CN104252081A - Liquid crystal micro-lens array and manufacturing method thereof - Google Patents
Liquid crystal micro-lens array and manufacturing method thereof Download PDFInfo
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Abstract
本发明涉及一种液晶微透镜阵列及其制备方法,所述液晶微透镜阵列包括:一第二透明基板;一透明介质层,设置于所述第二透明基板上方,且所述透明介质层上表面对应于每一个微透镜区域均具有一凹部;一第二透明导电薄膜,设置于所述透明介质层上方;一第二配向层,设置于所述第二透明导电薄膜上方;一液晶层,设置于所述第二配向层上方;一第一配向层,设置于所述液晶层上方;一第一透明导电薄膜,设置于所述第一配向层上方;一第一透明基板,设置于所述第一透明导电薄膜上方。本发明有效解决了多电极驱动液晶微透镜,工艺复杂,且由于场分布很难控制均匀的缺点。
The present invention relates to a liquid crystal microlens array and a preparation method thereof. The liquid crystal microlens array comprises: a second transparent substrate; a transparent medium layer arranged above the second transparent substrate, and on the transparent medium layer The surface has a concave portion corresponding to each microlens area; a second transparent conductive film, arranged above the transparent medium layer; a second alignment layer, arranged above the second transparent conductive film; a liquid crystal layer, disposed above the second alignment layer; a first alignment layer disposed above the liquid crystal layer; a first transparent conductive film disposed above the first alignment layer; a first transparent substrate disposed on the above the first transparent conductive film. The invention effectively solves the disadvantages of multi-electrode driven liquid crystal micro-lens, complex process, and difficulty in uniform field distribution control.
Description
技术领域 technical field
本发明涉及裸眼立体显示技术领域,尤其涉及一种液晶微透镜阵列及其制备方法。 The invention relates to the technical field of naked-eye stereoscopic display, in particular to a liquid crystal microlens array and a preparation method thereof. the
背景技术 Background technique
裸眼3D (Three Dimensional) 显示器不需要观看者佩戴眼镜或者头盔等助视设备就能观看到3D影像,已成为显示领域的新发展趋势。在实际应用中,观看者往往希望根据所提供显示图像的要求自由地在3D显示模式和2D显示模式之间切换,这样的显示装置称为2D-3D可切换显示装置。现有2D-3D可切换显示装置一般采用液晶微透镜,目前可实现的液晶微透镜主要分为两类:一类为主动式液晶微透镜,即液晶被限制在具有一定曲率半径的微透镜状聚合物中,并有双电极驱动;另一类为多电极驱动的方式,即在液晶层的一侧排布多个互相独立的电极,在电极上施加不连续的电压分布,由于液晶分子的偏转角度与施加在其上的电场强度成正相关关系,则在施加较高电压电极的上方区域内液晶分子偏转角度大于施加较低电压电极上方区域内液晶分子的偏转角度,调节各电压大小使得液晶层成为一个微透镜,应用此种方式制作的液晶微透镜优点是偏转角度可由电压控制,即液晶层折射率分布是可控的,从而形成的微透镜焦距也是可控的;而此种方法在制作微透镜阵列时的缺点就是需要引入精细电极制备,制作驱动电路流程较为复杂,且由于电场分布很难控制均匀,影响显示效果;制作微透镜阵列时,当微透镜阵列面积增大,微透镜个数增多时,无法实现每个微透镜的电极都很好的引出来。 Glasses-free 3D (Three Dimensional) displays do not require viewers to wear glasses or helmets to watch 3D images, which has become a new development trend in the display field. In practical applications, viewers often want to freely switch between a 3D display mode and a 2D display mode according to the requirements of the provided display images, such a display device is called a 2D-3D switchable display device. Existing 2D-3D switchable display devices generally use liquid crystal microlenses. At present, the liquid crystal microlenses that can be realized are mainly divided into two categories: one is active liquid crystal microlenses, that is, the liquid crystal is limited to a microlens with a certain radius of curvature. In the polymer, there is a double-electrode drive; the other is a multi-electrode drive method, that is, a plurality of mutually independent electrodes are arranged on one side of the liquid crystal layer, and a discontinuous voltage distribution is applied to the electrodes. Due to the liquid crystal molecules The deflection angle is positively correlated with the electric field strength applied to it, and the deflection angle of the liquid crystal molecules in the area above the electrode with a higher voltage is greater than the deflection angle of the liquid crystal molecules in the area above the electrode with a lower voltage. Adjust the voltage to make the liquid crystal layer becomes a microlens, the advantage of the liquid crystal microlens made in this way is that the deflection angle can be controlled by voltage, that is, the refractive index distribution of the liquid crystal layer is controllable, and the focal length of the formed microlens is also controllable; and this method is in The disadvantage of making a microlens array is that it needs to introduce fine electrode preparation, and the process of making the driving circuit is relatively complicated, and it is difficult to control the uniform distribution of the electric field, which affects the display effect; when making a microlens array, when the area of the microlens array increases, the microlens When the number increases, the electrodes of each microlens cannot be drawn out well. the
针对多电极驱动的方式存在的上述不足,本发明采用液晶微透镜电极间距控制电场分布,形成液晶微透镜,提出一种液晶微透镜阵列及其制备方法。 Aiming at the above-mentioned shortcomings of the multi-electrode driving method, the present invention uses liquid crystal micro-lens electrode spacing to control electric field distribution to form liquid crystal micro-lenses, and proposes a liquid crystal micro-lens array and a preparation method thereof. the
发明内容 Contents of the invention
有鉴于此,本发明的目的是针对传统多电极液晶微透镜阵列制作工艺难度大的缺点,提供一种液晶微透镜阵列及其制备方法。 In view of this, the object of the present invention is to provide a liquid crystal microlens array and a preparation method thereof, aiming at the disadvantage that the traditional multi-electrode liquid crystal microlens array is difficult to manufacture. the
本发明采用以下方案实现:一种液晶微透镜阵列,其特征在于,包括: The present invention adopts the following scheme to realize: a kind of liquid crystal microlens array, it is characterized in that, comprises:
一第二透明基板; a second transparent substrate;
一透明介质层,设置于所述第二透明基板上方,且所述透明介质层上表面对应于每一个微透镜区域均具有一凹部,所述凹部为通过各向异性蚀刻硅表面或各向同性蚀刻玻璃表面,辅以后续软印刷进行图形转移形成,或通过3D打印技术直接形成; A transparent medium layer is arranged above the second transparent substrate, and the upper surface of the transparent medium layer has a concave portion corresponding to each microlens area, and the concave portion is etched by anisotropic silicon surface or isotropic Etching the glass surface, supplemented by subsequent soft printing for graphic transfer, or directly formed by 3D printing technology;
一第二透明导电薄膜,设置于所述透明介质层上方,且具有与所述透明介质层上表面相同的凹部; A second transparent conductive film, disposed above the transparent medium layer, and having the same concave portion as the upper surface of the transparent medium layer;
一第二配向层,设置于所述第二透明导电薄膜上方,且所述第二配向层上表面与所述第二透明基板平行; A second alignment layer, disposed above the second transparent conductive film, and the upper surface of the second alignment layer is parallel to the second transparent substrate;
一液晶层,设置于所述第二配向层上方; a liquid crystal layer disposed above the second alignment layer;
一第一配向层,设置于所述液晶层上方; a first alignment layer disposed above the liquid crystal layer;
一第一透明导电薄膜,设置于所述第一配向层上方; A first transparent conductive film disposed above the first alignment layer;
一第一透明基板,设置于所述第一透明导电薄膜上方。 A first transparent substrate is arranged above the first transparent conductive film.
