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CN104218220A - Manufacturing method of positive active material for lithium battery - Google Patents

Manufacturing method of positive active material for lithium battery Download PDF

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Publication number
CN104218220A
CN104218220A CN201310218573.7A CN201310218573A CN104218220A CN 104218220 A CN104218220 A CN 104218220A CN 201310218573 A CN201310218573 A CN 201310218573A CN 104218220 A CN104218220 A CN 104218220A
Authority
CN
China
Prior art keywords
atom
lithium
active material
cobalt
lithium battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310218573.7A
Other languages
Chinese (zh)
Inventor
施承启
李超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
COMTEC SOLAR (JIANGSU) Co Ltd
Original Assignee
COMTEC SOLAR (JIANGSU) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by COMTEC SOLAR (JIANGSU) Co Ltd filed Critical COMTEC SOLAR (JIANGSU) Co Ltd
Priority to CN201310218573.7A priority Critical patent/CN104218220A/en
Publication of CN104218220A publication Critical patent/CN104218220A/en
Pending legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The invention discloses a manufacturing method of a positive active material for a lithium battery, and the manufacturing method is as follows: first, a lithium compound, a compound containing nickel, cobalt and manganese atoms and titanium oxide are mixed for calcining, a calcined lithium composite oxide is milled into powder, and attached to the surface of a lithium battery positive pole, and after electrifying, the lithium composite oxide powder is absorbed on the surface of the lithium battery positive pole to form the positive active material. The manufacturing method is simple, the positive active material is prepared by a an industrially advantageous method, and is convenient and simple.

Description

A kind of positive pole active material for lithium cell manufacture method
 
Technical field
The invention belongs to battery manufacture technical field, be specifically related to a kind of positive pole active material for lithium cell manufacture method, to produce the lithium battery of cycle characteristics excellence.
Background technology
In recent years, along with the universal and miniaturization of the portable machines such as mobile phone, notebook computer, the battery with nonaqueous electrolyte such as lithium battery are progressively used as its power supply.And from tackling nearest environmental problem, the traction-type cell using it as electric automobile etc. also causes concern gradually.As positive pole active material for lithium cell, conventionally extensively adopt LiCoO 2(cobalt acid lithium) is as the material that can form 4V level battery.Use LiCoO 2during as positive active material, discharge capacity is about 160mA/g, is practical as LiCo0 2the cobalt of raw material be scarce resource, and skewness, so Expenses Cost, raw material supplying is unstable.
Summary of the invention
Goal of the invention: the present invention is directed to the deficiencies in the prior art, propose a kind of use and can give lithium battery a kind of positive pole active material for lithium cell manufacture method of excellent cycle characteristics especially.
Technical scheme: a kind of positive pole active material for lithium cell manufacture method, described manufacture method is first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08-1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface.
As preferably, described nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5～1:0.5～5.
As preferably, described calcining heat is 800-1200 ℃.
As preferably, described in comprise nickle atom, manganese atom and cobalt atom compound be cohesion shape complex hydroxide.
Beneficial effect: utilize manufacture method of the present invention simple, this positive active material can be manufactured by industrial favourable method, convenient succinct.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5～1:0.5～5; Above-mentioned calcining heat is 800 ℃; The above-mentioned compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.
Embodiment 2:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.10 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5～1:0.5～5; Above-mentioned calcining heat is 1000 ℃; Stating the compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.
Embodiment 3:
A kind of positive pole active material for lithium cell manufacture method, first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface; Above-mentioned nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5～1:0.5～5; Above-mentioned calcining heat is 800-1200 ℃; The above-mentioned compound that comprises nickle atom, manganese atom and cobalt atom is cohesion shape complex hydroxide.

Claims (4)

1. a positive pole active material for lithium cell manufacture method, it is characterized in that: described manufacture method is first by lithium compound, the mode that the compound that comprises nickle atom, cobalt atom and manganese atom and titanium oxide are 1.08-1.12 according to lithium atom with respect to the atomic ratio Li/{Ni+Co+Mn+Ti} of nickle atom, cobalt atom, manganese atom and titanium atom is mixed, and calcining; Again the resulting lithium composite xoide of calcining is milled into powder, invests lithium battery anode surface, after energising, be just adsorbed in lithium battery anode surface.
2. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described nickle atom: cobalt atom: the atomic ratio of manganese atom is 1:0.5～1:0.5～5.
3. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described calcining heat is 800-1200 ℃.
4. positive pole active material for lithium cell manufacture method according to claim 1, is characterized in that: described in comprise nickle atom, manganese atom and cobalt atom compound be cohesion shape complex hydroxide.
CN201310218573.7A 2013-06-04 2013-06-04 Manufacturing method of positive active material for lithium battery Pending CN104218220A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310218573.7A CN104218220A (en) 2013-06-04 2013-06-04 Manufacturing method of positive active material for lithium battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310218573.7A CN104218220A (en) 2013-06-04 2013-06-04 Manufacturing method of positive active material for lithium battery

Publications (1)

Publication Number Publication Date
CN104218220A true CN104218220A (en) 2014-12-17

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310218573.7A Pending CN104218220A (en) 2013-06-04 2013-06-04 Manufacturing method of positive active material for lithium battery

Country Status (1)

Country Link
CN (1) CN104218220A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1022792A1 (en) * 1999-01-25 2000-07-26 SANYO ELECTRIC Co., Ltd. Positive electrode for non-aqueous electrolyte cell and manufacturing method of the same
CN102479951A (en) * 2010-11-19 2012-05-30 日本化学工业株式会社 Positive electrode active material for lithium secondary battery, manufacturing method thereof, and lithium secondary battery

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1022792A1 (en) * 1999-01-25 2000-07-26 SANYO ELECTRIC Co., Ltd. Positive electrode for non-aqueous electrolyte cell and manufacturing method of the same
CN102479951A (en) * 2010-11-19 2012-05-30 日本化学工业株式会社 Positive electrode active material for lithium secondary battery, manufacturing method thereof, and lithium secondary battery

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Application publication date: 20141217