CN104725711A - Hybrid polyacrylic fibreglass sleeve - Google Patents
Hybrid polyacrylic fibreglass sleeve Download PDFInfo
- Publication number
- CN104725711A CN104725711A CN201510102480.7A CN201510102480A CN104725711A CN 104725711 A CN104725711 A CN 104725711A CN 201510102480 A CN201510102480 A CN 201510102480A CN 104725711 A CN104725711 A CN 104725711A
- Authority
- CN
- China
- Prior art keywords
- glass fibre
- polypropylene
- resin
- sleeve according
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011152 fibreglass Substances 0.000 title abstract 5
- 239000011347 resin Substances 0.000 claims abstract description 54
- 229920005989 resin Polymers 0.000 claims abstract description 54
- 239000003365 glass fiber Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011521 glass Substances 0.000 claims abstract description 9
- 239000006004 Quartz sand Substances 0.000 claims abstract description 8
- 238000003618 dip coating Methods 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 8
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 229910052903 pyrophyllite Inorganic materials 0.000 claims abstract description 8
- 239000004743 Polypropylene Substances 0.000 claims description 40
- 229920001155 polypropylene Polymers 0.000 claims description 40
- 239000000203 mixture Substances 0.000 claims description 29
- 239000004698 Polyethylene Substances 0.000 claims description 28
- 229920002125 Sokalan® Polymers 0.000 claims description 21
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 21
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 21
- 239000004584 polyacrylic acid Substances 0.000 claims description 21
- -1 polypropylene Polymers 0.000 claims description 21
- 239000002253 acid Substances 0.000 claims description 19
- 239000003513 alkali Substances 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 14
- 229920005629 polypropylene homopolymer Polymers 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 150000001282 organosilanes Chemical class 0.000 claims description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 5
- 229910017083 AlN Inorganic materials 0.000 claims description 4
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 4
- 239000003112 inhibitor Substances 0.000 claims description 4
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 4
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000012856 packing Methods 0.000 claims description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 claims description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical compound [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 235000012239 silicon dioxide Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 2
- 239000000347 magnesium hydroxide Substances 0.000 claims description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 2
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 235000019738 Limestone Nutrition 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 230000000704 physical effect Effects 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 238000009941 weaving Methods 0.000 abstract 1
- 239000011810 insulating material Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
The invention discloses a hybrid polyacrylic fibreglass sleeve. The hybrid polyacrylic fibreglass sleeve is prepared by weaving alkali-free glass fiber into a tube, coating the tube with resin mixed liquor by dip-coating, and heating for dying the tube, wherein the alkali-free glass fiber is prepared by melting quartz sand, alumina, pyrophyllite and limestone into glass and then directly preparing the glass into fiber, and the diameter of the alkali-free glass fiber is 3-20 microns; and the resin mixed liquor is mainly prepared by mixing PE resin with an organic silicone modified polyacrylate hybrid material. The fibreglass sleeve provided by the invention is woven by using good alkali-free glass fiber, so that the fibreglass sleeve has the characteristics of good physical properties, good toughness, excellent flame retardancy, good heat resistance and corrosion resistance, and the like.
Description
Technical field
The invention belongs to glass fiber insulating sleeve production field, be specifically related to a kind of polypropylene acid glass fibre sleeve.
Background technology
Insulating material is one of the base mateiral of electrician, electronic product, it is to electrician's industrial expansion, there is unimportant effect, say in a sense, the development and progression of insulating material industry, be directly connected to country's generating, transmission of electricity and the development with electric industry, and affect the development and progress of national economy.Insulating material is the key condition that electric product has modern technique index, is also that electric product can the important guarantee of long-term safety reliability service.Therefore, require insulating material industry, development new variety, provide premium quality product; Improve constantly quality product, ensure that product is reliable and stable.
At present, in the conventional production practices of glass fiber insulating sleeve, the glass fiber insulating sleeve after to coated with resins is needed to be cured.Insulativity and the thermotolerance that how can increase glass fibre sleeve become the direction needing most research at present.
