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CN103710161A - Cleaning agent for removing heavy dirt and greasy dirt - Google Patents

Cleaning agent for removing heavy dirt and greasy dirt Download PDF

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Publication number
CN103710161A
CN103710161A CN201310753862.7A CN201310753862A CN103710161A CN 103710161 A CN103710161 A CN 103710161A CN 201310753862 A CN201310753862 A CN 201310753862A CN 103710161 A CN103710161 A CN 103710161A
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cleaning agent
surfactant
parts
water
dirt
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CN103710161B (en
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张青
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Shanghai Jiao Tong University
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Abstract

本发明公开了一种去除重垢和油污的清洗剂,所述的清洗剂包括以下重量百分含量的组分:表面活性剂5-30%;pH调节剂 5-20%;乙醇胺衍生物1-10%;杂醇油10-25%;香精 0-3%;余量为水;所述的表面活性剂选自阴离子表面活性剂和非离子表面活性剂中的一种或两种;所述的杂醇油为采用淀粉为原料发酵生产食用酒精工艺中产生的副产物。本发明中公开的清洗剂在室温及较低温度条件下就能有效地渗透到硬质材料表面沉积的重垢和油污中;而且能够防止油油污和污垢的再沉积,其对擦洗所用的棉、麻、化纤等纤维及金属丝不造成污染,使擦洗的纤维和金属丝易于用水漂洗干净。The invention discloses a cleaning agent for removing heavy dirt and oil stains. The cleaning agent comprises the following components in weight percentage: 5-30% of surfactant; 5-20% of pH regulator; ethanolamine derivative 1 -10%; Fusel oil 10-25%; Essence 0-3%; The balance is water; The surfactant is selected from one or both of anionic surfactants and nonionic surfactants; The fusel oil mentioned above is a by-product produced in the process of producing edible alcohol by fermenting starch as a raw material. The cleaning agent disclosed in the present invention can effectively penetrate into the heavy dirt and greasy dirt deposited on the hard material surface under room temperature and lower temperature conditions; , hemp, chemical fiber and other fibers and metal wires do not cause pollution, so that the scrubbed fibers and metal wires are easy to rinse with water.

