CN104031463A - Water-based plastic composite printing ink - Google Patents
Water-based plastic composite printing ink Download PDFInfo
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- CN104031463A CN104031463A CN201410313991.9A CN201410313991A CN104031463A CN 104031463 A CN104031463 A CN 104031463A CN 201410313991 A CN201410313991 A CN 201410313991A CN 104031463 A CN104031463 A CN 104031463A
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- water
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- plastic composite
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000004033 plastic Substances 0.000 title claims abstract description 22
- 229920003023 plastic Polymers 0.000 title claims abstract description 22
- 239000002131 composite material Substances 0.000 title claims abstract description 19
- 238000007639 printing Methods 0.000 title abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 53
- 229920005989 resin Polymers 0.000 claims abstract description 53
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000013530 defoamer Substances 0.000 claims abstract description 16
- 239000002270 dispersing agent Substances 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000006229 carbon black Substances 0.000 claims abstract description 4
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 4
- 238000002844 melting Methods 0.000 claims description 19
- 239000006185 dispersion Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 9
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical group CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 claims description 6
- 229960002887 deanol Drugs 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 6
- QNVRIHYSUZMSGM-UHFFFAOYSA-N hexan-2-ol Chemical compound CCCCC(C)O QNVRIHYSUZMSGM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 239000000470 constituent Substances 0.000 claims description 5
- -1 dimethyl siloxane Chemical class 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000004576 sand Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005642 Oleic acid Substances 0.000 claims description 4
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000007046 ethoxylation reaction Methods 0.000 claims description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 4
- IAFBRPFISOTXSO-UHFFFAOYSA-N 2-[[2-chloro-4-[3-chloro-4-[[1-(2,4-dimethylanilino)-1,3-dioxobutan-2-yl]diazenyl]phenyl]phenyl]diazenyl]-n-(2,4-dimethylphenyl)-3-oxobutanamide Chemical compound C=1C=C(C)C=C(C)C=1NC(=O)C(C(=O)C)N=NC(C(=C1)Cl)=CC=C1C(C=C1Cl)=CC=C1N=NC(C(C)=O)C(=O)NC1=CC=C(C)C=C1C IAFBRPFISOTXSO-UHFFFAOYSA-N 0.000 claims description 3
- BSWXAWQTMPECAK-UHFFFAOYSA-N 6,6-diethyloctyl dihydrogen phosphate Chemical compound CCC(CC)(CC)CCCCCOP(O)(O)=O BSWXAWQTMPECAK-UHFFFAOYSA-N 0.000 claims description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 229920002678 cellulose Polymers 0.000 claims description 3
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- VVNRQZDDMYBBJY-UHFFFAOYSA-M sodium 1-[(1-sulfonaphthalen-2-yl)diazenyl]naphthalen-2-olate Chemical compound [Na+].C1=CC=CC2=C(S([O-])(=O)=O)C(N=NC3=C4C=CC=CC4=CC=C3O)=CC=C21 VVNRQZDDMYBBJY-UHFFFAOYSA-M 0.000 claims description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- 239000001488 sodium phosphate Substances 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 3
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 3
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 3
- 229920002907 Guar gum Polymers 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000000665 guar gum Substances 0.000 claims description 2
- 229960002154 guar gum Drugs 0.000 claims description 2
- 235000010417 guar gum Nutrition 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 229920001522 polyglycol ester Polymers 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- OSNILPMOSNGHLC-UHFFFAOYSA-N 1-[4-methoxy-3-(piperidin-1-ylmethyl)phenyl]ethanone Chemical compound COC1=CC=C(C(C)=O)C=C1CN1CCCCC1 OSNILPMOSNGHLC-UHFFFAOYSA-N 0.000 abstract 1
- SGHZXLIDFTYFHQ-UHFFFAOYSA-L Brilliant Blue Chemical compound [Na+].[Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C(=CC=CC=2)S([O-])(=O)=O)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 SGHZXLIDFTYFHQ-UHFFFAOYSA-L 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 1
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007647 flexography Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 235000014101 wine Nutrition 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to water-based plastic composite printing ink. The water-based plastic composite printing ink comprises, by weight, 30-60 percent of pigment, 10-20 percent of vehicle, 10-30 percent of aminating agent, 5-10 percent of dispersing agent, 5-10 percent of defoamer and the balance solvent. The pigment is one or more of bright red, lithol scarlet, benzidine yellow, brilliant blue, carbon black and titanium dioxide. The vehicle is one or more of resin 315 or resin 310 or resin M04 or resin 317 or resin 54 or resin Z604 or resin 36 or resin 81or resin 73 or resin 14. The aminating agent is dmae or ammonia. The printing ink is very friendly to the environment, capable of being used on various plastics according to demands, good in bonding effect, bright in color, convenient to use in printing and high in peeling strength and can meet various printing demands.
