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CN104592823A - 镍酸铋纳米线多功能涂料 - Google Patents

镍酸铋纳米线多功能涂料 Download PDF

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CN104592823A
CN104592823A CN201510055852.5A CN201510055852A CN104592823A CN 104592823 A CN104592823 A CN 104592823A CN 201510055852 A CN201510055852 A CN 201510055852A CN 104592823 A CN104592823 A CN 104592823A
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nickelate
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CN104592823B (zh
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裴立宅
蔡征宇
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Nanjing Rong Hui Metal Technology Co ltd
Shenxian Lukai Comprehensive Service Co ltd
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Anhui University of Technology AHUT
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Abstract

本发明公开了一种镍酸铋纳米线多功能涂料，属于涂料技术领域。该涂料的质量百分比组成如下：镍酸铋纳米线21-38％、纳米硅酸钙6-14％、水性氟碳乳液11-21％、苯乙烯丙烯酸酯共聚合物乳液4-9％、丙二醇甲醚醋酸酯3-8％、羟基硅油乳液4-8％、水17-33％、脂肪醇聚氧乙烯醚羧酸钠1-3％、聚酰胺蜡0.5-2％、有机膨润土0.3-1％、二甲基亚砜0.3-1％、聚丙烯酰胺0.05-0.2％、乙二醇丁醚醋酸酯1.2-3％、丙烯酸树脂0.2-0.6％。本发明镍酸铋纳米线多功能涂料性能稳定，具有防腐、阻燃、耐磨、耐碎落、防污和防水等多种功能，在建筑及设备用涂料方面具有良好的应用前景。