Summary of the invention
The object of this invention is to provide a kind of polypropylene acid glass fibre sleeve, the formula materials wide material sources that this invention provides, it is convenient to obtain, safety and environmental protection.
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
Wherein, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
Wherein, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
Wherein, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
Wherein, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
Compared with prior art, the present invention has following beneficial effect:
(1) the invention provides glass fibre sleeve adopts good alkali free glass fibre to work out, and has good physical behavior.
(2) features such as it is extensive that the resin mixture liquor adopted in the present invention has material source, with low cost, substantially increase economic benefit.
(3) features such as glass fibre sleeve provided by the invention has good toughness, and flame retardant resistance is good, and heat-and corrosion-resistant performance is good.
Embodiment
Embodiment 1
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50 parts
Deionized water 1 part
Antimonous oxide 3 parts
Stearic acid 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.1 part
Modified manometer silicon dioxide 0.5 part.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3-5 hour at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
Embodiment 2
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 20 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 80 parts
Deionized water 35 parts
Zinc borate 6 parts
Zinic stearas 2 parts
MIT 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 50%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 5 hours at 90 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 70%.
Embodiment 3
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 10 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
4 parts, aluminium hydroxide
Calcium stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 40%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 4 hours at 80 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 45%.
Embodiment 4
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 5 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 60 parts
Deionized water 18 parts
Brominated flame retardant 4 parts
Lead stearate 2 parts
MIT 0.2 part
Modified Nano aluminium nitride 3 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 35%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 70 DEG C, adjust ph 9.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 60%.
Embodiment 5
A kind of polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 15 microns; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
Wherein, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 70 parts
Deionized water 10 parts
Ammonium polyphosphate 4 parts
Zinic stearas 1 part
1,2-isopropyl benzene isothiazolinone-3-ketone 0.3 part
Modified nano-titanium dioxide 5 parts.
Wherein, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30%.
Wherein, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, then add in polypropene blended liquid, isothermal reaction 3 hours at 65 DEG C, adjust ph 8.5.
Wherein, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20%.
The polypropylene acid glass fibre sleeve of above-mentioned each examples produce has good flame retardant properties, and have good toughness, have favorable elasticity simultaneously, heat-and corrosion-resistant performance is splendid; The features such as the raw material adopted has wide material sources, with low cost.
The foregoing is only one embodiment of the invention, do not limit the present invention, the technical scheme that the mode that all employings are equal to replacement or equivalent transformation obtains, all drop in protection scope of the present invention.
Claims (9)
1. a polypropylene acid glass fibre sleeve, it is characterized in that, the effective alkali free glass fibre of this cover is woven into pipe, and then in dip-coating, resin mixture liquor is made through heating, drying; Described alkali free glass fibre adopts quartz sand, aluminum oxide, pyrophyllite and Wingdale to be melt into glass and directly makes fiber, and diameter range is 3-20 micron; Described resin mixture liquor mainly adopts PE resin and organic-silicon-modified polyacrylic acid mixing material to be mixed.
2. a kind of polypropylene acid glass fibre sleeve according to claims 1, it is characterized in that, the formula of described resin mixture liquor comprises each component of following mass parts content:
PE resin 100 parts
Organic-silicon-modified polyacrylic acid mixing material 50-80 part
Deionized water 1-35 part
Fire retardant 3-6 part
Stablizer 1-2 part
Mould inhibitor 0.1-0.3 part
Water-based insulating packing 0.5-5 part.
3. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described PE resin refers to the mixture of linear low density polyethylene and Low Density Polyethylene, and the proportional range that linear low density polyethylene accounts for PE resin is 30-50%.
4. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described organic-silicon-modified polyacrylic acid mixing material be organosilane monomer is joined be added with emulsifying agent the aqueous solution in obtain organic silicon emulsion, add in polypropene blended liquid again, isothermal reaction 3-5 hour, adjust ph 8.5-9 at 65-90 DEG C.
