CN104397010A - Tefluthrin and sulfoxaflor containing pesticide composite and application thereof - Google Patents
Tefluthrin and sulfoxaflor containing pesticide composite and application thereof Download PDFInfo
- Publication number
- CN104397010A CN104397010A CN201410699355.4A CN201410699355A CN104397010A CN 104397010 A CN104397010 A CN 104397010A CN 201410699355 A CN201410699355 A CN 201410699355A CN 104397010 A CN104397010 A CN 104397010A
- Authority
- CN
- China
- Prior art keywords
- tefluthrin
- fluorine pyridine
- worm amine
- pyridine worm
- amine nitrile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005939 Tefluthrin Substances 0.000 title claims description 39
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 title claims description 38
- 239000000575 pesticide Substances 0.000 title claims description 16
- 239000005934 Sulfoxaflor Substances 0.000 title 1
- ZVQOOHYFBIDMTQ-UHFFFAOYSA-N [methyl(oxido){1-[6-(trifluoromethyl)pyridin-3-yl]ethyl}-lambda(6)-sulfanylidene]cyanamide Chemical compound N#CN=S(C)(=O)C(C)C1=CC=C(C(F)(F)F)N=C1 ZVQOOHYFBIDMTQ-UHFFFAOYSA-N 0.000 title 1
- 239000002131 composite material Substances 0.000 title 1
- BAOWVDHYZBLYMB-UHFFFAOYSA-N [F].C1=CC=NC=C1 Chemical compound [F].C1=CC=NC=C1 BAOWVDHYZBLYMB-UHFFFAOYSA-N 0.000 claims description 38
- -1 amine nitrile Chemical class 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 25
- 241000289763 Dasygaster padockina Species 0.000 claims description 17
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 8
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 8
- 235000018262 Arachis monticola Nutrition 0.000 claims description 8
- 239000002917 insecticide Substances 0.000 claims description 8
- 235000020232 peanut Nutrition 0.000 claims description 8
- 239000008187 granular material Substances 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 3
- 239000002671 adjuvant Substances 0.000 claims description 3
- 238000009472 formulation Methods 0.000 claims description 2
- 241001553178 Arachis glabrata Species 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 13
- 239000003814 drug Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 230000001988 toxicity Effects 0.000 description 8
- 231100000419 toxicity Toxicity 0.000 description 8
- 244000105624 Arachis hypogaea Species 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 241000607479 Yersinia pestis Species 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 229920002261 Corn starch Polymers 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 239000006004 Quartz sand Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000008120 corn starch Substances 0.000 description 2
- 230000001066 destructive effect Effects 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 238000001990 intravenous administration Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 description 1
- 241001136249 Agriotes lineatus Species 0.000 description 1
- 241000218473 Agrotis Species 0.000 description 1
- 241000218475 Agrotis segetum Species 0.000 description 1
- 241000272814 Anser sp. Species 0.000 description 1
- 241001174347 Atomaria Species 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 241001063424 Euxoa tritici Species 0.000 description 1
- 239000001828 Gelatine Substances 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000254043 Melolonthinae Species 0.000 description 1
- 241000975417 Oscinella frit Species 0.000 description 1
- 241000346285 Ostrinia furnacalis Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000269799 Perca fluviatilis Species 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 210000001015 abdomen Anatomy 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a tefluthrin and sulfoxaflor containing pesticide composite and application thereof. The tefluthrin and sulfoxaflor containing pesticide composite comprises tefluthrin and sulfoxaflor serving as active ingredients, and the balance of pesticide adjuvants, wherein the mass part ratio of the tefluthrin and sulfoxaflor in the pesticide composite is 50:1-1:50; the total mass of the tefluthrin and the sulfoxaflor accounts for 0.1 to 40 weight percent in the pesticide composite. The pesticide composite disclosed by the invention is prepared into particles in actual use, and is suitable for preventing peanut cutworms.
Description
Technical field
The present invention relates to a kind of composition pesticide, is with tefluthrin and fluorine pyridine worm amine nitrile for active ingredient, for preventing and treating peanut cutworm.
Background technology
Agrotis Lepidoptera Noctuidae, what agricultural crops worked the mischief has more than 10 to plant, and wherein black cutworm, white line dart moth of turnip, large cutworm, white edge cutworm and alert line cutworm etc. are particularly important.Polyphagy insect, mainly with larva harm seedling, subaerial for seedling stem bites broken by larva, makes whole strain dead, causes the disconnected ridge that is short of seedling, have a strong impact on crop yield.