Description

A kind of clean-out system of removing heavy dirt and greasy dirt
Technical field
The present invention relates to a kind of chemical field, relate in particular to a kind of clean-out system that is suitable for removing on crust heavy dirt and greasy dirt.
Technical background
Due to the demand of industry and daily life, people have carried out extensive and deep research to the cleaning of heavy oil greasy dirt, black dirt contaminated surface for a long time.Many contrivers have carried out many trials to the washing soil-removing action of various types of tensio-active agents, and the additive synergism of many tensio-active agents is also found, and for many years, many patents disclose many combinations to this.In majority is filled a prescription at present, as follows by the function distinguishing of additive: anion surfactant, nonionogenic tenside, pH adjusting agent, water quality stabilizer, sequestrant, permeate agent, inhibiter etc.Generally speaking, adopt anion surfactant and nonionogenic tenside composite be mainly to utilize that anion surfactant is strong to the removal ability of inorganic mineral dirt, nonionogenic tenside is removed the strong characteristic of ability to oily soil.This is accepted by people substantially.But reach the object of cleaning completely to the surface of being polluted by heavy oil stain is only not all right by general cleaning.The have certain corrosive nature of other strong alkali solution to institute's clean surface is especially especially obvious to the corrosive nature of metallic surface.But clean-out system of the prior art, meets own just few that crust is thoroughly cleaned, and for the crust that speckles with a large amount of greasy dirt dirts, particularly the heavy oil stain surface of pottery, enamel, spraying enamelled coating and metallic surface carries out thoroughly cleaning and remaining a difficult problem.
Summary of the invention
The object of the invention is to the problem for above-mentioned existence, proposed a kind of new clean-out system, not thorough for solving heavy dirt and greasy dirt cleaning to crust that clean-out system of the prior art exists, crust is had to the shortcoming of corrosive nature.
To achieve these goals and other objects, the present invention is achieved by the following technical solutions:
A clean-out system of removing heavy dirt and greasy dirt, described clean-out system comprises the component of following weight percentage:
Figure BDA0000451379940000011
Figure BDA0000451379940000021
Surplus is water;
Described tensio-active agent is selected from one or both in anion surfactant and nonionogenic tenside;
Described potato spirit is that fermenting raw materials is produced the by product producing in edible ethanol technique for adopting starch.
Fusel main body of oil described in the present invention be high-boiling point alcohol kind solvent as propyl carbinol and isopropylcarbinol etc., also contain a small amount of ester class and aldehydes.Potato spirit can with the miscible body of water forming section or dispersion, substitute conventional gylcol ether permeate agent, as a kind of new cheap permeate agent for removing the clean-out system of heavy dirt and greasy dirt.Permeate agent potato spirit Surfactant has solublization, makes detergent solution form stable Solution Dispersion system, thereby has improved seepage force and the cleaning force of tensio-active agent, reaches the thorough cleaning on counterweight dirt surface.
Preferably, described clean-out system comprises the component of following weight percentage:
Surplus is water.
Preferably, described anion surfactant is selected from one or more in long-chain fat alkyl-sulphate, alkylbenzene sulfonate, sulfonated α-olefin, alpha-sulfo fatty acid methyl ester sodium salt, secondary alkyl sulfonate, sulfosuccinate ester salt and fatty alcohol phosphates.
Preferably, described nonionogenic tenside is selected from one or more in alkyl alcohol Pluronic F-127 ether, alkylphenol Pluronic F-127 ether, alkyl fatty acid Pluronic F-127 ether-ether.
Preferably, described tensio-active agent comprises anion surfactant and nonionogenic tenside; Described anion surfactant and the weight ratio of nonionogenic tenside are 1:10~10:1.
Preferably, described tensio-active agent comprises anion surfactant and nonionogenic tenside; Described anion surfactant and the weight ratio of nonionogenic tenside are 1:3~3:1.
Preferably, described anion surfactant is Sodium dodecylbenzene sulfonate and/or sodium lauryl sulphate; Described nonionogenic tenside is Nonyl pheno (10) ether and/or lauryl alcohol polyethylene glycol oxide (12) ether.
Preferably, described pH adjusting agent is selected from one or more in mineral alkali, sodium carbonate, salt of wormwood, water glass and the Starsos such as sodium hydroxide, potassium hydroxide.
Preferably, described ethanolamine derivant is selected from one or more in Monoethanolamine MEA BASF, diethanolamine and trolamine and their derivative.
More preferably, described ethanolamine derivant is trolamine
In clean-out system in the present invention, adopt ethanolamine derivant to there is following beneficial effect as additive: 1) to increase the alkalescence source of clean-out system, by ethanolamine derivant ionization process, help the dispersion of insoluble calcium magnesium salts in clean-out system; 2) increase the solubleness of tensio-active agent, reduce the viscosity of clean-out system, increase the low-temperature stability of clean-out system; 3) as inhibiter, make metal after washing, there is antirust ability.
Preferably, the weight percentage of described potato spirit is 15-25%.
Essence described in the present invention is the conventional essence of clean-out system in prior art.Preferably, described essence is 10% essence alcoholic solution.
The invention also discloses a kind of method of preparing clean-out system described above, comprise the following steps: tensio-active agent, pH adjusting agent, ethanolamine derivant and part water are stirred to solids at 45-50 ℃ and all dissolve, under again under 45-50 ℃ of condition, add potato spirit, essence and excess water, stir; Cooling, filtration.The invention also discloses clean-out system described above in the purposes of removing the heavy dirt of crust and greasy dirt field.
Crust described in the present invention refers to pottery, enamel, spraying enamelled coating and metallic surface.
In the present invention, disclosed clean-out system just can effectively be penetrated in the heavy dirt and greasy dirt of hard material surface deposition under room temperature and lower temperature conditions, makes its swelling be easy to wipe; And on the surface of mechanically resistant material, formed effective protective layer after the scouring of the clean-out system in using the present invention, be conducive to prevent greasy dirt and redeposition, and be beneficial to the removing of new grease; It does not pollute cleaning the fibers such as cotton used, fiber crops, chemical fibre and wire in addition, makes fiber and the wire cleaned be easy to water rinse clean; In addition, this formula is without phosphatization washing composition, and the pollution that ecotope is caused is lighter.