在本发明一实施例中,所述第一透明基板和第二透明基板是透明玻璃、透明无机材料或透明有机聚合物材料。 In an embodiment of the present invention, the first transparent substrate and the second transparent substrate are transparent glass, transparent inorganic material or transparent organic polymer material. the
在本发明一实施例中,所述液晶微微透镜的形状为圆形或正多边形。 In an embodiment of the present invention, the shape of the liquid crystal microlens is a circle or a regular polygon. the
在本发明一实施例中,所述第一透明导电薄膜和第二透明导电薄膜为采用真空镀膜或喷涂技术形成的氧化铟锡薄膜、金属掺杂氧化锌薄膜、金属-石墨烯或金属-碳纳米管复合薄膜。 In an embodiment of the present invention, the first transparent conductive film and the second transparent conductive film are indium tin oxide films, metal-doped zinc oxide films, metal-graphene or metal-carbon films formed by vacuum coating or spraying techniques. Nanotube composite films. the
在本发明一实施例中,所述第一配向层和第二配向层经受摩擦处理,且摩擦方向一致。 In an embodiment of the present invention, the first alignment layer and the second alignment layer are subjected to rubbing treatment, and the rubbing directions are consistent. the
本发明还提供一种所述的液晶微透镜阵列的制备方法,其特征在于,包括以下步骤: The present invention also provides a kind of preparation method of described liquid crystal microlens array, it is characterized in that, comprises the following steps:
S11:提供一洁净的Si基板并采用光刻在其表面制作小孔光栅; S11: providing a clean Si substrate and making a small hole grating on its surface by photolithography;
S12:以所述小孔光栅为掩膜,采用氢氧化钾溶液,在所述Si基板表面各向异性刻蚀孔型凹槽; S12: using the pinhole grating as a mask, using a potassium hydroxide solution to anisotropically etch hole-shaped grooves on the surface of the Si substrate;
S13:采用硅橡胶制备所述孔型凹槽的硅橡胶负模板; S13: Using silicone rubber to prepare a silicone rubber negative template for the hole-shaped groove;
S14:提供一洁净的第二透明基板,在其表面均匀涂覆一层透明介质层,并将所述硅橡胶负模板平整放置于所述透明介质层上,施加一预定压力,采用加热或紫外光照射的方法使所述透明介质层固化; S14: Provide a clean second transparent substrate, uniformly coat a layer of transparent medium layer on its surface, place the silicone rubber negative template flatly on the transparent medium layer, apply a predetermined pressure, use heating or ultraviolet curing the transparent medium layer by light irradiation;
S15:将所述硅橡胶负模板与所述透明介质层分离; S15: separating the silicone rubber negative template from the transparent medium layer;
S16:在所述透明介质层表面制备第二透明导电薄膜。 S16: Prepare a second transparent conductive film on the surface of the transparent medium layer.
本发明还提供另一种所述的液晶微透镜阵列的制备方法,其特征在于,包括以下步骤: The present invention also provides another preparation method of the liquid crystal microlens array, which is characterized in that it comprises the following steps:
S21:提供一洁净的玻璃基板并采用光刻在其表面制作小孔光栅; S21: Provide a clean glass substrate and make a small hole grating on its surface by photolithography;
S22:以所述小孔光栅为掩膜,采用氢氟酸和氟化铵混合溶液,在所述玻璃基板表面各向同性刻蚀孔型凹槽; S22: using the pinhole grating as a mask, using a mixed solution of hydrofluoric acid and ammonium fluoride to isotropically etch hole-shaped grooves on the surface of the glass substrate;
S23:采用硅橡胶制备所述孔型凹槽的硅橡胶负模板; S23: Using silicone rubber to prepare a silicone rubber negative template for the hole-shaped groove;
S24:提供一洁净的第二透明基板,在其表面均匀涂覆一层透明介质层,并将所述硅橡胶负模板平整放置于所述透明介质层上,施加一定压力,采用加热或紫外光照射的方法使所述透明介质层固化; S24: Provide a clean second transparent substrate, uniformly coat a transparent medium layer on its surface, place the silicone rubber negative template flatly on the transparent medium layer, apply a certain pressure, and use heating or ultraviolet light curing the transparent medium layer by means of irradiation;
S25:将所述硅橡胶负模板与所述透明介质层分离; S25: separating the silicone rubber negative template from the transparent medium layer;
S26:在所述透明介质层表面制备第二透明导电薄膜。 S26: Prepare a second transparent conductive film on the surface of the transparent medium layer.
本发明还提供再一种所述的液晶微透镜阵列的制备方法,其特征在于,包括以下步骤: The present invention also provides another preparation method of the liquid crystal microlens array, which is characterized in that it comprises the following steps:
S31:提供一洁净的第二透明基板; S31: providing a clean second transparent substrate;
S32:采用3D打印技术在所述第二透明基板表面打印孔型凹槽,得到具有所述凹部的透明介质层表面; S32: Using 3D printing technology to print hole-shaped grooves on the surface of the second transparent substrate to obtain the surface of the transparent medium layer having the concave portion;
S33:在所述透明介质层表面制备第二透明导电薄膜。 S33: Prepare a second transparent conductive film on the surface of the transparent medium layer.
