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CN103755252A - Novel concrete and preparation method thereof - Google Patents

Novel concrete and preparation method thereof Download PDF

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Publication number
CN103755252A
CN103755252A CN201310725666.9A CN201310725666A CN103755252A CN 103755252 A CN103755252 A CN 103755252A CN 201310725666 A CN201310725666 A CN 201310725666A CN 103755252 A CN103755252 A CN 103755252A
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concrete
particles
polystyrene particles
cement
polystyrene
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吴辉琴
陈晓黎
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Guangxi University of Science and Technology
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Guangxi University of Science and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

本发明提供一种新型混凝土,包括减水剂、激发剂、水、粉煤灰与胶凝材料,所述胶凝材料包括水泥、矿粉与激发剂。所述混凝土还包括聚苯乙烯颗粒与改性剂。利用轻质骨料添加聚苯乙烯颗粒取代传统混凝土砌块中石子等粗骨料,以降低其自重、提高保温节能的性能,并解决添加聚苯乙烯颗粒的憎水性导致的胶凝材料浆体与添加聚苯乙烯颗粒界面粘结力小的缺陷。The invention provides a new type of concrete, which includes a water reducing agent, an activator, water, fly ash and a cementitious material, and the cementitious material includes cement, mineral powder and an activator. The concrete also includes polystyrene particles and modifiers. Use lightweight aggregates to add polystyrene particles to replace coarse aggregates such as stones in traditional concrete blocks to reduce its weight, improve thermal insulation and energy-saving performance, and solve the problem of cementitious material paste caused by the hydrophobicity of polystyrene particles Defects with low interfacial adhesion with added polystyrene particles.

