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CN104327524B - A kind of warm mix type water resistant damages bituminous paving reinforcing agent and preparation method thereof - Google Patents

A kind of warm mix type water resistant damages bituminous paving reinforcing agent and preparation method thereof Download PDF

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Publication number
CN104327524B
CN104327524B CN201410688004.3A CN201410688004A CN104327524B CN 104327524 B CN104327524 B CN 104327524B CN 201410688004 A CN201410688004 A CN 201410688004A CN 104327524 B CN104327524 B CN 104327524B
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agent
bituminous paving
reinforcing agent
water resistant
type water
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CN104327524A (en
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牛晓伟
刘伟
吴春颖
王文峰
王仁辉
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Nanjing jiaokerui Road Technology Co.,Ltd.
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Jiangsu Transportation Research Institute Co Ltd
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Abstract

The present invention discloses a kind of warm mix type water resistant and damages bituminous paving reinforcing agent, includes each component in terms of weight/mass percentage composition, low molecular weight polyethylene 30%~60%;PEO 30%~60%;Interfacial compatibilization agent 0%~10%;Inorganic strengthening agent 0%~3%.Using Interfacial compatibilization agent reduce bituminous paving reinforcing agent and pitch and interface between gathering materials can so that bituminous cements and the ability that wraps between gathering materials are greatly improved, and therefore improve the anti-water damage property of asphalt;When temperature is down under bituminous paving reinforcing agent fusing point, plastic component crystallization in bituminous paving reinforcing agent is separated out, due to the nucleating effect of inorganic strengthening agent, crystallize the plastic component separated out radiation growth centered on inorganic strengthening agent, and because of the compatibilization of Interfacial compatibilization agent with pitch and gathering materials and to form the network structure of bonds well, so as to greatly improve the high-temperature stability and high temperature anti-rut behavior of asphalt.