本发明的显著优点在于:通过液晶层两边的电极来控制液晶分子不同程度的偏转,达到液晶微透镜的效果,无需引出较多的电极,制作工艺简单且驱动电路较简单;并且,可实现大面积液晶微透镜阵列的制备。 The remarkable advantage of the present invention is that: the electrodes on both sides of the liquid crystal layer are used to control the deflection of the liquid crystal molecules in different degrees to achieve the effect of the liquid crystal microlens without drawing out more electrodes, the manufacturing process is simple and the driving circuit is relatively simple; moreover, a large Fabrication of Area Liquid Crystal Microlens Arrays. the
为使本发明的目的、技术方案及优点更加清楚明白,以下将通过具体实施例和相关附图,对本发明作进一步详细说明。 In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below through specific embodiments and related drawings. the
附图说明 Description of drawings
图1为本发明透明介质层表面有规律的凹凸形状为通过各向异性蚀刻硅表面辅以后续软印刷进行图形转移时,液晶微透镜阵列一个单元不加电场的结构示意图。 Figure 1 is a schematic diagram of the structure of a unit of a liquid crystal microlens array without an electric field when the regular concave-convex shape on the surface of the transparent medium layer of the present invention is transferred through anisotropic etching of the silicon surface and supplemented by subsequent soft printing. the
图2为本发明透明介质层表面有规律的凹凸形状为通过各向异性蚀刻硅表面辅以后续软印刷进行图形转移时,液晶微透镜阵列一个单元施加电场的结构示意图。 Fig. 2 is a schematic diagram of the structure of a liquid crystal microlens array unit applying an electric field when the regular concave-convex shape on the surface of the transparent medium layer of the present invention is transferred by anisotropically etching the silicon surface and supplemented by subsequent soft printing. the
图3为本发明透明介质层表面有规律的凹凸形状为通过各向同性蚀刻玻璃表面辅以后续软印刷进行图形转移时,液晶微透镜阵列一个单元施加电场的结构示意图。 Fig. 3 is a structural schematic diagram of an electric field applied to a unit of a liquid crystal microlens array when the regular concave-convex shape on the surface of the transparent medium layer of the present invention is transferred through isotropic etching of the glass surface and supplemented by subsequent soft printing. the
图4为本发明透明介质层表面有规律的凹凸形状为通过3D打印技术形成时,液晶微透镜阵列一个单元施加电场的结构示意图。 Fig. 4 is a structural schematic diagram of an electric field applied to a unit of a liquid crystal microlens array when the regular concave-convex shape on the surface of the transparent medium layer of the present invention is formed by 3D printing technology. the
图5为本发明实施例一中,Si面各向异性刻蚀示意图。 FIG. 5 is a schematic diagram of anisotropic etching on the Si surface in Embodiment 1 of the present invention. the
具体实施方式 Detailed ways
如图1所示,本发明提供一种液晶微透镜阵列,包括: As shown in Figure 1, the present invention provides a kind of liquid crystal microlens array, comprising:
一第二透明基板102; A second transparent substrate 102;
一透明介质层104,设置于所述第二透明基板102上方,且所述透明介质层104上表面对应于每一个微透镜区域均具有一凹部(即所述透明介质层上表面有规律地呈现凹凸形状),所述凹部为通过各向异性蚀刻硅表面或各向同性蚀刻玻璃表面,辅以后续软印刷进行图形转移形成,或通过3D打印技术直接形成; A transparent medium layer 104 is arranged above the second transparent substrate 102, and the upper surface of the transparent medium layer 104 has a concave portion corresponding to each microlens area (that is, the upper surface of the transparent medium layer regularly presents concave-convex shape), the concave part is formed by anisotropically etching the silicon surface or isotropically etching the glass surface, supplemented by subsequent soft printing for pattern transfer, or directly formed by 3D printing technology;
一第二透明导电薄膜105,设置于所述透明介质层104上方,且具有与所述透明介质层104上表面相同的凹部; A second transparent conductive film 105, disposed above the transparent medium layer 104, and has the same concave portion as the upper surface of the transparent medium layer 104;
一第二配向层107,设置于所述第二透明导电薄膜105上方,且所述第二配向层107上表面与所述第二透明基板102平行; A second alignment layer 107, disposed above the second transparent conductive film 105, and the upper surface of the second alignment layer 107 is parallel to the second transparent substrate 102;
一液晶层108,设置于所述第二配向层107上方; a liquid crystal layer 108, disposed above the second alignment layer 107;
一第一配向层106,设置于所述液晶层108上方,用于液晶分子的取向; a first alignment layer 106, disposed above the liquid crystal layer 108, for alignment of liquid crystal molecules;
一第一透明导电薄膜103,设置于所述第一配向层106上方; A first transparent conductive film 103, disposed above the first alignment layer 106;
一第一透明基板101,设置于所述第一透明导电薄膜103上方; A first transparent substrate 101, disposed above the first transparent conductive film 103;
所述透明介质层上表面对应于每一个微透镜区域具有的凹部为通过各向异性蚀刻硅表面或各向同性蚀刻玻璃表面,辅以后续软印刷进行图形转移形成,或者通过3D打印技术直接形成。 The concave portion corresponding to each microlens area on the upper surface of the transparent medium layer is formed by anisotropically etching the silicon surface or isotropically etching the glass surface, supplemented by subsequent soft printing for pattern transfer, or directly formed by 3D printing technology .
优选的,所述第一透明基板和第二透明基板是透明玻璃、透明无机材料或透明有机聚合物材料;所述液晶微透镜阵列为液晶柱微透镜阵列和液晶微透镜阵列,所述液晶微透镜的形状为圆形或正多边形;所述第一透明导电薄膜和第二透明导电薄膜为采用真空镀膜或喷涂技术形成的氧化铟锡(ITO)薄膜、金属掺杂氧化锌薄膜、金属-石墨烯或金属-碳纳米管复合薄膜;该第二透明导电薄膜和第一透明导电薄膜的距离呈现连续或非连续的有规律变化,用于灵活控制电场分布,形成液晶微透镜阵列;所述第一配向层和第二配向层经受摩擦处理,且摩擦方向一致。 Preferably, the first transparent substrate and the second transparent substrate are transparent glass, transparent inorganic material or transparent organic polymer material; the liquid crystal microlens array is a liquid crystal column microlens array and a liquid crystal microlens array, and the liquid crystal microlens array The shape of the lens is a circle or a regular polygon; the first transparent conductive film and the second transparent conductive film are indium tin oxide (ITO) films, metal-doped zinc oxide films, metal-graphite films formed by vacuum coating or spraying technology ene or metal-carbon nanotube composite film; the distance between the second transparent conductive film and the first transparent conductive film presents a continuous or discontinuous regular change, which is used to flexibly control the electric field distribution to form a liquid crystal microlens array; the second The first alignment layer and the second alignment layer are subjected to rubbing treatment, and the rubbing directions are consistent. the
