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CN104441683A - Manufacturing method of insulating cylinder and pipe fitting made from fiber composite material - Google Patents

Manufacturing method of insulating cylinder and pipe fitting made from fiber composite material Download PDF

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Publication number
CN104441683A
CN104441683A CN201410757670.8A CN201410757670A CN104441683A CN 104441683 A CN104441683 A CN 104441683A CN 201410757670 A CN201410757670 A CN 201410757670A CN 104441683 A CN104441683 A CN 104441683A
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Prior art keywords
winding
fiber
heating
glue
finished product
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Pending
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CN201410757670.8A
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Chinese (zh)
Inventor
程显军
于晓辉
司艳
于泓漪
隋佳欣
王跃东
姜俐化
孙婷
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XING BRANCH HOLDINGS Co Ltd
State Grid Corp of China SGCC
Dalian Power Supply Co State Grid Liaoning Electric Power Co Ltd
Original Assignee
XING BRANCH HOLDINGS Co Ltd
State Grid Corp of China SGCC
Dalian Power Supply Co State Grid Liaoning Electric Power Co Ltd
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Application filed by XING BRANCH HOLDINGS Co Ltd, State Grid Corp of China SGCC, Dalian Power Supply Co State Grid Liaoning Electric Power Co Ltd filed Critical XING BRANCH HOLDINGS Co Ltd
Priority to CN201410757670.8A priority Critical patent/CN104441683A/en
Publication of CN104441683A publication Critical patent/CN104441683A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/32Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core on a rotating mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0822Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using IR radiation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Electromagnetism (AREA)
  • Toxicology (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Thermal Sciences (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

本发明公开了一种纤维复合材料绝缘筒、管件的制造方法,其特征在于该方法包括纤维浸胶、纤维束缠绕张力设定、纤维束缠绕、加热固化、外表面光固化等项工艺步骤。用本发明的方法制造的纤维复合材料,制造成本比现有技术降低30%以上,材料的电气性能和机械性能都优于现有技术制造的纤维复合材料。The invention discloses a method for manufacturing a fiber composite insulating cylinder and a pipe fitting, which is characterized in that the method includes fiber dipping, fiber bundle winding tension setting, fiber bundle winding, heating and curing, and outer surface light curing. The manufacturing cost of the fiber composite material manufactured by the method of the invention is lower than that of the prior art by more than 30%, and the electrical properties and mechanical properties of the material are better than the fiber composite material manufactured by the prior art.

Description

一种纤维复合材料绝缘筒、管件的制造方法A kind of manufacturing method of fiber composite insulation cylinder and pipe fittings

技术领域 technical field

 本发明涉及一种电网行业绝缘筒、管件的制造方法,特别是一种纤维复合材料绝缘筒、管件的制造方法。 The invention relates to a method for manufacturing insulating cylinders and pipe fittings in the power grid industry, in particular to a method for manufacturing insulating cylinders and pipe fittings made of fiber composite materials.

背景技术 Background technique

目前,国内的超高压电器、高压开关及高压试验变压器,尤其是大长径比、大口径、超长管件的制造领域所用复合绝缘材料,主要是采用普通玻璃纤维和单一结构的双酚A环氧树脂复合成型。制造过程中需要使用大型金属芯模,其重量大,加工周期长,费用大,还需要有大型脱模装置,因此其生产成本高,效率低;纤维缠绕前芯模上需均匀涂抹脱模剂,以助顺利脱模,但实际操作中常因脱模剂涂抹不均匀,会造成难以脱模、无法脱模或脱模划伤内壁等诸多生产事故;过厚均匀涂抹脱模剂或使用高级无溶剂脱模剂,又会增加加工成本,造成生产成型过程复杂化,不可控性增加,质量稳定性差。 At present, the composite insulating materials used in domestic ultra-high voltage electrical appliances, high-voltage switches and high-voltage test transformers, especially in the field of manufacturing large-length-to-diameter, large-diameter, and super-long pipe fittings, mainly use ordinary glass fibers and single-structure bisphenol A rings. Oxygen resin composite molding. In the manufacturing process, a large metal core mold is required, which is heavy, has a long processing cycle, is expensive, and requires a large demoulding device, so its production cost is high and the efficiency is low; before fiber winding, the mandrel needs to be evenly coated with a mold release agent , to help smooth demoulding, but in actual operation, the uneven application of the demoulding agent often causes many production accidents such as difficulty in demoulding, inability to demould, or scratches on the inner wall of the demoulding; The solvent release agent will increase the processing cost, complicate the production molding process, increase uncontrollability, and poor quality stability.