Description

A kind of warm mix type water resistant damages bituminous paving reinforcing agent and preparation method thereof
Technical field
Bituminous paving reinforcing agent is damaged the present invention relates to a kind of bituminous paving additive, more particularly to a kind of warm mix type water resistant And its specific preparation method.
Background technology
Generally, the design service life of newly-built road is 10~15 years, but with canalized traffic and heavy duty, overload problems Continuous exacerbation, the actual life of bituminous paving greatly reduces, especially on the special road such as Heavy Traffic, Large Longitudinal Slope Section, bituminous paving is on active service and begins within 3~5 years rut occur, gathers around many diseases such as bag, pit, crack, Moisture Damage, is had a strong impact on The traffic safety of people.
At present, mainstream technology when hot-mix asphalt mixture is still traffic construction, due to mixing for hot-mix asphalt mixture Close and compacting temperature is typically up to 150 DEG C~190 DEG C, easily make ageing of asphalt, influence the pavement performance of asphalt;Simultaneously Construction at high temperature necessarily brings substantial amounts of energy resource consumption, is unfavorable for the sustainable development of energy-saving and emission-reduction, environmental protection;And pitch is mixed Material can discharge a large amount of CO, CO during construction at high temperature2、SO2And NOxDeng pernicious gas, environmental pollution is not only caused, also to applying The healthy of workman person brings high risks.
In general, can be by adding all kinds of modifying agent or additive in pitch or asphalt, such as:SBS, rubber Rubber powder, anti-rut agent, warm-mixing agent, antistripping agent etc., to improve the height temperature stability, construction workability, water resistant of bituminous paving Damage performance etc..But, the performance of current all kinds of bituminous paving additives is all more single, and a kind of usual additive is only capable of being directed to One or two kinds of pavement diseases are effectively punished, and while a kind of disease is solved, often other pavement performances are caused Adverse effect, for example:HMW PE class anti-rut agents, are improving bituminous paving high-temperature stability simultaneously, can reduce road surface low Warm nature energy and anti-water damage property;Although SBS modified pitch can improve the high temperature performance of bituminous paving simultaneously, necessary The mix and compaction moulding temperature of compound are improved, being significantly increased for energy consumption is caused.Add in addition, performance is stable in the market It is expensive plus agent product is generally imported product, it is unfavorable for promoting the use of on a large scale.
For problem above, researcher is continuously attempted to the function of additive from single type to multifunctional and composite type side To transformation, for example, Niu Yanhui etc. have developed one kind imitates high-performance modified dose entirely, the high temperatures of asphalt can be improved simultaneously Energy, cryogenic property and anti-water damage property;Hong Jinxiang etc. develops a kind of high-modulus asphalt modifying agent with warm mix effect, While improving Rut resistance, the anti-shear performance of bituminous paving, the viscosity of pitch can also be greatly reduced, so that pitch be mixed The compaction temperature of material reduces by 20~30 DEG C.
But, the research of current multifunctional and composite type bituminous paving additive also in the starting stage, each product it is specific Using effect is still among practice, especially with warm mix effect and composite type pitch road surface additive with low cost also very Rareness, the defect existed in view of above-mentioned existing composite type pitch road surface additive, the present inventor is based on being engaged in such product Practical experience and professional knowledge that design studies are enriched for many years, and coordinate the utilization of scientific principle, actively it is subject to research and innovation, it is intended to carry Go out a kind of new warm mix type water resistant and damage asphalt road surface reinforcing material, for energy-saving and emission-reduction, prolonging service life of pavement, support personnel Life security, there is important practical significance.
The content of the invention
It is a primary object of the present invention to overcome existing warm mix type water resistant to damage bituminous paving reinforcing agent and preparation method thereof The defect of presence, and a kind of new warm mix type water resistant is provided and damages bituminous paving reinforcing agent and preparation method thereof, improving, high temperature is steady While qualitative, the mix and compacting temperature of asphalt are reduced, thus more suitable for practicality, and with the utilization in industry Value.
The object of the invention to solve the technical problems is realized using following technical scheme, according to present invention proposition A kind of warm mix type water resistant damage bituminous paving reinforcing agent, comprising following each component, wherein each component in terms of weight/mass percentage composition,
Further, foregoing warm mix type water resistant damages bituminous paving reinforcing agent, and the weight of the low molecular weight polyethylene is equal Molecular weight is 1000~5000, and fusing point is 80 DEG C~120 DEG C;The selection polyethylene that molecular weight is small, fusing point is relatively low, is conducive to product Warm mix effect is realized, but if molecular weight is too small, adverse effect can be brought to the high-temperature stability of product.
Further, foregoing warm mix type water resistant damages bituminous paving reinforcing agent, and the fusing point of the PEO is 110 DEG C~140 DEG C.
Further, foregoing warm mix type water resistant damages bituminous paving reinforcing agent, and the Interfacial compatibilization agent is ethyl vinyl acetate One kind in vinyl acetate, hard grades of bitumen particle, maleic anhydride grafting low density polyethylene (LDPE), maleic anhydride grafted high density polyethylene Or two kinds and two or more mixtures.
Further, foregoing warm mix type water resistant damages bituminous paving reinforcing agent, and the inorganic strengthening agent is nano-calcium carbonate One or two kinds of and two or more mixtures in calcium, inorganic clay, nano silicon, wherein the inorganic strengthening agent Particle size range control is optimal selection within 1 μm, if granularity is excessive, fluidity of molten can be caused to be deteriorated, and influence is final Performance.
A kind of warm mix type water resistant damages the preparation method of bituminous paving reinforcing agent, and this method comprises the following steps,
Step 1):Low molecular weight polyethylene, PEO, Interfacial compatibilization agent and reinforcing agent are weighed in proportion, and in room Temperature is lower well mixed, obtains compound;
Step 2):Compound is put into extruder, is blended;
Step 3):Room temperature is cooled to after the extruded machine extrusion of mixture, grinds, obtains target product.
Further, foregoing warm mix type water resistant damages the preparation method of bituminous paving reinforcing agent, the step 2) be total to Mixed temperature is 130~160 DEG C.
Further, foregoing warm mix type water resistant damages the preparation method of bituminous paving reinforcing agent, and the extruder is double Screw extruder, screw speed is 80~110rpm.
By above-mentioned technical proposal, warm mix type water resistant of the present invention, which damages bituminous paving reinforcing agent and preparation method thereof, at least to be had Following advantages:
Each formula materials are carried out thermal response fusion by the present invention by reactive extrursion blending, utilize the polycyclic oxygen second of low melting point Alkane and low molecular weight polyethylene reduce the fusing point of final bituminous paving reinforcing agent, and then reduce the viscosity of pitch, so that pitch Compound can be issued in relatively low mix, compacting temperature and mix identical compactness under the conditions of heat is spread with heat, can be mixed hotter Asphalt is low 20 DEG C~30 DEG C of middle warm mix combined pressure reality condition shaping Warm-Mix Bitumen Mixture;Meanwhile, utilize Interfacial compatibilization Agent reduce bituminous paving reinforcing agent and pitch and interface between gathering materials can so that bituminous cements and wrapping up between gathering materials The ability of covering is greatly improved, and therefore improves the anti-water damage property of asphalt;The raising of cementitious matter and an adhesion that gathers materials The compacting of asphalt is also beneficial to, so that the middle warm compaction to compound plays certain synergy;When temperature is down to When under bituminous paving reinforcing agent fusing point, the plastic component crystallization in bituminous paving reinforcing agent is separated out, due to inorganic strengthening agent Nucleating effect, crystallizes the plastic component separated out radiation growth centered on inorganic strengthening agent, and because the increase-volume of Interfacial compatibilization agent is made With and with pitch and gather materials and to form the network structure of bonds well, so as to greatly improve the high-temperature stability and height of asphalt Warm anti-rut behavior.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, described in detail below with presently preferred embodiments of the present invention as after.
Embodiment
Further to illustrate the present invention to reach the technological means and effect that predetermined goal of the invention is taken, to according to this The warm mix type water resistant that invention is proposed damages bituminous paving reinforcing agent and preparation method thereof and its embodiment, feature and its work( Effect, is described in detail as after, wherein each material used is commercially available material.
Embodiment 1
The warm mix type water resistant of the present invention damages bituminous paving reinforcing agent, is made up of each component of following mass parts:
Wherein, the weight average molecular weight of low molecular weight polyethylene is 2500, and fusing point is 99 DEG C, and the fusing point of PEO is 131 DEG C, Interfacial compatibilization agent is ethylene-vinyl acetate, and the wherein content of vinyl acetate is 18%, and inorganic strengthening agent is nano-sized carbon Sour calcium.
Preparation process is as follows:
Above raw material are mixed in proportion at room temperature, double screw extruder are put into, control blending temperature is 130 DEG C, screw speed 85rpm, the extruded machine of mixture is cooled to room temperature after extruding, and grinds, that is, obtains the warm mix type of the present invention Water resistant damages bituminous paving reinforcing agent.
Embodiment 2
The warm mix type water resistant of the present invention damages bituminous paving reinforcing agent, is made up of each component of following mass parts:
Wherein, the weight average molecular weight of low molecular weight polyethylene is 3000, and fusing point is 85.6~106.5 DEG C, PEO Fusing point be 113 DEG C, Interfacial compatibilization agent is the mixture of hard grades of bitumen particle and ethylene-vinyl acetate, wherein hard grades of bitumen The mass ratio of particle and ethylene-vinyl acetate is 3:2, inorganic strengthening agent is nano-calcium carbonate and inorganic clay according to mass ratio 1:1 mixture.
Preparation process is as follows:
Above raw material are mixed in proportion at normal temperatures, double screw extruder are put into, control blending temperature is 155 DEG C, screw speed 90rpm, the extruded machine of mixture is cooled to room temperature after extruding, and grinds, that is, obtains the warm mix type of the present invention Water resistant damages bituminous paving reinforcing agent.
Embodiment 3
The warm mix type water resistant of the present invention damages bituminous paving reinforcing agent, is made up of each component of following mass parts:
Wherein the weight average molecular weight of low molecular weight polyethylene is 2500, and fusing point is 100 DEG C, and the fusing point of PEO is 131 DEG C, Interfacial compatibilization agent is hard grades of bitumen particle, and inorganic strengthening agent is nano-calcium carbonate.
Preparation process is as follows:
Above raw material are mixed in proportion at room temperature, double screw extruder is put into, it is 145 to control blending temperature DEG C, screw speed 100rpm, the extruded machine of mixture is cooled to room temperature after extruding, and grinds, that is, obtains the warm mix of the present invention Type water resistant damages bituminous paving reinforcing agent.
Verify example 1
The warm mix type water resistant that Example 1,2,3 is prepared respectively damages bituminous paving reinforcing agent, is added into by 7% volume Double imperial 70# matrix pitches, stir under the conditions of 145 DEG C, separately sampled, and asphalt material of the test added with reinforcing agent is distinguished Viscosity at 60 DEG C, 135 DEG C, 155 DEG C, 175 DEG C, result of the test is listed in table 1.
Table 1
Bituminous paving reinforcing agent Embodiment 1 Embodiment 2 Embodiment 3 70# matrix pitches
60 DEG C of viscosity (Pas) > 25000 > 25000 > 25000 226
135 DEG C of viscosity (Pas) 0.34 0.38 0.33 0.42
155 DEG C of viscosity (Pas) 0.16 0.18 0.15 0.17
175 DEG C of viscosity (Pas) 0.08 0.09 0.07 0.08
Experiment proves that the warm mix type water resistant prepared using the present invention damages bituminous paving reinforcing agent, can effectively improve drip 60 DEG C of blue or green viscosity, meanwhile, it can effectively reduce by 135 DEG C of viscosity of pitch, it is seen that the warm mix type water resistant prepared using the present invention Bituminous paving reinforcing agent is damaged, is conducive to improving the high temperature anti-rut behavior of asphalt, is mixed while also advantageously reducing pitch The mix and compacting temperature of material are closed, construction workability is improved, middle warm mix combined pressure reality, the effect of energy-saving and emission-reduction is reached.
Verify example 2
The warm mix type water resistant that Example 1,2,3 is prepared respectively damages bituminous paving reinforcing agent, using double imperial 70# matrix Pitch, limestone building stones are matched somebody with somebody according to Sup-20 grades, and bituminous paving reinforcing agent volume accounts for the 0.4% of asphalt, at 115 DEG C Under the conditions of compaction moulding asphalt, embodiment A, embodiment B, embodiment C are designated as respectively, test its high and low temperature performance and Anti-water damage property, and with not filling the 70# matrix pitch compounds (145 DEG C of compacting temperature) and SBS of bituminous paving reinforcing agent Modified asphalt mixture (165 DEG C of compacting temperature) is contrasted, and result of the test is listed in table 2.
Table 2
Proved by application test, bituminous paving reinforcing agent is damaged using the warm mix type water resistant for preparing of the present invention, can be Warm-Mix Bitumen Mixture is molded under 30 DEG C low compared with hot-mix asphalt mixture of middle warm mix combined pressure reality condition, and the high temperature of compound resists Rut performance is improved largely compared with hot-mix asphalt mixture, and anti-water damage property also has lifting, meanwhile, cryogenic property is also met Highway in China Asphalt Pavement Construction Technique specification (JTG F40-2004) requirement, will not cause unfavorable shadow to compound cryogenic property Ring.
The above, is only presently preferred embodiments of the present invention, not makees any formal limitation to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention Any simple modification for being made to above example, equivalent variations and modification, in the range of still falling within technical solution of the present invention.

