melamine resin (MF), epoxy resin (EP) and polyurethane resin (PUR).In the middle of these resins,
Preferred intensity and the excellent polyethylene terephthalate (PET) of the transparency.And, contain organic solvent in volatile materials
When, it is possible to dissolve resin, therefore resin can also be replaced, for example with the inorganic material such as metal, glass, ceramics come
Constitute container body 10.In the case where resin material is used as the constituent material of container body 10, it is possible to use be injected into
The methods of forming such as type, extrusion molding, blow molding, compression forming make container body 10.
The capacity of container body 10 can be adjusted according to the amount of the carrier of the volatile materials being accommodated in container body 10
It is whole.Be accommodated in the volatile materials of container body 10 carrier amount by want to make the place of volatile substances or range,
Make determining during use etc. for volatilization lasts.From volatilization efficiency or volatile materials lasting effect viewpoint and
Ensure from the viewpoint of the security of container body 10, the capacity of container is preferably set to 50~500cc or so.Container body 10
Outward appearance preferably clear is semi-transparently constituted, so as to confirm the state of received volatile materials from outside.But,
In the case that volatile materials is easily decomposed by light, it is also possible to by container body 10 is with arbitrary color dyes or attaches shading
The encapsulant of property.
As shown in Fig. 1 (b), lid 20 is constituted as the container with the end of the opening portion 11 of covering container body 10.Such as
Shown in Fig. 1 (b), lid 20 is constituted as follows, i.e. when container body 10 is installed on, and is incited somebody to action with the discontiguous state in opening portion 11
Opening portion 11 covers.As shown in Fig. 1 (a), in lid 20, evaporation hole 21 and limiting unit 22 are provided with.Evaporation hole 21 is for making
The volatile materials of inside of container body 10 is accommodated in the outside hole for releasing.The shape and number of evaporation hole 21 can be any
Set.Limiting unit 22 is directed towards the cylindrical member of the extension of opening portion 11 located at the inner crest face of lid 20.As shown in Fig. 1 (b),
When lid 20 is installed on into container body 10, gap 23 is formed between opening portion 11 and limiting unit 22.The size in gap 23
The size for being set to the carrier containing volatile materials than being accommodated in container body 10 is small.Using this kind of composition, in volatilization
In the case of being toppled over container 100, even if carrier moves to the vicinity of opening portion 11, limiting unit 22 can also turn into block, can be with
Carrier is stopped.Thus, carrier will not be full of in lid 20, be there will not be in carrier container body 10 and overflowed and be scattering into
The situation of surrounding.Thus, because carrier residence is in container body 10, thus without worrying that the volatilization to volatile materials is imitated
Rate, volatilization effect have undesirable effect.If in addition, the week toppled over and making carrier be scattering into container body by volatilization container
Enclose, the danger that be put into for carrier in mouth by the place or children for just having placement volatilization container of making dirty, but if this implementation
The volatilization of mode container 100, then without producing this kind of worry.Thus, user can safely dispose volatilization container
100。
In addition, in limiting unit 22, the throughput 24 in the small hole of size of carrier than being accommodated in container body 10 is provided with.
Using this kind of composition, it is possible to passed through the volatile materials that loaded body is supported using the evaporation hole 21 located at the surface of lid 20
Throughput 24 and release.Herein, due to so that throughput 24 is the size smaller than being accommodated in the size of the carrier of container body 10
The mode in hole constitute, therefore in the case where volatilization container 100 is toppled over, carrier is impossible to calm through throughput 24
Overflowed in device main body 10.Thus, volatile materials is also sharp not merely with the gap 23 between opening portion 11 and limiting unit 22
Volatilized with throughput 24, released from evaporation hole 21.Thus, it is possible to further improve the volatilization efficiency of volatile materials
And volatilization effect.
As described above, being provided with evaporation hole 21 in lid 20, its shape and number can arbitrarily be set, and evaporation hole 21
Size is constituted in the small mode of the size of the carrier than being accommodated in container body 10.Due to being this kind of composition, even if therefore waving
Hair container 100 is toppled over, just in case carrier overflows and in the case of being full of lid 20 from opening portion 11, be there will not be through volatilization
Hole 21 and to volatilization with outside container 100 overflow situation.Thus, it is possible to reliably prevent carrier to be scattering into volatilization container
Around 100, a mouthful moderate risk is strayed into without the pollution at the setting position for worrying to produce volatilization container 100, children.Thus,
User can safely dispose volatilization container 100.Further, since evaporation hole 21 is size as described above, therefore can be with
Multiple positions are set in lid 20.In the case where so constituting, due to increasing for releasing the hole of volatile materials, therefore
Volatilization efficiency can further be improved.Thus, it is possible to the effect to promptly playing volatile materials using space.Additionally,
In the case where the evaporation hole 21 of size as described above is equably arranged on into the whole surface of lid 20, due to volatility thing
Matter can be released from the whole surrounding of volatilization container 100, therefore make volatile materials throughout using spatially volatilizing, so that can
To be difficult in using space to produce：Well play volatile materials effect position with can not well play the effect
Position difference.