Description

镍酸铋纳米线多功能涂料
技术领域
本发明属于涂料技术领域，具体涉及一种镍酸铋纳米线多功能涂料。
背景技术
随着科技的发展，人们生活水平的提高和环保意识的增强，对建筑和设备用涂料的要求也不断提高。水性涂料具有安全、无毒、无害和无污染的特点，有良好的应用。目前已有专利报道了多种水性涂料，例如国家发明专利“储罐及槽车用水性防腐降温多功能涂料及其制备方法”(发明专利申请号：201210530978.X)公布了一种以丙烯酸乳液、碳酸钙、硫酸钡、滑石粉和空心玻璃微珠为主要原料的水性防腐涂料及其制备方法。国家发明专利“一种多功能涂料的制备方法”(发明专利申请号：201310601480.2)以云母粉、氢氧化铝、苯丙乳液、硅丙乳液、丙二醇、二甲基乙醇胺为主要原料制备出了一种防腐、阻燃涂料。
国家发明专利“一种白色环保型防水涂料”(发明专利申请号：201310359813.5)以水性聚氨酯、钛白粉、云母粉、泡花碱、古马隆树脂、4-叔丁基苯酚、硼酸、钨酸钠、甲基苯骈三氮唑、无水乙醇、烯基三甲氧基硅烷、聚氧丙烯甘油醚为原料制备出了一种白色防水涂料。国家发明专利“一种多功能涂料及其制备方法”(发明专利申请号：201110196723.X)以纳米竹碳、纳米碳化硼、乙醇为主要原料制备出了一种环境净化功能的涂料。以上这些涂料具有防腐、阻燃、防水及环境净化等功能，但是由于涂料组成成分的限制，现有涂料一般只能起到部分作用，功能较单一。随着建筑和设备用涂料要求的提高，仅靠现有涂料难以满足需求。
发明内容
为了解决以上问题，本发明提供一种多功能涂料，以镍酸铋纳米线作为主要原料，引入纳米硅酸钙作为填料，添加丙二醇甲醚醋酸酯、水性氟碳乳液、苯乙烯丙烯酸酯共聚合物乳液和羟基硅油乳液等成分，以期得到具有良好防腐、阻燃、耐磨、耐碎落、防污及防水功能的镍酸铋纳米线多功能涂料。
本发明所提供的镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线21-38％、纳米硅酸钙6-14％、水性氟碳乳液11-21％、苯乙烯丙烯酸酯共聚合物乳液4-9％、丙二醇甲醚醋酸酯3-8％、羟基硅油乳液4-8％、水17-33％、脂肪醇聚氧乙烯醚羧酸钠1-3％、聚酰胺蜡0.5-2％、有机膨润土0.3-1％、二甲基亚砜0.3-1％、聚丙烯酰胺0.05-0.2％、乙二醇丁醚醋酸酯1.2-3％、丙烯酸树脂0.2-0.6％。
本发明所述镍酸铋纳米线的直径为30-100nm，长度为10μm，纳米硅酸钙的尺寸低于100nm。
本发明所提供的镍酸铋纳米线的具体制备方法如下：
以乙酸镍、铋酸钠作为原料，水为溶剂，其中乙酸镍与铋酸钠的摩尔比为1:1，将乙酸镍、铋酸钠与水均匀混合后置于反应容器内并密封，于温度180-300℃、保温36-60h，其中乙酸镍与铋酸钠的重量不大于水重量的30％。
本发明所提供的镍酸铋纳米线多功能涂料的具体制备方法如下：
在低速搅拌下将水、镍酸铋纳米线、脂肪醇聚氧乙烯醚羧酸钠、二甲基亚砜和一半聚丙烯酰胺装入球磨机的球罐内，球磨7h，使之充分分散，然后将球磨后的物料转入多功能分散机，在搅拌下加入纳米硅酸钙，在多功能分散机上高速搅拌7h，通过高速剪切将其分散均匀。随后在低搅拌速度下缓慢滴加水性氟碳乳液、苯乙烯丙烯酸酯共聚合物乳液和羟基硅油乳液，随后加入剩余的聚丙烯酰胺、丙二醇甲醚醋酸酯、聚酰胺蜡、有机膨润土、乙二醇丁醚醋酸酯和丙烯酸树脂低速搅拌7h，最后得到涂料成品。
以镍酸铋纳米线作为主要原料，纳米硅酸钙作为填料，丙二醇甲醚醋酸酯作为成膜助剂、苯乙烯丙烯酸酯共聚合物乳液和羟基硅油乳液作为防水剂，添加脂肪醇聚氧乙烯醚羧酸钠作为分散剂、有机膨润土作为增稠剂、二甲基亚砜作为润湿剂、聚丙烯酰胺作为消泡剂、乙二醇丁醚醋酸酯作为防冻剂、丙烯酸树脂作为流平剂，可以得到稳定的镍酸铋纳米线多功能涂料。
镍酸铋纳米线、纳米硅酸钙难于与酸、碱和盐反应，熔点高，具有良好的防腐与阻燃特性。镍酸铋纳米线与乳液、纳米填料、成膜助剂等成分形成光滑、致密的涂层，使灰尘等污染物难于吸附于涂层表面，所以镍酸铋纳米线多功能涂料具有良好的防污功能。苯乙烯丙烯酸酯共聚合物乳液和羟基硅油乳液作为复合防水剂，易于在低温下凝聚，与镍酸铋纳米线、纳米硅酸钙等成分均匀混合、相互缠绕，形成多层致密的薄膜，阻止水分子的侵入与渗透，具有良好的防水效果，同时也增加了镍酸铋纳米线复合涂层的耐磨和耐碎落性，所以镍酸铋纳米线复合涂料具有良好的防水、耐磨和耐碎落性。乙二醇丁醚醋酸酯作为防冻剂，在镍酸铋纳米线多功能涂料中起到防冻作用。因此，镍酸铋纳米线多功能涂料具有良好的防腐、阻燃、耐磨、耐碎落、防污和防水等多种功能，在各种建筑和设备上具有良好的应用前景。本发明采用的镍酸铋纳米线稳定性好、无毒、无害和无污染，所用填料、乳液及助剂都是批量生产的材料，可以实现镍酸铋纳米线多功能涂料的制备。
附图说明
图1为实施例1制备的镍酸铋纳米线多功能涂料所形成涂层表面的低倍数SEM图像；
从图中可以看出复合涂料所形成的涂层表面致密，纳米颗粒中较均匀的分散着直径30-100nm、长10μm的镍酸铋纳米线。
图2为实施例1制备的镍酸铋纳米线多功能涂料所形成涂层表面的高倍数SEM图像；
