CN105419229B - A kind of hollow combined insulator winding pipe and preparation method thereof - Google Patents
A kind of hollow combined insulator winding pipe and preparation method thereof Download PDFInfo
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- 238000004804 winding Methods 0.000 title claims abstract description 119
- 239000012212 insulator Substances 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title abstract description 8
- 239000003292 glue Substances 0.000 claims abstract description 103
- 239000000835 fiber Substances 0.000 claims abstract description 71
- 239000003822 epoxy resin Substances 0.000 claims abstract description 61
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 61
- 239000003365 glass fiber Substances 0.000 claims abstract description 50
- 239000002131 composite material Substances 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 27
- 239000013530 defoamer Substances 0.000 claims abstract description 18
- 239000003085 diluting agent Substances 0.000 claims abstract description 15
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 9
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 33
- 239000011265 semifinished product Substances 0.000 claims description 17
- 238000007598 dipping method Methods 0.000 claims description 14
- 229920005989 resin Polymers 0.000 claims description 12
- 239000011347 resin Substances 0.000 claims description 12
- 230000004224 protection Effects 0.000 claims description 9
- MWSKJDNQKGCKPA-UHFFFAOYSA-N 6-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1CC(C)=CC2C(=O)OC(=O)C12 MWSKJDNQKGCKPA-UHFFFAOYSA-N 0.000 claims description 8
- 238000013329 compounding Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 229920006267 polyester film Polymers 0.000 claims description 4
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- NFVPEIKDMMISQO-UHFFFAOYSA-N 4-[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC=C(O)C=C1 NFVPEIKDMMISQO-UHFFFAOYSA-N 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 7
- 238000009413 insulation Methods 0.000 abstract description 3
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- AHDSRXYHVZECER-UHFFFAOYSA-N 2,4,6-tris[(dimethylamino)methyl]phenol Chemical group CN(C)CC1=CC(CN(C)C)=C(O)C(CN(C)C)=C1 AHDSRXYHVZECER-UHFFFAOYSA-N 0.000 description 8
- 239000011521 glass Substances 0.000 description 4
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- BCEJXMPUFHXHBT-KRWDZBQOSA-N CN(C=1C(=CC(N2[C@@H](CSC=12)C(=O)O)=O)CC1=CC=CC2=CC=CC=C12)C Chemical compound CN(C=1C(=CC(N2[C@@H](CSC=12)C(=O)O)=O)CC1=CC=CC2=CC=CC=C12)C BCEJXMPUFHXHBT-KRWDZBQOSA-N 0.000 description 3
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2023/00—Tubular articles
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Abstract
本发明公开了一种空心复合绝缘子用缠绕管及其制备方法,该缠绕管是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,所述环氧树脂胶由以下重量份数的原料组成:环氧树脂80~120份、固化剂50~80份、稀释剂5~10份、促进剂2~5份、消泡剂0.1~0.5份;所述稀释剂为环氧丙烷丁基醚;所述缠绕管的含胶量为25%~30%。本发明的空心复合绝缘子用缠绕管,环氧树脂胶具有合适的粘度和流动性,与玻璃纤维的结合性能好,多股玻璃纤维浸胶后容易挂胶并形成纤维纱片,提高缠绕效率;环氧树脂胶固化后与玻璃纤维形成的缠绕管强度高,致密性和气密性好,且具有良好的绝缘性能;含胶量适中,具有良好的机械性能和耐电击穿性能。
The invention discloses a winding tube for hollow composite insulators and a preparation method thereof. The winding tube is formed by winding and curing glass fibers impregnated with epoxy resin glue, and the epoxy resin glue is composed of the following raw materials in parts by weight: 80-120 parts of epoxy resin, 50-80 parts of curing agent, 5-10 parts of diluent, 2-5 parts of accelerator, 0.1-0.5 parts of defoamer; the diluent is propylene oxide butyl ether; the The glue content of the winding pipe is 25%-30%. In the winding tube for hollow composite insulators of the present invention, the epoxy resin glue has suitable viscosity and fluidity, and has good bonding performance with glass fibers. After the glass fibers are dipped in glue, it is easy to glue and form fiber yarn sheets, which improves the winding efficiency; After the epoxy resin is cured, the winding tube formed with the glass fiber has high strength, good compactness and air tightness, and has good insulation performance; the glue content is moderate, and it has good mechanical properties and electrical breakdown resistance.
Description
技术领域technical field
本发明属于电气设备技术领域,具体涉及一种空心复合绝缘子用缠绕管及其制备方法。The invention belongs to the technical field of electrical equipment, and in particular relates to a winding pipe for a hollow composite insulator and a preparation method thereof.
背景技术Background technique
绝缘子是高压电网及输送线路中的关键部件之一,其性能的好坏将直接影响高压电网的安全运行。目前使用的高压绝缘子有瓷绝缘子、玻璃绝缘子和复合绝缘子三大类。其中,复合绝缘子与瓷绝缘子、玻璃绝缘子相比,具有下列优点:重量轻、防震性好、抗污能力强、防爆性能优异、使用寿命长、疏水性好、使用范围广、维护费用低、生产成本低、产品交运时间短、无零值、抗紫外线性能强,因此,复合绝缘子自投放市场以来备受用户欢迎,得到快速发展。Insulators are one of the key components in high-voltage power grids and transmission lines, and their performance will directly affect the safe operation of high-voltage power grids. There are three types of high voltage insulators currently used: porcelain insulators, glass insulators and composite insulators. Among them, compared with porcelain insulators and glass insulators, composite insulators have the following advantages: light weight, good shock resistance, strong anti-pollution ability, excellent explosion-proof performance, long service life, good hydrophobicity, wide application range, low maintenance costs, production Low cost, short product delivery time, no zero value, and strong UV resistance, therefore, composite insulators have been welcomed by users since they were put on the market and have developed rapidly.