As long as constitute the material of lid 20 do not make the volatile materials of the inside for being accommodated in container body 10 rotten and
Lid 20 will not be made itself to be deteriorated because of the volatile materials received, etch, the material of corrosion etc., it is possible to use
With the previously described composition material identical material of container body 10.
The size of lid 20 will matchingly set with container body 10, as long as but by the opening portion 11 of container body 10
The degree for reliably covering.The outward appearance of lid 20 can both be constituted transparent or semitransparently identically with container body 10,
Or can also be by lid 20 arbitrary color dyes or the encapsulant of attaching light-proofness.
As long as be construed as limiting the material in portion 22 do not make the volatile materials of the inside for being accommodated in container body 10 rotten and
And limiting unit 22 will not be made itself to be deteriorated because of the volatile materials received, etch, the material of corrosion etc., can be with
Use the material identical material with previously described composition container body 10, lid 20.
The size of limiting unit 22 can carry out various settings.The volatilization of present embodiment with container 100 as shown in Fig. 2 with
Make the periphery of limiting unit 22 positioned at the width of substantially surface, the width of limiting unit 22 and the opening portion 11 of the periphery of opening portion 11
Roughly the same mode is constituted.By so composition, even if in the case where volatilization container 100 is toppled over, there will not be containing
Situation about being overflowed in the carrier container body 10 of volatile materials, can play excellent volatilization efficiency as described above and wave
Hair effect.
<Second embodiment>
Fig. 3 is the volatilization profile of container 200 of second embodiment of the present invention.As shown in figure 3, so that limiting unit
22 width (external diameter) mode bigger than the width (external diameter) of opening portion 11 constitutes volatilization container 200.That is, so that limit
The mode that the periphery in portion processed 22 is located at the outside of opening portion 11 is constituted.So that be formed at the periphery of limiting unit 22 and opening portion 11 it
Between horizontal direction and vertical direction gap 23 carrier of the size than being accommodated in volatilization container 200 the small side of size
Formula is constituted.Others composition is identical with first embodiment, therefore omits detailed description.By as shown in second embodiment
Ground is constituted, even if in the case where volatilization container 200 is toppled over, there will not be the carrier container body containing volatile materials
Situation about being overflowed in 10, can play the volatilization efficiency and volatilization effect excellent with first embodiment identical.
<3rd implementation method>
Fig. 4 is the volatilization profile of container 300 of third embodiment of the present invention.As shown in figure 4, so that limiting unit
22 width (external diameter) mode smaller than the width (external diameter) of opening portion 11 constitutes volatilization container 300.That is, so that limit
The mode that the periphery in portion processed 22 is located at the inner side of opening portion 11 is constituted.So that be formed at the periphery of limiting unit 22 and opening portion 11 it
Between horizontal direction and vertical direction gap 23 carrier of the size than being accommodated in volatilization container 300 the small side of size
Formula is constituted.Others composition is identical with first embodiment, therefore omits detailed description.By as shown in the 3rd implementation method
Ground is constituted, even if in the case where volatilization container 300 is toppled over, there will not be the carrier container body containing volatile materials
Situation about being overflowed in 10, can play the volatilization efficiency and volatilization effect excellent with first embodiment identical.
<4th implementation method>
Fig. 5 is the volatilization profile of container 400 of the 4th implementation method of the invention.As shown in figure 5, volatilization container
400 are construed as limiting portion by making the inner crest face 20a of lid 20 near the upper end of opening portion 11.That is, it is possible to use
Lid 20 itself is construed as limiting portion.The size in the gap 25 formed by the inner crest face 20a and opening portion 11 of lid 20 is set
The size for being set to the carrier containing volatile materials than being accommodated in volatilization container 400 is small.Even if in volatilization container 400
In the case of toppling over, carrier cannot also pass through gap 25, therefore without worrying to be overflowed in container body 10.Therefore, it is possible to send out
Wave the volatilization efficiency and volatilization effect excellent with first embodiment identical.Further, since lid 20 itself is used as limiting unit
Constitute, therefore attached component need not be used, can at low cost make volatilization container 400, it is also possible to as cheap
Product is supplied to consumer.
