CN104194115A - Antioxygenic and adhesive rheological agent cable accessory material - Google Patents
Antioxygenic and adhesive rheological agent cable accessory material Download PDFInfo
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- CN104194115A CN104194115A CN201410363624.XA CN201410363624A CN104194115A CN 104194115 A CN104194115 A CN 104194115A CN 201410363624 A CN201410363624 A CN 201410363624A CN 104194115 A CN104194115 A CN 104194115A
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- density polyethylene
- cable accessory
- raw material
- rheological agent
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- Pending
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- 239000000463 material Substances 0.000 title claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 12
- 239000000853 adhesive Substances 0.000 title abstract 2
- 230000001070 adhesive effect Effects 0.000 title abstract 2
- 230000003026 anti-oxygenic effect Effects 0.000 title abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000003365 glass fiber Substances 0.000 claims abstract description 7
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 7
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 7
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 4
- IRHZVMHXVHSMKB-UHFFFAOYSA-N fenbendazole Chemical compound [CH]1C2=NC(NC(=O)OC)=NC2=CC=C1SC1=CC=CC=C1 IRHZVMHXVHSMKB-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960005473 fenbendazole Drugs 0.000 claims abstract description 4
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052912 lithium silicate Inorganic materials 0.000 claims abstract description 4
- 229920001684 low density polyethylene Polymers 0.000 claims abstract description 4
- 239000004702 low-density polyethylene Substances 0.000 claims abstract description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 4
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 9
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 6
- 239000003500 flue dust Substances 0.000 claims description 6
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001526 metallocene linear low density polyethylene Polymers 0.000 claims description 6
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 6
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 6
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 4
- 239000002956 ash Substances 0.000 claims description 4
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 claims description 3
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 3
- 238000000498 ball milling Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229940015043 glyoxal Drugs 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 3
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000003712 anti-aging effect Effects 0.000 abstract description 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- 230000032683 aging Effects 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229920001451 polypropylene glycol Polymers 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 229940048086 sodium pyrophosphate Drugs 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Insulated Conductors (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses an antioxygenic and adhesive rheological agent cable accessory material which is prepared from the following raw materials in parts by weight: 60 to 80 parts of low density polyethylene, 30 to 40 parts of high density polyethylene, 2 to 3 parts of 2-methylimidazole, 1 to 2 parts of lithium metasilicate, 10 to 12 parts of precipitated silica, 0.8 to 1.3 parts of sodium pyrophosphate, 5 to 7 parts of polypropylene glycol adipate, 3 to 5 parts of quartz glass fibers, 10 to 14 parts of triethylene glycol di-2-ethylhexoate, 1 to 2 parts of anti-aging agent 4010, 1 to 2 parts of blocky calcareous material, 2 to 4 parts of polyvinyl alcohol, 0.6 to 1 part of fenbendazole and 6 to 10 parts of composite fillers. The cable accessory material disclosed by the invention is strong in aging resistance, stable in mechanical performance, good in fire resistance and high-low temperature resistance and easy to produce, and can ensure that the investment of production equipment is saved so as to realize efficient production. The cable accessory material is stable in performance and high in quality, and can be used for performing strong and durable protection on a cable accessory.
Description
Technical field
The present invention relates generally to cable accessory field, relates in particular to a kind of antioxygen adhesion rheological agent cable annex material.
Background technology
Along with developing rapidly of economic construction; improving constantly of people's standard of living; the fast development of all kinds of Infrastructure in town and country; increasing to all kinds of cable accessory demands; therefore the quality that improves constantly cable accessory seems very important; and improve constantly the performance of cable accessory sheath material, and improve the performances such as anticorrosion, wear-resisting, anti-aging, can guarantee the protection effect to cable accessory.
Summary of the invention
The object of the invention is just to provide a kind of antioxygen adhesion rheological agent cable annex material.