Description

A kind of new concrete and preparation method
Technical field
The present invention relates to a kind of new concrete, relate in particular to a kind of EPS concrete and preparation method.
Background technology
For adapting to extensive building industrialization, modern requirement, construction material, just gradually to lightweight, high-strength, multi-functional future development, has progressively entered the epoch of macromolecular material.Polystyrene foam (EPS) is a kind of nonpolar lightweight hydrophobic material, this super-light aggregate is added in cement concrete with different addition quantity, can produce the EPS concrete segment that density is different, use it for the building enclosure in house, can obtain good heat-insulating property, significant to building energy conservation.But the smooth and hydrophobic of EPS particle surface own, little with the inorganic coagulation material avidity of polarity, interface binding intensity is low, a little less than the bonding force of sand-cement slurry, causes the concrete intensity of EPS lower, and engineering application is restricted.Therefore, improving sand-cement slurry is the key problem in technology of preparation high-performance EPS cement-based material to the adhesive property of EPS particle.
Summary of the invention
One of object of the present invention is to provide a kind of new concrete and preparation method, utilize aglite to add granules of polystyrene and replace in conventional concrete building block the coarse aggregates such as stone, to reduce its deadweight, to improve the performance of heat preservation energy-saving, and solve and add the gelling material slurry defect little with adding granules of polystyrene interfacial adhesion that the hydrophobic nature of granules of polystyrene causes.
For achieving the above object, on the one hand, the invention provides a kind of new concrete, comprise water reducer, exciting agent, water, flyash and gelling material, described gelling material comprises cement, breeze and exciting agent.Described concrete also comprises granules of polystyrene and properties-correcting agent.
Further, described properties-correcting agent is trolamine.
Further, described granules of polystyrene granularity is at 3-5mm, and its tap density is 12.2 kg/m 3.
Further, the 10%-15% that the addition content of granules of polystyrene is described volume of concrete.
Further, the addition content of described trolamine has 6% of granules of polystyrene quality described in being.
On the other hand, the invention provides the foregoing concrete of a kind of manufacture, employing is not made shell method and is comprised: successively described granules of polystyrene, properties-correcting agent, gelling material, Sha Heshui are poured in agitator kettle and stirred, stir.
On the other hand, the invention provides the foregoing concrete of a kind of manufacture, employing make shell not ageing method comprise: spraying modified dose of described granules of polystyrene surface uniform to particle surface wetting evenly after, a certain amount of cement is evenly sprinkling upon to particle surface, particle is wrapped up by cement completely, stir and obtain masterbatch.Then add residue gelling material, sand, water, then stir.
On the other hand, the invention provides the foregoing concrete of a kind of manufacture, employing is made shell ageing method and is comprised: after spraying modified dose of described granules of polystyrene surface uniform soaks evenly to particle surface, a certain amount of cement is evenly sprinkling upon to particle surface, particle is wrapped up by cement completely, stir and obtain masterbatch.Masterbatch was sealed to ageing after 24 hours, add remaining gelling material, sand and water mix and blend.The present invention by adding granules of polystyrene and properties-correcting agent in new concrete, utilize aglite to add granules of polystyrene and replace in conventional concrete building block the coarse aggregates such as stone, to reduce its deadweight, to improve the performance of heat preservation energy-saving, and solve and add the gelling material slurry defect little with adding granules of polystyrene interfacial adhesion that the hydrophobic nature of granules of polystyrene causes.
Embodiment
Embodiment with concrete is further explained to explanation to new concrete of the present invention and preparation method below, but this is explained and is not formed the improper restriction to technical solution of the present invention.
The present invention is directed to new concrete selects trolamine modified polystyrene particle to make concrete segment proportioning in Table 1:
Figure 385396DEST_PATH_IMAGE001
Table 1
The anti-folding of granules of polystyrene concrete segment, compressive strength test the results are shown in Table 2:
Table 2
As shown in table 1, by volume, volume fraction is 10%, 15% to granules of polystyrene volume.For to make the cement amount of masterbatch be cement consumption 1/3rd, be approximately 2.5 times of EPS quality.Properties-correcting agent adopts trolamine, and wherein trolamine consumption is 6% of EPS granular mass.
Granules of polystyrene volume adopts three kinds of method of modifying to obtain cement-based material and 7 days, 28 days folding strength tables of blank sample while being 10%, 15%.Three kinds of method of modifying are respectively:
1) adopt and not make shell method and comprise: successively granules of polystyrene, properties-correcting agent, gelling material, Sha Heshui are poured in agitator kettle and stirred, stir.
2) adopt make shell not ageing method comprise: spraying modified dose of granules of polystyrene surface uniform to particle surface wetting evenly after, a certain amount of cement is evenly sprinkling upon to particle surface, particle is wrapped up by cement completely, stir and obtain masterbatch.Then add residue gelling material, sand, water, then stir.
3) adopt and to make shell ageing method and comprise: spraying modified dose of granules of polystyrene surface uniform to particle surface wetting evenly after, a certain amount of cement is evenly sprinkling upon to particle surface, particle is wrapped up by cement completely, stir and obtain masterbatch.Masterbatch was sealed to ageing after 24 hours, add remaining gelling material, sand and water mix and blend.Hence one can see that:
No matter granules of polystyrene volume is 10% or 15%, after the surface modification through properties-correcting agent trolamine, do not make shell (directly dispersing and mixing), make not ageing of shell, make three kinds of method of modifying of shell ageing and all can effectively improve the folding strength of granules of polystyrene lightweight concrete building block.But method of modifying is different, it is also different that the folding strength of building block improves degree.
No matter granules of polystyrene volume is 10% or 15%, the folding strength of not making shell method of modifying (2#, 6#) and not ageing method of modifying (3#, 7#) is close, and apparently higher than blank sample (1#, 5#) with make the folding strength of two groups of samples of shell ageing method of modifying (4#, 8#).When wherein granules of polystyrene volume is 15%, 28 days folding strengths of not ageing method of modifying (7#) sample are the highest, than blank sample (5#), improve 32.3%.
Hence one can see that:
(1) no matter granules of polystyrene volume is 10% or 15%, after the surface modification through properties-correcting agent trolamine, do not make shell (directly dispersing and mixing), make not ageing of shell, make three kinds of method of modifying of shell ageing and all can effectively improve the ultimate compression strength of granules of polystyrene lightweight concrete building block.But method of modifying is different, it is also different that the ultimate compression strength of building block improves degree.
(2) no matter granules of polystyrene volume is 10% or 15%, after maintenance 7 days, the ultimate compression strength of not making shell method of modifying (2#, 6#) and not ageing method of modifying (3#, 7#) sample is close, but apparently higher than blank sample (1#, 5#) with make two groups of sample ultimate compression strength of shell ageing method of modifying (4#, 8#).
(3) maintenance is after 28 days, and the ultimate compression strength of not ageing method of modifying (3#, 7#) sample is apparently higher than other method of modifying.When wherein granules of polystyrene volume is 10%, not ageing method of modifying (3#) than blank sample (1#), do not make shell method of modifying (2#) and make shell ageing (4#) ultimate compression strength and exceed respectively 57.4%, 9.2%, 27.4%; When granules of polystyrene volume is 15%, not ageing method of modifying (7#) than blank sample (5#), do not make shell method of modifying (6#) and make shell ageing (8#) ultimate compression strength and exceed respectively 58%, 9.7%, 27.4%.
By the present invention, improve the interface bonding degree of gelling material and granules of polystyrene, thereby improve resistance to compression, the folding strength of test block.
It should be noted that; the above-mentioned explanation of disclosed embodiment makes professional and technical personnel in the field for the present embodiment, to carry out multiple types like changing and revising apparently; this similar variation is all distortion that those skilled in the art can directly draw or be easy to just associate from content disclosed by the invention, all should belong to protection scope of the present invention.Therefore the present invention can not be subject to the restriction of this embodiment.