<5th implementation method>
Fig. 6 is the volatilization profile of container 500 of the 5th implementation method of the invention.As shown in fig. 6, volatilization container
500 are construed as limiting portion by making the inner side surface 20b of lid 20 around opening portion 11.That is, it is possible to use
Lid 20 itself is construed as limiting portion.The size in the gap 26 formed by the inner side surface 20b and opening portion 11 of lid 20 is set
The size for being set to the carrier containing volatile materials than being accommodated in volatilization container 500 is small.Even if in volatilization container 500
In the case of toppling over, carrier cannot also pass through gap 26, therefore without worrying to be overflowed in container body 10.And, in figure 6
In the case that shown volatilization is with container 500, once volatilization container 500 is toppled over, carrier will temporarily to opening portion 11 with
Overflowed between above lid 20, when making volatilization container 500 upright, the inside of container body 10 will be quickly returned to.
Therefore, it is possible to play the volatilization efficiency and volatilization effect excellent with first embodiment identical.Further, since lid 20 itself
Constituted as limiting unit, therefore attached component need not be used, can at low cost make volatilization container 500, it is also possible to
Consumer is supplied to as cheap product.
<Volatile materials>
[flying pest repellant]
Volatilization container 100~500 of the invention for example can be as repellent mosquito, buffalo gnat, midge, fly class, small fly
The flying pests such as class and the medicine volatilizer that uses are used.In this case, in the volatilization inside conduct of container 100~500
Volatile materials receives the flying pest repellant containing flying pest repellent composition.Although flying pest repellant can also be with
Constant state is accommodated in volatilization container 100~500 as former state, but if volatility material high, then have and be difficult to
The situation of control volatile quantity from container.Thus, in order that the disposal of flying pest repellant becomes easy, preferably will be appropriate
Flying pest repellant be dissolved in the water and prepared as the aqueous solution, or in flying pest repellant feelings insoluble in water
Under condition, prepared as the aqueous suspension of flying pest repellant, with the aqueous gel microballoon that is allowed to be maintained in gel micro-ball
Form is received.The microspheric flying pest repellant of aqueous gel is driven containing flying pest by absorbing water absorbent polymer
Keep away the flying pest of composition (also continuing composition containing flying pest repellent fragrance component, repellent effect as needed) and water
Repellent flavor compositions and prepare.Flying pest repellent composition is with volatile material, in this specification, by the evil of circling in the air
Worm repellent composition or the flying pest repellent flavor compositions containing the flying pest repellent composition as volatile materials at
Put.The selective volatilization material in the way of the vapour pressure for making 20 DEG C is 0.01~50Pa.Hereinafter, to constituting the one of volatile materials
All or part of flying pest repellent composition is illustrated.
Flying pest repellent composition contains：
A () is selected to lead to formula (I)：
CH3-COO-R1···(I)
(R1：Carbon number is 6~12 alcohol residue)
The acetate compound of expression, and/or with lead to formula (II)：
R2-CH2-COO-CH2- CH=CH2···(II)
(R2：Alkyl that carbon number is 4~7, the alkoxy that carbon number is 4~7, the cycloalkyl that carbon number is 4~7, carbon number are 4~7
Cycloalkyloxy or phenoxy group)
The fragrance component of one or more of the allyl ester compound of expression；With
B () is selected from the fragrance component of one or more of monoterpene system alcohol or aromatic alcohols that carbon number is 10.
As to lead to the acetate compound that formula (I) is represented, for example, can enumerate vertenex, acetic acid adjacent
T-butyl cyclohexyl methacrylate, acetic acid are to tertiary pentyl cyclohexyl, cyclacet, benzyl acetate, phenethyl acetate, acetic acid storax
Ester, acetic acid fennel ester, cinnamyl acetate, terpinyl acetate, dihydroterpinyl acetate, bergamio, ethyl linalyl acetate,
Vanillin acetate, geranyl acetate, neryl acetate, borneolacetate and isobornyl acetate etc..These acetic acid esters chemical combination
Thing can both be used alone, it is also possible to arbitrarily be applied in combination.
As allyl hexanoate, allyl heptanoate, pungent leading to the allyl ester compound that represents of formula (II), such as can be enumerated
Allyl propionate, isobutoxy allyl acetate, n-pentyloxy allyl acetate, allyl cyclohexane acetate, cyclohexylpropionic acid alkene
Propyl ester, cyclohexyloxy allyl acetate, Allyl Phenoxyacetate etc..These allyl ester compounds can both be used alone,
Can also arbitrarily be applied in combination.
