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CN104072304A - Bamboo charcoal compound microbial fertilizer and production method thereof - Google Patents

Bamboo charcoal compound microbial fertilizer and production method thereof Download PDF

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Publication number
CN104072304A
CN104072304A CN201410343438.XA CN201410343438A CN104072304A CN 104072304 A CN104072304 A CN 104072304A CN 201410343438 A CN201410343438 A CN 201410343438A CN 104072304 A CN104072304 A CN 104072304A
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Prior art keywords
bamboo charcoal
composite microbiological
microbiological fertilizer
charcoal composite
bamboo
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CN201410343438.XA
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Chinese (zh)
Inventor
蒲加军
蒲加兴
刘青海
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SEEK BIO-TECHNOLOGY (SHANGHAI) Co Ltd
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SEEK BIO-TECHNOLOGY (SHANGHAI) Co Ltd
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Publication of CN104072304A publication Critical patent/CN104072304A/en
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Abstract

The invention provides a bamboo charcoal compound microbial fertilizer and a production method thereof and relates to the technical field of microbial fertilizers. The bamboo charcoal compound microbial fertilizer comprises bamboo charcoal powder, humic acid, carbamide, ammonium dihydrogen phosphate, potassium sulfate and biological bacteria, and is powdery or granular. The production method of the bamboo charcoal compound microbial fertilizer comprises the following steps: bamboo charcoal powder, humic acid, carbamide, ammonium dihydrogen phosphate, potassium sulfate and biological bacteria are metered according to the production ratio and then fully mixed through a stirrer to obtain the powdery bamboo charcoal compound microbial fertilizer. The invention provides an environment-friendly solution method for processing leftovers generated in bamboo ware processing, and the obtained bamboo charcoal compound microbial fertilizer has the effects of having complete nutrient elements, adsorbing soil heavy metals and pesticide residues, improving the soil environment, enhancing disease resistance, increasing the yield, improving the crop quality and the like.

Description

A kind of bamboo charcoal composite microbiological fertilizer and production method thereof
Technical field
The present invention relates to microbial fertilizer technical field, be specifically related to a kind of bamboo charcoal composite microbiological fertilizer and production method thereof.
Background technology
Soil consists of mineral substance, organic matter and soil microorganisms etc.Microorganism is to play important effect in the initiation and development of soil, as decomposes organic and mineral substance etc.For a long time, along with using in a large number of chemical fertilizer, although in certain hour and degree, can improve the output of crop, but caused as the soil organism and beneficial microorganism sharply minimizing, soil acidification, harden, a series of ecological environment problems such as fertility decline, Nitrate Accumulation, body eutrophication.
Using when can provide nutrient for crop of Chemical Mixed Fertilizer, also can increase the organic matter of soil.But soil microorganisms but can not get supplementing.The composite microbiological fertilizer growing up on this basis combines organic and inorganic and function microorganism three, can provide required nutrient for crop, can increase again organic matter and the microorganism of soil, is a following important class source of manure.
China's bamboo resource is abundant, have the good reputation of " bamboo kingdom ".A large amount of bamboo product processing enterprises arise, and have produced a large amount of tankage in the bamboo product course of processing, and these tankage are fully utilized resource by pulverizing well-thought-out plan powder or being fired into bamboo charcoal.Wherein, bamboo charcoal is one of charcoal, at industrial circle, be widely used, and in the ascendant in the application of agriculture field.When archaeologist engages in archaeological studies in Brazilian Amazon River basin, find, the soil that has charcoal does not have the soil of charcoal to have higher soil fertility than closing on, and finds that charcoal can be present in soil for a long time, existing more than the 1000 year history having.This discovery has evoked domestic and international scientist and has studied the very big interest that charcoal pollutes, increases soil fertility at repairing environment and slows down the aspects such as atmosphere greenhouse gas concentration rising.
Existing lot of research shows, the charcoal effect such as noxious pollutant in the middle breeding that can improve Soil structure, chessom, preserve moisture and fertility, promotion soil microorganisms and absorption, passivation soil that is manured into soil.
Summary of the invention
The object of this invention is to provide a kind of bamboo charcoal composite microbiological fertilizer and production method thereof, it supports abundant, fixing nitrogen, dissolving phosphor and dissolving potassium, inhibition soil-borne disease of crop, can also secrete growth-promoting factors simultaneously, promotes plant growth, reaches increasing both production and income, improves the object of quality.
