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CN104497519B - A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics - Google Patents

A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics Download PDF

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Publication number
CN104497519B
CN104497519B CN201410689118.XA CN201410689118A CN104497519B CN 104497519 B CN104497519 B CN 104497519B CN 201410689118 A CN201410689118 A CN 201410689118A CN 104497519 B CN104497519 B CN 104497519B
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CN
China
Prior art keywords
low temperature
temperature resistant
terminal box
optical fiber
fiber cable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201410689118.XA
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Chinese (zh)
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CN104497519A (en
Inventor
蒋学功
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Jiahe Plastics Co Ltd
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Suzhou New District Jiahe Plastics Co Ltd
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Priority to CN201410689118.XA priority Critical patent/CN104497519B/en
Publication of CN104497519A publication Critical patent/CN104497519A/en
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Publication of CN104497519B publication Critical patent/CN104497519B/en
Expired - Fee Related legal-status Critical Current
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, be made up of the component of following weight part: PC:50 ~ 100 part; PBT:15 ~ 60 part; Meltability polytetrafluorethyletubular: 15 ~ 35 parts; Resistance to compression agent: 10 ~ 30 parts; Toughner: 3 ~ 7 parts; Toner: 1 ~ 5 part; Oxidation inhibitor: 0.2 ~ 2 part; Described toughner comprises maleic anhydride graft compatilizer; Described maleic anhydride graft compatilizer comprises maleic anhydride and meets POE, EVA, SBS, EPDM, PE or ABS; Described oxidation inhibitor comprises irgasfos 168; The specification of described toner comprises black masterbatch; Described resistance to compression agent comprises aramid fiber or aramid pulp.The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one provided by the invention, have stronger resistance to pressure, physical strength, acid-alkali-resistant degree, the advantage such as low temperature resistant, lightweight.

Description

A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics
Technical field
The present invention relates to a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, particularly relate to a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastic formula.
Background technology
One of important technology index of submarine optical fiber cable terminal box to bear hundreds of to one thousand atmospheric hydraulic pressure, and current submarine optical fiber cable terminal box poor voltage withstand capability, work-ing life is short, need frequently change.
In addition, there is low temperature resistant weak effect and the large problem of weight in existing submarine optical fiber cable terminal box.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of low temperature resistant, lightweight submarine optical fiber cable terminal box plastics; Further, the invention provides a kind of good pressure-resistant performance, the submarine optical fiber cable terminal box plastics that physical strength is large; Further, the present invention also has the corrosion resistant feature of acid and alkali-resistance.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:50 ~ 100 part; PBT:15 ~ 60 part; Meltability polytetrafluorethyletubular: 15 ~ 35 parts; Resistance to compression agent: 10 ~ 30 parts; Toughner: 3 ~ 7 parts; Toner: 1 ~ 5 part; Oxidation inhibitor: 0.2 ~ 2 part.
Described toughner comprises maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer comprises maleic anhydride and meets POE, EVA, SBS, EPDM, PE or ABS.
Described oxidation inhibitor comprises irgasfos 168.
The specification of described toner comprises black masterbatch.
Described resistance to compression agent comprises aramid fiber or aramid pulp.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one provided by the invention, the introducing of resistance to compression agent, greatly strengthen withstand voltage properties of the present invention, aramid fiber or aramid pulp have superstrength, high-modulus and high temperature resistant, acid-fast alkali-proof, the premium properties such as lightweight, and its intensity is 5 ~ 6 times of steel wire, modulus is 2 ~ 3 times of steel wire or glass fibre, toughness is 2 times of steel wire, and weight is only about 1/5 of steel wire, at the temperature of 560 degree, do not decompose, do not melt.It has good insulativity and ageing resistance, has very long life cycle; PBT(polybutylene terephthalate, English name Polybutyleneterephthalate) be thermoplastic polyester, have that intensity is high, resistance to fatigue, dimensional stabilizing, creep are little, the characteristic such as heat-resistant aging and solvent resistance (unstressed cracking); PC(polycarbonate, English name Polycarbonate) water white transparency, have excellent shock resistance and thermal diffusivity, spread heat is relatively more even and product appearance is smooth; Utilize the glass fibre that Meltability polytetrafluorethyletubular replaces in original terminal box plastic formula, while the problem of fragility avoiding glass fibre, add the characteristic of Meltability polytetrafluorethyletubular outstanding heat-resisting, cold-resistant (life-time service temperature range is-200 ~+260 DEG C) and wear resistance; Formula in the present invention, after combination, makes submarine optical fiber cable terminal box plastics have stronger resistance to pressure, physical strength, acid-alkali-resistant degree, the advantage such as lightweight, low temperature resistant.
Embodiment
Embodiment 1: a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:50 part; PBT:15 part; Meltability polytetrafluorethyletubular: 15 parts; Resistance to compression agent: 10 parts; Toughner: 3 parts; Toner: 1 part; Oxidation inhibitor: 0.2 part.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets POE.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one of the present embodiment, surface gloss 50%, resistance to impact shock 96MPa, tensile strength 78MPa, and acid and alkali-resistance is anticorrosive, low temperature resistant, the general 4kg of the existing terminal box of the light 0.8kg(of the more existing terminal box of weight).
Embodiment 2: a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:60 part; PBT:20 part; Meltability polytetrafluorethyletubular: 20 parts; Resistance to compression agent: 15 parts; Toughner: 4 parts; Toner: 2 parts; Oxidation inhibitor: 0.5 part.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EVA.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid pulp.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one of the present embodiment, surface gloss 55%, resistance to impact shock 112MPa, stretch strong 85MPa, and acid and alkali-resistance is anticorrosive, low temperature resistant, the light 1kg of the more existing terminal box of weight.
Embodiment 3: a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:70 part; PBT:30 part; Meltability polytetrafluorethyletubular: 25 parts; Resistance to compression agent: 25 parts; Toughner: 5 parts; Toner: 3 parts; Oxidation inhibitor: 1 part.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets SBS.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one of the present embodiment, surface gloss 58%, resistance to impact shock 120MPa, tensile strength 89MPa, and acid and alkali-resistance is anticorrosive, low temperature resistant, the light 1.5kg of the more existing terminal box of weight.
Embodiment 4: a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:80 part; PBT:40 part; Meltability polytetrafluorethyletubular: 30 parts; Resistance to compression agent: 28 parts; Toughner: 6 parts; Toner: 4 parts; Oxidation inhibitor: 1.5 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EPDM.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid fiber.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one of the present embodiment, surface gloss 63%, resistance to impact shock 133MPa, tensile strength 95MPa, and acid and alkali-resistance is anticorrosive, low temperature resistant, the light 1.7kg of the more existing terminal box of weight.
Embodiment 5: a kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:100 part; PBT:60 part; Meltability polytetrafluorethyletubular: 35 parts; Resistance to compression agent: 30 parts; Toughner: 7 parts; Toner: 5 parts; Oxidation inhibitor: 2 parts.
Described toughner is maleic anhydride graft compatilizer.
Described maleic anhydride graft compatilizer is that maleic anhydride meets EPDM.
Described oxidation inhibitor is irgasfos 168.
The specification of described toner is black masterbatch.
Described resistance to compression agent is aramid pulp.
The low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one of the present embodiment, surface gloss 69%, resistance to impact shock 149MPa, tensile strength 105MPa, and acid and alkali-resistance is anticorrosive, low temperature resistant, the light 2kg of the more existing terminal box of weight.
The above is only the preferred embodiment of the present invention; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (5)