Embodiment
Below, by specific specific examples explanation embodiments of the present invention, those skilled in the art can understand other advantage of the present invention and effect easily by the disclosed content of this specification sheets.The present invention can also be implemented or be applied by other different embodiment, and the every details in this specification sheets also can be based on different viewpoints and application, carries out various modifications or change not deviating under spirit of the present invention.
Embodiment 1
In being equipped with the stainless steel cauldron of mechanical stirring device, add 6 parts of Sodium dodecylbenzene sulfonatees, 3 parts, sodium hydroxide, 3 parts of water glass, 4 parts of trolamines, 50 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add again 15 parts of potato spirit, 1 part of 10% essence alcoholic solution, 18 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
Embodiment 2
In being equipped with the stainless steel cauldron of mechanical stirring device, add 6 parts, Nonyl pheno (10) ether, 3 parts, sodium hydroxide, 3 parts of water glass, 4 parts of trolamines, 50 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 15 parts of potato spirit, 1 part of 10% essence alcoholic solution, 18 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
Embodiment 3
In being equipped with the stainless steel cauldron of mechanical stirring device, add 2 parts of Sodium dodecylbenzene sulfonatees, 4 parts, Nonyl pheno (10) ether, 3 parts, sodium hydroxide, 3 parts of water glass, 4 parts of trolamines, 50 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 15 parts of potato spirit, 1 part of 10% essence alcoholic solution, 18 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
Embodiment 4
In being equipped with the stainless steel cauldron of mechanical stirring device, add 2 parts of sodium lauryl sulphate, 3 parts, lauryl alcohol polyethylene glycol oxide (12) ether, 3 parts, sodium hydroxide, 3 parts of water glass, 4 parts of trolamines, 50 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 20 parts, 14 parts of potato spirit, 1 part of 10% essence alcoholic solution and water, be stirred to evenly, cooling, filter to obtain finished product.
The clean-out system of preparing in embodiment of the present invention 1-4 is carried out to measure of merit, and method is as follows:
Select any and clay in lubricating oil, refined plant oil or Viscotrol C to be mixed to form fluid by 5:1; Respectively the pottery of certain geometrical dimension, enamel, spraying enamelled coating, stainless steel, copper, aluminium matter and these hard materials of polyvinylchloride resin plate are immersed in described fluid, taking-up is placed on 90-100 ℃ and dries 30 minutes, then with the clean-out system in embodiment 1-4, be coated on the contaminated surface of tested hard material, after the stop several seconds, use cellosilk mass wiping.Its test result is in Table 1.
Table 1
Figure BDA0000451379940000051
Table 1 remarks: note: ++ represent that cleaning performance is good; + represent that cleaning performance is general;-represent that cleaning performance is poor;--indicate without cleaning performance.
Embodiment 5
In being equipped with the stainless steel cauldron of mechanical stirring device, add 15 parts of Sodium dodecylbenzene sulfonatees, 6 parts, sodium hydroxide, 6 parts of water glass, 10 parts of trolamines, 31 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add again 10 parts of potato spirit, 2 parts of 10% essence alcoholic solutions, 20 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
The clean-out system of according to testing method identical in embodiment 1-4 being prepared by the present embodiment is tested, and its cleaning performance to pottery, enamel, spraying enamelled coating, stainless steel, copper, aluminium matter and these hard materials of polyvinylchloride resin plate is good.
Embodiment 6
In being equipped with the stainless steel cauldron of mechanical stirring device, add 2 parts of sodium lauryl sulphate, 6 parts, lauryl alcohol polyethylene glycol oxide (12) ether, 5 parts, sodium hydroxide, 2 parts of trolamines, 34 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 10 parts of potato spirit, 41 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
The clean-out system of according to testing method identical in embodiment 1-4 being prepared by the present embodiment is tested, and its cleaning performance to pottery, enamel, spraying enamelled coating, stainless steel, copper, aluminium matter and these hard materials of polyvinylchloride resin plate is good.
Embodiment 7
In being equipped with the stainless steel cauldron of mechanical stirring device, add 6 parts of sodium laurylsulfonates, 2 parts, lauryl alcohol polyethylene glycol oxide (12) ether, 5 parts, sodium hydroxide, 6 parts of trolamines, 30 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 20 parts of potato spirit, 31 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
The clean-out system of according to testing method identical in embodiment 1-4 being prepared by the present embodiment is tested, and its cleaning performance to pottery, enamel, spraying enamelled coating, stainless steel, copper, aluminium matter and these hard materials of polyvinylchloride resin plate is good.
Embodiment 8
In being equipped with the stainless steel cauldron of mechanical stirring device, add 5 parts, Nonyl pheno (10) ether, 3 parts, sodium hydroxide, 3 parts of water glass, 2 parts of trolamines, 49 parts, water, be warming up to 45-50 ℃, after solids all dissolves, add 10 parts of potato spirit, 1 part of 10% essence alcoholic solution, 27 parts, water, be stirred to evenly, cooling, filter to obtain finished product.
The clean-out system of according to testing method identical in embodiment 1-4 being prepared by the present embodiment is tested, and its cleaning performance to pottery, enamel, spraying enamelled coating, stainless steel, copper, aluminium matter and these hard materials of polyvinylchloride resin plate is good.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all can, under spirit of the present invention and category, modify or change above-described embodiment.Therefore, such as in affiliated technical field, have and conventionally know that the knowledgeable, not departing from all equivalence modifications that complete under disclosed spirit and technological thought or changing, must be contained by claim of the present invention.