5. a kind of polypropylene acid glass fibre sleeve according to claims 4, it is characterized in that, described polypropene blended liquid comprises homo-polypropylene and Co-polypropylene, and the content of homo-polypropylene is 20-70%.
6. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described fire retardant is one or more in antimonous oxide, zinc borate, brominated flame retardant, aluminium hydroxide, magnesium hydroxide, ammonium polyphosphate.
7. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described stablizer be stearic acid, Zinic stearas, calcium stearate, lead stearate one or more.
8. a kind of polypropylene acid glass fibre sleeve according to claims 2, it is characterized in that, described mould inhibitor is 1,2-isopropyl benzene isothiazolinone-3-ketone or MIT.
9. a kind of polypropylene acid glass fibre sleeve according to claims 2, is characterized in that, described water-based insulating packing is one or more in modified manometer silicon dioxide, modified nano-titanium dioxide, modified Nano aluminium nitride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510102480.7A CN104725711A (en) | 2015-03-10 | 2015-03-10 | Hybrid polyacrylic fibreglass sleeve |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510102480.7A CN104725711A (en) | 2015-03-10 | 2015-03-10 | Hybrid polyacrylic fibreglass sleeve |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104725711A true CN104725711A (en) | 2015-06-24 |
Family
ID=53450166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510102480.7A Pending CN104725711A (en) | 2015-03-10 | 2015-03-10 | Hybrid polyacrylic fibreglass sleeve |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104725711A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330941A (en) * | 2015-11-23 | 2016-02-17 | 安徽国泰印务有限公司 | Preparation technology for mould-proof fresh-keeping film |
| CN107604469A (en) * | 2017-09-05 | 2018-01-19 | 界首市宏利塑料有限公司 | A kind of nano combined foaming rope and preparation method |
| CN107879636A (en) * | 2017-10-12 | 2018-04-06 | 浙江畅通科技有限公司 | A kind of preparation method of compound glass microfibre |
| CN110570984A (en) * | 2019-09-27 | 2019-12-13 | 长沙华脉新材料有限公司 | High-compression-resistance power cable and preparation and application thereof |
| CN111945437A (en) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | High-flame-retardant corrosion-resistant glass fiber sleeve |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434134A (en) * | 2008-12-24 | 2009-05-20 | 北京化工大学 | Broadband multi-layer structured wave absorbing composite material and preparation thereof |
| CN102979097A (en) * | 2011-09-07 | 2013-03-20 | 上海启鹏工程材料科技有限公司 | Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof |
| CN103057174A (en) * | 2012-12-29 | 2013-04-24 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable conduit and manufacturing method thereof |
| CN103062528A (en) * | 2013-01-28 | 2013-04-24 | 河北宇通特种胶管有限公司 | Coiled plastic composite pipe reinforced with fibre |
| CN203093151U (en) * | 2012-12-29 | 2013-07-31 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable duct |
| CN103802335A (en) * | 2012-11-14 | 2014-05-21 | 辽宁辽杰科技有限公司 | Method for preparing fiber-reinforced thermoplastic composite material pipe |
-
2015
- 2015-03-10 CN CN201510102480.7A patent/CN104725711A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101434134A (en) * | 2008-12-24 | 2009-05-20 | 北京化工大学 | Broadband multi-layer structured wave absorbing composite material and preparation thereof |
| CN102979097A (en) * | 2011-09-07 | 2013-03-20 | 上海启鹏工程材料科技有限公司 | Weaving sleeve pipe type fiber reinforce plastic (FRP) rib and preparation method thereof |
| CN103802335A (en) * | 2012-11-14 | 2014-05-21 | 辽宁辽杰科技有限公司 | Method for preparing fiber-reinforced thermoplastic composite material pipe |