复合绝缘子是由芯棒、伞群和金具三部分构成,芯棒采用强度高的玻璃钢(玻璃纤维增强树脂)制成,既是承力件也是内绝缘件。复合绝缘子按玻璃钢芯棒的不同可分为实心和空心两种,实心玻璃钢芯棒一般采用引拔法生产,主要用于高压架空线路中;空心玻璃钢芯棒一般采用缠绕法成型,主要用于站内绝缘子,如互感器、高压开关及断路器等,称为空心复合绝缘子。与传统的瓷绝缘子及玻璃绝缘子相比,空心复合绝缘子具有质量轻、耐污闪能力强、制造工艺简单等优点,近几十年来发展十分迅速。空心玻璃钢芯棒作为空心复合绝缘子的芯体部件,承受着主要的机械应力、电应力,因此,对空心复合绝缘子用芯棒来说,要求其具备很好的机械性能、耐电击穿性能。The composite insulator is composed of three parts: mandrel, umbrella group and hardware. The mandrel is made of high-strength FRP (glass fiber reinforced resin), which is both a load-bearing part and an inner insulator. Composite insulators can be divided into two types: solid and hollow according to the difference of FRP core rods. Solid FRP core rods are generally produced by drawing method and are mainly used in high-voltage overhead lines; hollow FRP core rods are generally formed by winding method and are mainly used in stations. Insulators, such as transformers, high voltage switches and circuit breakers, are called hollow composite insulators. Compared with traditional porcelain insulators and glass insulators, hollow composite insulators have the advantages of light weight, strong pollution flashover resistance, simple manufacturing process, etc., and have developed rapidly in recent decades. As the core part of the hollow composite insulator, the hollow FRP mandrel bears the main mechanical stress and electrical stress. Therefore, for the mandrel for the hollow composite insulator, it is required to have good mechanical properties and electrical breakdown resistance.
目前,制作空心复合绝缘管芯棒的方法有两大类:玻璃纤维湿法缠绕成型、真空浸渍的玻璃布带缠绕成型。其中玻璃纤维湿法缠绕成型成本低,操作简便,但是其制备的缠绕管还不能满足使用中对机械性能和耐电击穿性能的要求。At present, there are two types of methods for making hollow composite insulating pipe mandrels: glass fiber wet winding molding, and vacuum impregnated glass cloth tape winding molding. Among them, glass fiber wet winding molding has low cost and is easy to operate, but the winding pipe prepared by it cannot meet the requirements for mechanical properties and electrical breakdown resistance in use.
现有技术中,CN100354988C公开了一种用玻璃纤维浸渍树脂基缠绕式复合绝缘子芯棒的制备方法,包括按重量比称取树脂基浸渍组合物,包括树脂、固化剂、促进剂,三者的重量比为90-120:80-90:1,所述树脂为环氧树脂,所述固化剂为甲基四氢苯酐,所述促进剂为S-440;将纱锭的一端通过树脂基胶槽将玻璃纤维环氧缠绕纱单丝放入熔化后的树脂基溶液中,然后把单丝的一端固定在金属环上;开启缠绕机按事先设定的程序工作,缠绕完毕后,连同缠绕工装件一同放到固化炉进行固化;然后等温度自动降至常温后卸下工装件、脱模,即完成整个工序。该缠绕式复合绝缘子芯棒结构简单,生产成本低。但是其在缠绕时采用的是单丝缠绕的形式,单位产品的生产时间过长,生产效率低下;单丝很容易产生断纱的问题,影响最终产品的成品率和机械强度;同时,单丝浸胶的挂胶量不好控制,往往挂胶量较低,造成最终产品中纤维空隙率增加,制品的气密性、防老化性能及机械强度等达不到使用的要求,同时也影响其耐电击穿性能。In the prior art, CN100354988C discloses a method for preparing a resin-based wound composite insulator mandrel impregnated with glass fiber, which includes weighing the resin-based impregnating composition by weight ratio, including resin, curing agent, and accelerator. The weight ratio is 90-120:80-90:1, the resin is epoxy resin, the curing agent is methyl tetrahydrophthalic anhydride, and the accelerator is S-440; one end of the spindle is passed through the resin-based glue tank Put the monofilament of glass fiber epoxy winding yarn into the melted resin-based solution, and then fix one end of the monofilament on the metal ring; turn on the winding machine and work according to the preset program. After winding, together with the winding tooling Put them together in a curing furnace for curing; then wait until the temperature automatically drops to room temperature, then remove the tooling and demould, and the whole process is completed. The winding composite insulator mandrel has simple structure and low production cost. However, it adopts the form of monofilament winding during winding, the production time of unit product is too long, and the production efficiency is low; monofilament is easy to produce the problem of broken yarn, which affects the yield and mechanical strength of the final product; at the same time, monofilament The amount of glue in the dipping is not easy to control, often the amount of glue is low, resulting in an increase in the fiber void ratio in the final product, and the air tightness, anti-aging performance and mechanical strength of the product cannot meet the requirements of use, and it also affects its quality. Resistance to electrical breakdown.
发明内容Contents of the invention
本发明的目的是提供一种空心复合绝缘子用缠绕管,具有良好的机械性能和耐电击穿性能。The object of the present invention is to provide a winding tube for hollow composite insulators, which has good mechanical properties and electrical breakdown resistance.
本发明的另一个目的是提供一种空心复合绝缘子用缠绕管的制备方法。Another object of the present invention is to provide a method for preparing wound pipes for hollow composite insulators.
