CN102952431A - Cigarette tipping paper water-based ink and preparation method - Google Patents
Cigarette tipping paper water-based ink and preparation method Download PDFInfo
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Abstract
The invention discloses cigarette tipping paper water-based ink and a preparation method, belonging to the technical field of water-based ink. The water-based ink is characterized by consisting of the following raw materials in parts by weight: 50-60 parts of water-based emulsion resin oil, 10-20 parts of iron oxide pigment, 10-20 parts of de-ionized water and 0.5-1.0 part of one or more of auxiliary agents of defoaming agent, anti-sedimentation agent, leveling agent, wetting agent, antibacterial agent, wetting dispersant and surface tension agent. The cigarette tipping paper water-based ink has the advantages of small fineness, high drying speed, high consistency, low viscosity, good dispersion stability, no setting precipitate, no agglomeration, no toxicity, no residual peculiar smell, good wet leveling property, good color development, no brittle fracture at a low temperature, no edge folding during drying, good water resistance, full and clear print, stable color, smooth and glossy surface, good storage stability and wide application range to printing raw paper and printing speed; and the cigarette tipping paper water-based ink can be produced by the method.
Description
Technical field
The invention belongs to the water color ink technical field, be specifically related to a kind of cigarette cork paper water color ink.
Background technology
Cork paper is commonly called as tipping paper, is the important materials of producing cigarette, is a kind of dedicated paper that cigarette filter tip and cigarette are linked together.For satisfying the requirements such as cigarette sign, rich colors, tipping paper usually will print, print the operations such as aftertreatment and become final tipping paper product.The printing of tipping paper is generally intaglio plate, flexographic printing, and take intaglio printing as main, its printing ink is at present take solvent type photogravure printing ink as main.In recent years, along with people's safety, environmental protection, healthy consciousness are constantly strengthened, a large amount of volatile organic solvents that relate in a large amount of printing-inks that use, the printing process and the dissolvent residual in the printed matter etc. have brought larger impact to environment and people's physical and mental health.Cigarette tipping paper, except the impact of volatile organic matter, filter tip contacts the harmful heavy metal composition in the tipping paper during owing to smoking with the direct of lip, such as arsenic, lead, mercury, chromium, every, nickel etc., can enter in the human body by the oral cavity and directly have influence on human consumer's health.Therefore, country rises to suitable height to cigarette with the considering of safety and sanitation of cork paper.Countries tobacco general bureau has put into effect the mandatory industry standard of sanitary index of limiting the quantity of about tobacco package cigarette tipping paper dissolvent residual and inorganic elements: YC171-2008 " cigarette tipping paper " in 2007, and corresponding detection method has been formulated in the enforcement of limit standard for this reason.
Why the safety and sanitation index of cigarette tipping paper is more and more so strict, trace it to its cause, mainly be in the tobacco bale dress, tipping paper is the part of cigarette, has preferably ventilation property, directly contact with human body again during suction, harmful inorganic elements and residual volatile organic compounds can directly have influence on the healthy and safe of the suction quality of cigarette and human consumer in the tipping paper.The principal element that affects in the tipping paper harmful inorganic elements and residual volatile organic compounds is printing-ink.Various pigment in the printing-ink are directly to cause the tipping paper product to have the important sources of harmful inorganic elements hidden danger; The organic solvent that adds during the dilution of employed and printing ink in the printing ink then is the important sources that there is residual volatile organic compounds composition in tipping paper, and cork paper will contact with the human body degree of depth, so its hygienic requirements is also relatively high.At present, the most traditional cork paper coating of China are pure dissolubilities, mostly contain organic solvent, and some is not only poisonous to human body for these organic solvents, and also can cause environmental pollution and the wasting of resources after the volatilization.Along with the increase of people to the demand of environment-friendly type printing ink, the environmental protectionization of cork paper printing-ink will be inevitable.At present a lot of printing factories have all invested water color ink to sight, and relevant enterprise and unit have proposed the technical scheme factory of many improvement " cork paper printing-ink " for this reason.Such as the patent No.: 200810233722.6, notification number: CN101429364 " environment friendly bacteriostatic water color ink for tipping paper "; The patent No.: 200910222386.X, notification number: CN 101718061A " preparation method of the cork paper of water color ink "; Number of patent application: 200910064249.8, publication number: CN 101812253A " a kind of cigarette tipping paper coated printing white printing China ink and production technique thereof " etc.But the above-mentioned patent No.: 200810233722.6 technical schemes also can only reduce arsenic in the printing, mercury, lead content 50%.The patent No.: the 200910222386.X technical scheme has description to water color ink and end.Number of patent application: 200910064249.8 technical schemes only are described coated printing white printing ink, and the cork paper with decorative effect be there is no description with the color water color ink.In addition, take a broad view of China's cigarette cork paper printing-ink, also there is following subject matter at present in the application of water color ink aspect cork paper:
(1) paper distortion is excessive.Because used a large amount of water-baseds in the water color ink, this has just caused paper excessive to the absorption of moisture, causes the distortion of paper comparatively serious.Also have, because paper repeatedly absorbs a large amount of moisture, cause the tensile strength of paper to reduce, paper becomes fragile, and affects later cigarette.