Description
Technical field
The present invention relates to a kind of water-based plastic composite print ink, belong to printing technology.
Background technology
In printing-ink technology; people rest on the aspect such as color and rheological property mostly to the concern of ink, and current environmental protection cry is more and more higher, and printing trader wants strict implement environmental protection standard aborning; therefore, the links on printing raw material supply chain has also produced chain reaction.The VOC discharging for eliminating printing ink solvent system, printing trader starts to seek new ink product, a kind of novel environment friendly printing material that water color ink arises at the historic moment just, be specially adapted to the strict wrapped products of health conditions requiring such as cigarette, wine, food, beverage, medicine, toy for children, having significant growth potential at specific packaging market, is the new direction of ink industry development.
The feature of Water-based plastic printing ink is nontoxic, tasteless, is applicable to various types of intaglio plates and wheel and turns flexography process, and transitivity and attachment fastness are good; Water color ink is easy to use, and thinner is the aqueous solution of water and alcohol, and printing ink layer glossiness is high, has the good transparency, water tolerance and weathering resistance.
Summary of the invention
The object of the present invention is to provide a kind of water-based plastic composite print ink, to prepare the good water-based plastic composite print of quality ink, there is the good feature of environmental protection, be convenient to printing and use.
To achieve these goals, technical scheme of the present invention is as follows.
A kind of water-based plastic composite print ink, by pigment, low-melting ink vehicle, aminating agent, dispersion agent, defoamer, solvent composition, above-mentioned each constituent mass per-cent is respectively pigment and accounts for 30～60%, low-melting ink vehicle accounts for 10～20%, aminating agent accounts for 10～30%, dispersion agent accounts for 5～10%, and defoamer accounts for 5～10%, and surplus is solvent.
Further, described pigment is one or several in bright red, Lithol Red, diarylide yellow, phthalocyanine blue, carbon black, titanium dioxide.
Further, described low-melting ink vehicle be in 315 resins, 310 resins, M04 resin, 317 resins, 54 resins, Z604 resin, 36 resins, 81 resins, 73 resins or 14 resins one or several.
Further, described aminating agent is dimethylaminoethanol or ammoniacal liquor, and pH value is 7.5～10.5.
Further, described dispersion agent is inorganic dispersant or organic dispersing agent, described inorganic dispersant be in water glass, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 or trisodium phosphate one or several, described organic dispersing agent is one or several in triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol, derivatived cellulose, polyacrylamide, guar gum or fatty acid polyglycol ester.
Further, described defoamer is one or several in butyl acrylate, the different monooctyl ester of toxilic acid, different hexadecanol, ethoxylation dimethyl siloxane, oleic acid, Styrene oxide 98min..
Further, described solvent is water or Virahol.
Further, above-mentioned water color ink compound method is, accurately weighs each raw material by formula, sends into sand mill dispersed after stirring, until fineness is qualified, progressively adds water and is ground to the fineness requirement that touches the mark, and adds emulsion and gets final product discharging.
In above-mentioned ink, low-melting ink vehicle main component is resin, and it is the heart of water color ink.The performances such as viscosity, glossiness, water resisting property, drying property, mobility, transitivity and the anchorage of ink are mainly determined by low-melting ink vehicle, the acid resistance of ink, the performance such as alkali resistance and resistance to solvent also has certain relation with low-melting ink vehicle, thereby the developing focus of ink is the research and development of ink vehicle.Selecting the important indicator of water soluble resin is molecular weight (Mw) and acid number (AV), and wherein important with molecular weight.There is highly filled low-molecular-weight resin, can make ink there is higher gloss degree, reduce moisture evaporation, accelerate rate of drying.High acid value resin solubility in ink is high, can improve the wettability of pigment, but can reduce wet abrasive resistance.Low acid value resin alkali resistance and resistance to detergents are good, but the dispersiveness of pigment and solubility are poor.Select the low-melting ink vehicle of acrylic resin as water color ink, ink all has significant advantage at aspects such as glossiness, weathering resistance, thermotolerance, water tolerance, chemical resistant properties and stain resistances, in the time of direct dispersing and dissolving or synthetic macromolecule emulsion, also there is good performance.In the present invention, adopt the modified acrylic ester resins such as esters of acrylic acid alkali soluble resins and maleic anhydride to use as ink film-forming resin.Why polymkeric substance has solubility, is that the carboxyl salify in amine and on side chain has water-soluble because contain hydrophilic functional groups (O-,-COOH ,-NH2 ,-OH) in resin.Adopting salify amination method is the conventional method of polymer waterborneization, containing the polymer of a certain amount of acidic functionality (carboxyl, sulfonic group, acid anhydrides), is 30～150 o'clock at acid number, uses in amine and salt, can form polymer waterborne system.
