CN103788911B - Environment-friendly adhesive containing modified nanometer bamboo charcoal powder - Google Patents
Environment-friendly adhesive containing modified nanometer bamboo charcoal powder Download PDFInfo
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- CN103788911B CN103788911B CN201410057025.5A CN201410057025A CN103788911B CN 103788911 B CN103788911 B CN 103788911B CN 201410057025 A CN201410057025 A CN 201410057025A CN 103788911 B CN103788911 B CN 103788911B
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- bamboo charcoal
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- charcoal powder
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- 239000000843 powder Substances 0.000 title claims abstract description 40
- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 31
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 31
- 241001330002 Bambuseae Species 0.000 title claims abstract description 31
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 31
- 239000011425 bamboo Substances 0.000 title claims abstract description 31
- 239000003610 charcoal Substances 0.000 title claims abstract description 31
- 239000000853 adhesive Substances 0.000 title claims abstract description 18
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 18
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010881 fly ash Substances 0.000 claims abstract description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- KJHYAEZMOHLVCH-UHFFFAOYSA-N 2-ethyl-1-benzofuran Chemical compound C1=CC=C2OC(CC)=CC2=C1 KJHYAEZMOHLVCH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 11
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 11
- 239000004793 Polystyrene Substances 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 11
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 11
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000010452 phosphate Substances 0.000 claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 claims abstract description 11
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 11
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000006004 Quartz sand Substances 0.000 claims abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 6
- 239000010445 mica Substances 0.000 claims abstract description 6
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 6
- 239000000661 sodium alginate Substances 0.000 claims abstract description 6
- 235000010413 sodium alginate Nutrition 0.000 claims abstract description 6
- 229940005550 sodium alginate Drugs 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims description 14
- 239000010883 coal ash Substances 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 229920013649 Paracril Polymers 0.000 claims description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 238000009775 high-speed stirring Methods 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 238000004898 kneading Methods 0.000 claims description 5
- 239000000347 magnesium hydroxide Substances 0.000 claims description 5
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 5
- 239000002105 nanoparticle Substances 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 239000001069 triethyl citrate Substances 0.000 claims description 5
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000013769 triethyl citrate Nutrition 0.000 claims description 5
- -1 phosphate ester Chemical class 0.000 abstract description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 abstract 2
- 229920000459 Nitrile rubber Polymers 0.000 abstract 1
- 239000012975 dibutyltin dilaurate Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000005350 fused silica glass Substances 0.000 abstract 1
- 229920005610 lignin Polymers 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000004513 sizing Methods 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- FGBJXOREULPLGL-UHFFFAOYSA-N ethyl cyanoacrylate Chemical compound CCOC(=O)C(=C)C#N FGBJXOREULPLGL-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 240000004859 Gamochaeta purpurea Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an environment-friendly adhesive containing modified nanometer bamboo charcoal powder. The environment-friendly adhesive comprises the following components in parts by weight: 100-150 parts of polyvinyl alcohol resin, 50-80 parts of 2-ethylbenzofuran, 20-30 parts of dibutyl phthalate, 15-20 parts of polystyrene, 10-15 parts of ditolyl phosphate ester, 20-30 parts of isophorone diisocyanate, 5-10 parts of nitrile rubber, 10-15 parts of calcium carbonate, 5-8 parts of titanium dioxide, 5-20 parts of nanometer magnesium hydrate, 15-20 parts of modified nanometer bamboo charcoal powder, 10-15 parts of lignin, 3-5 parts of fused silica, 3-5 parts of sodium alginate, 20-30 parts of quartz sand, 1-3 parts of boron powder, 5-10 parts of windshield washer fluid, 0.7-0.9 parts of dibutyltin dilaurate, 2-4 parts of mica iron oxide, 1-3 parts of silane coupling agent and 10-15 parts of modified fly ash. The adhesive disclosed by the invention has the characteristics of high adhesive strength, no pollution, long storage life and the like, and is harmless to a human body, and environment-friendly.
Description
Technology neighborhood
The present invention relates to sizing agent technology neighborhood, particularly relate to a kind of environment-protective adhesive containing modified Nano bamboo charcoal powder.
Background technology
Sizing agent is a kind of material that similar or inhomogeneous material tight can be combined.Along with development that is scientific and technical and national economy, tackiness agent has been widely used in every profession and trade and the high-tech neighborhoods such as wood working, construction work, textile printing and dyeing, shoemaking, leather, electronics, automobile, machinery, aerospace, biologic medical.