Tefluthrin belongs to pyrethroid insecticides, it is soil insecticide, the Lepidoptera that can prevent and treat coleoptera well and perch in soil and some Diptera pest, can prevent and treat the soil pests such as pumpkin 12 star first, wireworm, flea beetle, chafer, Atomaria linearis, cutworm, corn borer, Oscinella frit.Application method is flexible, and available conventional equipment spreads granula, table soil and ditch spread or seed treatment.
Fluorine pyridine worm amine nitrile is an insecticide of sulfimide, and sulfimide acts on the nervous system of insect, namely acts on binding site unique in choline receptor and plays insecticidal function.Can through leaf, stem, root absorption and entering in plant corpus.
The present inventor conducts in-depth research tefluthrin and the combination of fluorine pyridine worm amine nitrile, find that Diacloden and the combination of fluorine pyridine worm amine nitrile have synergistic effect to cutworm, granule is prepared into by existing technology, in actual use, good control efficiency is had to elimination of underground destructive pests cutworm, after further study, the present invention is completed.
Summary of the invention
Technical problem to be solved: the present invention is directed to prior art deficiency and provide a kind of containing tefluthrin and fluorine pyridine worm amine nitrile composition pesticide, said composition has synergistic effect, improves peanut cutworm control efficiency.
Technical scheme: a kind of composition pesticide containing tefluthrin and fluorine pyridine worm amine nitrile, active ingredient is tefluthrin and fluorine pyridine worm amine nitrile, tefluthrin and the ratio of quality and the number of copies of fluorine pyridine worm amine nitrile in composition pesticide are 50:1 ~ 1:50, and tefluthrin and the percentage by weight of fluorine pyridine worm amine nitrile quality summation in composition pesticide are 0.1 ~ 40%.
The formulation of composition pesticide of the present invention by selecting suitable insecticides adjuvant to be processed into granule.
Described insecticides adjuvant is: 0.5% ~ 3% dispersing aid, 0.1% ~ 2% sustained release agent, 0.1% ~ 5% binding agent, 0.5% ~ 20% carrier, and all the other are filler.Wherein, sustained release agent is the one of polyvinyl alcohol or gum Arabic, binding agent is the one of polyethylene glycol or industrial gelatine, and dispersing aid is the one of corn starch or sweet potato starch, and described filler is the mixing of one or more of calcium bicarbonate, kaolin and quartz sand.
Composition pesticide of the present invention is mainly used in the control of control elimination of underground destructive pests, especially peanut cutworm.
The present invention is tefluthrin and fluorine pyridine worm amine cyanide composition, can improve agricultural insect pests control effect, also plays positive impetus to the minimizing countryside tax system of user and the increasing both production and income of agricultural.
Specifically, granule of the present invention has following advantage:
1, tefluthrin and fluorine pyridine worm amine nitrile combine and have synergistic function, significantly improve the control efficiency to insect, expand insecticidal spectrum simultaneously, solve the defect to some insect weak effect when single dose is used alone than the single use of single dose.
2, tefluthrin and fluorine pyridine worm amine nitrile combine, and decrease Pesticide use amount, reduce use cost, alleviate pollution to environment.
3, tefluthrin is different from the fluorine pyridine worm amine nitrile mechanism of action, and the two mixture can delay the generation of pest resistance to insecticide, adds the service life of agricultural chemicals.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Embodiment one: Toxicity Determination is tested
For examination worm: indoor for many generations raise Individual Size consistent with physiological status three age cutworm larva.
Reagent agent: the former medicine of tefluthrin and the former medicine of fluorine pyridine worm amine nitrile.
Test method: adopt drop method to measure, with reference to " People's Republic of China (PRC) agricultural industry criteria NY/T1154.1-2006 ", concrete grammar is as follows.
First by micro intravenous drip device solvent clean, regulate dropper to stand-by state.Then the examination worm CO of neat and consistent is chosen with writing brush
2mild paralysis is placed in 9cm culture dish, finally with micro intravenous drip device, medicament is dripped to the belly of polypide by head, every some drops physic liquor 0.5 μ L, the process of the corresponding acetone contained with drop 0.5 μ L is contrast, the examination worm after drop is placed in temperature 28 ± 1 DEG C, relative moisture is in the intelligent insectary of 70%.Often process and repeat for 4 times, often repeat 20 examination worms.After process, 24h investigation examination worm death condition, records total borer population and dead borer population.
Carry out statistical analysis with DPS statistical analysis software, calculate the LC of each medicament
50, and co-toxicity coefficient (the CTC value of mixture is calculated according to the abundant method of Sun Yun.)