The aminating agent of above-mentioned ink: the consumption of amine and the kind film forming properties after to resin aquation and aquation has considerable influence, requires aminating agent volatilizable, good stability, smell is less.Extent of hydration is higher, and the viscosity of ink is larger, reach after the requirement of water-soluble and stability in storage, and further aquation to 100%, general pH value is controlled at 7.5～8.5 for good.At several amine for resin aquation, dry best using ammoniacal liquor as aminating agent, but ammoniacal liquor easily volatilizees, and causes resin liquid stability bad.Consider from viscosity and glossiness, most suitable with dimethylaminoethanol, but consider from cost and performance, dimethylaminoethanol price is higher, can select ammoniacal liquor to add a small amount of AMP, to make up the unstable volatile deficiency of ammoniacal liquor, also improve the color developing of ink simultaneously.
The ink of above-mentioned preparation carries out intaglio printing compound bag on BOPP film, when printing, can pass through Infrared Heating or electronic dehydration, and print speed reaches 20～80 ms/min, and stripping strength is more than 2.8N/cm.
This beneficial effect of the invention is: printing-ink of the present invention has good environment-friendly type, can use as required on various plastics, and cohesiveness is good, bright-colored, prints easy to usely, and stripping strength is high, can meet various printing needs.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is described, to better understand the present invention.
embodiment 1
Water-based plastic composite print ink in the present embodiment, by pigment, low-melting ink vehicle, aminating agent, dispersion agent, defoamer, solvent composition, above-mentioned each constituent mass per-cent is respectively pigment and accounts for 30%, low-melting ink vehicle accounts for 10%, and aminating agent accounts for 10%, and dispersion agent accounts for 5%, defoamer accounts for 5%, and surplus is solvent.Described pigment is bright red, Lithol Red mixture.Described low-melting ink vehicle is 315 resins, 310 resins, M04 resin compound.Described aminating agent is dimethylaminoethanol, and pH value is 7.5.Described dispersion agent is inorganic dispersant, and described inorganic dispersant is water glass, tripoly phosphate sodium STPP mixture.Described defoamer is butyl acrylate, the different monooctyl ester of toxilic acid, different hexadecanol mixture.Described solvent is water.Above-mentioned water color ink compound method is, accurately weighs each raw material by formula, sends into sand mill dispersed after stirring, until fineness is qualified, progressively adds water and is ground to the fineness requirement that touches the mark, and adds emulsion and gets final product discharging.
embodiment 2
Water-based plastic composite print ink in the present embodiment, by pigment, low-melting ink vehicle, aminating agent, dispersion agent, defoamer, solvent composition, above-mentioned each constituent mass per-cent is respectively pigment and accounts for 60%, low-melting ink vehicle accounts for 10%, and aminating agent accounts for 10%, and dispersion agent accounts for 5%, defoamer accounts for 10%, and surplus is solvent.Described pigment is diarylide yellow, phthalocyanine blue mixture.Described low-melting ink vehicle is 317 resins, 54 resins, Z604 resin compound.Described aminating agent is ammoniacal liquor, and pH value is 10.Described dispersion agent is organic dispersing agent, and described organic dispersing agent is triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol, derivatived cellulose mixture.Described defoamer is ethoxylation dimethyl siloxane, oleic acid, Styrene oxide 98min. mixture.Described solvent is Virahol.Above-mentioned water color ink compound method is, accurately weighs each raw material by formula, sends into sand mill dispersed after stirring, until fineness is qualified, progressively adds water and is ground to the fineness requirement that touches the mark, and adds emulsion and gets final product discharging.
embodiment 3
Water-based plastic composite print ink in the present embodiment, by pigment, low-melting ink vehicle, aminating agent, dispersion agent, defoamer, solvent composition, above-mentioned each constituent mass per-cent is respectively pigment and accounts for 40%, low-melting ink vehicle accounts for 15%, and aminating agent accounts for 15%, and dispersion agent accounts for 10%, defoamer accounts for 10%, and surplus is solvent.Described pigment is carbon black, titanium dioxide mixture.Described low-melting ink vehicle is Z604 resin, 36 resins, 81 resins, 73 resins, 14 resin compounds.Described aminating agent is dimethylaminoethanol, and pH value is 9.Described dispersion agent is inorganic dispersant, and described inorganic dispersant is Sodium hexametaphosphate 99, trisodium phosphate mixture.Described defoamer is different hexadecanol, ethoxylation dimethyl siloxane, oleic acid, Styrene oxide 98min. mixture.Described solvent is Virahol.Above-mentioned water color ink compound method is, accurately weighs each raw material by formula, sends into sand mill dispersed after stirring, until fineness is qualified, progressively adds water and is ground to the fineness requirement that touches the mark, and adds emulsion and gets final product discharging.