从图中可以看出复合涂料所形成的涂层表面致密，纳米颗粒中较均匀的分散着直径30-100nm、长10μm的镍酸铋纳米线。
具体实施方式
以下结合具体实施例详述本发明，但本发明不局限于下述实施例。
实施例1
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线38％
纳米硅酸钙6％
水性氟碳乳液11％
苯乙烯丙烯酸酯共聚合物乳液4％
丙二醇甲醚醋酸酯3％
羟基硅油乳液8％
水26.15％
脂肪醇聚氧乙烯醚羧酸钠1％
聚酰胺蜡0.5％
有机膨润土0.3％
二甲基亚砜0.3％
聚丙烯酰胺0.05％
乙二醇丁醚醋酸酯1.2％
丙烯酸树脂0.2％。
实施例2
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线21％
纳米硅酸钙10.2％
水性氟碳乳液21％
苯乙烯丙烯酸酯共聚合物乳液9％
丙二醇甲醚醋酸酯8％
羟基硅油乳液3％
水17％
脂肪醇聚氧乙烯醚羧酸钠3％
聚酰胺蜡2％
有机膨润土1％
二甲基亚砜1％
聚丙烯酰胺0.2％
乙二醇丁醚醋酸酯3％
丙烯酸树脂0.6％。
实施例3
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线22％
纳米硅酸钙14％
水性氟碳乳液12％
苯乙烯丙烯酸酯共聚合物乳液5％
丙二醇甲醚醋酸酯4％
羟基硅油乳液5％
水33％
脂肪醇聚氧乙烯醚羧酸钠1.5％
聚酰胺蜡0.6％
有机膨润土0.5％
二甲基亚砜0.5％
聚丙烯酰胺0.1％
乙二醇丁醚醋酸酯1.5％
丙烯酸树脂0.3％。
实施例4
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线22.5％
纳米硅酸钙11.3％
水性氟碳乳液17.4％
苯乙烯丙烯酸酯共聚合物乳液7.3％
丙二醇甲醚醋酸酯7.6％
羟基硅油乳液7.4％
水17.8％
脂肪醇聚氧乙烯醚羧酸钠2.5％
聚酰胺蜡1.5％
有机膨润土0.8％
二甲基亚砜0.8％
聚丙烯酰胺0.15％
乙二醇丁醚醋酸酯2.45％
丙烯酸树脂0.5％。
实施例5
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线28.5％
纳米硅酸钙10.5％
水性氟碳乳液17.5％
苯乙烯丙烯酸酯共聚合物乳液6.8％
丙二醇甲醚醋酸酯6.2％
羟基硅油乳液6.3％
水17.04％
脂肪醇聚氧乙烯醚羧酸钠2.1％
聚酰胺蜡1.4％
有机膨润土0.53％
二甲基亚砜0.57％
聚丙烯酰胺0.12％
乙二醇丁醚醋酸酯1.98％
丙烯酸树脂0.46％。
实施例6
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线31.5％
纳米硅酸钙9.1％
水性氟碳乳液14.9％
苯乙烯丙烯酸酯共聚合物乳液5.8％
丙二醇甲醚醋酸酯4.2％
羟基硅油乳液5.7％
水22.44％
脂肪醇聚氧乙烯醚羧酸钠1.8％
聚酰胺蜡1.2％
有机膨润土0.42％
二甲基亚砜0.58％
聚丙烯酰胺0.12％
乙二醇丁醚醋酸酯1.88％
丙烯酸树脂0.36％。
实施例7
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线33.5％
纳米硅酸钙7.8％
水性氟碳乳液12.2％
苯乙烯丙烯酸酯共聚合物乳液5.6％
丙二醇甲醚醋酸酯4.4％
羟基硅油乳液5.1％
水25.3％
脂肪醇聚氧乙烯醚羧酸钠1.7％
聚酰胺蜡0.88％
有机膨润土0.72％
二甲基亚砜0.62％
聚丙烯酰胺0.18％
乙二醇丁醚醋酸酯1.74％
丙烯酸树脂0.26％。
实施例8
确定镍酸铋纳米线多功能涂料的质量百分比组成如下：
镍酸铋纳米线35.5％
纳米硅酸钙7.7％
水性氟碳乳液11.3％
苯乙烯丙烯酸酯共聚合物乳液5.1％
丙二醇甲醚醋酸酯3.9％
羟基硅油乳液4.9％
水26.2％
脂肪醇聚氧乙烯醚羧酸钠1.1％
聚酰胺蜡1.12％
有机膨润土0.48％
二甲基亚砜0.51％
聚丙烯酰胺0.09％
乙二醇丁醚醋酸酯1.72％
丙烯酸树脂0.38％。
表1、本发明实施例1～8所得镍酸铋纳米线多功能涂料的性能测试结果

Claims (2)

1.一种镍酸铋纳米线多功能涂料，其特征在于：以质量百分比计，该涂料配方如下：
镍酸铋纳米线21-38％
纳米硅酸钙6-14％
水性氟碳乳液11-21％
苯乙烯丙烯酸酯共聚合物乳液4-9％
丙二醇甲醚醋酸酯3-8％
羟基硅油乳液4-8％
水17-33％
脂肪醇聚氧乙烯醚羧酸钠1-3％
聚酰胺蜡0.5-2％
有机膨润土0.3-1％
二甲基亚砜0.3-1％
聚丙烯酰胺0.05-0.2％
乙二醇丁醚醋酸酯1.2-3％
丙烯酸树脂0.2-0.6％。
2.如权利要求1所述一种镍酸铋纳米线多功能涂料，其特征在于：所述镍酸铋纳米线的直径为30-100nm，长度为10μm，纳米硅酸钙的尺寸低于100nm。
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