(2) rate of drying is too slow.The rate of drying of water color ink is excessively slow, affects print speed and following process, also may be that the phenomenons such as photographic fog and scumming appear in intaglio plate.
(3) smell is larger.Smell in the water color ink mainly comes from the Ammonia material that uses in the resin ammonifying process.
(4) also there are some problems in water resisting property and moisture-resistant intensity index aspect.
Above-mentioned these factors have hindered the application of water color ink on cork paper.Therefore, on the technical foundation of existing water color ink, according to the characteristics of cork paper, cigarette tipping paper printing ink is carried out intensive research, the factor of harmful inorganic elements and residual volatile organic compounds in the strict control effect tipping paper, thereby ensure the quality of tipping paper product, develop and have more safety, health, healthy, be fit to the cigarette cork paper water color ink of cork paper printing, and carry out industrialization production, with satisfying the market and environmental protection in the urgent need to, be very necessary.
Summary of the invention
The objective of the invention is to provide a kind of cigarette cork paper water color ink and making method, this cigarette is little with cork paper water color ink fineness, and rate of drying is fast, and denseness is high, viscosity is low, dispersion stabilization is good, and is nontoxic without condensing without scleroma property precipitation, the noresidue peculiar smell; Have good moistening levelling property, color developing is good, not embrittlement of low temperature, when dry not crimping, water-tolerant, trace is full, clear, color and luster stable, surface smoothing gloss, excellent storage stability, to the wide accommodation of printing body paper and print speed; The method can be produced above-mentioned cigarette cork paper water color ink.
Above-mentioned goal of the invention is achieved through the following technical solutions, a kind of cigarette cork paper water color ink, and its main points are to be comprised of the raw material by following composition by weight proportioning:
10～20 parts+defoamer of 10～20 parts+deionized water of 50～60 parts+iron oxide pigment of aqueous emulsifying sylvic oil, anti-sedimentation agent, flow agent, wetting agent, antiseptic-germicide, 0. 5～1.0 parts of one or more in wetting dispersing agent, the surface tension agent aid.
To be described aqueous emulsifying sylvic oil form by the component of following weight proportion for above-mentioned cigarette cork paper water color ink, one of its technical scheme:
3～6 parts of 2～5 parts+AMP-95 of 30～45 parts+methyl ethyl-amine of 2～5 parts+deionized water of 45～55 parts+food grade of aqueous synthetic-resin ethanol.
To be described aqueous synthetic-resin form by the component of following weight proportion for above-mentioned cigarette cork paper water color ink, one of its technical scheme:
1～3 part of 10～20 parts+linking agent of 20～30 parts+season of 30～40 parts+soybean oil of water-borne acrylic resin, 0.01～0.5 part+rosin of 8～15 parts+magnesium oxide of 1～6 part+MALEIC ANHYDRIDE of luxuriant tetrol.
Above-mentioned cigarette cork paper water color ink, one of its technical scheme are that described linking agent is aziridine connection agent SaC-100, and it is the potent type linking agent of a kind of normal-temperature reaction, a kind of polyfunctional aziridine linking agent of 100% active quantities; Pressing 1-3% adds in the water-borne acrylic resin emulsion,, chemicals-resistant water-fast to it, sticking power high temperature resistant and on special substrate all improve significantly, can increase the black phenomenon of dragging that printing ink produces to the sticking power of different base, when avoiding printing, strengthen printing ink water resistant and chemical moral character, accelerate set time.