如图1所示为本发明当所述第一透明介质层表面有规律的凹凸形状为通过各向异性蚀刻硅表面辅以后续软印刷进行图形转移时,液晶微透镜阵列一个单元不加电场的结构示意图。此时液晶分子沿与基板平行方向排列,液晶分子的长轴方向与偏振光的偏振方向一致,不会对光路产生影响,故偏振光109直线穿过。当施加电场时,液晶分子在电场的作用下发生一定偏转,当第一电极和第二电极距离较小时,电场较大,液晶分子完全偏转成与基板垂直,对偏振光的折射率最大,第一电极和第二电极距离增大,液晶之间电场减小,液晶偏转角度也减小,对偏振光109的折射率变小,形成梯度折射率微透镜,如图2所示。 As shown in Fig. 1, in the present invention, when the regular uneven shape on the surface of the first transparent medium layer is transferred by anisotropic etching of the silicon surface and supplemented by subsequent soft printing, a unit of the liquid crystal microlens array does not apply an electric field. Schematic. At this time, the liquid crystal molecules are arranged in a direction parallel to the substrate, and the long axis direction of the liquid crystal molecules is consistent with the polarization direction of the polarized light, which will not affect the optical path, so the polarized light 109 passes straight through. When an electric field is applied, the liquid crystal molecules deflect to a certain extent under the action of the electric field. When the distance between the first electrode and the second electrode is small, the electric field is large, and the liquid crystal molecules are completely deflected to be perpendicular to the substrate, and the refractive index for polarized light is the largest. As the distance between the first electrode and the second electrode increases, the electric field between the liquid crystals decreases, the deflection angle of the liquid crystals also decreases, and the refractive index of the polarized light 109 becomes smaller, forming a gradient index microlens, as shown in FIG. 2 . the
当所述透明介质层表面有规律的凹凸形状为通过各向异性蚀刻硅表面辅以后续软印刷进行图形转移时,如图1和图2所示,有规律的凹凸形状电极的制备包含以下步骤: When the regular concave-convex shape on the surface of the transparent medium layer is transferred by anisotropic etching of the silicon surface and subsequent soft printing, as shown in Figures 1 and 2, the preparation of the regular concave-convex shape electrode includes the following steps :
S11:如图5所示,提供一洁净的Si(100)基板并采用光刻在其表面制作小孔光栅; S11: as shown in Figure 5, provide a clean Si (100) substrate and use photolithography to make a small hole grating on its surface;
S12:以所述小孔光栅为掩膜,采用氢氧化钾(KOH)溶液,在所述Si(100)基板表面各向异性刻蚀孔型凹槽; S12: using the pinhole grating as a mask, using a potassium hydroxide (KOH) solution to anisotropically etch hole-shaped grooves on the surface of the Si(100) substrate;
S13:采用硅橡胶制备所述孔型凹槽的硅橡胶负模板; S13: Using silicone rubber to prepare a silicone rubber negative template for the hole-shaped groove;
S14:提供一洁净的第二透明基板,在其表面均匀涂覆一层透明介质层,并将所述硅橡胶负模板平整放置于所述透明介质层上(即所述硅橡胶负模板具有孔型凹槽的一面置于所述透明介质层上),施加一预定压力,采用加热或紫外光照射的方法使所述透明介质层固化; S14: Provide a clean second transparent substrate, uniformly coat a layer of transparent medium layer on its surface, and place the silicone rubber negative template flatly on the transparent medium layer (that is, the silicone rubber negative template has holes One side of the shaped groove is placed on the transparent medium layer), a predetermined pressure is applied, and the transparent medium layer is cured by heating or ultraviolet light irradiation;
S15:将所述硅橡胶负模板与所述透明介质层分离,得到有规律的凹凸形状的透明介质层表面; S15: separating the silicone rubber negative template from the transparent medium layer to obtain a regular concave-convex surface of the transparent medium layer;
S16:在所述透明介质层表面制备第二透明导电薄膜,形成有规律的凹凸形状电极。 S16: preparing a second transparent conductive film on the surface of the transparent medium layer to form regular concave-convex electrodes.
当所述透明介质层表面有规律的凹凸形状为通过各向同性蚀刻玻璃表面辅以后续软印刷进行图形转移时,如图3所示,有规律的凹凸形状电极的制备包含以下步骤: When the regular concave-convex shape on the surface of the transparent medium layer is transferred by isotropically etching the glass surface and supplemented by subsequent soft printing, as shown in Figure 3, the preparation of the regular concave-convex shape electrode includes the following steps:
S21:提供一洁净的玻璃基板并采用光刻在其表面制作小孔光栅; S21: Provide a clean glass substrate and make a small hole grating on its surface by photolithography;
S22:以所述小孔光栅为掩膜,采用氢氟酸(FH)和氟化铵(NH4F)混合溶液,在所述玻璃基板表面各向同性刻蚀孔型凹槽; S22: using the pinhole grating as a mask, using a mixed solution of hydrofluoric acid (FH) and ammonium fluoride (NH 4 F), to isotropically etch hole-shaped grooves on the surface of the glass substrate;
S23:采用硅橡胶制备所述孔型凹槽的硅橡胶负模板; S23: Using silicone rubber to prepare a silicone rubber negative template for the hole-shaped groove;
S24:提供一洁净的第二透明基板,在其表面均匀涂覆一层透明介质层,并将所述硅橡胶负模板平整放置于所述透明介质层上(即所述硅橡胶负模板具有孔型凹槽的一面置于所述透明介质层上),施加一定压力,采用加热或紫外光照射的方法使所述透明介质层固化; S24: Provide a clean second transparent substrate, uniformly coat a layer of transparent medium layer on its surface, and place the silicone rubber negative template flatly on the transparent medium layer (that is, the silicone rubber negative template has holes One side of the shaped groove is placed on the transparent medium layer), a certain pressure is applied, and the transparent medium layer is cured by heating or ultraviolet light irradiation;
S25:将所述硅橡胶负模板与所述透明介质层分离,得到所述有规律的凹凸形状的第一透明介质层表面; S25: Separate the silicone rubber negative template from the transparent medium layer to obtain the surface of the first transparent medium layer with regular concave-convex shapes;
S26:在所述透明介质层表面制备第二透明导电薄膜,形成有规律的凹凸形状电极。 S26: Prepare a second transparent conductive film on the surface of the transparent medium layer to form regular concave-convex electrodes. the
当所述透明介质层表面有规律的凹凸形状为通过3D打印技术形成时,如图4所示,有规律的凹凸形状电极的制备包含以下步骤: When the regular concave-convex shape on the surface of the transparent medium layer is formed by 3D printing technology, as shown in Figure 4, the preparation of the regular concave-convex shape electrode includes the following steps:
S31:提供一洁净的第二透明基板; S31: providing a clean second transparent substrate;
S32:采用3D打印技术在所述第二透明基板表面打印孔型凹槽,得到有规律的凹凸形状具有所述凹部的透明介质层表面; S32: Using 3D printing technology to print hole-shaped grooves on the surface of the second transparent substrate to obtain a surface of the transparent medium layer having regular concave-convex shapes with the concave parts;
S33:在所述有规律的凹凸形状透明介质层表面制备第二透明导电薄膜,形成有规律的凹凸形状电极。 S33: Prepare a second transparent conductive film on the surface of the regular concave-convex shape transparent medium layer to form regular concave-convex shape electrodes.