As the representational example of the aromatic alcohols that monoterpene system alcohol or carbon number are 10, for example, terpineol, geraniol, two
Hydrogen myrcenol, borneol, menthol, citronellol, nerol, linalool, ethyl linalool, Thymol, eugenol and
To terpane -3,8- glycol etc..These monoterpene system alcohol or the aromatic alcohols that carbon number is 10 can both be used alone, it is also possible to appoint
Meaning it is applied in combination.
Flying pest repellent flavor compositions can also as flying pest repellent fragrance component, suitably add it is above-mentioned with
The monoterpene such as outer fragrance component, such as limonene system hydrocarbon, menthones, carvol, pulegone, down ketone, damascone
Etc. (Damascone) the monoterpene system aldehyde such as monoterpene system ketone, citral, citronellal, neral, perillaldehyde, cinnamyl formate, formic acid are fragrant
The ester compounds such as leaf ester, phenylethyl alcohol, diphenyl ether, dihydro indenyl -2,4- dioxs (Dihydroindenyl-2,4-
Dioxane, indolarome) etc., further, it is also possible to suitably various essential oil classes of the addition containing above-mentioned fragrance component, for example
Jasmin oil, neroli oil, peppermint oil, bergamot oil, orange oil, pelargonium oil, petit grain oil, lemon oil, citronella oil, lemongrass oil,
Cassia oil, eucalyptus oil, eucalyptus citriodora oil, thyme linaloe oil etc..
Flying pest repellent flavor compositions are preferably as the repellent effect after the volatilization of flying pest repellent fragrance component
Continue composition, the vapour pressure for coordinating 20 DEG C is more than one the ethylene glycol and/or glycol ether of 0.2~20Pa.As its tool
Style, can enumerate propane diols (10.7Pa), DPG (1.3Pa), tripropylene glycol (0.67Pa), diethylene glycol (DEG) (3Pa), three sweet
Alcohol (1Pa), 1,3 butanediols, hexylene glycol (6.7Pa), ethylene glycol benzyl ether (2.7Pa), diethylene glycol monobutyl ether (3Pa), dipropyl two
Alcohol monobutyl ether and Tripropylene glycol monomethyl Ether.The numerical value in bracket after material name represents 20 DEG C of vapour pressure.These repellents are imitated
Fruit continues in the middle of composition, preferably uses DPG.And, above-mentioned ethylene glycol and/or glycol ether both can individually make
With, it is also possible to arbitrarily it is applied in combination.
In flying pest repellent flavor compositions, for example, can also coordinate insecticidal constituent, deodorant composition, degerming antibacterial
The others functional components such as composition.As insecticidal constituent, can enumerate normal temperature volatility pyrethroid system Prallethrin,
Third Flumethrin, transfluthrin, metofluthrin etc..As deodorant composition, it is representational be selected from grass family, Theaceae,
Plant extracts in Ginkgoaceae, Oleaceae, Moraceae, Rutaceae, Malpighiaceae, Ebenaceae.Furthermore it is also possible to add be referred to as
Leaf alcohol, the leaf aldehyde of " green perfume (or spice) " etc. assign relaxation effect.These functional components can both be used alone, it is also possible to
Arbitrarily it is applied in combination.
When the microspheric flying pest repellant of aqueous gel is prepared, preferred flying to infiltration water absorbent polymer in advance
Matching surface activating agent in Xiang pest repelling flavor compositions (infiltration liquid).Surfactant is by flying pest repellent combinations of perfumes
Thing is reliably held at the inside of gel micro-ball, contributes to its sustained releaseization.As a result, it is possible to that plays stably for a long time circles in the air
Pest repelling effect.As surfactant, for example, can enumerate the senior alkane of polyoxyethylene rilanit special, polyoxyethylene
Base ethers (polyoxyethylenelauryl ether, polyoxyethylene oleyl ether etc.), polyoxyethylene phenyl ethers, polyoxy Asia second
Base higher fatty acids esters, polyoxyethylene sorbitan fatty acid ester class, polyoxyethylene glycerine fatty acid esters, polyoxy
The nonionic surfactants such as ethylidene polyoxypropylene alkyl ether, lauryl amine oxide, stearic amine oxide, bay
The senior alkyl amine oxide system surfactant such as amido propyl dimethylamine oxide.These surfactants both can be independent
Use, it is also possible to be arbitrarily applied in combination.