Above-mentioned cigarette cork paper water color ink, one of its technical scheme are that described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
A kind of method for preparing cigarette usefulness cork paper water color ink, its main points are:
A, aqueous synthetic-resin are made: the raw material of pressing following composition by weight proportioning: 1～3 part of 10～20 parts+linking agent of 20～30 parts+season of 30～40 parts+soybean oil of water-borne acrylic resin, 0.01～0.5 part+rosin of 8～15 parts+magnesium oxide of 1～6 part+MALEIC ANHYDRIDE of luxuriant tetrol, carry out stirring reaction in reactor, temperature of reaction is 275～285 ℃;
B, aqueous emulsifying sylvic oil make: by the raw material of following composition by weight proportioning: 3 0～4 5 parts of 2～5 parts+deionized waters of 45～55 parts+food grade of aqueous synthetic-resin ethanol+_ 3～6 parts of 2～5 parts+AMP-95 of methyl ethyl-amine, in reactor, carry out stirring reaction, temperature of reaction is 70～80 ℃, tests after the emulsification;
C, cigarette are made of the cork paper water color ink: the raw material of pressing following composition by weight proportioning: 10～20 parts+defoamer of 10～20 parts+deionized water of 50～60 parts+iron oxide pigment of aqueous emulsifying sylvic oil, anti-sedimentation agent, flow agent, wetting agent, antiseptic-germicide, 0. 5～1.0 parts of in wetting dispersing agent, the surface tension agent aid one or more, disperse, grind, filter, check, get at last cigarette cork paper water color ink.
The above-mentioned method for preparing cigarette usefulness cork paper water color ink, one of its technical scheme are that described linking agent is aziridine connection agent SaC-100.
The above-mentioned method for preparing cigarette usefulness cork paper water color ink, one of its technical scheme is that described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
Beneficial effect of the present invention: solved a following difficult problem:
1, reasonable selection the linking agent of water-borne acrylic resin as main water-base resin, the water soluble resin preparation is one of key of water color ink, also is the important factor of the physics and chemistry character that determines that the printing ink film forming is later.Water soluble resin comprises from water water soluble resin and buck soluble resin.Water soluble resin refers to contain-resin of OH, the buck soluble resin be contain-COOH ,-the NH2 resin.What the present invention adopted is the buck soluble resin, by the hydrophilic radical to macromolecular chain introducing q.s, as-COOH ,-NH2 etc., make resin reach water miscible effect.To be divided into water dilution type low-melting ink vehicle be that caustic solubility low-melting ink vehicle and water-dispersion low-melting ink vehicle are latex to low-melting ink vehicle in the water color ink.The kind of resin that can be used as water dilution low-melting ink vehicle is a lot, such as shellac, maleic acid resin, maleic acid resin Modified Shell-lac for Cuprous Surface Anticorrosion, urethane resin, water-compatible amino resin and water soluble alkene acid resin etc.Compare by the simultaneous test to various resin properties, each performance of water-borne acrylic resin all is better than other water-base resin, so the present invention has selected water-borne acrylic resin as main water-base resin.
2, reasonable selection pure water as main solvent, water also is an important solvent in the printing ink industry, because it has preferably environmental-protecting performance, so that it has preferably application prospect in printing ink.Say from the strict sense, relatively high for the requirement of the water that is used for water color ink.If water hardness is excessive, in this alkaline system of water color ink, be easy to make printing ink to produce precipitation.This storage for printing ink is very unfavorable, so, the pure water that cigarette of the present invention has selected the process deionization to process with cork paper water color ink product.
3, reasonable selection ethanol as main solubility promoter, in the manufacturing processed of water color ink binder, except using main solvent water, in order to prepare the better binder of performance, also to add some solubility promoters.The selection of solubility promoter is extremely important, and selected solubility promoter must can dissolve employed resin, amine and salt, can mix with the water arbitrary proportion.Along with the printing ink industrial expansion, day by day variation of the type of the employed polymkeric substance of printing ink and combination selects suitable solvent to become quite important, namely will consider the factor of two aspects, the firstth, solvent is to the dissolving power of high molecular polymer, and the secondth, the volatilization ability of solvent from printing ink.In order to satisfy above-mentioned requirements, the present invention adopts and has selected food grade ethanol as solubility promoter.Because the organic solvent that uses in water color ink can be regulated the drying property of printing ink.For the cork paper printing-ink, what cork paper adopted mostly at present is intaglio printing, and the drying mode of printing ink is mainly also dry by volatilizing.Can regulate the rate of drying of printing ink so select suitable organic solvent.Because the evaporation rate of water is slow, therefore, when accelerating ink setting, can select faster organic solvent of evaporation rate ratio.Organic solvent at present commonly used has methyl alcohol, ethanol, Virahol, isopropylcarbinol, toluene, acetone etc.Methyl alcohol has preferably dissolving power to resin, also has faster rate of drying simultaneously.But because the rate of drying of methyl alcohol is too fast, make solvent dry too fast on printing press, and then so that printing ink when printing press prints, ink viscosity rises too fast, the problems such as heap version may occur, add that the volatilization of methyl alcohol also is disadvantageous to human body, examine in addition the nontoxicity of filter cork paper water color ink, so the present invention has selected food grade ethanol as solubility promoter.