Claims (8)

1.一种新型混凝土,包括减水剂、激发剂、水、粉煤灰与胶凝材料,所述胶凝材料包括水泥、矿粉与激发剂,其特征在于: 1. A novel concrete, comprising water-reducing agent, activator, water, fly ash and cementitious material, described cementitious material comprises cement, mineral powder and activator, is characterized in that: 所述混凝土还包括聚苯乙烯颗粒与改性剂。 The concrete also includes polystyrene particles and modifiers. 2.如权利要求1所述的新型混凝土,其特征在于:所述改性剂为三乙醇胺。 2. novel concrete as claimed in claim 1 is characterized in that: described modifying agent is triethanolamine. 3.如权利要求1所述的新型混凝土,其特征在于:所述聚苯乙烯颗粒粒度在3-5mm,其堆积密度为12.2 kg/m33. The new type of concrete according to claim 1, characterized in that: the particle size of the polystyrene particles is 3-5 mm, and its bulk density is 12.2 kg/m 3 . 4.如权利要求1所述的新型混凝土,其特征在于:聚苯乙烯颗粒的掺加量为所述混凝土体积的10%-15%。 4. The novel concrete according to claim 1, characterized in that: the admixture of polystyrene particles is 10%-15% of the volume of the concrete. 5.如权利要求1所述的新型混凝土,其特征在于:所述三乙醇胺的掺加量为所述有聚苯乙烯颗粒质量的6%。 5. The novel concrete as claimed in claim 1, characterized in that: the admixture of the triethanolamine is 6% of the mass of the polystyrene particles. 6.一种制备如权利要求1所述的新型混凝土的方法,其特征在于:采用不造壳法,其包括,依次将所述聚苯乙烯颗粒、改性剂、胶凝材料、砂和水倒入搅拌锅中搅拌,搅拌均匀。 6. A method for preparing novel concrete as claimed in claim 1, characterized in that: adopting a non-shell method, which comprises, sequentially mixing said polystyrene particles, modifying agent, cementitious material, sand and water Pour into mixing pot and stir, stirring to combine. 7.一种制备如权利要求1所述的新型混凝土的方法,其特征在于:采用造壳不陈化法,其包括,在所述聚苯乙烯颗粒表面均匀喷洒三乙醇胺改性剂至颗粒表面润湿均匀后,将一定量的水泥均匀撒在颗粒表面,使颗粒完全被水泥包裹,搅拌均匀得到母料, 7. A method for preparing novel concrete as claimed in claim 1, characterized in that: a shell-making non-aging method is adopted, which comprises uniformly spraying a triethanolamine modifier on the surface of the polystyrene particles until the surface of the particles is wetted After uniformity, sprinkle a certain amount of cement evenly on the surface of the particles, so that the particles are completely covered by cement, and stir evenly to obtain the masterbatch. 然后加入剩余胶凝材料、砂、水,再进行搅拌。 Then add the remaining cementitious material, sand, water, and stir again. 8.一种制备如权利要求1所述的新型混凝土的方法,其特征在于:采用造壳陈化法,其包括,在所述聚苯乙烯颗粒表面均匀喷洒三乙醇胺改性剂至颗粒表面润湿均匀后,将一定量的水泥均匀撒在颗粒表面,使颗粒完全被水泥包裹,搅拌均匀得到母料, 8. A method for preparing novel concrete as claimed in claim 1, characterized in that: a shell-making aging method is adopted, which comprises uniformly spraying a triethanolamine modifier on the surface of the polystyrene particles until the surface of the particles is evenly wetted Finally, a certain amount of cement is evenly sprinkled on the surface of the particles, so that the particles are completely covered by cement, and the masterbatch is obtained by stirring evenly. 将母料密封陈化24 小时后,加入其余的胶凝材料、砂及水混合搅拌。 After sealing and aging the masterbatch for 24 hours, add the rest of the cementitious material, sand and water to mix and stir.
CN201310725666.9A 2013-12-25 2013-12-25 Novel concrete and preparation method thereof Pending CN103755252A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108794060A (en) * 2018-07-19 2018-11-13 常州大学 A kind of resource utilization method of maize straw
CN109293389A (en) * 2018-12-03 2019-02-01 安徽工业大学 A new type of wall material and preparation method thereof
CN110953630A (en) * 2019-11-14 2020-04-03 中铁第四勘察设计院集团有限公司 Floor heating structure
CN112408921A (en) * 2020-12-15 2021-02-26 温州鼎玛建筑技术有限公司 Energy-saving concrete for building and preparation process thereof
CN113149553A (en) * 2020-08-10 2021-07-23 河海大学 Light heat-preservation high-strength concrete and preparation method thereof
CN114797615A (en) * 2022-04-26 2022-07-29 浙江大学 Modified cementing material, preparation method thereof and mixing system