In water absorbent polymer, acrylic acid series water absorbent polymer is preferably used.Acrylic acid series water absorbent polymer
Water imbibition is excellent, can absorb more than 100 times of deadweight of water.If the acrylic acid series water imbibition of particle diameter about 2mm or so is gathered
Compound, then can also be expanded into particle diameter about 10mm or so after absorbing infiltration liquid while substantially transparent state is maintained.Make
Be acrylic acid series water absorbent polymer, can enumerate acrylic acid/acrylate copolymer (acrylic acid/sodium acrylate salt copolymer,
Acrylic acid/potassium acrylate salt copolymer etc.), the copolymer of acrylamide/acrylic acid or its salt.
In the preparation of the microspheric flying pest repellant of aqueous gel, for example, to the suitable capacity with opening portion
Transparent vessel in add ormal weight water absorbent polymer, followed by injection the infiltration liquid containing flying pest repellant
Operation.Now, as the container for preparing the microspheric flying pest repellant of aqueous gel, it is also possible to waved using of the invention
Hair container.Other are arrived in this case, can save and change the prepared microspheric flying pest repellant of aqueous gel
Time in volatilization container.In the preparation of the microspheric flying pest repellant of aqueous gel, water absorbent polymer and leaching
Sepage whichsoever can before to the ordering in launching in container.In addition, in infiltration liquid, as needed, it is also possible to suitable
Locality is with bitters, pH adjusting agent, colouring agents such as preservative, the Bitrex such as stabilization agent, the isothiazoline systems such as bonding solvent, BHT
Deng.
Solvent used, for example, can enumerate second in preparation as the microspheric flying pest repellant of aqueous gel
Hydrocarbon system solvents such as the lower alcohols such as alcohol, isopropanol, ketone series solvent, ester series solvent, normal paraffin hydrocarbons, isoparaffin etc..These solvents were both
Can be used alone, it is also possible to be arbitrarily applied in combination.
[dress material insect-proof agent]
The volatile materials in volatilization container 100~500 of the invention is accommodated in except flying pest as described above
Beyond repellant, for example, can also be and imitated with the vermins-proof effect to dress material insects such as casemaking clothes moth class, khapra beetle class, tassel tail classes, desinsection
The dress material insect-proof agent of fruit.That is, it is preferred that identical with above-mentioned flying pest repellant, by appropriate dress material insect-proof agent
It is dissolved in the water and is prepared as the aqueous solution, or in the case where dress material is insoluble in water with insect-proof agent, uses anti-as dress material
Prepared by the aqueous suspension of worm agent, to be allowed to the form storage of the aqueous gel microballoon being maintained in gel micro-ball.Aqueous gel is micro-
The dress material insect-proof agent of ball-type is that (as needed, also dress material uses anti-by making water absorbent polymer absorb dress material insect prevention composition
Worm fragrance component, pyrethroid system insecticidal constituent, continuation fragrance component) and prepare.
The dress material insect-proof agent being accommodated in volatilization container 100~500 of the invention can be made comprising following composition
It is standby, i.e. (c) is as dress material insect prevention composition with following formula (III)：
CH3-COO-R3···(III)
(R3：Carbon number is 6~12 alcohol residue)
More than one acetate compound, (d) for representing have volatile more than one plan deinsectization at normal temperatures
Chrysanthemum ester system insecticidal constituent.Additionally, the dress material insect-proof agent being accommodated in volatilization container 100~500 of the invention can be except
Also prepared comprising following composition ground beyond dress material insect prevention composition and pyrethroid system insecticidal constituent, i.e. (e) dress material insect prevention spices
Composition and (f) have the continuation fragrance component of the continuation longer than dress material insect prevention fragrance component.Hereinafter, to each composition
Illustrate.
(c) dress material insect prevention composition
The specific acetate compound represented with the formula (III) used as dress material insect prevention composition be with it is described later
The ester compounds that pyrethroid system insecticidal constituent is similar in chemical constitution.The volatility of acetate compound has following
Characteristic, i.e. the volatility with the terpene compound that can be added as dress material insect prevention fragrance component described later is substantially equal
Degree, and it is bigger than the volatility of pyrethroid system insecticidal constituent.Thus, acetate compound can be with pyrethroid system
Insecticidal constituent synergistically plays enhancing based on cooperative effect in the long-time from using initial stage more than the several months
Vermins-proof effect.In addition, in the duration of dress material insect prevention composition, also improve armaticity using acetate compound.