The present invention is achieved by the following technical solutions:
A kind of antioxygen adhesion rheological agent cable annex material, it is made up of the raw material of following weight parts:
Low Density Polyethylene 60-80, high density polyethylene(HDPE) 30-40, glyoxal ethyline 2-3, lithium silicate 1-2, precipitated silica 10-12, trisodium phosphate 0.8-1.3, hexanodioic acid propanediol polyester 5-7, quartz glass fibre 3-5, triglycol two 2-ethylhexoate 10-14, antioxidant 4010 1-2,10000 years grey 1-2, polyvinyl alcohol 2-4, fenbendazole 0.6-1, compounded mix 6-10;
Described compounded mix is made up of the raw material of following weight parts:
Montmorillonite powder 20-30, metallocene linear-low density polyethylene 10-16, yttrium oxide 2-3, tri (propylene glycol) diacrylate 2-3, Stockholm tar 1-2, methylisothiazolinone 1-2, flue dust 2-3;
Above-mentioned methylisothiazolinone is joined in 4-6 times of water, add montmorillonite powder, metallocene linear-low density polyethylene, yttrium oxide, at 80-110 DEG C, insulated and stirred 20-30 minute, adds flue dust, mixes, ball milling, add the each raw material of residue, 60-100 rev/min of dispersed with stirring 4-7 minute, dries, grind, be described compounded mix.
A preparation method for antioxygen adhesion rheological agent cable annex material, comprises the following steps:
Above-mentioned quartz glass fibre, precipitated silica, 10000 years ashes, compounded mixs are mixed with hexanodioic acid propanediol polyester, at 80-100 DEG C, be uniformly mixed 3-5 minute, add the each raw material of residue, melt extrude, cooling, granulation, obtains described cable accessory material.
Advantage of the present invention is:
Cable accessory material resistance to deterioration of the present invention is strong, stable mechanical performance, and flame retardant properties is good, and resistant of high or low temperature is good, is easy to produce, and can save production unit and drop into, and is beneficial to efficiency and produces, and product performance are stable, and quality is high, strong and lasting to the protectiveness of cable accessory.
Embodiment
Embodiment 1
A kind of antioxygen adhesion rheological agent cable annex material, it by following weight parts (kilogram) raw material form:
Low Density Polyethylene 60, high density polyethylene(HDPE) 40, glyoxal ethyline 3, lithium silicate 1, precipitated silica 12, trisodium phosphate 1.3, hexanodioic acid propanediol polyester 5, quartz glass fibre 5, triglycol two 2-ethylhexoates 14, antioxidant 4010 2,10000 years ashes 2, polyvinyl alcohol 2, fenbendazole 0.6, compounded mix 10;
Described compounded mix is made up of the raw material of following weight parts:
Montmorillonite powder 30, metallocene linear-low density polyethylene 16, yttrium oxide 3, tri (propylene glycol) diacrylate 2, Stockholm tar 2, methylisothiazolinone 1, flue dust 3;
Above-mentioned methylisothiazolinone is joined in 6 times of water, add montmorillonite powder, metallocene linear-low density polyethylene, yttrium oxide, at 110 DEG C, insulated and stirred 30 minutes, adds flue dust, mixes, ball milling, add the each raw material of residue, 100 revs/min of dispersed with stirring 7 minutes, dry, grind, be described compounded mix.
A preparation method for antioxygen adhesion rheological agent cable annex material, comprises the following steps:
Above-mentioned quartz glass fibre, precipitated silica, 10000 years ashes, compounded mixs are mixed with hexanodioic acid propanediol polyester, be uniformly mixed 5 minutes at 100 DEG C, add the each raw material of residue, melt extrude, cooling, granulation, obtains described cable accessory material.
Tensile strength: >=15MPa;
Elongation at break: >=260%.