Claims (8)

1. warm mix type water resistant damages bituminous paving reinforcing agent, it is characterised in that:Comprising following each component, wherein each component is with quality hundred Divide content meter,
Low molecular weight polyethylene 30%~60%;
PEO 30%~60%;
Interfacial compatibilization agent 0%~10%;
Inorganic strengthening agent 0%~3%;
The Interfacial compatibilization agent is ethylene-vinyl acetate, hard grades of bitumen particle, maleic anhydride grafting low density polyethylene (LDPE), horse One or more kinds of mixtures in maleic anhydride grafted high density polyethylene (HDPE).
2. the warm mix type water resistant according to claim 1 damages bituminous paving reinforcing agent, it is characterised in that:The low molecule The weight average molecular weight of weight northylen is 1000 ~ 5000, and fusing point is 80 DEG C ~ 120 DEG C.
3. the warm mix type water resistant according to claim 1 damages bituminous paving reinforcing agent, it is characterised in that:The polycyclic oxygen The fusing point of ethane is 110 DEG C ~ 140 DEG C.
4. the warm mix type water resistant according to claim 1 damages bituminous paving reinforcing agent, it is characterised in that:The inorganic increasing Strong agent is one or more kinds of mixtures in nano-calcium carbonate, inorganic clay, nano silicon.
5. the warm mix type water resistant according to claim 4 damages bituminous paving reinforcing agent, it is characterised in that:The inorganic enhancing 1 μm of the granularity < of agent.
6. warm mix type water resistant according to claim 1 damages the preparation method of bituminous paving reinforcing agent, it is characterised in that:The party Method comprises the following steps,
Step 1):Low molecular weight polyethylene, PEO, Interfacial compatibilization agent and reinforcing agent are weighed in proportion, and at room temperature It is well mixed, obtain compound;
Step 2):Compound is put into extruder, is blended;
Step 3):Room temperature is cooled to after the extruded machine extrusion of mixture, grinds, obtains target product.
7. the warm mix type water resistant according to claim 6 damages the preparation method of bituminous paving reinforcing agent, it is characterised in that: The step 2)Blending temperature be 130 ~ 160 DEG C.
8. the warm mix type water resistant according to claim 6 damages the preparation method of bituminous paving reinforcing agent, it is characterised in that: The extruder is double screw extruder, and screw speed is 80 ~ 110rpm.
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