As the alcohol residue (R in the acetate compound represented with the formula (III)3), can enumerate can use carbon number
Alkyl-substituted cycloalkyl, phenylalkyl (carbon number between phenyl and ester group is 1~3), the terpene that carbon number is 1~3 for 1~5
Enol residue etc..That is, as acetate compound, can enumerate vertenex, verdox,
Acetic acid is to tertiary pentyl cyclohexyl, cyclacet, benzyl acetate, phenethyl acetate, methyl phenyl carbinyl acetate, acetic acid fennel
Ester, cinnamyl acetate, terpinyl acetate, dihydroterpinyl acetate, bergamio, ethyl linalyl acetate, Vanillin acetate,
Geranyl acetate, neryl acetate, borneolacetate and isobornyl acetate etc..In the middle of them, suitable acetic acid esters chemical combination
Thing be vertenex, verdox, cyclacet, benzyl acetate, terpinyl acetate,
Dihydroterpinyl acetate and ethyl linalyl acetate.These acetate compounds can be used alone, but can also make
For two or more mixtures is used.
(d) pyrethroid system insecticidal constituent
As the pyrethroid system insecticidal constituent being applied in combination with above-mentioned dress material insect prevention composition, eneyne chrysanthemum can be enumerated
Ester, the third Flumethrin, transfluthrin, metofluthrin and terallethrin etc..These pyrethroid system desinsections into
Dividing to be used alone, but can also be used as two or more mixtures.In addition, being killed in these pyrethroid systems
In worm composition, there are based on asymmetric carbon, the optical isomer of double bond, geometric isomer, but can also be independent by them
Ground is used as arbitrary mixture.
(e) dress material insect prevention fragrance component
The dress material insect-proof agent in volatilization container 100~500 of the invention is accommodated in order to further enhance using just
The vermins-proof effect in stage phase, can contain terpene compound as dress material insect prevention fragrance component.The confirmation such as the present inventor, if
In above-mentioned dress material insect prevention composition and use terpene compound, then can be long lasting for using the vermins-proof effect of initial stage.Separately
Outward, terpene compound also has as the function of deodorant tune, thus, it is possible to improve armaticity within the longer time.As terpenes
Compound, can enumerate terpineol, citronellol, geraniol, nerol, linalool, dihydro linalool, tetrahydrolinalool, dihydro
Terpenic series aldehyde, the Sheep's-parsleys such as the terpenic series such as myrcenol, menthol, borneol, isoborneol alcohol, citronellal, citral, dimethyl octanal
Terpenic series ketone such as ketone, dihydro carvone, pulegone, menthones etc..These terpene compounds can be used alone, but
Can also be used as two or more mixtures.Terpene compound can also be the shape of the plants essential oil containing terpene compound
State.As plants essential oil, citronella oil, orange oil, lemon oil, limette oil, grape-fruit seed oil, lavender oil, peppermint oil, osmanthus can be enumerated
Skin oil, eucalyptus oil, eucalyptus citriodora oil, Japan cypress oil, oil of grapefruit, cedar oil, pelargonium oil, thyme white oil, peppermint oil, Jasmine
Oil, oil of juniper wood, green tea essential oil etc..
(f) continuation fragrance component
The dress material insect-proof agent in volatilization container 100~500 of the invention is accommodated in order to further improve insect prevention effect
Fruit and the continuation of fragrance, can contain continuation fragrance component.If fragrant in above-mentioned dress material insect prevention composition and dress material insect prevention
Outside material composition, also using continuation fragrance component, then will be tailed off using the going down for vermins-proof effect of later stage, Ke Yishi
It is now able to undergo the long-term dress material insect prevention composition for using of 6~about 12 months.As continuation fragrance component, can enumerate
Jiale muskiness, muskone, jasminolene, brazilic acid glycol ester, oak moss (methyl atrarate), 1-Hexyl salicylate, tangerine
Brilliant (oranger crystal) etc..These continuation fragrance components can be used alone, but can also be used as two or more
Mixture use.
(composition of dress material insect-proof agent)
Dress material insect prevention composition is preferably set with the compounding ratio ((c): (d)) of pyrethroid system insecticidal constituent with weight ratio meter
It is 0.02: 1~0.4: 1.If the scope, then can intend removing while vermins-proof effect of the enhancing using initial stage
Dress material insect prevention composition is set to play a role in the whole duration of worm chrysanthemum ester system insecticidal constituent.As a result, it is possible to using by intending
Insecticidal effect and the cooperative effect of the vermins-proof effect brought by dress material insect prevention composition that pyrethrins system insecticidal constituent brings, when long
Between persistently play enhanced effect and armaticity.Even if the compounding ratio of dress material insect prevention composition and pyrethroid system insecticidal constituent
((c): (d)) is more than above range, the insecticidal effect brought by pyrethroid system insecticidal constituent and by dress material insect prevention composition band
The cooperative effect of vermins-proof effect come also has culminated, less can desired effects further raising.If dress material insect prevention into
Divide and had below above range, then and cannot fully obtained with the compounding ratio ((c): (d)) of pyrethroid system insecticidal constituent
Obtain and effect is cooperateed with by pyrethroid system the insecticidal constituent insecticidal effect for bringing and the vermins-proof effect brought by dress material insect prevention composition
Situation about answering.