在图中,为了表示清楚放大了层和区域的厚度,但作为示意图不应该被认为严格反映了几何尺寸的比例关系。参考图是本发明的理想化实施例的示意图,本发明所示的实施例不应该被认为仅限于图中所示的区域的特定形状,而是包括所得到的形状(比如制造引起的偏差)。在本实施例中均以矩形表示,图中的表示是示意性的,但这不应该被认为限制本发明的范围。 In the drawings, the thicknesses of layers and regions are exaggerated for clarity, but as schematic diagrams, they should not be considered to strictly reflect the proportional relationship of geometric dimensions. The referenced figures are schematic illustrations of idealized embodiments of the present invention, and the illustrated embodiments of the present invention should not be considered limited to the particular shapes of the regions shown in the figures, but include resulting shapes (such as manufacturing-induced deviations) . All are represented by rectangles in this embodiment, and the representation in the figure is schematic, but this should not be considered as limiting the scope of the present invention. the
为了让一般技术人员更好的理解本发明,优选的,本发明具体实施例中透明基板选用玻璃基板,透明导电薄膜选用氧化铟锡(ITO),透明介质层选用亚克力(PMMA),配向层选用聚酰亚胺(PI),用于制作硅橡胶负模板的硅橡胶材料选用聚二甲基硅氧烷(PDMS)且其单体和交联剂的比列选用10:1。下面通过实施例介绍液晶微透镜阵列具体的制备方法。 In order to allow those skilled in the art to better understand the present invention, preferably, the transparent substrate in the specific embodiment of the present invention is a glass substrate, the transparent conductive film is made of indium tin oxide (ITO), the transparent medium layer is made of acrylic (PMMA), and the alignment layer is made of Polyimide (PI), the silicone rubber material used to make the silicone rubber negative template is polydimethylsiloxane (PDMS), and the ratio of its monomer to crosslinking agent is 10:1. The specific preparation method of the liquid crystal microlens array will be introduced below through the examples. the
实施例一 Embodiment one
如图1和图2所示,本实施例为当所述透明介质层表面有规律的凹凸形状为通过各向异性蚀刻硅表面辅以后续软印刷进行图形转移时,液晶微透镜阵列的制备方法,其具体方案包括以下步骤: As shown in Figures 1 and 2, this embodiment is a method for preparing a liquid crystal microlens array when the regular concave-convex shape on the surface of the transparent medium layer is transferred by anisotropically etching the silicon surface and supplemented by subsequent soft printing. , its specific scheme includes the following steps:
S11:提供一洁净的Si(100)基板并采用光刻在其表面制作小孔光栅; S11: Provide a clean Si(100) substrate and make a small hole grating on its surface by photolithography;
选取单面抛光Si (100)基片,置于清洗液Win-10的水溶液中(体积比为Win-10 : DI水= 3 : 97),利用频率为32KHz的超声机清洗15min,喷淋2min后,再置于清洗液Win-41的水溶液中(体积比为Win-41 : DI水= 5 : 95),利用频率为40KHz的超声机清洗10min,经循环自来水喷淋漂洗2min后,再利用频率为28KHz的超声机在DI纯净水中清洗10min,经氮气枪吹干后置于50℃洁净烘箱中保温30min以上备用。 Select a single-sided polished Si (100) substrate, place it in the aqueous solution of cleaning solution Win-10 (volume ratio is Win-10 : DI water = 3 : 97), use an ultrasonic machine with a frequency of 32KHz to clean for 15 minutes, and spray for 2 minutes Finally, put it in the aqueous solution of cleaning solution Win-41 (volume ratio is Win-41 : DI water = 5 : 95), use an ultrasonic machine with a frequency of 40KHz to clean for 10 minutes, spray and rinse with circulating tap water for 2 minutes, and then reuse The ultrasonic machine with a frequency of 28KHz was cleaned in DI pure water for 10 minutes, dried with a nitrogen gun, and then placed in a clean oven at 50°C for more than 30 minutes for later use.
如图5所示,在上述洁净基板Si (100)基片表面,采用等离子体增强化学气相沉积(PECVD)法沉积约100 nm SiO2薄膜,在SiO2薄膜上均匀涂覆一层光刻胶RJZ304,110℃烘烤20分钟后,经过曝光和显影后在SiO2薄膜薄膜上形成具有小孔光栅阵列(对应微微透镜阵列)图案的光刻胶;以光刻胶为掩膜,采用反应离子刻蚀方法,将暴露的SiO2薄膜刻蚀除去,被光刻胶保护的SiO2薄膜留下来,光刻胶清洗后,形成SiO2薄膜小孔光栅阵列(具有小孔光栅图案光刻胶的镂空小孔部分,本实施例中镂空小孔部分为圆形,对应微透镜阵列)。 As shown in Figure 5, on the surface of the above-mentioned clean substrate Si (100) substrate, a 100 nm SiO 2 film was deposited by plasma enhanced chemical vapor deposition (PECVD), and a layer of photoresist was uniformly coated on the SiO 2 film RJZ304, after baking at 110°C for 20 minutes, after exposure and development, a photoresist with a pattern of a small hole grating array (corresponding to a microlens array) is formed on the SiO 2 film; the photoresist is used as a mask, and reactive ions are used Etching method, the exposed SiO2 film is etched away, and the SiO2 film protected by the photoresist is left. After the photoresist is cleaned, the SiO2 film aperture grating array (with the aperture grating pattern photoresist) is formed. Hollow small hole part, the hollow small hole part is circular in this embodiment, corresponding to the microlens array).
S12:以所述小孔光栅为掩膜,采用氢氧化钾(KOH)溶液,在Si(100)基板表面各向异性刻蚀孔型凹槽; S12: using the pinhole grating as a mask, using a potassium hydroxide (KOH) solution to anisotropically etch hole-shaped grooves on the surface of the Si(100) substrate;
将设置有SiO2薄膜小孔光栅阵列110的Si(100)基板置于30 wt.% 氢氧化钾(KOH)水溶液,溶液温度为80℃,由于KOH溶液对Si(100)面的刻蚀速度远远大于对Si(111)面的刻蚀速度,将形成如图5所示的倒三角锥形凹槽。 Put the Si(100) substrate with the SiO 2 film pinhole grating array 110 in a 30 wt.% potassium hydroxide (KOH) aqueous solution at a temperature of 80°C. Due to the etching speed of the KOH solution on the Si(100) surface Far greater than the etching rate for the Si(111) surface, an inverted triangular conical groove as shown in Figure 5 will be formed.