为了实现以上目的,本发明所采用的技术方案是:In order to achieve the above object, the technical solution adopted in the present invention is:
一种空心复合绝缘子用缠绕管,该缠绕管是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,所述环氧树脂胶由以下重量份数的原料组成:环氧树脂80~120份、固化剂50~80份、稀释剂5~10份、促进剂2~5份、消泡剂0.1~0.5份;所述稀释剂为环氧丙烷丁基醚;所述缠绕管的含胶量为25%~30%。A winding tube for hollow composite insulators, the winding tube is formed by winding and curing glass fibers impregnated with epoxy resin glue, and the epoxy resin glue is composed of the following raw materials in parts by weight: 80-120 parts of epoxy resin, 50-80 parts of curing agent, 5-10 parts of diluent, 2-5 parts of accelerator, 0.1-0.5 parts of defoamer; the diluent is propylene oxide butyl ether; the glue content of the winding tube is 25% to 30%.
所述含胶量是指环氧树脂胶固化后占整个缠绕管的质量百分比(环氧树脂胶在固化前后质量不会发生较大变化)。本发明的缠绕管的含胶量(固化后)为25%~30%;余量为玻璃纤维。The glue content refers to the mass percentage of the epoxy resin glue in the whole winding tube after curing (the quality of the epoxy resin glue will not change greatly before and after curing). The glue content (after curing) of the winding pipe of the present invention is 25% to 30%; the balance is glass fiber.
所述环氧树脂为E51型环氧树脂。优选的,所述环氧树脂为中石化巴陵石化提供的EP CYD-128环氧树脂。The epoxy resin is E51 type epoxy resin. Preferably, the epoxy resin is EP CYD-128 epoxy resin provided by Sinopec Baling Petrochemical.
所述玻璃纤维为无碱玻璃纤维无捻纱。优选的,所述玻璃纤维为无碱玻璃纤维无捻粗纱。The glass fiber is non-alkali glass fiber non-twisted yarn. Preferably, the glass fiber is an alkali-free glass fiber roving.
所述固化剂为甲基四氢苯酐。所述固化剂的凝胶化温度为120~140℃,后固化温度为140~160℃。优选的,所述固化剂为嘉兴联兴化工新材料有限公司提供的JHY906固化剂(甲基四氢苯酐)。The curing agent is methyl tetrahydrophthalic anhydride. The gelling temperature of the curing agent is 120-140°C, and the post-curing temperature is 140-160°C. Preferably, the curing agent is JHY906 curing agent (methyltetrahydrophthalic anhydride) provided by Jiaxing Lianxing New Chemical Materials Co., Ltd.
所述稀释剂为活性稀释剂660(市售商品)。The diluent is reactive diluent 660 (commercially available).
所述促进剂为2,4,6-三(二甲氨基甲基)苯酚。所述促进剂为DMP-30(市售商品)。The accelerator is 2,4,6-tris(dimethylaminomethyl)phenol. The accelerator is DMP-30 (commercially available).
所述消泡剂为有机硅消泡剂。所述消泡剂优选BYK A530消泡剂。The defoamer is a silicone defoamer. The defoamer is preferably BYK A530 defoamer.
所述环氧树脂胶是将配方量的环氧树脂、固化剂、稀释剂、促进剂和消泡剂混合后制成的;所述环氧树脂胶的粘度为0.35~0.45Pa·s(浸胶时控制粘度)。所述缠绕管是由浸渍环氧树脂胶的多股玻璃纤维形成的纤维纱片缠绕固化形成的。The epoxy resin glue is made by mixing the epoxy resin, curing agent, diluent, accelerator and defoamer in the formula quantity; the viscosity of the epoxy resin glue is 0.35~0.45Pa·s (immersion Control the viscosity when gluing). The winding pipe is formed by winding and curing a fiber yarn sheet formed by a plurality of strands of glass fibers impregnated with epoxy resin glue.
本发明的空心复合绝缘子用缠绕管,是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,环氧树脂胶在环氧树脂、固化剂、促进剂基础上加入稀释剂、消泡剂复配,具有合适的粘度和流动性,与玻璃纤维的结合性能好,多股玻璃纤维浸胶后容易挂胶并形成纤维纱片,固化后与玻璃纤维形成的缠绕管强度高,致密性和气密性好,且具有良好的绝缘性能;该缠绕管的含胶量适中,具有良好的机械性能和耐电击穿性能,满足电力电网、变电站对于空心复合绝缘子用缠绕管的使用要求。The winding pipe for hollow composite insulators of the present invention is formed by winding and curing glass fibers impregnated with epoxy resin glue, and the epoxy resin glue is compounded by adding diluent and defoamer on the basis of epoxy resin, curing agent and accelerator , with suitable viscosity and fluidity, and good bonding performance with glass fiber. After dipping multi-strand glass fiber, it is easy to hang glue and form fiber yarn sheet. After curing, the winding tube formed with glass fiber has high strength, compactness and air tightness. Good, and has good insulation performance; the rubber content of the winding pipe is moderate, has good mechanical properties and electrical breakdown resistance, and meets the requirements for the use of winding pipes for hollow composite insulators in power grids and substations.