At present, in order to improve some performance of tackiness agent, add some properties-correcting agent, thickening material, tackifier, emulsifying agent etc., and in these materials, some is poisonous in sizing agent of being everlasting, some or even extremely poison, and majority can produce environmental pollution.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of and have that water-tolerant, bonding strength are high, environmentally safe, environmental protection harmless to human body the sizing agent containing modified Nano bamboo charcoal powder.
The present invention adopts following technical scheme to achieve these goals:
A kind of environment-protective adhesive containing modified Nano bamboo charcoal powder, comprise the component of following weight part: polyvinyl alcohol resin 100-150 part, 2-ethyl benzofuran 50-80 part, dibutyl phthalate 20-30 part, polystyrene 15-20 part, dixylenyl phosphate 10-15 part, isophorone diisocyanate 20-30 part, paracril 5-10 part, calcium carbonate 10-15 part, titanium dioxide 5-8 part, nano-sized magnesium hydroxide 5-20 part, modified Nano bamboo charcoal powder 15-20 part, xylogen 10-15 part, gas-phase silica 3-5 part, sodium alginate 3-5 part, quartz sand 20-30 part, boron powder 1-3 part, bath of glass 5-10 part, dibutyl tin laurate 0.7-0.9 part, iron mica 2-4 part, silane coupling agent 1-3 part, modified coal ash 10-15 part.
The preparation method of described modified Nano bamboo charcoal powder is: bamboo charcoal powder 10-15% sodium hydroxide solution soaks 5-8h, then deionized water wash is used, dry, add again and be equivalent to 2,4 of its weight 1-2%, the ethyl α-cyanoacrylate of 6 trisphenols, 1-3%, the crosslink agent DCP of 1-3%, 3000-5000 rev/min is stirred 30-50 minute, dry, grind to form nanometer powder.
Described modified coal ash is prepared by following steps: first dried in 100-110 DEG C of baking oven by flyash, then the flyash after oven dry is put into high-speed kneading machine, add be equivalent to flyash weight 3-5% aluminate coupling agent, the wooden sodium sulfonate of 2-4%, the triethyl citrate of 2-4%, the whiteruss of 1-2% and 2-5% talcum powder, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the described environment-protective adhesive containing modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, dibutyl phthalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100-130 DEG C, high-speed stirring 3-4h;
(2) again other compositions are joined in the reactor in step (1), stir 1-2h, be cooled to normal temperature, pack.
Compared with the prior art, beneficial effect of the present invention is as follows:
The present invention is by adding the compositions such as modified Nano bamboo charcoal powder, xylogen in sizing agent, effectively can eliminate toxicity and the pollution on the environment of sizing agent, simultaneously, add modified coal ash, significantly improve the dispersing uniformity of each component, the adhesion intensity of sizing agent can be improved, and have that cost is low, the feature of excellent effect.Sizing agent of the present invention has the features such as bonding strength is high, pollution-free, storage period is longer, harmless to human body, environmental protection.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1:
A kind of environment-protective adhesive containing modified Nano bamboo charcoal powder, comprise the component of following weight part: polyvinyl alcohol resin 130 parts, 2-ethyl benzofuran 70 parts, dibutyl phthalate 20 parts, polystyrene 15 parts, dixylenyl phosphate 13 parts, isophorone diisocyanate 25 parts, paracril 7 parts, 10 parts, calcium carbonate, titanium dioxide 5 parts, nano-sized magnesium hydroxide 6 parts, modified Nano bamboo charcoal powder 18 parts, 15 parts, xylogen, gas-phase silica 4 parts, sodium alginate 4 parts, quartz sand 25 parts, 2 parts, boron powder, bath of glass 6 parts, dibutyl tin laurate 0.8 part, iron mica 3 parts, silane coupling agent 2 parts, modified coal ash 13 parts.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder 15% sodium hydroxide solution soaks 8h, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, the ethyl α-cyanoacrylate of 3%, the crosslink agent DCP of 3%, 5000 revs/min are stirred 50 minutes, dry, grind to form nanometer powder.
Modified coal ash is prepared by following steps: first dried in 110 DEG C of baking ovens by flyash, then the flyash after oven dry is put into high-speed kneading machine, add be equivalent to flyash weight 5% aluminate coupling agent, 3% wooden sodium sulfonate, the triethyl citrate of 3%, the whiteruss of 2% and 4% talcum powder, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the environment-protective adhesive containing modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, dibutyl phthalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 130 DEG C, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 1h, be cooled to normal temperature, pack.