Claims (10)

1.一种去除重垢和油污的清洗剂,其特征在于,所述的清洗剂包括以下重量百分含量的组分:1. a cleaning agent for removing heavy dirt and greasy dirt, is characterized in that, described cleaning agent comprises the component of following percentage by weight: 余量为水;The remainder is water; 所述的表面活性剂选自阴离子表面活性剂和非离子表面活性剂中的一种或两种;The surfactant is selected from one or both of anionic surfactants and nonionic surfactants; 所述的杂醇油为采用淀粉为原料发酵生产食用酒精工艺中产生的副产物。The fusel oil is a by-product produced in the process of fermenting and producing edible alcohol using starch as a raw material. 2.如权利要求1所述的清洗剂,其特征在于,所述的阴离子表面活性剂选自长链脂肪烷基硫酸盐、烷基苯磺酸盐、α-烯烃磺酸盐、α-磺基脂肪酸甲酯钠盐、仲烷基磺酸盐、磺基琥珀酸酯盐和脂肪醇磷酸酯盐中的一种或多种。2. Cleaning agent as claimed in claim 1, is characterized in that, described anionic surfactant is selected from long-chain fatty alkyl sulfate, alkylbenzene sulfonate, α-olefin sulfonate, α-sulfonate One or more of fatty acid methyl ester sodium salt, secondary alkyl sulfonate, sulfosuccinate salt and fatty alcohol phosphate ester salt. 3.如权利要求1所述的清洗剂,其特征在于,所述的非离子表面活性剂选自烷基醇聚环氧乙烯醚、烷基酚聚环氧乙烯醚、烷基脂肪酸聚环氧乙烯醚酯中的一种或多种。3. cleaning agent as claimed in claim 1, is characterized in that, described nonionic surfactant is selected from alkyl alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, alkyl fatty acid polyoxyethylene ether One or more of vinyl ether esters. 4.如权利要求1所述的清洗剂,其特征在于,所述的表面活性剂包括阴离子表面活性剂和非离子表面活性剂;所述的阴离子表面活性剂和非离子表面活性剂的重量比为1:10~10:1。4. cleaning agent as claimed in claim 1, is characterized in that, described surfactant comprises anionic surfactant and nonionic surfactant; The weight ratio of described anionic surfactant and nonionic surfactant It is 1:10~10:1. 5.如权利要求1所述的清洗剂,其特征在于,所述的表面活性剂包括阴离子表面活性剂和非离子表面活性剂;所述的阴离子表面活性剂和非离子表面活性剂的重量比为1:3~3:1。5. cleaning agent as claimed in claim 1, is characterized in that, described surfactant comprises anionic surfactant and nonionic surfactant; The weight ratio of described anionic surfactant and nonionic surfactant It is 1:3~3:1. 6.如权利要求1所述的清洗剂,其特征在于,所述的pH调节剂选自氢氧化钠、氢氧化钾无机碱、碳酸钠、碳酸钾、硅酸钠和偏硅酸钠中的一种或多种。6. cleaning agent as claimed in claim 1, is characterized in that, described pH adjusting agent is selected from sodium hydroxide, potassium hydroxide inorganic alkali, sodium carbonate, salt of wormwood, sodium silicate and sodium metasilicate one or more. 7.如权利要求1所述的清洗剂,其特征在于,所述的乙醇胺衍生物选自一乙醇胺、二乙醇胺和三乙醇胺及它们的衍生物中的一种或多种。7. The cleaning agent according to claim 1, characterized in that, said ethanolamine derivative is selected from one or more of monoethanolamine, diethanolamine, triethanolamine and their derivatives. 8.如权利要求1所述的清洗剂,其特征在于,所述的杂醇油的重量百分含量为15-25%。8. cleaning agent as claimed in claim 1 is characterized in that, the weight percent composition of described fusel oil is 15-25%. 9.一种制备如权利要求1-8任一所述的清洗剂的方法,包括以下步骤:将表面活性剂、pH调节剂、乙醇胺衍生物和部分水在45-50℃下搅拌至固体物全部溶解,再在45-50℃条件下加入杂醇油、香精和余量水,搅拌、冷却、过滤。9. A method for preparing a cleaning agent as described in any one of claims 1-8, comprising the steps of stirring surfactant, pH regulator, ethanolamine derivative and part of water at 45-50°C until solid All dissolved, then add fusel oil, essence and the rest of water at 45-50°C, stir, cool, and filter. 10.如权利要求1-8任一权利要求所述的清洗剂在去除硬表面重垢和油污领域的用途。10. use of the cleaning agent according to any one of claims 1-8 in removing heavy dirt and greasy dirt from hard surfaces.
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CN104263546A (en) * 2014-10-02 2015-01-07 济南瑞东实业有限公司 Efficient pollution-free industrial water-based full cleaning agent and preparation method thereof
CN104450277A (en) * 2014-11-27 2015-03-25 镇江润德节能科技有限公司 Preparation method for electroplating cleaning degreasing agent
CN105062708A (en) * 2015-08-10 2015-11-18 兰州瑞普科技实业有限责任公司 Cleaning agent for water-oil heat exchange plate type heat exchanger
CN105543880A (en) * 2015-12-22 2016-05-04 苏州博洋化学股份有限公司 Cleaning agent special for grinding and preparation method thereof
CN106047515A (en) * 2016-05-25 2016-10-26 天津市环境保护科学研究院 Detergent and use method
CN106318686A (en) * 2016-08-16 2017-01-11 中轻日化科技有限公司 Efficient and environment-friendly concentrated hard surface cleaning agent
CN106676552A (en) * 2016-12-30 2017-05-17 宁波际超新材料科技有限公司 Phosphorus-free degreasant and manufacturing method thereof
CN106929165A (en) * 2017-03-03 2017-07-07 安徽欣创节能环保科技股份有限公司 A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter
CN109370810A (en) * 2018-11-26 2019-02-22 济南惠成达科技有限公司 A kind of heavy oil greasy dirt detergent and preparation method thereof
CN109468176A (en) * 2018-12-29 2019-03-15 河南绿澳化工科技有限公司 A kind of kitchen appliance scavenger specially
CN109777672A (en) * 2017-11-10 2019-05-21 宁夏宝塔化工中心实验室(有限公司) A kind of non-aqueous cleaning agent of oil product use for laboratory and preparation method thereof
CN112592770A (en) * 2020-11-30 2021-04-02 中海油能源发展股份有限公司 Heavy oil cleaning agent and preparation and cleaning methods thereof