In order to solve the existing problem of background technology, the present invention is by the following technical solutions: it comprises following raw materials according: bamboo charcoal powder 10-30 weight part, humic acids 20-50 weight part, urea 3-30 weight part, primary ammonium phosphate 2-20 weight part, potassium sulfate 5-25 weight part, biological inoculum 0.2-1 weight part; Described bamboo charcoal composite microbiological fertilizer is powdery or particulate state.
As preferably, described biological inoculum is one or more in subtilis, bacillus laterosporus, bacillus megaterium, colloid bacillus cereus, azotobacter chroococcum.
As preferably, described biological inoculum is preferably 0.2-1 weight part.
As preferably, described biological inoculum is the mixed bacterium of azotobacter chroococcum, subtilis, bacillus megaterium and colloid bacillus cereus, and the blending ratio in described mixed bacterium is 1-2.5:1-2.5:1-2.5:1.
As preferably, described bamboo charcoal composite microbiological fertilizer also comprises binding agent 5-15 weight part.Binding agent is to play adhesion effect during for granulation, when particulate state fertiliser production, can add.
As preferably, described binding agent is a kind of in attapulgite, clay, kaolin, wilkinite and starch.
As preferably, in described bamboo charcoal composite microbiological fertilizer, living bacteria count >=0.20 is hundred million/gram; Total nutrient (N+P2O5+K2O) in described bamboo charcoal composite microbiological fertilizer is 6.0%-25.0%.
The present invention also provides a kind of production method of bamboo charcoal composite microbiological fertilizer, comprises the preparation section of bamboo charcoal powder, and the method is carried out according to the following steps:
(1) preparation of bamboo charcoal powder: choose that suitable bamboo wood or bamboo waste are broken to cut off, after nature or artificial seasoning, through high temperature carbonization, pulverize through pulverizer again after cooling;
(2) above-mentioned bamboo charcoal powder, humic acids, urea, primary ammonium phosphate, potassium sulfate and biological inoculum are measured according to producting proportion, after adopting stirrer fully to mix, prepare powdery bamboo charcoal composite microbiological fertilizer; Or, above-mentioned bamboo charcoal powder, humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are measured according to producting proportion, after adopting stirrer fully to mix, through granulator granulation, obtain particulate state bamboo charcoal composite microbiological fertilizer.
As preferably, the fineness of the described pulverizing of step (1) is 80-100 order, described dry after the water content of bamboo charcoal be less than or equal to 9%.
As preferably, described biological inoculum is preferably one or more in subtilis, bacillus laterosporus, bacillus megaterium, colloid bacillus cereus, azotobacter chroococcum.
Principle of work of the present invention is: bamboo charcoal is a kind of porous material, has pore texture flourishing, that vary in size, and its surface has the abundant functional groups such as carbonyl, carboxyl simultaneously.Therefore, bamboo charcoal has very strong adsorption; In addition, in bamboo charcoal, contain the multiple elements such as phosphorus, potassium, calcium, magnesium.So bamboo charcoal not only has the Soil structure of improvement, keeps soil from packing together, regulate the soil moisture, the function of preserve moisture and fertility, can also discharge contained mineral element, and the supply of balance nutrient can also be adsorbed the residual of agricultural chemicals, heavy metal and chemical fertilizer in soil simultaneously.In addition, humic acids has fertilizer synergistic, improves soil, stimulates plant growth, improves the functions such as agricultural product quality.So be on the basis of raw material selecting bamboo charcoal, by adding inorganic nutrients (urea, primary ammonium phosphate, potassium sulfate) and humic acids etc., product at rehabilitating soil, improve Soil structure and recover soil vitality in, can also provide comprehensive, balanced nutrition for plant growth.
Bamboo charcoal composite microbiological fertilizer of the present invention combines bamboo charcoal and inorganic nutrients, biological bacteria as bamboo charcoal composite microbiological fertilizer first, on the basis of bamboo charcoal, by adding other nutritive substance and probiotics, reach the function that other bamboo charcoal composite microbiological fertilizers do not have.