发明内容 Contents of the invention

本发明的目的是提供一种纤维复合材料绝缘筒、管件的制造方法。 The object of the present invention is to provide a method for manufacturing a fiber composite insulation cylinder and a pipe fitting.

本发明的技术方案是:一种纤维复合材料绝缘筒、管件的制造方法,其特征在于该方法包括以下工艺步骤: The technical solution of the present invention is: a method for manufacturing a fiber composite insulating cylinder and a pipe fitting, which is characterized in that the method includes the following process steps:

A、纤维浸胶,将胶液置于胶槽中,加热至20-40℃,黏度为0.2-1.0Pa·s,将纤维集束后从胶槽一端浸入胶液中并缓慢向胶槽另一端移动至槽外,控制纤维素的移动速度为0.2-0.9米/分钟,含胶量在15%-30%之间; A. Fiber dipping, put the glue in the glue tank, heat it to 20-40°C, the viscosity is 0.2-1.0Pa·s, after the fibers are bundled, immerse in the glue from one end of the glue tank and slowly to the other end of the glue tank Move to the outside of the tank, control the moving speed of cellulose to 0.2-0.9 m/min, and the glue content is between 15%-30%;

B、纤维束缠绕张力设定,初张力按纤维强度的5%-10%选取,在螺旋缠绕和平面缠绕中,纤维束的张力控制在0.45-1.8公斤,在径向缠绕中,纤维束的张力控制在2.7-3.6公斤; B. Fiber bundle winding tension setting, the initial tension is selected according to 5%-10% of fiber strength, in spiral winding and plane winding, the tension of fiber bundle is controlled at 0.45-1.8 kg, in radial winding, the fiber bundle The tension is controlled at 2.7-3.6 kg;

C、纤维束缠绕,浸胶后的纤维束使用缠绕机进行纵、环向交叉螺旋缠绕,环向缠绕的缠绕角在85°-90°之间,纵向缠绕的缠绕角为15°或30°或45°,缠绕速度最大不超过0.9米/秒钟,缠绕形成半成品; C. Winding of fiber bundles. The fiber bundles after dipping are wound longitudinally and circumferentially in a cross-helical manner using a winding machine. The winding angle of the circumferential winding is between 85°-90°, and the winding angle of the longitudinal winding is 15° or 30°. Or 45°, the maximum winding speed does not exceed 0.9 m/s, and the winding forms a semi-finished product;

D、加热固化,用红外加热装置对半成品进行加热固化,加热时保持半成品缓慢转动,在30-80℃的加热条件下,加热固化时间为30-80分钟; D. Heating and curing. Use an infrared heating device to heat and cure the semi-finished product. Keep the semi-finished product slowly rotating during heating. Under the heating condition of 30-80°C, the heating and curing time is 30-80 minutes;

E、外表面光固化:将光固化剂均匀涂覆于加热固化后半成品的外表面,用胶辊反复压实排出空气,然后用紫外光光源照射15-30秒钟,直至硬化。 E. Light curing of the outer surface: Apply the light curing agent evenly on the outer surface of the semi-finished product after heating and curing, repeatedly compact with rubber rollers to discharge the air, and then irradiate with ultraviolet light source for 15-30 seconds until hardening.

以上所述的纤维为碳纤维或玻璃纤维。 The fibers mentioned above are carbon fibers or glass fibers.

本发明采用纤维缠绕及快速固化成型工艺,使得纤维复合材料超高压电器、高压开关及高压试验变压器,尤其是大长径比、大口径、超长管件的制造无需再使用大型芯模和脱模剂,从而提高了生产效率,降低了制造成本,减轻了劳动强度。用本发明的方法制造的纤维复合材料,制造成本比现有技术降低30%以上,材料的电气性能和机械性能都优于现有技术制造的纤维复合材料。 The invention adopts fiber winding and rapid solidification molding process, so that the manufacture of fiber composite ultra-high-voltage electrical appliances, high-voltage switches and high-voltage test transformers, especially large-length-to-diameter ratio, large-diameter, and super-long pipes, does not need to use large mandrels and demoulding agent, thereby improving production efficiency, reducing manufacturing costs, and reducing labor intensity. The manufacturing cost of the fiber composite material manufactured by the method of the invention is lower than that of the prior art by more than 30%, and the electrical properties and mechanical properties of the material are better than the fiber composite material manufactured by the prior art.