S13:采用硅橡胶制备孔型凹槽的负模板; S13: Using silicone rubber to prepare a negative template for the hole groove;
取所述步骤S12中制备的含倒三角锥形凹槽阵列的Si基片密封置于装有三甲基氯硅烷分子(TMCS)的容器里,放置约5分钟后取出,此时该Si基片表面自组装一层TMCS分子,用于防粘。按所述硅橡胶所需比例制备单体和交联剂的混合物,本实施例按单体和交联剂10:1的比列配置聚二甲基硅氧烷(PDMS)混合物,搅拌至均匀混合。将上述自组装一层TMCS的Si基片水平放置于一容器中,倒入聚二甲基硅氧烷(PDMS)混合物,静置约30分钟至起泡全部消除,将该容器放入80℃烘箱两小时以上,待PDMS完全固化后取出,将PDMS与Si基片分离,切割PDMS形成三角锥阵列的硅橡胶负模板。 Take the Si substrate containing the array of inverted triangular conical grooves prepared in the step S12 and seal it in a container containing trimethylchlorosilane molecules (TMCS), and take it out after standing for about 5 minutes. At this time, the Si substrate A layer of TMCS molecules is self-assembled on the surface for anti-sticking. Prepare a mixture of monomers and crosslinking agents according to the required ratio of the silicone rubber. In this example, a mixture of polydimethylsiloxane (PDMS) is prepared according to the ratio of monomers and crosslinking agents of 10:1, and stirred until uniform mix. Put the above self-assembled Si substrate with one layer of TMCS horizontally in a container, pour the polydimethylsiloxane (PDMS) mixture, let it stand for about 30 minutes until all the bubbles are eliminated, put the container at 80°C Oven for more than two hours, take out the PDMS after it is completely cured, separate the PDMS from the Si substrate, and cut the PDMS to form a silicone rubber negative template of the triangular pyramid array.
S14:提供一洁净的透明基板102(第二透明基板),在其表面均匀涂覆一层透明介质层(透明介质层),并将S13所得硅橡胶负模板平整放置于透明介质层上,施加一定压力,采用加热或紫外光照射的方法使其固化; S14: Provide a clean transparent substrate 102 (second transparent substrate), uniformly coat a layer of transparent medium layer (transparent medium layer) on its surface, place the silicone rubber negative template obtained in S13 flatly on the transparent medium layer, apply Under a certain pressure, it is cured by heating or ultraviolet light irradiation;
取一洁净的玻璃基板102,优选的,采用旋涂方法在其表面均匀涂覆一层PMMA,将S13所得三角锥阵列硅橡胶负模板三角锥阵列朝下平整放置于透明介质层上,施加一定压力使得在PMMA上形成倒三角锥形凹槽阵列,并采用加热方式使PMMA固化。 Take a clean glass substrate 102, preferably, uniformly coat a layer of PMMA on its surface by using a spin coating method, place the triangular pyramid array silicon rubber negative template triangular pyramid array obtained in S13 on the transparent medium layer flatly, and apply a certain The pressure makes an array of inverted triangular conical grooves formed on the PMMA, and the PMMA is cured by heating.
S15:将硅橡胶负模板与透明介质层分离,得到所述有规律的凹凸形状的透明介质层表面; S15: separating the silicone rubber negative template from the transparent medium layer to obtain the surface of the regular concave-convex shape of the transparent medium layer;
PMMA固化后,将硅橡胶负模板揭下,形成有规律的凹凸形状第一透明介质层表面104。 After the PMMA is solidified, the silicone rubber negative template is peeled off to form the surface 104 of the first transparent medium layer with regular concave-convex shapes.
S16:在有规律的凹凸形状的透明介质层表面制备透明导电薄膜,形成有规律的凹凸形状电极; S16: Prepare a transparent conductive film on the surface of a regular concave-convex shape transparent medium layer to form a regular concave-convex shape electrode;
优选的,在有规律的凹凸形状的第一透明介质层表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极105。同样,取另一洁净的玻璃基板101,在其表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极103。 Preferably, an ITO transparent conductive film with a thickness of 300nm is prepared by magnetron sputtering on the surface of the regular concave-convex shape of the first transparent medium layer to form a regular concave-convex shape transparent conductive electrode 105. Similarly, another clean glass substrate 101 was taken, and an ITO transparent conductive film with a thickness of 300 nm was prepared on its surface by magnetron sputtering to form regular concave-convex shape transparent conductive electrodes 103.
S17:在透明导电电极103和105的表面制备液晶配向层; S17: preparing a liquid crystal alignment layer on the surface of the transparent conductive electrodes 103 and 105;
在透明导电电极103和105的表面采用旋涂方法均匀涂覆一层厚度约80nm的聚酰亚胺(PI),并置于260℃的烘箱中烘烤2小时后取出自然冷却后,采用液晶面板制备专用摩擦机进行摩擦取向,分别在两透明导电电极上形成PI液晶配向层106和107。 A layer of polyimide (PI) with a thickness of about 80nm is uniformly coated on the surface of the transparent conductive electrodes 103 and 105 by spin coating, and placed in an oven at 260°C for 2 hours, then taken out and cooled naturally, and then liquid crystal A special rubbing machine for panel preparation is used for rubbing alignment, and PI liquid crystal alignment layers 106 and 107 are respectively formed on the two transparent conductive electrodes. the
S18:液晶微透镜制备。 S18: Preparation of liquid crystal microlens. the
采用液晶面板制作标准工艺,经过框胶印刷、基板贴合、灌注液晶、封口、液晶再取向等步骤,形成完整的液晶微透镜。 Using the standard process of LCD panel production, a complete liquid crystal microlens is formed through steps such as frame glue printing, substrate bonding, liquid crystal filling, sealing, and liquid crystal reorientation. the
实施例二 Example two
如图3所示,本实施例为当所述透明介质层表面有规律的凹凸形状为通过各向同性蚀刻玻璃表面辅以后续软印刷进行图形转移时,液晶微透镜阵列的制备方法,其具体方案包括以下步骤: As shown in Figure 3, this embodiment is a method for preparing a liquid crystal microlens array when the regular concave-convex shape on the surface of the transparent medium layer is transferred by isotropically etching the glass surface and supplemented by subsequent soft printing. The protocol includes the following steps:
S21:提供一洁净的玻璃基板并采用光刻在其表面制作小孔光栅; S21: Provide a clean glass substrate and make a small hole grating on its surface by photolithography;
将玻璃基板置于清洗液Win-10的水溶液中(体积比为Win-10 : DI水= 3 : 97),利用频率为32KHz的超声机清洗15min,喷淋2min后,再置于清洗液Win-41的水溶液中(体积比为Win-41 : DI水= 5 : 95),利用频率为40KHz的超声机清洗10min,经循环自来水喷淋漂洗2min后,再利用频率为28KHz的超声机在DI纯净水中清洗10min,经氮气枪吹干后置于50℃洁净烘箱中保温30min以上备用。 Put the glass substrate in the aqueous solution of the cleaning solution Win-10 (volume ratio of Win-10 : DI water = 3 : 97), use an ultrasonic machine with a frequency of 32KHz to clean it for 15 minutes, spray it for 2 minutes, and then place it in the cleaning solution Win -41 in aqueous solution (volume ratio Win-41 : DI water = 5 : 95), use an ultrasonic machine with a frequency of 40KHz to clean for 10 minutes, spray and rinse with circulating tap water for 2 minutes, and then use an ultrasonic machine with a frequency of 28KHz in DI Rinse in pure water for 10 minutes, blow dry with a nitrogen gun, and place in a clean oven at 50°C for at least 30 minutes for later use.