Actual measurement toxicity index (ATI)=(standard agent LC
50/ reagent agent LC
50) × 100
In theoretical toxicity index (TTI)=A medicament toxicity index × mixture A percentage composition+B medicament toxicity index × mixture in the percentage composition of B
Co-toxicity coefficient (CTC)=[the theoretical toxicity index (TTI) of mixture actual measurement toxicity index (ATI)/mixture] × 100
According to the NY/T11547.7-2006 insecticide combination effect criteria for classifying: co-toxicity coefficient (CTC) >=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80 < co-toxicity coefficient (CTC) < 120 show as summation action.
Measurement result shows, to cutworm CTC value >=120 in the scope of tefluthrin and fluorine pyridine worm amine nitrile portfolio ratio 50:1 ~ 1:50, illustrate that tefluthrin and fluorine pyridine worm amine nitrile combine and belong to synergistic effect to the synergy of cutworm, tefluthrin and fluorine pyridine worm amine nitrile combine has reasonability and feasibility.
The Toxicity Determination result of table 1, tefluthrin and fluorine pyridine worm amine nitrile combination to cutworm
| Medicament title and proportioning (weight ratio) | LC 50(mg/L) | ATI | TTI | CTC |
| Tefluthrin | 1.43 | 100.00 | - | - |
| Fluorine pyridine worm amine nitrile | 2.76 | 51.81 | - | - |
| Tefluthrin: fluorine pyridine worm amine nitrile (50:1) | 1.12 | 127.68 | 99.06 | 128.90 |
| Tefluthrin: fluorine pyridine worm amine nitrile (25:1) | 1.11 | 128.83 | 98.14 | 131.26 |
| Tefluthrin: fluorine pyridine worm amine nitrile (1:1) | 1.31 | 109.16 | 95.91 | 143.81 |
| Tefluthrin: fluorine pyridine worm amine nitrile (1:25) | 1.93 | 74.09 | 53.67 | 138.06 |
| Tefluthrin: fluorine pyridine worm amine nitrile (1:50) | 2.03 | 70.44 | 52.76 | 133.53 |
Embodiment two: prepare 6% tefluthrin fluorine pyridine worm amine chlorfenapyr particle agent
Following material is all weight percentage: tefluthrin 5%, fluorine pyridine worm amine nitrile 1%, corn starch 8%, gum Arabic 6%, quartz sand 2%, kaolin surplus.
Above-mentioned material is mixed in compounding kettle, through the granulation of high tower coating, under 40 DEG C ~ 70 DEG C conditions, is dried to particle water content is less than 3%, screening, particle size range 2000 μm ~ 4000 μm, through after the assay was approved, namely obtains required 6% tefluthrin fluorine pyridine worm amine chlorfenapyr particle agent.
Embodiment three: the test of pesticide effectiveness
Reagent agent:
(1) test medicine: 6% tefluthrin fluorine pyridine worm amine chlorfenapyr particle agent (5:1);
(2) medicament is contrasted: 5% tefluthrin granule, 1% fluorine pyridine worm amine chlorfenapyr particle agent
Controlling object: peanut cutworm
Application method: spread fertilizer over the fields before sowing
Test period: on March 21st, 2014
Test site: Wild Goose Lake village, Ren Shan town, Huidong County of Guangdong Province
Result of the test table 2 shows, 6% tefluthrin fluorine pyridine worm amine chlorfenapyr particle agent control peanut cutworm effect is better than 5% tefluthrin granule, 1% fluorine pyridine worm amine chlorfenapyr particle agent, to peanut safety.
Table 2, tefluthrin and the agent of fluorine pyridine worm amine nitrile combination particle prevent and treat peanut cutworm field control effectiveness test result.
Claims (3)
1. one kind contains the composition pesticide of tefluthrin and fluorine pyridine worm amine nitrile, it is characterized in that: active ingredient is tefluthrin and fluorine pyridine worm amine nitrile, tefluthrin and the ratio of quality and the number of copies of fluorine pyridine worm amine nitrile in composition pesticide are 50:1 ~ 1:50, and tefluthrin and the percentage by weight of fluorine pyridine worm amine nitrile quality summation in composition pesticide are 0.1 ~ 40%.
2. a kind of composition pesticide containing tefluthrin and fluorine pyridine worm amine nitrile according to claim 1, is characterized in that: by the formulation selecting suitable insecticides adjuvant to be processed into granule.