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263546A (en) * 2014-10-02 2015-01-07 济南瑞东实业有限公司 Efficient pollution-free industrial water-based full cleaning agent and preparation method thereof
CN104450277A (en) * 2014-11-27 2015-03-25 镇江润德节能科技有限公司 Preparation method for electroplating cleaning degreasing agent
CN105062708A (en) * 2015-08-10 2015-11-18 兰州瑞普科技实业有限责任公司 Cleaning agent for water-oil heat exchange plate type heat exchanger
CN105543880A (en) * 2015-12-22 2016-05-04 苏州博洋化学股份有限公司 Cleaning agent special for grinding and preparation method thereof
CN106047515A (en) * 2016-05-25 2016-10-26 天津市环境保护科学研究院 Detergent and use method
CN106318686B (en) * 2016-08-16 2020-06-05 中轻日化科技有限公司 Efficient environment-friendly concentrated hard surface cleaning agent
CN106318686A (en) * 2016-08-16 2017-01-11 中轻日化科技有限公司 Efficient and environment-friendly concentrated hard surface cleaning agent
CN106676552A (en) * 2016-12-30 2017-05-17 宁波际超新材料科技有限公司 Phosphorus-free degreasant and manufacturing method thereof
CN106929165A (en) * 2017-03-03 2017-07-07 安徽欣创节能环保科技股份有限公司 A kind of cleaning agent and cleaning method for being applied to hot rolling sewage circulating high rate filter
CN109777672A (en) * 2017-11-10 2019-05-21 宁夏宝塔化工中心实验室(有限公司) A kind of non-aqueous cleaning agent of oil product use for laboratory and preparation method thereof
CN109370810A (en) * 2018-11-26 2019-02-22 济南惠成达科技有限公司 A kind of heavy oil greasy dirt detergent and preparation method thereof
CN109468176A (en) * 2018-12-29 2019-03-15 河南绿澳化工科技有限公司 A kind of kitchen appliance scavenger specially
CN112592770A (en) * 2020-11-30 2021-04-02 中海油能源发展股份有限公司 Heavy oil cleaning agent and preparation and cleaning methods thereof

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