在上述洁净玻璃表面,采用磁控溅射沉积约100 nm Cr薄膜,在Cr薄膜上均匀涂覆一层光刻胶RJZ304,110℃烘烤20分钟后,经过曝光和显影后在Cr薄膜上形成具有小孔光栅阵列(对应微透镜阵列)图案的光刻胶;置于含Ce(NH4)2(NO3)6 和 HClO4 的水溶液刻蚀液中,以光刻胶为掩膜,暴露的金属部分(具有小孔光栅图案光刻胶的镂空小孔部分,本实施例中镂空小孔部分为圆形)被刻蚀,被光刻胶保护的金属留下来,光刻胶清洗后,最终形成Cr薄膜小孔光栅(对应微透镜阵列)。 On the above-mentioned clean glass surface, a 100 nm Cr film was deposited by magnetron sputtering, and a layer of photoresist RJZ304 was uniformly coated on the Cr film, and after baking at 110°C for 20 minutes, it was exposed and developed to form on the Cr film A photoresist with a pattern of a small hole grating array (corresponding to a microlens array); placed in an aqueous etching solution containing Ce(NH 4 ) 2 (NO 3 ) 6 and HClO 4 , using the photoresist as a mask, exposing The metal part (the hollowed out small hole part with the small hole grating pattern photoresist, the hollowed out small hole part is circular in this embodiment) is etched, and the metal protected by the photoresist is left. After the photoresist is cleaned, Finally, a Cr film pinhole grating (corresponding to a microlens array) is formed.
S22:以所述Cr薄膜小孔光栅为掩膜,采用氢氟酸(FH)和氟化铵(NH4F)混合溶液,在基板表面各向异性刻蚀孔型凹槽; S22: using the Cr film pinhole grating as a mask, using a mixed solution of hydrofluoric acid (FH) and ammonium fluoride (NH 4 F) to anisotropically etch hole-shaped grooves on the surface of the substrate;
将设置有Cr薄膜小孔光栅阵列玻璃基板置于5 wt.% 氢氟酸(FH)水溶液,Cr薄膜小孔光栅阵列为掩膜,室温下刻蚀玻璃,将形成微透镜状孔型凹槽。 Place the glass substrate with the Cr film pinhole grating array in 5 wt.% hydrofluoric acid (FH) aqueous solution, the Cr film pinhole grating array is used as a mask, and the glass is etched at room temperature to form microlens-shaped hole grooves . the
S23:采用硅橡胶制备孔型凹槽的负模板; S23: Using silicone rubber to prepare a negative template for the hole groove;
取所述步骤S22中制备的含微透镜状孔型凹槽的玻璃基片,用稀盐酸出去表面的Cr薄膜,清洗干净后密封置于装有三甲基氯硅烷分子(TMCS)的容器里,放置约5分钟后取出,此时该玻璃基片表面自组装一层TMCS分子,用于防粘。按所述硅橡胶所需比例制备单体和交联剂的混合物,本实施例按单体和交联剂10:1的比列配置聚二甲基硅氧烷(PDMS)混合物,搅拌至均匀混合。将上述自组装一层TMCS的玻璃基片水平放置于一容器中,倒入聚二甲基硅氧烷(PDMS)混合物,静置约30分钟至起泡全部消除,将该容器放入80℃烘箱两小时以上,待PDMS完全固化后取出,将PDMS与玻璃分离,切割PDMS形成孔型凹槽的硅橡胶负模板(微透镜形状)。 Take the glass substrate containing microlens-shaped hole-shaped grooves prepared in the step S22, remove the Cr film on the surface with dilute hydrochloric acid, clean it, seal it and place it in a container containing trimethylchlorosilane molecules (TMCS), Take it out after standing for about 5 minutes. At this time, the surface of the glass substrate self-assembles a layer of TMCS molecules for anti-sticking. Prepare a mixture of monomers and crosslinking agents according to the required ratio of the silicone rubber. In this example, a mixture of polydimethylsiloxane (PDMS) is prepared according to the ratio of monomers and crosslinking agents of 10:1, and stirred until uniform mix. Place the above self-assembled glass substrate with one layer of TMCS horizontally in a container, pour the polydimethylsiloxane (PDMS) mixture, let it stand for about 30 minutes until all the bubbles are eliminated, and put the container at 80°C Oven for more than two hours, take out the PDMS after it is completely cured, separate the PDMS from the glass, and cut the PDMS to form a silicone rubber negative template (microlens shape) with hole grooves.
S24:提供一洁净的透明基板202(第二透明基板),在其表面均匀涂覆一层透明介质层(透明介质层),并将S23所得硅橡胶负模板平整放置于透明介质层上,施加一定压力,采用加热或紫外光照射的方法使其固化; S24: Provide a clean transparent substrate 202 (second transparent substrate), uniformly coat a layer of transparent medium layer (transparent medium layer) on its surface, place the silicone rubber negative template obtained in S23 flatly on the transparent medium layer, apply Under a certain pressure, it is cured by heating or ultraviolet light irradiation;
取一洁净的玻璃基板202,优选的,采用旋涂方法在其表面均匀涂覆一层PMMA,将S23所得微透镜状孔型凹槽硅橡胶负模板微透镜阵列朝下平整放置于透明介质层上,施加一定压力使得在PMMA上形成微透镜状孔型凹槽阵列,并采用加热方式使PMMA固化。 Take a clean glass substrate 202, preferably, use a spin coating method to uniformly coat a layer of PMMA on its surface, and place the microlens-like hole-shaped groove silicone rubber negative template microlens array obtained in S23 on the transparent medium layer flatly. On, a certain pressure is applied to form a microlens-like hole-shaped groove array on the PMMA, and the PMMA is cured by heating.
S25:将硅橡胶负模板与透明介质层分离,得到所述有规律的凹凸形状的透明介质层表面; S25: separating the silicone rubber negative template from the transparent medium layer to obtain the surface of the regular concave-convex shape of the transparent medium layer;
PMMA固化后,将硅橡胶负模板揭下,形成有规律的凹凸形状第一透明介质层表面204。 After the PMMA is cured, the silicone rubber negative template is removed to form the surface 204 of the first transparent medium layer with regular concave-convex shapes.