Compared with prior art, the present invention has following beneficial effect:
1, for the tankage that produce in the bamboo product course of processing, process solution route new, environmental protection is provided, the while is also for the production of bamboo charcoal composite microbiological fertilizer provides new raw material.
2, compare with traditional fertilizer (chemical fertilizer, Chemical Mixed Fertilizer etc.), the present invention has following advantage: breed at rhizosphere by profitable strain (1), suppresses disease and pest, promotes root of the crop, stem, leaf to grow vigorously; The beneficial functions bacterium (subtilis etc.) of adding can occupy nutrition site and some antibiotics materials of secretion of crop root, can effectively antibacterial and sterilization, also can suppress the erosion of crop root insect.Can secrete the promoting crop growth factor, promote the growth of crop simultaneously.(2) improve soil aggregate, activating soil, promotes soil water-retaining, fertilizer conservation, ventilation, increases soil fertility; Bamboo charcoal has porousness microtexture and larger specific surface area, its surface has the abundant functional groups such as carbonyl, carboxyl simultaneously, give it and there is the special roles such as heavy metal, agricultural chemicals and the chemical fertilizer of absorption in soil be residual, can also improve the loss of soil aeration, water-retentivity, reduction nutrient, play the effect of fertilizer conservation, reduction fertilizer amount simultaneously.(3) promote crop root to absorb the nutritive element in soil, make the required nutrient of plant growth reach the equilibrium of supply and demand; Bamboo charcoal has improves the good growth that soil aeration, preserve moisture and fertility characteristic can promote crop root, and more crop provides balanced nutrient.(4) fixed nitrogen, P and K decomposing, the utilization ratio of raising fertilizer, reduces fertilizer amount; The porousness of bamboo charcoal and the beneficial functions bacterium (azotobacter chroococcum, bacillus megaterium and colloid bacillus cereus) that is interpolation containing multi mineral mass-energy provide the good place of growth and breeding, promote beneficial functions bacterium fixed nitrogen nutrient, decompose, discharge phosphorus, the potassium nutrition of indissoluble in soil, reduce the consumption of chemical fertilizer.(5) organic and inorganic, microorganism triple effect unification, improves crop yield, improves quality; The inorganic nutrients that humic acids etc. are organic, complete and powerful profitable strain, three's combination, when improving soil, finally promotes the good growth of crop, realizes the increasing both production and income of crop, improves quality etc.
Accompanying drawing explanation:
Fig. 1 is bamboo charcoal complex microorganism production technological process of the present invention.
Embodiment:
Following embodiment, is further described foregoing of the present invention.But scope is not limited only to following embodiment.All technology realizing based on foregoing of the present invention all belong to the scope of protection of the invention.
Embodiment 1
Selected suitable bamboo wood or bamboo waste are cut off, after nature or artificial seasoning, through high temperature carbonization, pulverize after cooling through pulverizer again, obtaining fineness is 80-100 object bamboo charcoal powder, and water content is less than or equal to 9%.
The bamboo charcoal powder of acquisition and humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are carried out to accurate feed proportioning according to the proportioning raw materials of table 1.Through stirrer, stir fully and mix, adopt granulator granulation, prepare particulate state bamboo charcoal composite microbiological fertilizer.Described biological inoculum is subtilis.
The production formula of table 1 bamboo charcoal composite microbiological fertilizer
Raw material Bamboo charcoal powder Humic acids Urea Primary ammonium phosphate Potassium sulfate Biological inoculum Attapulgite
Proportioning (kilogram) 280 487 40 30 60 3 100
Embodiment 2
Except following technique, other are as embodiment 1.Described biological inoculum is bacillus laterosporus.
The bamboo charcoal powder of acquisition and humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are carried out to accurate feed proportioning according to the proportioning raw materials of table 2.Through stirrer, stir fully and mix, prepare powdery bamboo charcoal composite microbiological fertilizer.
The production formula of table 2 bamboo charcoal composite microbiological fertilizer
Raw material Bamboo charcoal powder Humic acids Urea Primary ammonium phosphate Potassium sulfate Biological inoculum
Proportioning (kilogram) 200 475 155 67 100 3
Embodiment 3
Except following technique, other are as embodiment 1.