| CN103057174A (en) * | 2012-12-29 | 2013-04-24 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable conduit and manufacturing method thereof |
| CN203093151U (en) * | 2012-12-29 | 2013-07-31 | 山东省呈祥电工电气有限公司 | Plastic steel composite cable duct |
| CN103062528A (en) * | 2013-01-28 | 2013-04-24 | 河北宇通特种胶管有限公司 | Coiled plastic composite pipe reinforced with fibre |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330941A (en) * | 2015-11-23 | 2016-02-17 | 安徽国泰印务有限公司 | Preparation technology for mould-proof fresh-keeping film |
| CN107604469A (en) * | 2017-09-05 | 2018-01-19 | 界首市宏利塑料有限公司 | A kind of nano combined foaming rope and preparation method |
| CN107879636A (en) * | 2017-10-12 | 2018-04-06 | 浙江畅通科技有限公司 | A kind of preparation method of compound glass microfibre |
| CN110570984A (en) * | 2019-09-27 | 2019-12-13 | 长沙华脉新材料有限公司 | High-compression-resistance power cable and preparation and application thereof |
| CN110570984B (en) * | 2019-09-27 | 2020-08-25 | 宝胜（宁夏)线缆科技有限公司 | High-compression-resistance power cable and preparation and application thereof |
| CN111945437A (en) * | 2020-06-29 | 2020-11-17 | 安徽浩天新型材料有限公司 | High-flame-retardant corrosion-resistant glass fiber sleeve |
| CN111945437B (en) * | 2020-06-29 | 2023-10-31 | 安徽浩天新型材料有限公司 | High flame-retardant corrosion-resistant glass fiber sleeve |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104725711A (en) | Hybrid polyacrylic fibreglass sleeve | |
| CN103665496B (en) | Flame resistance rubber | |
| CN102875932B (en) | A kind of PVC power pipe material and preparation method thereof | |
| CN102702930A (en) | Preparation method of boric high-heat-resistance wear-resistant heavy-duty inner coating for petroleum pipeline | |
| CN101928409A (en) | A kind of halogen-free intumescent flame retardant for polyethylene and preparation method thereof | |
| CN104231575B (en) | Halogen-free and phosphorus-free PBT enhanced composite material and preparation method thereof | |
| CN104293107A (en) | Impact-resistant high-adhesive-force inflaming-retarding modified bisphenol A epoxy resin paint | |
| CN111961384A (en) | Solvent type ultrathin expansion type steel structure fireproof coating and preparation method thereof | |
| CN104725817A (en) | Environmentally-friendly flame-retardant reinforced impact-resistant PC composite material | |
| CN107805342A (en) | A kind of high heat-resistant impact MPP electric power protection pipes and preparation method thereof | |
| CN105331170A (en) | Environment-friendly nano-fire-proofing coating and preparation method thereof | |
| CN107474696A (en) | A kind of epoxy coating with high impact resistance and preparation method thereof | |
| CN103881237A (en) | Anti-aging polypropylene plastic | |
| CN106811001A (en) | Corrosion-resistant epoxy paint | |
| CN105315845A (en) | High-strength water-resistant corrosion-resistant epoxy resin powder coating | |
| CN104292421B (en) | Composition epoxy resin and its reactive flame retardant | |
| CN106928653B (en) | Epoxy resin composition for prepreg, preparation method thereof and prepreg | |
| CN104194574A (en) | Coating with high flame retardancy and strong adhesive force | |
| CN104530973A (en) | Fireproof paint formula | |
| CN104789177A (en) | Nano-modified flame-retardant epoxy electronic pouring sealant and preparation method thereof | |
| CN104592755B (en) | A kind of enhanced phenolic glass fiber moulding compound | |
| CN106832773A (en) | A kind of cable anti-corrosion material | |
| CN114106517B (en) | High-strength high-toughness flame-retardant epoxy resin and preparation method thereof | |
| CN106752725A (en) | Epoxy anticorrosive paint | |
| CN104530697A (en) | Flame-retardant high-fluidity high-temperature nylon and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150624 |