CN103694864A - Heat-resisting waterproof organic silicone impregnating paint - Google Patents
Heat-resisting waterproof organic silicone impregnating paint Download PDFInfo
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- CN103694864A CN103694864A CN201310630150.6A CN201310630150A CN103694864A CN 103694864 A CN103694864 A CN 103694864A CN 201310630150 A CN201310630150 A CN 201310630150A CN 103694864 A CN103694864 A CN 103694864A
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- 239000003973 paint Substances 0.000 title claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 10
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims abstract description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims abstract description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 7
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims abstract description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004202 carbamide Substances 0.000 claims abstract description 7
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 4
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003822 epoxy resin Substances 0.000 claims abstract description 4
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 229920002050 silicone resin Polymers 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000002966 varnish Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229940043232 butyl acetate Drugs 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 229940082004 sodium laurate Drugs 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- PIILXFBHQILWPS-UHFFFAOYSA-N tributyltin Chemical compound CCCC[Sn](CCCC)CCCC PIILXFBHQILWPS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- HVHNMNGARPCGGD-UHFFFAOYSA-N 2-nitro-p-phenylenediamine Chemical compound NC1=CC=C(N)C([N+]([O-])=O)=C1 HVHNMNGARPCGGD-UHFFFAOYSA-N 0.000 abstract 1
- 239000005711 Benzoic acid Substances 0.000 abstract 1
- GCTFWCDSFPMHHS-UHFFFAOYSA-M Tributyltin chloride Chemical compound CCCC[Sn](Cl)(CCCC)CCCC GCTFWCDSFPMHHS-UHFFFAOYSA-M 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 229920000180 alkyd Polymers 0.000 abstract 1
- 235000010233 benzoic acid Nutrition 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 230000037303 wrinkles Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 101000655188 Homo sapiens Tachykinin-3 Proteins 0.000 description 1
- 102100033009 Tachykinin-3 Human genes 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to paint, and particularly relates to a heat-resisting waterproof organic silicone impregnating paint. The paint is prepared from the following raw materials in parts by weight: 23-26 parts of organic silicone resin, 2-3 parts of diethylenetriamine, 12-14 parts of alkyd resin, 14-16 parts of E-12 epoxy resin, 8-10 parts of maleic anhydride, 3-5 parts of benzoic acid, 10-12 parts of trimethylolpropane triacrylate, 50-55 parts of polyester acrylate, 1-2 parts of nitro-p-phenylenediamine, 2-3 parts of urea, 1-2 parts of dibenzothiazyl disulfide DM, 2-3 parts of paraffin, 1-2 parts of tributyl tin chloride, 2-3 parts of crosslinking agent TAC, 5-6 parts of assistant, 10-12 parts of xylene and 10-12 parts of butyl acetate. The paint film disclosed by the invention is hard and flexible, strong in adhesive force on an object, fast to dry, compact and impact resistant, can endure high temperature and damp heat, is waterproof and damp-proof, anti-rust and anti-corrosion, good in electric property, and safe and reliable to use.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to a kind of high temperature resistant waterproof silicone impregnating varnish and preparation technology thereof.
Background technology
Paint is seen everywhere in schedule life; it has been mainly the effect of protection and decoration, and according to different environments for use, the kind of paint is also varied; traditional paint ubiquity smell weighs, easily comes off, perishable; the problems such as inadequate environmental protection, can not meet the service requirements of human consumer to paint, therefore; need to improve the formula of original paint; the practicality and the weather resistance that increase paint, reduce its harm to environment and human body, and can adapt to various environment for use conditions.
Summary of the invention
The object of the invention is to, a kind of high temperature resistant waterproof silicone impregnating varnish is provided, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of high temperature resistant waterproof silicone impregnating varnish, it is characterized in that, material of the present invention is made by the raw material of following weight part: silicone resin 23-26, diethylenetriamine 2-3, Synolac 12-14, E-12 epoxy resin 14-16, MALEIC ANHYDRIDE 8-10, phenylformic acid 3-5, Viscoat 295 10-12, polyester acrylate 50-55, 2-nitro P-pHENYLENE dI AMINE 1-2, urea 2-3, dibenzothiazyl disulfide DM1-2, paraffin 2-3, tributyl tin trichloride 1-2, linking agent TAC2-3, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.
Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
Described a kind of high temperature resistant waterproof silicone impregnating varnish, its preparation technology is:
(1) phenylformic acid, Viscoat 295, paraffin, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds MALEIC ANHYDRIDE, urea, dibenzothiazyl disulfide DM, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Compared with prior art, the present invention's paint possesses following advantage: paint film is hard pliable and tough, with the strong adhesion of object, fast drying, fine and close shock-resistant, can be high temperature resistant damp and hot, and anti-water resistance tide, antirust, anti-corrosive, electrical property is good, safe and reliable.
Embodiment
Embodiment
The present embodiment paint is made by following weight part raw material: silicone resin 26, diethylenetriamine 3, Synolac 14, E-12 epoxy resin 16, MALEIC ANHYDRIDE 10, phenylformic acid 5, Viscoat 295 12, polyester acrylate 55,2-nitro P-pHENYLENE dI AMINE 2, urea 3, dibenzothiazyl disulfide DM2, paraffin 3, tributyl tin trichloride 1, linking agent TAC3, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.