The bamboo charcoal powder of acquisition and humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are carried out to accurate feed proportioning according to the proportioning raw materials of table 4.Biological inoculum in table 4 is that azotobacter chroococcum, bacillus megaterium and colloid bacillus cereus compare mixed strains by 1:1:1 quality.Through stirrer, stir fully and mix, prepare powdery bamboo charcoal composite microbiological fertilizer.
The production formula of table 3 bamboo charcoal composite microbiological fertilizer
Raw material Bamboo charcoal powder Humic acids Urea Primary ammonium phosphate Potassium sulfate Biological inoculum
Proportioning (kilogram) 180 363 220 112 100 3
Embodiment 4
Except following technique, other are as embodiment 2.
The bamboo charcoal powder of acquisition and humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are carried out to accurate feed proportioning according to the proportioning raw materials of table 4.Biological inoculum in table 4 is that bacillus megaterium and colloid bacillus cereus compare mixed strains by 2:1 quality.Through stirrer, stir fully and mix, adopt granulator granulation, prepare particulate state bamboo charcoal composite microbiological fertilizer.
The production formula of table 4 bamboo charcoal composite microbiological fertilizer
Raw material Bamboo charcoal powder Humic acids Urea Primary ammonium phosphate Potassium sulfate Biological inoculum Wilkinite
Proportioning (kilogram) 180 295 220 112 100 3 90
Embodiment 5
Except following technique, other are as embodiment 1.
The proportioning raw materials of the bamboo charcoal powder of acquisition, humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent table 4 is carried out to accurate feed proportioning.Biological inoculum in table 5 be azotobacter chroococcum, subtilis, bacillus megaterium and colloid bacillus cereus by 1:2:1:1 quality, compare mixed strains.Through stirrer, stir fully and mix, adopt granulator granulation, prepare particulate state bamboo charcoal composite microbiological fertilizer.
The production formula of table 5 bamboo charcoal composite microbiological fertilizer
Raw material Bamboo charcoal powder Humic acids Urea Primary ammonium phosphate Potassium sulfate Biological inoculum Starch
Proportioning (kilogram) 115 250 220 120 200 5 90
By the bamboo charcoal composite microbiological fertilizer of embodiment 1-5 according to the requirement of < < bamboo charcoal composite microbiological fertilizer > > industry standard (NY/T 798-2004) and detection method to detecting, detected result is as shown in table 6 and table 7.
The detected result of table 6 bamboo charcoal composite microbiological fertilizer
The detected result of the heavy metal of table 7 bamboo charcoal composite microbiological fertilizer
Project Arsenic (mg/kg) Chromium (mg/kg) Cadmium (mg/kg) Plumbous (mg/kg) Mercury (mg/kg)
Content <50 <70 <5 <65 <1
From the detected result of table 6 and table 7, can find out, embodiment 1,2,3,4 and 5 bamboo charcoal composite microbiological fertilizer reach the < < of Ministry of Agriculture bamboo charcoal composite microbiological fertilizer > > industry standard (NY/T 798-2004) standard, hundred million/gram of living bacteria count >=0.20, total nutrient (N+P205+K2O) >=6.0%, moisture≤30.0%, pH value is 5.5 ~ 8.5.In product, heavy metal content also reaches heavy metal limit technical requirements.
Test example
Capsicum field test effect
One, test materials and method
1, for examination soil
The full nitrogen 162.6mg/kg of the organic 28.2g/kg of pH::7.8
Rapid available phosphorus (P2O5) 27.3mg/kg available potassium (K2O) 157.8mg/kg
2, for studying thing
Crop: capsicum
3, for examination fertilizer
Time bamboo charcoal composite microbiological fertilizer composite fertilizer of section (15-15-15)
Refined organic fertilizer (NPK >=5.0%, organic >=45.0%)
4, test design
Three processing are established in this test, random alignment, in triplicate, each community area 20 m2 (2 m * 10 m).
A: conventional fertilizer application: composite fertilizer (15-15-15) 50kg+ fertilizer 200kg
B: bamboo charcoal composite microbiological fertilizer 80 kg/ mus (particulate state bamboo charcoal composite microbiological fertilizer in embodiment 5, living bacteria count >=0.8 hundred million/g, NPK >=25.0%)
C: without base manure
5, field planting management method
According to test design requirement, base manure evenly spreads fertilizer over the fields in soil before whole ground, and later stage and management are identical with habits fertilization.Observe collection period to each processing, and always add up collection period to output.