一种上述的空心复合绝缘子用缠绕管的制备方法,包括下列步骤:A method for preparing the above-mentioned wound pipe for hollow composite insulators, comprising the following steps:
1)配胶:取配方量的环氧树脂、固化剂、稀释剂、促进剂和消泡剂混合均匀制成环氧树脂胶,将环氧树脂胶置入恒温的胶槽中;1) Glue compounding: Mix the epoxy resin, curing agent, diluent, accelerator and defoamer evenly to make epoxy resin glue, and put the epoxy resin glue into the constant temperature glue tank;
2)模具处理:取芯模,在芯模表面涂上脱模剂;2) Mold treatment: take the mandrel, and apply a release agent on the mandrel surface;
3)浸胶缠绕:将多股玻璃纤维无捻纱穿过胶槽使纤维浸胶并形成纤维纱片,引出纤维纱片在芯模端头固定后,将纤维纱片持续缠绕在芯模上,缠绕角度为52°~56°,缠绕张力为1.1~2kN,缠绕速度为1.0~1.5m/s;缠绕结束后在外侧缠上一层薄膜保护带,得半成品;3) Glue-dipped winding: pass multiple strands of glass fiber untwisted yarn through the glue tank to dip the fiber and form a fiber yarn sheet, and after the fiber yarn sheet is drawn out and fixed at the end of the mandrel, the fiber yarn sheet is continuously wound on the mandrel , the winding angle is 52°~56°, the winding tension is 1.1~2kN, and the winding speed is 1.0~1.5m/s; after winding, wrap a layer of film protection tape on the outside to get a semi-finished product;
4)固化:将步骤3)所得半成品进行固化后脱模,即得。4) Curing: The semi-finished product obtained in step 3) is cured and demolded to obtain the product.
步骤1)中,所述胶槽的温度为60℃。所述环氧树脂胶的粘度控制在0.35~0.45Pa·s。In step 1), the temperature of the glue tank is 60°C. The viscosity of the epoxy resin glue is controlled at 0.35-0.45 Pa·s.
步骤1)中,所述环氧树脂胶在置入胶槽之前进行预热;所述预热是指将环氧树脂胶在50℃条件下保温预热8h。In step 1), the epoxy resin glue is preheated before being put into the glue tank; the preheating refers to preheating the epoxy resin glue at 50° C. for 8 hours.
步骤2)中,所述脱模剂为美国AXEL公司的818液体脱模剂。所述脱模剂的涂覆方法为喷涂或用软布蘸脱模剂,在芯模表面擦拭涂覆均匀。In step 2), the release agent is 818 liquid release agent from AXEL Corporation of the United States. The coating method of the release agent is to spray or dip a soft cloth in the release agent, and wipe the surface of the mandrel to coat evenly.
步骤3)中,所述玻璃纤维无捻纱在使用之前经过烘干处理;所述烘干处理是在60~80℃条件下烘干24h。玻璃纤维表面含有水分,不仅影响树脂基材与玻璃纤维之间的粘接性能,同时将引起应力腐蚀,使微裂纹等缺陷进一步扩展,从而引起制品的强度和耐老化性能下降,因此玻璃纤维在使用之前经过烘干处理。In step 3), the glass fiber untwisted yarn is dried before use; the drying treatment is at 60-80° C. for 24 hours. The surface of the glass fiber contains moisture, which not only affects the bonding performance between the resin substrate and the glass fiber, but also causes stress corrosion and further expands defects such as microcracks, thereby causing a decrease in the strength and aging resistance of the product. Tumble dry before use.
步骤3)的缠绕过程中,以纤维纱片铺满芯模表面为一层纤维层,从内向外一层一层缠绕;缠绕层数依据要求的厚度设定。In the winding process of step 3), the surface of the mandrel is covered with fiber yarn sheets to form a layer of fiber layer, which is wound layer by layer from the inside to the outside; the number of winding layers is set according to the required thickness.
步骤3)的缠绕过程中,丝嘴距芯模表面的距离H设置为40~60mm;纱团数设置为14~20团纱。纤维纱片的宽度依据纱团数设定。During the winding process in step 3), the distance H between the yarn nozzle and the surface of the mandrel is set at 40-60 mm; the number of yarn clusters is set at 14-20 clusters. The width of the fiber yarn sheet is set according to the number of yarn packages.
步骤3)中,将9~12股玻璃纤维无捻纱穿过胶槽使纤维浸胶并形成宽度为14~20mm的纤维纱片。In step 3), 9-12 strands of glass fiber untwisted yarns are passed through the glue tank to impregnate the fibers and form fiber yarn sheets with a width of 14-20 mm.
步骤3)中,以纤维纱片铺满芯模为一层纤维层,内层纤维层的缠绕角度为52°~56°,最外两层纤维层的缠绕角度为90°。缠绕过程中,封头停留角为120°。In step 3), the mandrel is covered with fiber yarn sheets as a fiber layer, the winding angle of the inner fiber layer is 52°-56°, and the winding angle of the outermost two fiber layers is 90°. During the winding process, the stop angle of the head is 120°.
缠绕过程中需控制缠绕参数:缠绕张力依据芯模结构、增强纤维强度、胶液粘度及芯模是否加热而定,本发明的缠绕张力为1.1~2kN。本发明的空心复合绝缘子用缠绕管的制备方法为湿法缠绕,缠绕速度(出纱速度)受到纤维浸胶过程的限制,为1.0~1.5m/s;当缠绕速度(出纱速度)过快时,芯模转速很高,会出现树脂胶液在离心力作用下从缠绕结构中向外迁移和溅洒的想象,制品中胶液的分布和含量无法控制,影响最终产品的性能。During the winding process, the winding parameters need to be controlled: the winding tension depends on the structure of the mandrel, the strength of the reinforced fiber, the viscosity of the glue, and whether the mandrel is heated. The winding tension of the present invention is 1.1-2kN. The preparation method of the winding tube for hollow composite insulators of the present invention is wet winding, and the winding speed (yarn output speed) is limited by the fiber dipping process, which is 1.0-1.5m/s; when the winding speed (yarn output speed) is too fast When the mandrel rotates at a high speed, the imagination of the resin glue migrating and splashing outward from the winding structure under the action of centrifugal force will appear. The distribution and content of the glue in the product cannot be controlled, which will affect the performance of the final product.