Continuation fragrance component is preferred with weight ratio meter with the compounding ratio ((f): (d)) of pyrethroid system insecticidal constituent
It is set to 0.02: 1~0.4: 1.If the scope, then outside above-mentioned dress material insect prevention composition, continuation spices can also be utilized
Composition extends dress material insect-proof agent during use, while can be in the whole duration of pyrethroid system insecticidal constituent
In continuation fragrance component is played a role.As a result, it is possible to using the desinsection brought by pyrethroid system insecticidal constituent
Effect and the cooperative effect of the vermins-proof effect brought by dress material insect prevention composition and continuation fragrance component, for longer periods persistently send out
Wave the effect and armaticity being further enhanced.If the cooperation of continuation fragrance component and pyrethroid system insecticidal constituent
Ratio ((f): (d)) exceedes above range, then the volatile quantity of pyrethroid system insecticidal constituent is suppressed, cannot so as to have
The situation of sufficient insecticidal effect is obtained in during use.If continuation fragrance component and pyrethroid system insecticidal constituent
Compounding ratio ((f): (d)) had below above range, then and cannot fully realize what is brought by continuation fragrance component
The extension during use of dress material insect-proof agent.
Be accommodated in dress material insect-proof agent in volatilization container 100~500 of the invention can except above-mentioned each composition with
Outward, various additives are also contained.For example can suitably contain mould inhibitor (2- phenylphenols (OPP), 4- isopropyl -3- methyl
Phenol (IPMP), Kathon, isopropyl methyl phenol, o-phenyl phenol etc.), (day is flat for antiseptic
Cypress alcohol, eugenol, allyl isothiocyanate etc.), aromatic (limonene, australene, phenylethanol, amyl cinnamic aldehyde, acetic acid
Benzyl ester etc.), degerming component, stabilization agent, pH adjusting agent, colouring agent, hydrocarbon system compound (hexane, paraffin etc.), the various stones such as BHT
Oily series solvent etc..Furthermore it is also possible to suitably contain the spices such as leaf alcohol, leaf aldehyde referred to as " green perfume (or spice) ".By to clothing
Green perfume (or spice) is added in material insect-proof agent, it is possible to assign relaxation effect to user when the accommodating container of clothing is opened.
<Medicine volatilizer>
The microspheric flying pest repellant of the aqueous gel containing volatile materials is prepared as described above or dress material is used
Insect-proof agent, is stowed in volatilization container 100~500 of the invention, and the device of gained can be as medicament of the invention
Volatilization device is used.Fig. 7 is the use of the volatilization solid of the medicine volatilizer 100 ' of container 100 of first embodiment
Figure.In the inside of the medicine volatilizer 100 ', the microspheric flying pest repellant 50 of aqueous gel is accommodated in volatilization and is used
In container 100 '.It is the 20 of the weight of acrylic acid series water absorbent polymer in infiltration liquid measure for the size of aqueous gel microballoon
When more than times, prepared in the way of the diameter for reaching 5~15mm.Medicine volatilizer 100 ' can be in entry, kitchen, health
Between, living room, outside the space such as interior, warehouse, the in-car such as bedroom or courtyard, room, for repellent culex, underground mosquito, aedes albopictus
Deng the use of the flying pests such as mosquito class, buffalo gnat, midge class, fly class, small flies (fruit bat class, eye fly class etc.), moth fly class, casemaking clothes moth class
On the way, security and convenience are excellent.
Particularly, in the case of the above-mentioned dress material insect-proof agent of the middle storage of medicine volatilizer 100 ', medicament volatilization dress
Putting 100 ' can expeditiously and effectively make dress material insect prevention composition volatilize.As long as the medicine volatilizer 100 ' is placed
In wardrobe, drawer, closet, dress material containing box etc., it is possible to play excellent vermins-proof effect, insecticidal effect.
And, the medicament for being accommodated in the inside of medicine volatilizer 100 ' of the invention is not limited in as described above flying
Xiang insects repellant, dress material insect-proof agent.Can also using with deodorizing effect, fragrance effect volatile materials as medicament system
It is standby, it is allowed to support in aqueous gel microballoon, it is accommodated in medicine volatilizer 100 '.In such cases, medicine volatilizer
100 ' can be in the spaces such as the interiors such as entry, kitchen, toilet, living room, bedroom, warehouse, in-car or wardrobe, drawer, wall
Used in the accommodation spaces such as cupboard, dress material containing box.