具体实施方式 Detailed ways

实施例1: Example 1:

A、将由特种的双酚A,双酚F的环氧树脂,增韧剂、改性剂、促进剂、稀释剂混合配制而成、黏度为0.4 Pa·s的胶液置于胶槽中,将碳纤维低捻纱集束后从胶槽一端浸入胶液中并缓慢向胶槽另一端移动至槽外,控制纤维素的移动速度为0.5米/分钟,含胶量在20%。 A. Put the glue solution prepared by mixing special bisphenol A, bisphenol F epoxy resin, toughener, modifier, accelerator, and diluent with a viscosity of 0.4 Pa·s in the glue tank. After the carbon fiber low-twisted yarn is bundled, it is immersed in the glue solution from one end of the glue tank and slowly moves to the other end of the glue tank to the outside of the tank. The moving speed of the cellulose is controlled at 0.5 m/min, and the glue content is 20%.

B、浸胶后的纤维束用多维电脑控制缠绕机进行纵、环向交叉螺旋缠绕,环向缠绕的缠绕角控制在85°,纵向缠绕的缠绕角控制在15°,缠绕速度为0.7米/秒钟;在螺旋缠绕和平面缠绕中,纤维束的张力控制在1公斤,在径向缠绕中,纤维束的张力控制在3公斤,缠绕形成半成品。 B. The fiber bundle after dipping is controlled by a multi-dimensional computer winding machine for longitudinal and circumferential cross-helical winding, the winding angle of the circumferential winding is controlled at 85°, the winding angle of the longitudinal winding is controlled at 15°, and the winding speed is 0.7 m/ Second; in spiral winding and planar winding, the tension of the fiber bundle is controlled at 1 kg, in radial winding, the tension of the fiber bundle is controlled at 3 kg, and the winding forms a semi-finished product.

C、用旋转红外固化炉对半成品进行加热固化,加热时保持半成品在炉内缓慢转动,在65℃的加热条件下,加热固化时间为60分钟。 C. Use a rotary infrared curing furnace to heat and cure the semi-finished product. During heating, keep the semi-finished product rotating slowly in the furnace. Under the heating condition of 65°C, the heating and curing time is 60 minutes.

D、将由特种低粘度环氧树脂、光引发剂、链转移剂、光敏剂混合配制的光固化剂均匀涂覆于加热固化后半成品的外表面,用胶辊反复压实排出空气,然后用紫外光旋转固化装置的紫外光源照射20秒钟,直至硬化,得到成品。 D. Evenly coat the photocuring agent prepared by mixing special low-viscosity epoxy resin, photoinitiator, chain transfer agent and photosensitizer on the outer surface of the semi-finished product after heating and curing, and repeatedly compact the air with a rubber roller, and then use ultraviolet light The ultraviolet light source of the light rotation curing device is irradiated for 20 seconds until hardening to obtain a finished product.

实施例2: Example 2:

A、将由特种的双酚A,双酚F的环氧树脂,增韧剂、改性剂、促进剂、稀释剂混合配制而成、黏度为0.9 Pa·s的胶液置于胶槽中,将玻璃纤维无捻粗纱集束后从胶槽一端浸入胶液中并缓慢向胶槽另一端移动至槽外,控制纤维素的移动速度为0.9米/分钟,含胶量在30%。 A. Put the glue solution prepared by mixing special bisphenol A, bisphenol F epoxy resin, toughener, modifier, accelerator, and diluent with a viscosity of 0.9 Pa·s in the glue tank. After the glass fiber roving is bundled, it is immersed in the glue solution from one end of the glue tank and slowly moves to the other end of the glue tank to the outside of the tank. The moving speed of the cellulose is controlled to 0.9 m/min, and the glue content is 30%.

B、浸胶后的纤维束用多维电脑控制缠绕机进行纵、环向交叉螺旋缠绕,环向缠绕的缠绕角控制在90°,纵向缠绕的缠绕角控制在45°,缠绕速度为0.9米/秒钟;在螺旋缠绕和平面缠绕中,纤维束的张力控制在1.8公斤,在径向缠绕中,纤维束的张力控制在3.6公斤,缠绕形成半成品。 B. The fiber bundle after dipping is controlled by a multi-dimensional computer winding machine for longitudinal and circumferential cross-helical winding, the winding angle of the circumferential winding is controlled at 90°, the winding angle of the longitudinal winding is controlled at 45°, and the winding speed is 0.9 m/ Second; in spiral winding and planar winding, the tension of the fiber bundle is controlled at 1.8 kg, and in radial winding, the tension of the fiber bundle is controlled at 3.6 kg, and the winding forms a semi-finished product.

C、用旋转红外固化炉对半成品进行加热固化,加热时保持半成品在炉内缓慢转动,在80℃的加热条件下,加热固化时间为80分钟。 C. Use a rotary infrared curing furnace to heat and cure the semi-finished product. During heating, keep the semi-finished product rotating slowly in the furnace. Under the heating condition of 80°C, the heating and curing time is 80 minutes.