缠绕过程中注意控制胶含量、纱架出纱线是否有断纱现象。During the winding process, pay attention to controlling the glue content and whether there is any yarn breakage in the yarn out of the creel.
玻璃纤维浸胶含量的高低及其分步对制品性能影响很大,直接影响制品的重量级厚度;含胶量过高,制品的复合强度降低;含胶量过低,制品里的纤维空隙率增加,使制品的气密性、防老化性能及剪切强度下降,同时也影响纤维强度的发挥。因此,纤维浸胶过程必须严格控制,使所得缠绕管的含胶量为25%~30%(质量百分比)。纤维含胶量是在纤维浸胶过程中进行控制的。浸胶过程是树脂胶液涂覆或浸挂在增强纤维表面,之后胶液向增强纤维内部扩散和渗透,这两个阶段是同时进行的。浸胶过程中,影响纤维含胶量的因素很多,如纤维规格、胶液粘度、缠绕张力、缠绕速度、刮胶机构、操作温度等,其中胶液粘度、缠绕张力、缠绕速度最重要。The level of glass fiber dipping glue content and its steps have a great influence on the performance of the product, directly affecting the heavyweight thickness of the product; if the glue content is too high, the composite strength of the product will decrease; if the glue content is too low, the fiber void ratio in the product will decrease. Increase, the air tightness, anti-aging performance and shear strength of the product will decrease, and it will also affect the performance of fiber strength. Therefore, the fiber dipping process must be strictly controlled so that the glue content of the resulting wound pipe is 25% to 30% (mass percentage). The fiber glue content is controlled during the fiber dipping process. The dipping process is that the resin glue is coated or impregnated on the surface of the reinforcing fiber, and then the glue diffuses and penetrates into the inside of the reinforcing fiber. These two stages are carried out simultaneously. During the dipping process, there are many factors that affect the glue content of fibers, such as fiber specifications, glue viscosity, winding tension, winding speed, scraping mechanism, operating temperature, etc. Among them, glue viscosity, winding tension, and winding speed are the most important.
所述薄膜保护带为聚酯薄膜或聚四氟乙烯薄膜。在最外侧缠上一层薄膜保护带的作用是防止未固化的树脂滴落。The film protection tape is a polyester film or a polytetrafluoroethylene film. The role of wrapping a layer of film protection tape on the outermost side is to prevent uncured resin from dripping.
固化过程是保证缠绕制品充分固化的重要条件,直接影响缠绕制品的性能及质量,加热固化可提高化学反应速度,缩短固化时间,缩短生产周期、提高生产效率。加热固化比常温固化的缠绕制品强度至少可提高20%~30%。The curing process is an important condition to ensure that the winding products are fully cured, which directly affects the performance and quality of the winding products. Heating and curing can increase the chemical reaction speed, shorten the curing time, shorten the production cycle and improve production efficiency. The strength of the winding product cured by heating can be increased by at least 20% to 30% compared with that cured at room temperature.
步骤4)中,所述固化为分阶段固化,所述分阶段固化是指将所述半成品依次在90℃条件下保温90min、120℃条件下保温150min、160℃条件下保温30min。In step 4), the curing is staged curing, and the staged curing means that the semi-finished product is kept at 90°C for 90 minutes, at 120°C for 150 minutes, and at 160°C for 30 minutes.
本发明的空心复合绝缘子用缠绕管制备方法,包括配胶、模具处理、浸胶缠绕和固化、脱模的步骤,浸胶缠绕步骤是将多股玻璃纤维无捻纱穿过胶槽使纤维浸胶并形成纤维纱片,将纤维纱片持续缠绕在芯模上,相对于单丝缠绕,大大缩短了单个制品的生产周期,生产效率高;将缠绕速度控制在合适的范围内,防止芯模转速太高而导致的胶液向外迁移和间洒的情况,同时几乎无断纱现象,成品率高;通过合理控制各步骤的操作和技术参数,所得制品含胶量适中,致密性好,复合强度高,提高了制品的气密性、防老化性能、耐电击穿性能和机械强度,满足电力电网、变电站对于空心复合绝缘子用缠绕管的使用要求,具有良好的经济效益;该制备方法工艺简单,操作方便,稳定可靠,易于自动化控制,适合大规模工业化生产。The preparation method of winding pipe for hollow composite insulators of the present invention includes the steps of compounding glue, mold treatment, dipping winding and curing, and demoulding. Glue and form a fiber yarn sheet, and continuously wind the fiber yarn sheet on the mandrel. Compared with monofilament winding, the production cycle of a single product is greatly shortened, and the production efficiency is high; the winding speed is controlled within an appropriate range to prevent the mandrel from Too high a rotating speed causes the glue to migrate outwards and sprinkling. At the same time, there is almost no yarn breakage, and the yield is high; through reasonable control of the operation and technical parameters of each step, the resulting product has a moderate glue content and good compactness. The composite strength is high, which improves the airtightness, anti-aging performance, electrical breakdown resistance and mechanical strength of the product, meets the requirements of power grids and substations for winding tubes for hollow composite insulators, and has good economic benefits; the preparation method The process is simple, the operation is convenient, stable and reliable, easy for automatic control, and suitable for large-scale industrial production.
附图说明Description of drawings
图1为实施例1的空心复合绝缘子用缠绕管的制备方法的工艺流程示意图。Fig. 1 is a schematic diagram of the process flow of the preparation method of the wound pipe for hollow composite insulators in Example 1.