As described above, volatilization container 100~500 of the invention can as can according to be accommodated in inside volatility
The species of material, purposes are constituted in the very outstanding medicine volatilizer 100 ' of the convenience that various places are used.
Industrial applicability
Volatilization container of the invention can be used for storage flying pest repellant, dress material insect-proof agent, deodorant, fragrance
The container of the medicaments such as agent.
Symbol description
10 container bodies
11 opening portions
20 lids
Above 20a lids
20b lids side
21 evaporation holes
22 limiting units
23rd, 25,26 gap
24 throughputs
The microspheric flying pest repellant of 50 aqueous gels
100 volatilization containers
100 ' medicine volatilizers
Claims (6)
1. a kind of volatilization container, is the volatilization container for making volatile materials to outside volatilization,
Possess：
Container body, it has the opening portion of carrier of the storage containing the volatile materials；With
Lid, it is provided with the volatile materials that will be volatilized from the carrier to the outside evaporation hole released, with it is described
Be installed on the mode that the opening portion covers in the container body by the discontiguous state in opening portion,
Limiting unit is provided with the inside of the lid, when the lid is installed in the container body, the limiting unit
Prevent the carrier from the opening portion to spilling around the container body,
The limiting unit located at the lid inner crest face, to form at it chi than the carrier between the opening portion
The mode in very little small gap, is constituted as the cylindrical member extended downwards from the inner crest face.
2. volatilization container according to claim 1, wherein,
In the cylindrical member, the circulation for making the size of carrier described in the ratio of volatile materials circulation small is provided with
Portion.
3. volatilization container according to claim 1 and 2, wherein,
The evaporation hole in the lid is constituted in the small mode of the size than the carrier.
4. a kind of medicine volatilizer, the medicament volatilization of the volatilization container being the use of any one of claims 1 to 3
Device,
The aqueous of the aqueous solution that at least absorbs the volatile materials or aqueous suspension is accommodated in water absorbent polymer
The medicament of gel micro-ball type is used as the carrier.
5. medicine volatilizer according to claim 4, wherein,
The volatile materials is selected from least in flying pest repellent composition, dress material insect prevention composition and fragrance component
Kind.
6. medicine volatilizer according to claim 4, wherein,
The volatile materials is selected from least in flying pest repellent fragrance component and dress material insect prevention fragrance component
Kind.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013-236309 | 2013-11-14 | ||
| JP2013236309A JP6189185B2 (en) | 2013-11-14 | 2013-11-14 | Volatilization container and chemical volatilization device |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104627542A CN104627542A (en) | 2015-05-20 |
| CN104627542B true CN104627542B (en) | 2017-07-07 |
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| CN201410643813.2A Active CN104627542B (en) | 2013-11-14 | 2014-11-11 | Volatilization container and medicine volatilizer |
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| CN (1) | CN104627542B (en) |
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| JP2017209095A (en) * | 2016-05-23 | 2017-11-30 | 保司 黒田 | Container for snake and insect pest repellant |
| CN208388070U (en) * | 2017-12-27 | 2019-01-18 | 宁波香木町日用品有限公司 | Container containing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2836808Y (en) * | 2005-01-10 | 2006-11-15 | 花仙子企业股份有限公司 | Improved aroma device volatilizes cotton body |
| CN200994935Y (en) * | 2006-10-20 | 2007-12-26 | 刘新明 | Essence bottle |
| CN201424213Y (en) * | 2009-03-24 | 2010-03-17 | 陈红斌 | Solid-state volatile substance container |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4264153B2 (en) * | 1998-12-24 | 2009-05-13 | 長谷川香料株式会社 | Liquid volatilization equipment |
| JP2007176529A (en) * | 2005-12-27 | 2007-07-12 | Earth Chem Corp Ltd | Volatile chemical agent container |
| JP4310654B2 (en) * | 2006-02-14 | 2009-08-12 | 小林製薬株式会社 | Transpiration container |
| JP4816568B2 (en) * | 2007-05-28 | 2011-11-16 | 大日本印刷株式会社 | Chemical volatilization device |
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2013
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2836808Y (en) * | 2005-01-10 | 2006-11-15 | 花仙子企业股份有限公司 | Improved aroma device volatilizes cotton body |
| CN200994935Y (en) * | 2006-10-20 | 2007-12-26 | 刘新明 | Essence bottle |
| CN201424213Y (en) * | 2009-03-24 | 2010-03-17 | 陈红斌 | Solid-state volatile substance container |
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| CN104627542A (en) | 2015-05-20 |
| JP2015093733A (en) | 2015-05-18 |
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