4, reasonable selection the AMP-95 brute force be divided into powder as neutralizing agent, when utilizing alkali soluble resins as waterborne binder, need to add an amount of neutralizing agent.The effect of neutralizing agent is the amine salt that the resin anion(R.A) that will contain hydroxyl becomes solubility.Neutralizing agent commonly used has ammoniacal liquor, monoethanolamine, 2-amino-2-methyl-1-propanol, trolamine etc.Because ammoniacal liquor has evaporation rate preferably, cheap price and good water tolerance, becomes water color ink and uses the most general neutralizing agent.But for cigarette cork paper water color ink, the more important thing is and will consider safety, and ammoniacal liquor has larger smell, the present invention considers from composite factor, selects AMP-95 as neutralizing agent.Used and also had some other function behind the AMP-95 neutralizing agent:
(1) is conducive to improve the glossiness of water color ink, because AMP-95 is that a kind of brute force is divided into powder, finally when ink setting, can from film, vapors away.This means that it can not remain in films, thereby can not affect gloss.In addition, use after the AMP-95, make pigment-dispersing more abundant, also have in improving glossiness.
(2) be conducive to reduce corrosion, AMP-95 can effectively keep water color ink alkaline pH value, thereby effectively suppresses the seam of barrel cage and the corrosion of edge, and AMP-95 also helps to reduce simultaneously steel and ironing surface sudden strain of a muscle rust in addition.
(3) help to produce low smell coating along with the rules that vOc is discharged are more and more stricter, the user likes using the water color ink of low smell, and AMP-95 is the best substitute products of ammoniacal liquor.
(4) be conducive to reduce the coating cost because AMP-95 is a kind of multifunctional assistant, so can when reducing cost, make the performance of water color ink still can be equivalent to even surpass the water color ink that does not add AMP-95.
5, reasonable selection iron oxide pigment as the pigment of cigarette with the cork paper water color ink, pigment is the present-color material of printing ink, it is directly connected to the stability of quality of colour and the color of printing ink.When selecting water color ink pigment, what at first must consider is the form and aspect of pigment, secondly also to consider be pigment gloss, chemical resistance, easily disperse and with the problems such as intermiscibility of other components.According to the colour characteristics of pigment and physics, chemical property, that the present invention selects is red, yellow, Black Rouge pigment series is as the pigment of cigarette with the cork paper water color ink, and iron oxide pigment has good weathering resistance, resistance to acids and bases, light fastness.These excellent performances are not that other mineral dyes or pigment dyestuff can have concurrently.That U.S. Lockwood ROCKWOOD is red, yellow, Black Rouge pigment and the present invention adopts, so can satisfy cigarette with the requirement of cork paper water color ink to the low remnants of heavy metal.
6, solved the problem of pH value stabilization, the low printing ink caking that easily causes of the pH value of water color ink, pH value height then its viscosity is then relatively low.General water color ink often will detect the variation of water color ink pH value in printing process in the past, when the pH value is lower than 7, should add an amount of pH value stabilization agent, thereby made water color ink keep good printing state.The pH value of water color ink is take neutrality as standard, and the pH value is adjusted at 8 o'clock, its flowability, glossiness reaches optimum regime, but in printing process because the volatilization of amine solvent, ink viscosity can increase rapidly, glossiness descends, and flowability is reported to the leadship after accomplishing a task, so that a large amount of substandard products can occur.The at present adjustment of water color ink pH value mainly is to add alcohols and amine solvent, such as monoethanolamine and ammoniacal liquor etc.The present invention has adopted the AMP-95 brute force to be divided into powder in order to reach the purpose of stablizing the pH value.When the aqueous emulsifying sylvic oil is made, AMP-95 and common anionic dispersing agents are mixed use, its dispersion effect is much better more than being used alone dispersion agent.Thereby guaranteed that cigarette is stable with the extremely excellent PH of cork paper water color ink.