Embodiment 2:
A kind of environment-protective adhesive containing modified Nano bamboo charcoal powder, comprise the component of following weight part: polyvinyl alcohol resin 100 parts, 2-ethyl benzofuran 50 parts, dibutyl phthalate 20 parts, polystyrene 15 parts, dixylenyl phosphate 10 parts, isophorone diisocyanate 20 parts, paracril 5 parts, 10 parts, calcium carbonate, titanium dioxide 7 parts, nano-sized magnesium hydroxide 5, part, modified Nano bamboo charcoal powder 15 parts, 10 parts, xylogen, gas-phase silica 3 parts, sodium alginate 3 parts, quartz sand 20 parts, 1 part, boron powder, bath of glass 5 parts, dibutyl tin laurate 0.7 part, iron mica 2 parts, silane coupling agent 2 parts, modified coal ash 10 parts.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder 10% sodium hydroxide solution soaks 7h, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, the ethyl α-cyanoacrylate of 1%, the crosslink agent DCP of 1%, 3000 revs/min are stirred 30 minutes, dry, grind to form nanometer powder.
Modified coal ash is prepared by following steps: first dried in 100 DEG C of baking ovens by flyash, then the flyash after oven dry is put into high-speed kneading machine, add be equivalent to flyash weight 3% aluminate coupling agent, 2% wooden sodium sulfonate, the triethyl citrate of 2%, the whiteruss of 1% and 2% talcum powder, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the environment-protective adhesive containing modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, dibutyl phthalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100 DEG C, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 1h, be cooled to normal temperature, pack.
Embodiment 3:
A kind of environment-protective adhesive containing modified Nano bamboo charcoal powder, comprise the component of following weight part: polyvinyl alcohol resin 150 parts, 2-ethyl benzofuran 80 parts, dibutyl phthalate 30 parts, polystyrene 20 parts, dixylenyl phosphate 15 parts, isophorone diisocyanate 30 parts, paracril 10 parts, 15 parts, calcium carbonate, titanium dioxide 8 parts, nano-sized magnesium hydroxide 20 parts, modified Nano bamboo charcoal powder 20 parts, 15 parts, xylogen, gas-phase silica 5 parts, sodium alginate 5 parts, quartz sand 30 parts, 3 parts, boron powder, bath of glass 8 parts, dibutyl tin laurate 0.9 part, iron mica 4 parts, silane coupling agent 3 parts, modified coal ash 15 parts.
Wherein, the preparation method of modified Nano bamboo charcoal powder is: bamboo charcoal powder 15% sodium hydroxide solution soaks 5h, then use deionized water wash, dry, then add and be equivalent to 2 of its weight 2%, 4,6 trisphenols, the ethyl α-cyanoacrylate of 3%, the crosslink agent DCP of 3%, 5000 revs/min are stirred 50 minutes, dry, grind to form nanometer powder.
Described modified coal ash is prepared by following steps: first dried in 110 DEG C of baking ovens by flyash, then the flyash after oven dry is put into high-speed kneading machine, add be equivalent to flyash weight 5% aluminate coupling agent, 4% wooden sodium sulfonate, the triethyl citrate of 4%, the whiteruss of 2% and 5% talcum powder, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
The preparation method of the described environment-protective adhesive containing modified Nano bamboo charcoal powder, comprises following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, dibutyl phthalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 130 DEG C, high-speed stirring 3h;
(2) again other compositions are joined in the reactor in step (1), stir 2h, be cooled to normal temperature, pack.
Claims (3)
1. the environment-protective adhesive containing modified Nano bamboo charcoal powder, it is characterized in that: the component comprising following weight part: polyvinyl alcohol resin 100-150 part, 2-ethyl benzofuran 50-80 part, dibutyl phthalate 20-30 part, polystyrene 15-20 part, dixylenyl phosphate 10-15 part, isophorone diisocyanate 20-30 part, paracril 5-10 part, calcium carbonate 10-15 part, titanium dioxide 5-8 part, nano-sized magnesium hydroxide 5-20 part, modified Nano bamboo charcoal powder 15-20 part, xylogen 10-15 part, gas-phase silica 3-5 part, sodium alginate 3-5 part, quartz sand 20-30 part, boron powder 1-3 part, bath of glass 5-10 part, dibutyl tin laurate 0.7-0.9 part, iron mica 2-4 part, silane coupling agent 1-3 part, modified coal ash 10-15 part.