3. a kind of composition pesticide containing tefluthrin and fluorine pyridine worm amine nitrile according to claim 2, is characterized in that: for preventing and treating peanut cutworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410699355.4A CN104397010A (en) | 2014-11-26 | 2014-11-26 | Tefluthrin and sulfoxaflor containing pesticide composite and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410699355.4A CN104397010A (en) | 2014-11-26 | 2014-11-26 | Tefluthrin and sulfoxaflor containing pesticide composite and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104397010A true CN104397010A (en) | 2015-03-11 |
Family
ID=52634734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410699355.4A Pending CN104397010A (en) | 2014-11-26 | 2014-11-26 | Tefluthrin and sulfoxaflor containing pesticide composite and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104397010A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101478877A (en) * | 2006-06-23 | 2009-07-08 | 美国陶氏益农公司 | A method to control insects resistant to common insecticides |
| CN101657102A (en) * | 2007-04-12 | 2010-02-24 | 巴斯夫欧洲公司 | The pesticide combination that comprises cyanosulfoximine compounds |
| CN101909448A (en) * | 2007-11-16 | 2010-12-08 | 巴斯夫欧洲公司 | The pesticide combination that comprises cyanosulfoximine compounds |
| CN102100235A (en) * | 2011-03-23 | 2011-06-22 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor and pyrethroid |
| CN102202511A (en) * | 2008-10-08 | 2011-09-28 | 先正达参股股份有限公司 | Pesticidal combinations containing sulfoxaflor |
-
2014
- 2014-11-26 CN CN201410699355.4A patent/CN104397010A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101478877A (en) * | 2006-06-23 | 2009-07-08 | 美国陶氏益农公司 | A method to control insects resistant to common insecticides |
| CN101657102A (en) * | 2007-04-12 | 2010-02-24 | 巴斯夫欧洲公司 | The pesticide combination that comprises cyanosulfoximine compounds |
| CN101909448A (en) * | 2007-11-16 | 2010-12-08 | 巴斯夫欧洲公司 | The pesticide combination that comprises cyanosulfoximine compounds |
| CN102202511A (en) * | 2008-10-08 | 2011-09-28 | 先正达参股股份有限公司 | Pesticidal combinations containing sulfoxaflor |
| CN102100235A (en) * | 2011-03-23 | 2011-06-22 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing sulfoxaflor and pyrethroid |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101669478A (en) | Pesticide combination | |
| CN106376570A (en) | Fludioxonil-containing seed coating agent composition and application thereof | |
| CN111134146A (en) | Synergistic granule and preparation method and application thereof | |
| CN104304269A (en) | Herbicidal composition for paddy field | |
| CN108402071B (en) | Multifunctional suspension seed coating agent special for millet in spring valley area | |
| CN100551241C (en) | A method for improving the effect of pesticides on controlling lepidopteran pests | |
| CN102007909A (en) | Spinosad-containing pesticidal composition | |
| CN114732023B (en) | Insecticidal composition containing Oxazosulfyl and chlorantraniliprole and application thereof | |
| CN101755817B (en) | Insecticidal composition for controlling underground pest | |
| CN104381261A (en) | Insecticide composition containing chlorine chlorfenapyr and pyridalyl | |
| CN103636610A (en) | Methoxyfenozide-cyantraniliprole-containing insecticidal composition | |
| CN104705318B (en) | A kind of Pesticidal combination containing rosin acid sodium and spiral shell worm ethyl ester | |
| CN102860316A (en) | Insecticidal composite containing spinetoram | |
| CN104397010A (en) | Tefluthrin and sulfoxaflor containing pesticide composite and application thereof | |
| CN104430436B (en) | Diafenthiuron and pyridalyl Pesticidal combination | |
| CN114698643B (en) | An agricultural composition containing clothianidin | |
| CN118340170B (en) | Granule containing high-efficiency cyfluthrin and clothianidin and application thereof | |
| CN105994341B (en) | Anthranilamide compound and nicotine compound compounded pesticides | |
| CN104094957A (en) | Deinsectization composition containing chlorine chlorfenapyr and indoxacarb | |
| CN109744252B (en) | Synergistic composition for preventing and treating citrus mites | |
| CN115568472B (en) | Insecticidal composition containing benzpyrimoxan and dicyclanil ester and application thereof | |
| CN102027926A (en) | Pesticidal composition of ethiprole and spinosad | |
| CN114532343B (en) | Insecticidal composition containing oxazine and thiamethoxam | |
| CN108157371B (en) | Pesticide composition for seed coating agent | |
| CN104522013B (en) | A kind of Pesticidal combination containing diafenthiuron and Ivermectin HCL |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150311 |