7, adopt three-step approach to produce synthesis technique, optimized traditional water color ink production technique.The production technique of water color ink original research is: with water soluble acrylic resin 25%-35%, water 15%-25%, ethanol 50%-15%, triethylamine 5%-10%, pigment 10%-30% and auxiliary agent 1%-3% directly mix, stirring, dispersion and grinding produce water color ink.At present domestic enterprise's water color ink production technique is to adopt two step method mostly: namely: the first step is for grinding the preparation mill base: with water soluble resin, pigment, auxiliary agent and the mixing such as solvent such as water, by the high speed dispersor dispersed with stirring, grind to form standby color paste.Second step is preparation printing ink: standby color paste, auxiliary agent and solvent such as water etc. are mixed, produce water color ink by grinding distribution.Adopt two step method, product in use always exists tinting strength and attachment fastness not good, the disadvantages such as low in glossiness.And the present invention is by studying for a long period of time and testing, adopted first synthetic water-base resin linking agent, then synthetic water-based emulsifying resins oil, the resynthesis cigarette has guaranteed the advance of each performance index such as paper printing use ink product tinting strength, sticking power and glossiness with the three-step production process technology of cork paper water color ink product.
Embodiment
Below be the embodiment that the present invention-cigarette is used the cork paper water color ink, it is comprised of the raw material by following composition by weight proportioning:
0. 3 parts of 0. 5 parts+anti-sedimentation agent of 15 parts+deionized water of the 55 parts+U.S. of aqueous emulsifying sylvic oil Lockwood ROCKWOOD red iron oxide pigment, 15 parts+defoamer DC62 WE-786A25 type emulsifying waxs; Described aqueous emulsifying sylvic oil forms by the component of following weight proportion: aqueous synthetic-resin is 5 parts of 3 parts+AMP-95 of 35 parts+methyl ethyl-amine of 3 parts+deionized water of 50 parts+food grade of linking agent ethanol dispersion agents; Described aqueous synthetic-resin forms by the component of following weight proportion: 2 parts of 15 parts+linking agents of 25 parts+season of 35 parts+soybean oil of water-borne acrylic resin, 0.2 part+rosin of 10 parts+magnesium oxide of 3 parts+MALEIC ANHYDRIDE of luxuriant tetrol; Described linking agent is 2 parts of aziridine connection agent SaC-100.
The above embodiments are prepared by following " preparing the method that cigarette is used the cork paper water color ink " embodiment:
A, aqueous synthetic-resin are that linking agent is made: the raw material of pressing following composition by weight proportioning: 2 parts of 15 parts+linking agents of 25 parts+season of 35 parts+soybean oil of water-borne acrylic resin, 0.2 part+rosin of 10 parts+magnesium oxide of 3 parts+MALEIC ANHYDRIDE of luxuriant tetrol; It is that aziridine joins agent SaC-100 that described linking agent is 2 parts, and above-mentioned raw materials carries out stirring reaction in reactor, and temperature of reaction is 275～285 ℃;
B, aqueous emulsifying sylvic oil make: by the raw material of following composition by weight proportioning: aqueous synthetic-resin is that 5 parts of 3 parts+AMP-95 of 35 parts+methyl ethyl-amine of 3 parts+deionized water of 50 parts+food grade of linking agent ethanol dispersion agents carry out stirring reaction in reactor, temperature of reaction is 70～80 ℃, tests after the emulsification;
C, cigarette are made of the cork paper water color ink: the raw material of pressing following composition by weight proportioning: 0. 5 parts of 15 parts+defoamer of 15 parts+deionized water of the 55 parts+U.S. of aqueous emulsifying sylvic oil Lockwood ROCKWOOD red iron oxide pigment DC62,0. 3 parts of anti-sedimentation agent WE-786A25 type emulsifying waxs, disperse, grind, filter, check, get at last cigarette cork paper water color ink.