具体实施方式Detailed ways
下面结合具体实施方式对本发明做进一步的说明。The present invention will be further described below in combination with specific embodiments.
具体实施方式中,所述环氧树脂为中石化巴陵石化提供的EP CYD-128环氧树脂;甲基四氢苯酐由嘉兴联兴化工新材料有限公司提供;脱模剂为美国AXEL公司的818液体脱模剂。In a specific embodiment, the epoxy resin is EP CYD-128 epoxy resin provided by Sinopec Baling Petrochemical; methyltetrahydrophthalic anhydride is provided by Jiaxing Lianxing New Chemical Materials Co., Ltd.; Liquid release agent.
实施例1Example 1
本实施例的空心复合绝缘子用缠绕管,是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,所述环氧树脂胶由以下重量份数的原料组成:环氧树脂80份、甲基四氢苯酐65份、环氧丙烷丁基醚10份、2,4,6-三(二甲氨基甲基)苯酚3份、BYK A530消泡剂0.5份;所述缠绕管的含胶量为25%(质量百分比)。所述玻璃纤维为无碱玻璃纤维无捻纱。The winding tube for hollow composite insulators in this embodiment is formed by winding and curing glass fibers impregnated with epoxy resin glue. The epoxy resin glue is composed of the following raw materials in parts by weight: 80 parts of epoxy resin, methyl tetra 65 parts of hydrophthalic anhydride, 10 parts of propylene oxide butyl ether, 3 parts of 2,4,6-tris(dimethylaminomethyl)phenol, 0.5 part of BYK A530 defoamer; the glue content of the winding tube is 25 % (mass percentage). The glass fiber is non-alkali glass fiber non-twisted yarn.
本实施例的空心复合绝缘子用缠绕管的制备方法,工艺流程如图1所示,包括下列步骤:The manufacturing method of the wound pipe for the hollow composite insulator of this embodiment, the process flow is shown in Figure 1, including the following steps:
1)配胶:取配方量的E51型环氧树脂、甲基四氢苯酐、环氧丙烷丁基醚、2,4,6-三(二甲氨基甲基)苯酚和BYK A530消泡剂混合均匀制成环氧树脂胶,将所述环氧树脂胶在50℃条件下保温预热8h后,置入60℃恒温的胶槽中;所述环氧树脂胶的粘度控制在0.35Pa·s;1) Glue compounding: Mix E51 type epoxy resin, methyl tetrahydrophthalic anhydride, propylene oxide butyl ether, 2,4,6-tris(dimethylaminomethyl)phenol and BYK A530 defoamer in the formula amount Prepare epoxy resin glue evenly, heat and preheat the epoxy resin glue at 50°C for 8 hours, and then put it into a glue tank with a constant temperature of 60°C; the viscosity of the epoxy resin glue is controlled at 0.35Pa·s ;
2)模具处理:取芯模,在芯模表面涂上脱模剂;2) Mold treatment: take the mandrel, and apply a release agent on the mandrel surface;
3)浸胶缠绕:选用12团无碱玻璃纤维无捻粗纱团,无碱玻璃纤维无捻粗纱使用前在60℃条件下烘干24h;3) Dipping and winding: select 12 balls of non-alkali glass fiber roving, and dry the non-alkali glass fiber roving at 60°C for 24 hours before use;
从纤维架上引出12股无碱玻璃纤维无捻粗纱穿过胶槽使纤维浸胶并形成宽度为20mm的纤维纱片,引出纤维纱片在芯模端头缠绕3圈固定;丝嘴距芯模表面的距离H设置为60mm;Lead out 12 strands of non-alkali glass fiber rovings from the fiber frame to pass through the glue tank to impregnate the fibers and form a fiber yarn sheet with a width of 20mm. The fiber yarn sheet is wound 3 times at the end of the mandrel and fixed; The distance H of the mold surface is set to 60mm;
开启缠绕装置,将纤维纱片持续缠绕在芯模上,保证纤维铺满模具表面,缠绕张力为2kN,缠绕速度为1.0m/s;以纤维纱片铺满芯模表面为一层纤维层,从内向外一层一层缠绕,内层纤维层的缠绕角度为54°,最外两层纤维层的缠绕角度为90°,封头停留角为120°;缠绕过程中注意刮胶,控制胶含量;Turn on the winding device and continuously wind the fiber yarn on the mandrel to ensure that the fiber covers the surface of the mold. The winding tension is 2kN and the winding speed is 1.0m/s; Winding layer by layer from the inside to the outside, the winding angle of the inner fiber layer is 54°, the winding angle of the outermost two fiber layers is 90°, and the stop angle of the head is 120°; during the winding process, pay attention to scraping and controlling the glue content;
缠绕结束后在外侧缠上一层聚酯薄膜保护带,防止未固化的胶液滴落,得半成品;After winding, wrap a layer of polyester film protection tape on the outside to prevent the uncured glue from dripping and get a semi-finished product;
4)固化:将步骤3)所得半成品置于固化炉中进行分阶段固化,所述分阶段固化是指将所述半成品依次在90℃条件下保温90min、120℃条件下保温150min、160℃条件下保温30min,后冷却;4) Curing: The semi-finished product obtained in step 3) is placed in a curing furnace for stage-by-stage curing. The stage-by-stage curing means that the semi-finished product is kept at 90°C for 90 minutes, at 120°C for 150 minutes, and at 160°C. Keep warm for 30 minutes, then cool down;
冷却后用脱模机脱模,即得。After cooling, use a demoulding machine to demould, that is to say.