Two, test results and analysis
1, the impact on yield of hot pepper
In capsicum collection period, we observe respectively and add up three processing, and result is as shown in table 8:
The situation of table 8 different treatment to yield of hot pepper
As can be seen from Table 8, process the yield of hot pepper of two (using bamboo charcoal composite microbiological fertilizer) apparently higher than processing one and processing three, with processing one (conventional fertilizer application).Compare, volume increase reaches 9.1%, and fertilizer efficiency is remarkable.
Three, conclusion (of pressure testing)
Use bamboo charcoal composite microbiological fertilizer and can significantly promote the growth of pepper plant, when increasing output (9.1%), can improve utilization rate of fertilizer, reduce agricultural chemicals and fertilizer amount, the effects such as quality of raising agricultural-food.

Claims (8)

1. a bamboo charcoal composite microbiological fertilizer, is characterized in that: comprise following raw materials according: bamboo charcoal powder 10-30 weight part, humic acids 20-50 weight part, urea 3-30 weight part, primary ammonium phosphate 2-20 weight part, potassium sulfate 5-25 weight part, biological inoculum 0.2-1 weight part; Described bamboo charcoal composite microbiological fertilizer is powdery or particulate state.
2. the production method of bamboo charcoal composite microbiological fertilizer, comprises and it is characterized in that the preparation section of bamboo charcoal powder: the method is carried out according to the following steps:
(1) preparation of bamboo charcoal powder: choose that suitable bamboo wood or bamboo waste are broken to cut off, after nature or artificial seasoning, through high temperature carbonization, pulverize through pulverizer again after cooling;
(2) above-mentioned bamboo charcoal powder, humic acids, urea, primary ammonium phosphate, potassium sulfate and biological inoculum are measured according to producting proportion, after adopting stirrer fully to mix, prepare powdery bamboo charcoal composite microbiological fertilizer; Or, above-mentioned bamboo charcoal powder, humic acids, urea, primary ammonium phosphate, potassium sulfate, biological inoculum and binding agent are measured according to producting proportion, after adopting stirrer fully to mix, through granulator granulation, obtain particulate state bamboo charcoal composite microbiological fertilizer.
3. a kind of bamboo charcoal composite microbiological fertilizer according to claim 1, is characterized in that, described biological inoculum is one or more in subtilis, bacillus laterosporus, bacillus megaterium, colloid bacillus cereus, azotobacter chroococcum.
4. a kind of bamboo charcoal composite microbiological fertilizer according to claim 1, is characterized in that, described biological inoculum is 0.2-1 weight part.
5. a kind of bamboo charcoal composite microbiological fertilizer according to claim 1, is characterized in that, in described particulate state bamboo charcoal composite microbiological fertilizer, also contains binding agent 5-15 weight part.
6. a kind of bamboo charcoal composite microbiological fertilizer according to claim 4, is characterized in that, described binding agent is a kind of in attapulgite, clay, kaolin, wilkinite and starch.
7. a kind of bamboo charcoal composite microbiological fertilizer according to claim 1, is characterized in that, in described bamboo charcoal composite microbiological fertilizer, living bacteria count >=0.20 is hundred million/gram; Total nutrient in described bamboo charcoal composite microbiological fertilizer is 6.0%-25.0%.
8. the production method of bamboo charcoal composite microbiological fertilizer according to claim 2, is characterized in that, the fineness of the described pulverizing of step (1) is 80-100 order, and the water content of described dry rear bamboo charcoal is less than or equal to 9%.