S26:在有规律的凹凸形状的透明介质层表面制备透明导电薄膜,形成有规律的凹凸形状电极; S26: Prepare a transparent conductive film on the surface of the regular concave-convex shape transparent medium layer to form a regular concave-convex shape electrode;
优选的,在有规律的凹凸形状的透明介质层表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极205。同样,取另一洁净的玻璃基板201,在其表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极203。 Preferably, an ITO transparent conductive film with a thickness of 300 nm is prepared by magnetron sputtering on the surface of the regular concave-convex shape of the transparent medium layer to form a regular concave-convex shape transparent conductive electrode 205. Similarly, another clean glass substrate 201 was taken, and an ITO transparent conductive film with a thickness of 300nm was prepared on its surface by magnetron sputtering to form regular concave-convex shape transparent conductive electrodes 203.
S27:在透明导电电极203和205的表面制备液晶配向层; S27: preparing a liquid crystal alignment layer on the surface of the transparent conductive electrodes 203 and 205;
在透明导电电极203和205的表面采用旋涂方法均匀涂覆一层厚度约80nm的聚酰亚胺(PI),并置于260℃的烘箱中烘烤2小时后取出自然冷却后,采用液晶面板制备专用摩擦机进行摩擦取向,分别在两透明导电电极上形成PI液晶配向层206和207。 The surface of the transparent conductive electrodes 203 and 205 is evenly coated with a layer of polyimide (PI) with a thickness of about 80nm by the spin coating method, and placed in an oven at 260°C for 2 hours, then taken out and cooled naturally, and then liquid crystal A special rubbing machine for panel preparation is used for rubbing alignment, and PI liquid crystal alignment layers 206 and 207 are respectively formed on the two transparent conductive electrodes. the
S28:液晶微微透镜制备。 S28: Preparation of liquid crystal microlenses. the
采用液晶面板制作标准工艺,经过框胶印刷、基板贴合、灌注液晶、封口、液晶再取向等步骤,形成完整的液晶微透镜。 Using the standard process of LCD panel production, a complete liquid crystal microlens is formed through steps such as frame glue printing, substrate bonding, liquid crystal filling, sealing, and liquid crystal reorientation. the
实施例三 Embodiment three
如图4所示,本实施例为当所述透明介质层表面有规律的凹凸形状为通过3D打印技术形成时,液晶微透镜阵列的制备方法,其具体方案包括以下步骤: As shown in Figure 4, this embodiment is a method for preparing a liquid crystal microlens array when the regular concave-convex shape on the surface of the transparent medium layer is formed by 3D printing technology, and its specific scheme includes the following steps:
S31:提供一洁净的透明基板(第二透明基板); S31: providing a clean transparent substrate (second transparent substrate);
将玻璃基板置于清洗液Win-10的水溶液中(体积比为Win-10 : DI水= 3 : 97),利用频率为32KHz的超声机清洗15min,喷淋2min后,再置于清洗液Win-41的水溶液中(体积比为Win-41 : DI水= 5 : 95),利用频率为40KHz的超声机清洗10min,经循环自来水喷淋漂洗2min后,再利用频率为28KHz的超声机在DI纯净水中清洗10min,经氮气枪吹干后置于50℃洁净烘箱中保温30min以上备用。 Put the glass substrate in the aqueous solution of the cleaning solution Win-10 (volume ratio of Win-10 : DI water = 3 : 97), use an ultrasonic machine with a frequency of 32KHz to clean it for 15 minutes, spray it for 2 minutes, and then place it in the cleaning solution Win -41 in aqueous solution (volume ratio Win-41 : DI water = 5 : 95), use an ultrasonic machine with a frequency of 40KHz to clean for 10 minutes, spray and rinse with circulating tap water for 2 minutes, and then use an ultrasonic machine with a frequency of 28KHz in DI Rinse in pure water for 10 minutes, blow dry with a nitrogen gun, and place in a clean oven at 50°C for at least 30 minutes for later use.
S32:采用3D打印技术在所述第二透明基板表面打印孔型凹槽,得到所述有规律的凹凸形状的透明介质层表面304; S32: Using 3D printing technology to print hole-shaped grooves on the surface of the second transparent substrate to obtain the regular concave-convex shape of the transparent medium layer surface 304;
S33:在有规律的凹凸形状的透明介质层304表面制备透明导电薄膜,形成有规律的凹凸形状电极305; S33: Prepare a transparent conductive film on the surface of the regular concave-convex shape transparent medium layer 304 to form a regular concave-convex shape electrode 305;
优选的,在有规律的凹凸形状的透明介质层304表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极305。同样,取另一洁净的玻璃基板301,在其表面采用磁控溅射制备厚度为300nm 的ITO透明导电薄膜,形成有规律的凹凸形状透明导电电极303。 Preferably, the ITO transparent conductive film with a thickness of 300nm is prepared by magnetron sputtering on the surface of the regular concave-convex shape transparent medium layer 304 to form a regular concave-convex shape transparent conductive electrode 305. Similarly, another clean glass substrate 301 was taken, and an ITO transparent conductive film with a thickness of 300nm was prepared on its surface by magnetron sputtering to form regular concave-convex transparent conductive electrodes 303.
S34:在透明导电电极303和305的表面制备液晶配向层; S34: preparing a liquid crystal alignment layer on the surface of the transparent conductive electrodes 303 and 305;
在透明导电电极303和305的表面采用旋涂方法均匀涂覆一层厚度约80nm的聚酰亚胺(PI),并置于260℃的烘箱中烘烤2小时后取出自然冷却后,采用液晶面板制备专用摩擦机进行摩擦取向,分别在两透明导电电极上形成PI液晶配向层306和307。 The surface of the transparent conductive electrodes 303 and 305 is evenly coated with a layer of polyimide (PI) with a thickness of about 80nm by the spin coating method, and placed in an oven at 260°C for 2 hours, then taken out and cooled naturally, and then liquid crystal A special rubbing machine for panel preparation is used for rubbing alignment, and PI liquid crystal alignment layers 306 and 307 are respectively formed on the two transparent conductive electrodes. the
S35:液晶微透镜制备。 S35: Preparation of liquid crystal microlens. the
采用液晶面板制作标准工艺,经过框胶印刷、基板贴合、灌注液晶、封口、液晶再取向等步骤,形成完整的液晶微透镜。 Using the standard process of LCD panel production, a complete liquid crystal microlens is formed through steps such as frame glue printing, substrate bonding, liquid crystal filling, sealing, and liquid crystal reorientation. the
上列较佳实施例,对本发明的目的、技术方案和优点进行了进一步详细说明,所应理解的是,以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。 The above-listed preferred embodiments have further described the purpose, technical solutions and advantages of the present invention in detail. It should be understood that the above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Within the spirit and principles of the present invention, any modifications, equivalent replacements, improvements, etc., shall be included within the protection scope of the present invention. the
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