1. low temperature resistant light-duty submarine optical fiber cable terminal box plastics, are made up of the component of following weight part: PC:50 ~ 100 part; PBT:15 ~ 60 part; Meltability polytetrafluorethyletubular: 15 ~ 35 parts; Resistance to compression agent: 10 ~ 30 parts; Toughner: 3 ~ 7 parts; Toner: 1 ~ 5 part; Oxidation inhibitor: 0.2 ~ 2 part; Described resistance to compression agent comprises aramid fiber or aramid pulp.
2. the low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one according to claim 1, is characterized in that: described toughner comprises maleic anhydride graft compatilizer.
3. the low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one according to claim 2, is characterized in that: described maleic anhydride graft compatilizer comprises maleic anhydride graft POE, EVA, SBS, EPDM, PE or ABS.
4. the low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one according to claim 1, is characterized in that: described oxidation inhibitor comprises irgasfos 168.
5. the low temperature resistant light-duty submarine optical fiber cable terminal box plastics of one according to claim 1, is characterized in that: the specification of described toner comprises black masterbatch.
CN201410689118.XA 2014-11-26 2014-11-26 A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics Expired - Fee Related CN104497519B (en)

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CN201410689118.XA CN104497519B (en) 2014-11-26 2014-11-26 A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics

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Application Number Priority Date Filing Date Title
CN201410689118.XA CN104497519B (en) 2014-11-26 2014-11-26 A kind of low temperature resistant light-duty submarine optical fiber cable terminal box plastics

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109880338B (en) * 2019-02-27 2021-10-01 上海升广科技有限公司 Preparation method of polycarbonate plastic formula based on polycarbonate plastic with high-temperature steam sterilization resistance, wear resistance and flame retardance
CN111320856A (en) * 2020-04-20 2020-06-23 江苏京利华新材料有限公司 Composite material for high-performance PC, PBT and PTFE and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1916076A (en) * 2006-09-07 2007-02-21 浙江俊尔新材料有限公司 Frigostabile PC/PBT plastic alloy
CN203193232U (en) * 2013-02-25 2013-09-11 上海佳量模具有限公司 Outdoor junction box
CN103421293A (en) * 2013-08-09 2013-12-04 深圳市科聚新材料有限公司 Polycarbonate composite material and preparation method thereof
CN103483797A (en) * 2013-09-29 2014-01-01 深圳市科聚新材料有限公司 PC (poly carbonate) material and preparation method and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3642496B2 (en) * 1993-03-09 2005-04-27 宇部日東化成株式会社 Optical fiber support spacer
JP2014001374A (en) * 2012-05-25 2014-01-09 Toray Ind Inc Polybutylene terephthalate resin composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1916076A (en) * 2006-09-07 2007-02-21 浙江俊尔新材料有限公司 Frigostabile PC/PBT plastic alloy
CN203193232U (en) * 2013-02-25 2013-09-11 上海佳量模具有限公司 Outdoor junction box
CN103421293A (en) * 2013-08-09 2013-12-04 深圳市科聚新材料有限公司 Polycarbonate composite material and preparation method thereof
CN103483797A (en) * 2013-09-29 2014-01-01 深圳市科聚新材料有限公司 PC (poly carbonate) material and preparation method and application thereof

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