Above-described embodiment is the name of product of applying unit: WH-YC808, through " national chemical building material quality supervision and test " center " detects, and its assay is as follows:
Project name technical indicator detected value
1, color: approximate index is consistent with standard specimen
2, tinting strength (%): 〉=95-105 100
3, fineness (um) :≤5 2.5
4, pH value: 7.5-8.5 7.9
5, first dryness (m): 〉=1-3 1.8
6, attachment fastness (%): 〉=95 97.3
7, viscosity (s): 40-50 43.51
8, surface tension (N/cm): 35 * 10
-5Greater than 38 * 10
-5
9, limit of harmful substance (mg/kg):
(1) barium :≤0.1 does not detect
(2) every :≤0.1 does not detect
(3) chromium :≤0.4 0.2
(4) lead :≤0.1 does not detect
(5) arsenic :≤0.l does not detect
(6) mercury :≤0.1 does not detect
(7) selenium :≤0.1 does not detect
(8) antimony :≤0.1 does not detect
10, molten Ji residual quantity (mg/m
2):
(1) ethanol≤0.9
(2) Virahol≤0.l does not detect
(3) ethyl acetate≤0.1 does not detect
(4) propyl acetate≤0.1 does not detect
(5) butylacetate≤0.1 does not detect
(6) acetone≤0.l does not detect
(7) butanone≤0.1 does not detect
(8) propylene-glycol ethyl ether≤0.l does not detect
(9) propylene glycol monomethyl ether≤0.l does not detect
11, benzene,toluene,xylene residual quantity (mg/m
2)
(1) benzene :≤0.1 does not detect
(2) toluene :≤0.l does not detect
(3) dimethylbenzene :≤0.1 does not detect
Above detection shows, the present invention has reached the mandatory industry standard of sanitary index that countries tobacco general bureau limits the quantity of about tobacco package cigarette tipping paper dissolvent residual and inorganic elements: the requirement of YC171-2008 " cigarette tipping paper ".
Claims (10)
1. cigarette cork paper water color ink, it is characterized in that being formed by the raw material by following composition by weight proportioning: 10～20 parts+defoamer of 10～20 parts+deionized water of 50～60 parts+iron oxide pigment of aqueous emulsifying sylvic oil, anti-sedimentation agent, flow agent, wetting agent, antiseptic-germicide, 0. 5～1.0 parts of one or more in wetting dispersing agent, the surface tension agent aid.
2. according to claim 1 or described cigarette cork paper water color ink, it is characterized in that described aqueous emulsifying sylvic oil forms by the component of following weight proportion: 3～6 parts of 2～5 parts+AMP-95 of 3 0～4 5 parts+methyl ethyl-amine of 2～5 parts+deionized water of 45～55 parts+food grade of aqueous synthetic-resin ethanol.
3. cigarette according to claim 2 cork paper water color ink is characterized in that described aqueous synthetic-resin forms by the component of following weight proportion: 1～3 part of 10～20 parts+linking agent of 20～30 parts+season of 30～40 parts+soybean oil of water-borne acrylic resin, 0.01～0.5 part+rosin of 8～15 parts+magnesium oxide of 1～6 part+MALEIC ANHYDRIDE of luxuriant tetrol.
4. cigarette according to claim 3 cork paper water color ink is characterized in that described linking agent is aziridine connection agent SaC-100.
5. cigarette according to claim 1 and 2 cork paper water color ink is characterized in that described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
6. cigarette according to claim 3 cork paper water color ink is characterized in that described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
7. cigarette according to claim 4 cork paper water color ink is characterized in that described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
8. one kind prepares the method that cigarette is used the cork paper water color ink, it is characterized in that:
A, aqueous synthetic-resin are made: the raw material of pressing following composition by weight proportioning: 1～3 part of 10～20 parts+linking agent of 20～30 parts+season of 30～40 parts+soybean oil of water-borne acrylic resin, 0.01～0.5 part+rosin of 8～15 parts+magnesium oxide of 1～6 part+MALEIC ANHYDRIDE of luxuriant tetrol, carry out stirring reaction in reactor, temperature of reaction is 275～285 ℃;
B, aqueous emulsifying sylvic oil are made: by the raw material of following composition by weight proportioning: 3～6 parts of 2～5 parts+AMP-95 of 30～45 parts+methyl ethyl-amine of 2～5 parts+deionized water of 45～55 parts+food grade of aqueous synthetic-resin ethanol, in reactor, carry out stirring reaction, temperature of reaction is 70～80 ℃, tests after the emulsification;
C, cigarette are made of the cork paper water color ink: the raw material of pressing following composition by weight proportioning: 10～20 parts+defoamer of 10～20 parts+deionized water of 50～60 parts+iron oxide pigment of aqueous emulsifying sylvic oil, anti-sedimentation agent, flow agent, wetting agent, antiseptic-germicide, 0. 5～1.0 parts of in wetting dispersing agent, the surface tension agent aid one or more, disperse, grind, filter, check, get at last cigarette cork paper water color ink.