CN201410343438.XA 2014-07-18 2014-07-18 Bamboo charcoal compound microbial fertilizer and production method thereof Pending CN104072304A (en)

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CN104744161A (en) * 2015-03-18 2015-07-01 黄成博 Long-term nitrogen and phosphorus compound fertilizer containing bamboo charcoal powder
CN105175160A (en) * 2015-10-21 2015-12-23 宋永平 Bamboo charcoal phytoremediation organic fertilizer and preparation method thereof
CN105272582A (en) * 2015-10-21 2016-01-27 宋永平 Highly-efficient bamboo charcoal organic fertilizer and preparation method thereof
CN105330480A (en) * 2015-10-30 2016-02-17 马鞍山市心洲葡萄专业合作社 Moisturizing and soil moisture preserving soil remediation fertilizer
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CN104744161A (en) * 2015-03-18 2015-07-01 黄成博 Long-term nitrogen and phosphorus compound fertilizer containing bamboo charcoal powder
CN105175160A (en) * 2015-10-21 2015-12-23 宋永平 Bamboo charcoal phytoremediation organic fertilizer and preparation method thereof
CN105272582A (en) * 2015-10-21 2016-01-27 宋永平 Highly-efficient bamboo charcoal organic fertilizer and preparation method thereof
CN105330480A (en) * 2015-10-30 2016-02-17 马鞍山市心洲葡萄专业合作社 Moisturizing and soil moisture preserving soil remediation fertilizer
CN105367335B (en) * 2015-11-19 2019-04-16 中国科学院南京土壤研究所 Charcoal base beach saline land improves conditioner and its preparation method and application
CN105367335A (en) * 2015-11-19 2016-03-02 中国科学院南京土壤研究所 Biochar-based coast saline-alkali land improvement conditioner and preparation method and application thereof
CN105399580A (en) * 2015-12-11 2016-03-16 深圳市芭田生态工程股份有限公司 Plant nutrition conditioning fertilizer capable of reducing pesticide residue in soil
CN105948941A (en) * 2016-04-15 2016-09-21 沈阳农业大学 Charcoal-based fertilizer special for buckwheat and preparation method and application of charcoal-based fertilizer
CN106190141A (en) * 2016-07-04 2016-12-07 时科生物科技(上海)有限公司 A kind of bamboo charcoal soil conditioner and preparation method thereof
CN106831124A (en) * 2017-01-20 2017-06-13 姚逍逸 A kind of Ipomoea batatas fertilizer and preparation method thereof
CN107652147A (en) * 2017-11-25 2018-02-02 陈琼燕 Soil-improving fertilizer synergistic regulator and production method thereof
CN107698363A (en) * 2017-11-25 2018-02-16 陈琼燕 Insect-repelling fertilizer synergistic regulator and production method thereof
CN107721658A (en) * 2017-11-25 2018-02-23 陈琼燕 A kind of fertilizer synergistic regulator and its production method
CN110577446A (en) * 2018-06-08 2019-12-17 广东龙飞生物有限公司 Compound microbial fertilizer capable of being stored for long time and preparation method thereof
CN110577431A (en) * 2018-06-08 2019-12-17 广东龙飞生物有限公司 Composite microbial fertilizer capable of adapting to high osmotic pressure and preparation method thereof
CN110041125A (en) * 2019-04-26 2019-07-23 北京日宏科技有限公司 A kind of compound fertilizer and its preparation method and application with absorption heavy metal effect
CN110304961A (en) * 2019-06-21 2019-10-08 李光良 A kind of biological organic chemical fertilizer and preparation method thereof
CN110305671A (en) * 2019-06-25 2019-10-08 江苏里下河地区农业科学研究所 One kind is for facilities vegetable continuous cropping soil biological modification agent and its preparation and application method
CN111410583A (en) * 2020-04-07 2020-07-14 河南省丰夷肥业有限公司 Sweet waxy corn photocatalytic nitrogen fixation biological carbon fertilizer and preparation method thereof
CN111592407A (en) * 2020-06-05 2020-08-28 永春天福兴农业技术有限公司 A kind of microbial soil conditioner and its preparation method and application
CN111670782A (en) * 2020-06-08 2020-09-18 南京农业大学 A kind of compound microorganism cultivation substrate and its application
CN113099939A (en) * 2021-04-29 2021-07-13 西南科技大学 Cultivation method for increasing yield and quality of bamboo shoots by germination of scattered bamboo shoots
CN116789502A (en) * 2023-06-30 2023-09-22 沈阳农业大学 Organic compound fertilizer for promoting continuous cropping peanut to absorb and utilize nitrogen and preparation method thereof
CN116789502B (en) * 2023-06-30 2025-07-25 沈阳农业大学 Organic compound fertilizer for promoting continuous cropping peanut to absorb and utilize nitrogen and preparation method thereof
CN117303979A (en) * 2023-09-28 2023-12-29 淮北师范大学 Preparation method and application of straw carbon-based microbial fertilizer

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Application publication date: 20141001