实施例2Example 2
本实施例的空心复合绝缘子用缠绕管,是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,所述环氧树脂胶由以下重量份数的原料组成:环氧树脂100份、甲基四氢苯酐80份、环氧丙烷丁基醚5份、2,4,6-三(二甲氨基甲基)苯酚2份、BYK A530消泡剂0.3份:所述缠绕管的含胶量为27%(质量百分比)。所述玻璃纤维为无碱玻璃纤维无捻粗纱。The winding pipe for hollow composite insulators in this embodiment is formed by winding and curing glass fibers impregnated with epoxy resin glue, and the epoxy resin glue is composed of the following raw materials in parts by weight: 100 parts of epoxy resin, methyl tetra 80 parts of hydrophthalic anhydride, 5 parts of propylene oxide butyl ether, 2 parts of 2,4,6-tris(dimethylaminomethyl)phenol, 0.3 parts of BYK A530 defoamer: the glue content of the winding tube is 27 % (mass percentage). The glass fiber is an alkali-free glass fiber roving.
本实施例的空心复合绝缘子用缠绕管的制备方法,工艺流程图同实施例1,包括下列步骤:The preparation method of the wound pipe for the hollow composite insulator of this embodiment, the process flow chart is the same as that of Embodiment 1, including the following steps:
1)配胶:取配方量的E51型环氧树脂、甲基四氢苯酐、环氧丙烷丁基醚、2,4,6-三(二甲氨基甲基)苯酚和BYK A530消泡剂混合均匀制成环氧树脂胶,将所述环氧树脂胶在50℃条件下保温预热8h后,置入60℃恒温的胶槽中;所述环氧树脂胶的粘度控制在0.40Pa·s;1) Glue compounding: Mix E51 type epoxy resin, methyl tetrahydrophthalic anhydride, propylene oxide butyl ether, 2,4,6-tris(dimethylaminomethyl)phenol and BYK A530 defoamer in the formula amount Prepare epoxy resin glue evenly, heat and preheat the epoxy resin glue at 50°C for 8 hours, and then put it into a glue tank with a constant temperature of 60°C; the viscosity of the epoxy resin glue is controlled at 0.40Pa·s ;
2)模具处理:取芯模,在芯模表面涂上脱模剂;2) Mold treatment: take the mandrel, and apply a release agent on the mandrel surface;
3)浸胶缠绕:选用10团无碱玻璃纤维无捻粗纱团,无碱玻璃纤维无捻粗纱使用前在70℃条件下烘干24h;3) Dipping and winding: select 10 balls of non-alkali glass fiber roving, and dry the non-alkali glass fiber roving at 70°C for 24 hours before use;
从纤维架上引出10股无碱玻璃纤维无捻粗纱穿过胶槽使纤维浸胶并形成宽度为16mm的纤维纱片,引出纤维纱片在芯模端头缠绕5圈固定;丝嘴距芯模表面的距离H设置为50mm;Lead out 10 strands of non-alkali glass fiber roving from the fiber rack to pass through the glue tank to impregnate the fiber and form a fiber yarn sheet with a width of 16mm, and wrap the fiber yarn sheet at the end of the mandrel for 5 turns to fix it; The distance H of the mold surface is set to 50mm;
开启缠绕装置,将纤维纱片持续缠绕在芯模上,保证纤维铺满模具表面,缠绕张力为1.5kN,缠绕速度为1.3m/s;以纤维纱片铺满芯模表面为一层纤维层,从内向外一层一层缠绕,内层纤维层的缠绕角度为56°,最外两层纤维层的缠绕角度为90°,封头停留角为120°;缠绕过程中注意刮胶,控制胶含量;Turn on the winding device, and continuously wind the fiber yarn on the mandrel to ensure that the fiber covers the surface of the mold, the winding tension is 1.5kN, and the winding speed is 1.3m/s; the fiber yarn is covered with the fiber yarn on the surface of the mandrel. , winding layer by layer from the inside to the outside, the winding angle of the inner fiber layer is 56°, the winding angle of the outermost two fiber layers is 90°, and the stop angle of the head is 120°; during the winding process, pay attention to scraping glue, control Glue content;
缠绕结束后在外侧缠上一层聚酯薄膜保护带,防止未固化的胶液滴落,得半成品;After winding, wrap a layer of polyester film protection tape on the outside to prevent the uncured glue from dripping and get a semi-finished product;
4)固化:将步骤3)所得半成品置于固化炉中进行分阶段固化,所述分阶段固化是指将所述半成品依次在90℃条件下保温90min、120℃条件下保温150min、160℃条件下保温30min,后冷却;4) Curing: The semi-finished product obtained in step 3) is placed in a curing furnace for stage-by-stage curing. The stage-by-stage curing means that the semi-finished product is kept at 90°C for 90 minutes, at 120°C for 150 minutes, and at 160°C. Keep warm for 30 minutes, then cool down;
冷却后用脱模机脱模,即得。After cooling, use a demoulding machine to demould, that is to say.
实施例3Example 3
本实施例的空心复合绝缘子用缠绕管,是由浸渍环氧树脂胶的玻璃纤维缠绕固化形成的,所述环氧树脂胶由以下重量份数的原料组成:环氧树脂120份、甲基四氢苯酐50份、环氧丙烷丁基醚8份、2,4,6-三(二甲氨基甲基)苯酚5份、BYK A530消泡剂0.1份;所述缠绕管的含胶量为30%(质量百分比)。所述玻璃纤维为无碱玻璃纤维无捻粗纱。The winding tube for hollow composite insulators in this embodiment is formed by winding and curing glass fibers impregnated with epoxy resin glue. The epoxy resin glue is composed of the following raw materials in parts by weight: 120 parts of epoxy resin, methyl tetra 50 parts of hydrophthalic anhydride, 8 parts of propylene oxide butyl ether, 5 parts of 2,4,6-tris(dimethylaminomethyl)phenol, 0.1 part of BYK A530 defoamer; the glue content of the winding tube is 30 % (mass percentage). The glass fiber is an alkali-free glass fiber roving.