9. a kind of cigarette for preparing according to claim 8 is characterized in that with the method for cork paper water color ink described linking agent is aziridine connection agent SaC-100.
10. a kind of cigarette for preparing according to claim 8 is characterized in that with the method for cork paper water color ink described iron oxide pigment is red iron oxide pigment, or yellow iron oxide pigment, or black iron oxide pigment.
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| CN104946007A (en) * | 2015-07-01 | 2015-09-30 | 苏州市博来特油墨有限公司 | Special antibacterial water-based ink for tipping paper |
| CN109651872A (en) * | 2019-01-30 | 2019-04-19 | 楚雄市华丽包装实业有限责任公司 | A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink and preparation method thereof |
| CN110511611A (en) * | 2019-10-17 | 2019-11-29 | 温州立可达印业股份有限公司 | A kind of aqueous tipping paper printing ink |
| CN110669379A (en) * | 2019-10-16 | 2020-01-10 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
| CN111019434A (en) * | 2019-12-25 | 2020-04-17 | 广东德康化工实业有限公司 | Treatment-free PC (polycarbonate) water-based pad printing ink and preparation method thereof |
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| CN112411261A (en) * | 2020-11-12 | 2021-02-26 | 张彪 | Colored cigarette paper of printing process and manufacturing method thereof |
| CN113943505A (en) * | 2021-07-12 | 2022-01-18 | 广东新宏泽包装股份有限公司 | Novel recyclable and nontoxic printing material |
| CN116496659A (en) * | 2023-04-28 | 2023-07-28 | 英科卡乐油墨(湖北)有限公司 | High-temperature-resistant water-based ink for cigarette tipping material |
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| CN103666088A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | Special aqueous gold ink for tipping paper, preparation method and application thereof |
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| CN104231727B (en) * | 2014-10-13 | 2017-01-18 | 北京印刷学院 | Gravure yellow ink for pure water type tipping paper and preparation method thereof |
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| CN104449035A (en) * | 2014-11-26 | 2015-03-25 | 成都锦汇科技有限公司 | Water-based ink with condensation prevention capacity |
| CN104946007A (en) * | 2015-07-01 | 2015-09-30 | 苏州市博来特油墨有限公司 | Special antibacterial water-based ink for tipping paper |
| CN109651872A (en) * | 2019-01-30 | 2019-04-19 | 楚雄市华丽包装实业有限责任公司 | A kind of cigarette tipping paper, internal lining paper environment-friendly antibacterial water-based ink and preparation method thereof |
| CN110669379A (en) * | 2019-10-16 | 2020-01-10 | 江苏科技大学 | Quick-drying water-based ink composition and preparation method and application thereof |
| CN110511611A (en) * | 2019-10-17 | 2019-11-29 | 温州立可达印业股份有限公司 | A kind of aqueous tipping paper printing ink |
| CN111019434A (en) * | 2019-12-25 | 2020-04-17 | 广东德康化工实业有限公司 | Treatment-free PC (polycarbonate) water-based pad printing ink and preparation method thereof |
| CN111500113A (en) * | 2020-06-05 | 2020-08-07 | 杭州海维特化工科技有限公司 | Copper plate paper gravure water-based ink and preparation method thereof |
| CN112411261A (en) * | 2020-11-12 | 2021-02-26 | 张彪 | Colored cigarette paper of printing process and manufacturing method thereof |
| CN113943505A (en) * | 2021-07-12 | 2022-01-18 | 广东新宏泽包装股份有限公司 | Novel recyclable and nontoxic printing material |
| CN116496659A (en) * | 2023-04-28 | 2023-07-28 | 英科卡乐油墨(湖北)有限公司 | High-temperature-resistant water-based ink for cigarette tipping material |
| CN117569120A (en) * | 2023-11-29 | 2024-02-20 | 青岛嘉泽包装有限公司 | Preparation process of temperature-resistant water-based ink tipping paper |
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Application publication date: 20130306 |