D、将由特种低粘度环氧树脂、光引发剂、链转移剂、光敏剂混合配制的光固化剂均匀涂覆于加热固化后半成品的外表面,用胶辊反复压实排出空气,然后用紫外光旋转固化装置的紫外光源照射30秒钟,直至硬化,得到成品。 D. Evenly coat the photocuring agent prepared by mixing special low-viscosity epoxy resin, photoinitiator, chain transfer agent and photosensitizer on the outer surface of the semi-finished product after heating and curing, and repeatedly compact the air with a rubber roller, and then use ultraviolet light The ultraviolet light source of the light rotation curing device is irradiated for 30 seconds until hardening to obtain a finished product.

Claims (2)

1.一种纤维复合材料绝缘筒、管件的制造方法,其特征在于该方法包括以下工艺步骤: 1. A method for manufacturing a fiber composite insulating cylinder and a pipe fitting, characterized in that the method comprises the following processing steps: A、纤维浸胶,将胶液置于胶槽中,加热至20-40℃,黏度为0.2-1.0Pa·s,将纤维集束后从胶槽一端浸入胶液中并缓慢向胶槽另一端移动至槽外,控制纤维素的移动速度为0.2-0.9米/分钟,含胶量在15%-30%之间; A. Fiber dipping, put the glue in the glue tank, heat it to 20-40°C, the viscosity is 0.2-1.0Pa·s, after the fibers are bundled, immerse in the glue from one end of the glue tank and slowly to the other end of the glue tank Move to the outside of the tank, control the moving speed of cellulose to 0.2-0.9 m/min, and the glue content is between 15%-30%; B、纤维束缠绕张力设定,初张力按纤维强度的5%-10%选取,在螺旋缠绕和平面缠绕中,纤维束的张力控制在0.45-1.8公斤,在径向缠绕中,纤维束的张力控制在2.7-3.6公斤; B. Fiber bundle winding tension setting, the initial tension is selected according to 5%-10% of fiber strength, in spiral winding and plane winding, the tension of fiber bundle is controlled at 0.45-1.8 kg, in radial winding, the fiber bundle The tension is controlled at 2.7-3.6 kg; C、纤维束缠绕,浸胶后的纤维束使用缠绕机进行纵、环向交叉螺旋缠绕,环向缠绕的缠绕角在85°-90°之间,纵向缠绕的缠绕角为15°或30°或45°,缠绕速度最大不超过0.9米/秒钟,缠绕形成半成品; C. Winding of fiber bundles. The fiber bundles after dipping are wound longitudinally and circumferentially in a cross-helical manner using a winding machine. The winding angle of the circumferential winding is between 85°-90°, and the winding angle of the longitudinal winding is 15° or 30°. Or 45°, the maximum winding speed does not exceed 0.9 m/s, and the winding forms a semi-finished product; D、加热固化,用红外加热装置对半成品进行加热固化,加热时保持半成品缓慢转动,在30-80℃的加热条件下,加热固化时间为30-80分钟; D. Heating and curing. Use an infrared heating device to heat and cure the semi-finished product. Keep the semi-finished product slowly rotating during heating. Under the heating condition of 30-80°C, the heating and curing time is 30-80 minutes; E、外表面光固化:将光固化剂均匀涂覆于加热固化后半成品的外表面,用胶辊反复压实排出空气,然后用紫外光光源照射15-30秒钟,直至硬化。 E. Light curing of the outer surface: Apply the light curing agent evenly on the outer surface of the semi-finished product after heating and curing, repeatedly compact with rubber rollers to discharge the air, and then irradiate with ultraviolet light source for 15-30 seconds until hardening. 2.根据权利要求1所述的一种纤维复合材料绝缘筒、管件的制造方法,其特征在于所述的纤维为碳纤维或玻璃纤维。 2. A method for manufacturing a fiber composite insulation cylinder and pipe fittings according to claim 1, characterized in that said fibers are carbon fibers or glass fibers.
CN201410757670.8A 2014-12-12 2014-12-12 Manufacturing method of insulating cylinder and pipe fitting made from fiber composite material Pending CN104441683A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106246149A (en) * 2016-09-12 2016-12-21 胜利油田新大管业科技发展有限责任公司 A kind of fiberglass seperated layer water injection downhole tubular
CN109397723A (en) * 2018-10-24 2019-03-01 郑州郑飞木业有限责任公司 A kind of manufacture craft of guiding tube

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CN106246149A (en) * 2016-09-12 2016-12-21 胜利油田新大管业科技发展有限责任公司 A kind of fiberglass seperated layer water injection downhole tubular
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CN109397723A (en) * 2018-10-24 2019-03-01 郑州郑飞木业有限责任公司 A kind of manufacture craft of guiding tube

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