Claims (2)
1. an antioxygen adhesion rheological agent cable annex material, is characterized in that what it was made up of the raw material of following weight parts:
Low Density Polyethylene 60-80, high density polyethylene(HDPE) 30-40, glyoxal ethyline 2-3, lithium silicate 1-2, precipitated silica 10-12, trisodium phosphate 0.8-1.3, hexanodioic acid propanediol polyester 5-7, quartz glass fibre 3-5, triglycol two 2-ethylhexoate 10-14, antioxidant 4010 1-2,10000 years grey 1-2, polyvinyl alcohol 2-4, fenbendazole 0.6-1, compounded mix 6-10;
Described compounded mix is made up of the raw material of following weight parts:
Montmorillonite powder 20-30, metallocene linear-low density polyethylene 10-16, yttrium oxide 2-3, tri (propylene glycol) diacrylate 2-3, Stockholm tar 1-2, methylisothiazolinone 1-2, flue dust 2-3;
Above-mentioned methylisothiazolinone is joined in 4-6 times of water, add montmorillonite powder, metallocene linear-low density polyethylene, yttrium oxide, at 80-110 DEG C, insulated and stirred 20-30 minute, adds flue dust, mixes, ball milling, add the each raw material of residue, 60-100 rev/min of dispersed with stirring 4-7 minute, dries, grind, be described compounded mix.
2. a preparation method for antioxygen adhesion rheological agent cable annex material as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned quartz glass fibre, precipitated silica, 10000 years ashes, compounded mixs are mixed with hexanodioic acid propanediol polyester, at 80-100 DEG C, be uniformly mixed 3-5 minute, add the each raw material of residue, melt extrude, cooling, granulation, obtains described cable accessory material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410363624.XA CN104194115A (en) | 2014-07-29 | 2014-07-29 | Antioxygenic and adhesive rheological agent cable accessory material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410363624.XA CN104194115A (en) | 2014-07-29 | 2014-07-29 | Antioxygenic and adhesive rheological agent cable accessory material |
Publications (1)
Publication Number | Publication Date |
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CN104194115A true CN104194115A (en) | 2014-12-10 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201410363624.XA Pending CN104194115A (en) | 2014-07-29 | 2014-07-29 | Antioxygenic and adhesive rheological agent cable accessory material |
Country Status (1)
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CN (1) | CN104194115A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105895215A (en) * | 2016-05-18 | 2016-08-24 | 安徽华通电缆集团有限公司 | Anti-static anti-interference cable |
CN107043482A (en) * | 2016-11-18 | 2017-08-15 | 安徽伊法拉电气有限公司 | Transformer shield material and preparation method thereof |
CN107151358A (en) * | 2017-06-09 | 2017-09-12 | 芜湖航天特种电缆厂股份有限公司 | PVAL/ glass fibre composite cable sealing sheaths and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1251313A (en) * | 1969-02-20 | 1971-10-27 | ||
CN101089037A (en) * | 2007-06-22 | 2007-12-19 | 丁士德 | Antioxidant electrical cable material with blocking rheologic agent |
CN103509232A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Black weather-stress-cracking-resistant polyethylene cable sheath material and preparation method thereof |
CN103937092A (en) * | 2014-03-20 | 2014-07-23 | 安徽春辉仪表线缆集团有限公司 | Thermally conductive and insulating power cable sheath material |
-
2014
- 2014-07-29 CN CN201410363624.XA patent/CN104194115A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1251313A (en) * | 1969-02-20 | 1971-10-27 | ||
CN101089037A (en) * | 2007-06-22 | 2007-12-19 | 丁士德 | Antioxidant electrical cable material with blocking rheologic agent |
CN103509232A (en) * | 2013-08-30 | 2014-01-15 | 安徽天民电气科技有限公司 | Black weather-stress-cracking-resistant polyethylene cable sheath material and preparation method thereof |
CN103937092A (en) * | 2014-03-20 | 2014-07-23 | 安徽春辉仪表线缆集团有限公司 | Thermally conductive and insulating power cable sheath material |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105895215A (en) * | 2016-05-18 | 2016-08-24 | 安徽华通电缆集团有限公司 | Anti-static anti-interference cable |
CN107043482A (en) * | 2016-11-18 | 2017-08-15 | 安徽伊法拉电气有限公司 | Transformer shield material and preparation method thereof |
CN107151358A (en) * | 2017-06-09 | 2017-09-12 | 芜湖航天特种电缆厂股份有限公司 | PVAL/ glass fibre composite cable sealing sheaths and preparation method thereof |
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Application publication date: 20141210 |
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