2. the environment-protective adhesive containing modified Nano bamboo charcoal powder according to claim 1, it is characterized in that: described modified coal ash is prepared by following steps: first flyash is dried in 100-110 DEG C of baking oven, then the flyash after oven dry is put into high-speed kneading machine, add be equivalent to flyash weight 3-5% aluminate coupling agent, the wooden sodium sulfonate of 2-4%, the triethyl citrate of 2-4%, the whiteruss of 1-2% and 2-5% talcum powder, after high-speed mixing, dry, pulverize and grind to form ultrafine powder.
3. the preparation method of the environment-protective adhesive containing modified Nano bamboo charcoal powder according to claim 1, is characterized in that: comprise following preparation process:
(1) by recipe ratio, just polyvinyl alcohol resin, 2-ethyl benzofuran, dibutyl phthalate, polystyrene, dixylenyl phosphate, isophorone diisocyanate, paracril, dibutyl tin laurate join reactor and are heated to 100-130 DEG C, high-speed stirring 3-4h;
(2) again other compositions are joined in the reactor in step (1), stir 1-2h, be cooled to normal temperature, pack.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057025.5A CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410057025.5A CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
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| Publication Number | Publication Date |
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| CN103788911A CN103788911A (en) | 2014-05-14 |
| CN103788911B true CN103788911B (en) | 2015-06-10 |
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| CN201410057025.5A Expired - Fee Related CN103788911B (en) | 2014-02-20 | 2014-02-20 | Environment-friendly adhesive containing modified nanometer bamboo charcoal powder |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104559907B (en) * | 2014-12-26 | 2017-03-22 | 嵊州亿源投资管理有限公司 | Environment-friendly composite adhesive as well as preparation method and application thereof |
| CN105646823B (en) * | 2016-01-13 | 2018-01-09 | 宜兴市华夏化工材料有限公司 | A kind of preparation method and applications of bamboo fibre superfine powder |
| CN106010556A (en) * | 2016-05-31 | 2016-10-12 | 山东胜伟园林科技有限公司 | Bamboo charcoal nanopowder-containing penetration resisting material, and method for planting blueberries in saline and alkaline land by using penetration resisting material |
| CN105885490A (en) * | 2016-06-22 | 2016-08-24 | 杨玉双 | Environmentally friendly coating added with modified nano bamboo charcoal powder and preparation method of environmentally friendly coating |
| CN106381031A (en) * | 2016-08-30 | 2017-02-08 | 乐凯特科技铜陵有限公司 | Three-proofing lacquer for high-temperature-resistant printed circuit board and preparation method thereof |
| CN106699046A (en) * | 2016-11-17 | 2017-05-24 | 铜陵祥云消防科技有限责任公司 | Washing resistant heat insulation and flame retardant material for exterior walls |
| CN106674716A (en) * | 2016-12-23 | 2017-05-17 | 安徽天元电缆有限公司 | Eco-friendly flame-retardant thermoplastic elastomer and preparation method thereof |
| CN107117823A (en) * | 2017-06-30 | 2017-09-01 | 合肥利裕泰玻璃制品有限公司 | A kind of foam glass and preparation method thereof |
| CN107142793A (en) * | 2017-07-05 | 2017-09-08 | 合肥市片叶装饰工程有限公司 | Environment-friendly antibacterial wallpaper |
| CN108531089A (en) * | 2018-05-07 | 2018-09-14 | 安吉祥力胶粘剂有限公司 | A kind of special adhesive of environment friendly decorative material and preparation method thereof |
| CN109998222B (en) * | 2019-04-25 | 2020-10-23 | 东莞市东城赤洪节能设备厂 | a breathing insole |
| CN111346619B (en) * | 2020-04-20 | 2022-08-26 | 黑龙江大学 | Preparation method of modified red mud filter material and removal of ammonia nitrogen in low-temperature sewage by using modified red mud filter material |
| CN113862824A (en) * | 2021-10-22 | 2021-12-31 | 广州明晖新材料有限公司 | High-temperature-resistant brush wire and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2005105010A (en) * | 2003-09-26 | 2005-04-21 | Yamaguchi Prefecture | Inorganic coating material and voc-adsorbing functional material using the same |
| CN102965050B (en) * | 2012-11-02 | 2016-03-02 | 铜陵祥云消防科技有限责任公司 | A kind of adhesive for packaging of nano diatomite modification |
| CN103013135B (en) * | 2012-11-25 | 2016-05-11 | 合肥宏杰新材料科技有限公司 | A kind of automobile air valve oil sealing rubber and preparation method thereof |
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