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101492943A (en) * 2009-01-24 2009-07-29 南京倍立达实业有限公司 Self-insulating decorative building block and method for producing the same
CN101525226A (en) * 2009-04-13 2009-09-09 吕运征 Insulating dry powder mortar
CN103011713A (en) * 2012-12-30 2013-04-03 李丰刚 Waste foam concrete insulation material and preparation method thereof
CN103121814A (en) * 2013-02-22 2013-05-29 广西工学院 Lightweight concrete and preparation method and applications thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101492943A (en) * 2009-01-24 2009-07-29 南京倍立达实业有限公司 Self-insulating decorative building block and method for producing the same
CN101525226A (en) * 2009-04-13 2009-09-09 吕运征 Insulating dry powder mortar
CN103011713A (en) * 2012-12-30 2013-04-03 李丰刚 Waste foam concrete insulation material and preparation method thereof
CN103121814A (en) * 2013-02-22 2013-05-29 广西工学院 Lightweight concrete and preparation method and applications thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108794060A (en) * 2018-07-19 2018-11-13 常州大学 A kind of resource utilization method of maize straw
CN109293389A (en) * 2018-12-03 2019-02-01 安徽工业大学 A new type of wall material and preparation method thereof
CN110953630A (en) * 2019-11-14 2020-04-03 中铁第四勘察设计院集团有限公司 Floor heating structure
CN113149553A (en) * 2020-08-10 2021-07-23 河海大学 Light heat-preservation high-strength concrete and preparation method thereof
CN112408921A (en) * 2020-12-15 2021-02-26 温州鼎玛建筑技术有限公司 Energy-saving concrete for building and preparation process thereof
CN114797615A (en) * 2022-04-26 2022-07-29 浙江大学 Modified cementing material, preparation method thereof and mixing system

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Inventor after: Wu Huiqin

Inventor after: Dong Jianmiao

Inventor after: Chen Xiaoli

Inventor after: Wu Chao

Inventor before: Wu Huiqin

Inventor before: Chen Xiaoli

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Application publication date: 20140430