The above is the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention; can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (8)
1. a water-based plastic composite print ink, it is characterized in that: this ink is by pigment, low-melting ink vehicle, aminating agent, dispersion agent, defoamer, solvent composition, above-mentioned each constituent mass per-cent is respectively pigment and accounts for 30～60%, low-melting ink vehicle accounts for 10～20%, aminating agent accounts for 10～30%, dispersion agent accounts for 5～10%, and defoamer accounts for 5～10%, and surplus is solvent.
2. water-based plastic composite print ink according to claim 1, is characterized in that: described pigment is one or several in bright red, Lithol Red, diarylide yellow, phthalocyanine blue, carbon black, titanium dioxide.
3. water-based plastic composite print ink according to claim 1, is characterized in that: described low-melting ink vehicle be in 315 resins, 310 resins, M04 resin, 317 resins, 54 resins, Z604 resin, 36 resins, 81 resins, 73 resins or 14 resins one or several.
4. water-based plastic composite print ink according to claim 1, is characterized in that: described aminating agent is dimethylaminoethanol or ammoniacal liquor, pH value is 7.5～10.5.
5. water-based plastic composite print ink according to claim 1, it is characterized in that: described dispersion agent is inorganic dispersant or organic dispersing agent, described inorganic dispersant be in water glass, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 or trisodium phosphate one or several, described organic dispersing agent is one or several in triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol, derivatived cellulose, polyacrylamide, guar gum or fatty acid polyglycol ester.
6. water-based plastic composite print ink according to claim 1, is characterized in that: described defoamer is one or several in butyl acrylate, the different monooctyl ester of toxilic acid, different hexadecanol, ethoxylation dimethyl siloxane, oleic acid, Styrene oxide 98min..
7. water-based plastic composite print ink according to claim 1, is characterized in that: described solvent is water or Virahol.
8. according to the water-based plastic composite print ink described in claim 1 to 7, it is characterized in that: above-mentioned water color ink compound method is, accurately weigh each raw material by formula, after stirring, send into sand mill dispersed, until fineness is qualified, progressively add water and be ground to the fineness requirement that touches the mark, add emulsion and get final product discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410313991.9A CN104031463A (en) | 2014-07-03 | 2014-07-03 | Water-based plastic composite printing ink |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410313991.9A CN104031463A (en) | 2014-07-03 | 2014-07-03 | Water-based plastic composite printing ink |
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| CN104031463A true CN104031463A (en) | 2014-09-10 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263076A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly coca-red double-PE ink and preparation method thereof |
| CN104403418A (en) * | 2014-11-26 | 2015-03-11 | 成都锦汇科技有限公司 | Ink for ballpoint pen |
| CN105368147A (en) * | 2015-12-22 | 2016-03-02 | 四川迈科睿新材料有限责任公司 | Waterborne ink for PP (polypropylene) film and preparation method of waterborne ink |
| CN107828278A (en) * | 2017-11-09 | 2018-03-23 | 苏州同里印刷科技股份有限公司 | A kind of packing box printing environment-friendly type aqueous ink and its production technology |
| CN109476403A (en) * | 2016-07-25 | 2019-03-15 | 塞鲁贝股份公司 | water degradable bag |
| CN111995904A (en) * | 2020-09-23 | 2020-11-27 | 昆山飞林彩印包装有限公司 | Water-based environment-friendly ink and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104263076A (en) * | 2014-10-24 | 2015-01-07 | 成都普瑞斯特新材料有限公司 | Environment-friendly coca-red double-PE ink and preparation method thereof |
| CN104263076B (en) * | 2014-10-24 | 2015-12-30 | 成都普瑞斯特新材料有限公司 | Laughable red pair of PE ink of environment-friendly type and preparation method thereof |
| CN104403418A (en) * | 2014-11-26 | 2015-03-11 | 成都锦汇科技有限公司 | Ink for ballpoint pen |
| CN105368147A (en) * | 2015-12-22 | 2016-03-02 | 四川迈科睿新材料有限责任公司 | Waterborne ink for PP (polypropylene) film and preparation method of waterborne ink |
| CN109476403A (en) * | 2016-07-25 | 2019-03-15 | 塞鲁贝股份公司 | water degradable bag |
| CN107828278A (en) * | 2017-11-09 | 2018-03-23 | 苏州同里印刷科技股份有限公司 | A kind of packing box printing environment-friendly type aqueous ink and its production technology |
| CN111995904A (en) * | 2020-09-23 | 2020-11-27 | 昆山飞林彩印包装有限公司 | Water-based environment-friendly ink and preparation method thereof |
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