本实施例的空心复合绝缘子用缠绕管的制备方法,工艺流程如图1所示,包括下列步骤:The manufacturing method of the wound pipe for the hollow composite insulator of this embodiment, the process flow is shown in Figure 1, including the following steps:
1)配胶:取配方量的E51型环氧树脂、甲基四氢苯酐、环氧丙烷丁基醚、2,4,6-三(二甲氨基甲基)苯酚和BYK A530消泡剂混合均匀制成环氧树脂胶,将所述环氧树脂胶在50℃条件下保温预热8h后,置入60℃恒温的胶槽中;所述环氧树脂胶的粘度控制在0.45Pa·s;1) Glue compounding: Mix E51 type epoxy resin, methyl tetrahydrophthalic anhydride, propylene oxide butyl ether, 2,4,6-tris(dimethylaminomethyl)phenol and BYK A530 defoamer in the formula amount Prepare epoxy resin glue uniformly, heat the epoxy resin glue at 50°C for 8 hours, and put it into a glue tank with constant temperature at 60°C; the viscosity of the epoxy resin glue is controlled at 0.45Pa·s ;
2)模具处理:取芯模,在芯模表面涂上脱模剂;2) Mold treatment: take the mandrel, and apply a release agent on the mandrel surface;
3)浸胶缠绕:选用9团无碱玻璃纤维无捻粗纱团,无碱玻璃纤维无捻粗纱使用前在80℃条件下烘干24h;3) Dipping and winding: select 9 balls of non-alkali glass fiber roving, and dry the non-alkali glass fiber roving at 80°C for 24 hours before use;
从纤维架上引出9股无碱玻璃纤维无捻粗纱穿过胶槽使纤维浸胶并形成宽度为14mm的纤维纱片,引出纤维纱片在芯模端头缠绕7圈固定;丝嘴距芯模表面的距离H设置为40mm;Lead out 9 strands of non-alkali glass fiber roving from the fiber frame to pass through the glue tank to impregnate the fiber and form a fiber yarn sheet with a width of 14mm, and wrap the fiber yarn sheet at the end of the mandrel for 7 turns to fix it; The distance H of the mold surface is set to 40mm;
开启缠绕装置,将纤维纱片持续缠绕在芯模上,保证纤维铺满模具表面,缠绕张力为1.1kN,缠绕速度为1.5m/s;以纤维纱片铺满芯模表面为一层纤维层,从内向外一层一层缠绕,内层纤维层的缠绕角度为52°,最外两层纤维层的缠绕角度为90°,封头停留角为120°;缠绕过程中注意刮胶,控制胶含量;Turn on the winding device, and continuously wind the fiber yarn on the mandrel to ensure that the fiber covers the surface of the mold, the winding tension is 1.1kN, and the winding speed is 1.5m/s; the fiber yarn covering the surface of the mandrel is a fiber layer , winding layer by layer from the inside to the outside, the winding angle of the inner fiber layer is 52°, the winding angle of the outermost two fiber layers is 90°, and the stop angle of the head is 120°; during the winding process, pay attention to scraping glue, control Glue content;
缠绕结束后在外侧缠上一层聚四氟乙烯薄膜保护带,防止未固化的胶液滴落,得半成品;After winding, wrap a layer of polytetrafluoroethylene film protection tape on the outside to prevent the uncured glue from dripping and get a semi-finished product;
4)固化:将步骤3)所得半成品置于固化炉中进行分阶段固化,所述分阶段固化是指将所述半成品依次在90℃条件下保温90min、120℃条件下保温150min、160℃条件下保温30min,后冷却;4) Curing: The semi-finished product obtained in step 3) is placed in a curing furnace for stage-by-stage curing. The stage-by-stage curing means that the semi-finished product is kept at 90°C for 90 minutes, at 120°C for 150 minutes, and at 160°C. Keep warm for 30 minutes, then cool down;
冷却后用脱模机脱模,即得。After cooling, use a demoulding machine to demould, that is to say.
实验例Experimental example
本实验例对实施例1-3所得空心复合绝缘子用缠绕管的性能进行检测,结果如表1所示。In this experimental example, the performance of the wound tube for hollow composite insulators obtained in Examples 1-3 was tested, and the results are shown in Table 1.
表1实施例1-3所得空心复合绝缘子用缠绕管的性能检测结果Table 1 The performance test results of the wound tube for the hollow composite insulator obtained in Examples 1-3
从表1可以看出,实施例1-3所得空心复合绝缘子用缠绕管的吸水率为0.0489%~0.0611%,弯曲强度为119~134MPa,体积电阻率为(3.9~5.1)×1013Ω·cm。实验结果表明,本发明的空心复合绝缘子用缠绕管含胶量适中,致密性和气密性好,具有良好的机械性能和绝缘性能,满足电力电网、变电站对于空心复合绝缘子用缠绕管的使用要求。It can be seen from Table 1 that the water absorption of the wound pipe for hollow composite insulators obtained in Examples 1-3 is 0.0489%-0.0611%, the bending strength is 119-134MPa, and the volume resistivity is (3.9-5.1)×10 13 Ω· cm. Experimental results show that the winding pipe for hollow composite insulators of the present invention has moderate glue content, good compactness and air tightness, good mechanical properties and insulation performance, and meets the use requirements of winding pipes for hollow composite insulators in power grids and substations.
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