Described auxiliary agent is made by the raw material of following weight part: loess 2, polytetrafluoroethylene powder 5, altax 2, Silane coupling agent KH550 4, sodium laurate 2, jade 2, Whitfield's ointment 3, phthalic ester 40, Tenox PG 4, coix seed oil 3, vanadium diboride 2, l-Epicatechol 3; Preparation method sends into loess, jade in calcining furnace and at 720-740 ℃, calcines 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.
Described a kind of high temperature resistant waterproof silicone impregnating varnish, its preparation technology is:
(1) phenylformic acid, Viscoat 295, paraffin, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;
(2) material of step (1) is cooled to 70-85 ℃, adds MALEIC ANHYDRIDE, urea, dibenzothiazyl disulfide DM, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 60 μ m slurries, obtains.
The performance test results of the present invention's paint is:
| Test event | Technical indicator |
| Outward appearance | Paint film is smooth, light is plentiful |
| Surface drying time/h | ≤2 |
| Do solid work time/h | ≤22 |
| Snappiness/mm | ≤2 |
| Pencil hardness (7d) | ≥2H |
| Shock strength kg/cm | ≥50 |
| Sticking power grade | ≤1 |
| Humidity resistance (85 ℃ * 48h) | Non-foaming, wrinkle resistant, do not come off |
| Water tolerance (25 ℃ * 48h) | Non-foaming, wrinkle resistant, do not come off |
| Alkali resistance (68h) | Non-foaming, wrinkle resistant, do not come off |
| Acid resistance (68h) | Non-foaming, wrinkle resistant, do not come off |
| Coating surface resistivity/Ω | 4.6×10 12 |
| Thermotolerance (300 ℃ * 100h) | Completely do not come off |
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a high temperature resistant waterproof silicone impregnating varnish, it is characterized in that, this paint is made by the raw material of following weight part: silicone resin 23-26, diethylenetriamine 2-3, Synolac 12-14, E-12 epoxy resin 14-16, MALEIC ANHYDRIDE 8-10, phenylformic acid 3-5, Viscoat 295 10-12, polyester acrylate 50-55, 2-nitro P-pHENYLENE dI AMINE 1-2, urea 2-3, dibenzothiazyl disulfide DM 1-2, paraffin 2-3, tributyl tin trichloride 1-2, linking agent TAC 2-3, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12,
Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
2. a kind of high temperature resistant waterproof silicone impregnating varnish as claimed in claim 1, its manufacture craft is:
(1) phenylformic acid, Viscoat 295, paraffin, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds MALEIC ANHYDRIDE, urea, dibenzothiazyl disulfide DM, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630150.6A CN103694864A (en) | 2013-11-29 | 2013-11-29 | Heat-resisting waterproof organic silicone impregnating paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630150.6A CN103694864A (en) | 2013-11-29 | 2013-11-29 | Heat-resisting waterproof organic silicone impregnating paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103694864A true CN103694864A (en) | 2014-04-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310630150.6A Pending CN103694864A (en) | 2013-11-29 | 2013-11-29 | Heat-resisting waterproof organic silicone impregnating paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103694864A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881542A (en) * | 2014-02-25 | 2014-06-25 | 蚌埠凯盛工程技术有限公司 | High temperature-resistant waterproof organic silicon impregnating varnish |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1646640A (en) * | 2002-04-15 | 2005-07-27 | 日本瑞翁株式会社 | Varnish, shaped item, electrical insulating film, laminate, flame retardant slurry and process for producing flame retardant particle and varnish |
| US20070179268A1 (en) * | 2006-01-27 | 2007-08-02 | Alain Lejeune | Low VOC epoxy silane oligomer and compositions containing same |
| CN101412887A (en) * | 2008-11-10 | 2009-04-22 | 嘉丰木业（苏州）有限公司 | Floor paint |
| CN102015935A (en) * | 2008-03-18 | 2011-04-13 | 纳米X有限公司 | Method for the production of a highly abrasion-resistant vehicle paint, vehicle paint, and the use thereof |
| CN102757728A (en) * | 2011-04-25 | 2012-10-31 | 陶氏环球技术有限公司 | Moisture-solidified antifouling paint composition |
| CN103382366A (en) * | 2013-06-27 | 2013-11-06 | 马鞍山采石矶涂料有限公司 | High-temperature resistance organic silicon impregnating varnish and preparation method thereof |
-
2013
- 2013-11-29 CN CN201310630150.6A patent/CN103694864A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1646640A (en) * | 2002-04-15 | 2005-07-27 | 日本瑞翁株式会社 | Varnish, shaped item, electrical insulating film, laminate, flame retardant slurry and process for producing flame retardant particle and varnish |
| US20070179268A1 (en) * | 2006-01-27 | 2007-08-02 | Alain Lejeune | Low VOC epoxy silane oligomer and compositions containing same |
| CN102015935A (en) * | 2008-03-18 | 2011-04-13 | 纳米X有限公司 | Method for the production of a highly abrasion-resistant vehicle paint, vehicle paint, and the use thereof |
| CN101412887A (en) * | 2008-11-10 | 2009-04-22 | 嘉丰木业（苏州）有限公司 | Floor paint |
| CN102757728A (en) * | 2011-04-25 | 2012-10-31 | 陶氏环球技术有限公司 | Moisture-solidified antifouling paint composition |
| CN103382366A (en) * | 2013-06-27 | 2013-11-06 | 马鞍山采石矶涂料有限公司 | High-temperature resistance organic silicon impregnating varnish and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881542A (en) * | 2014-02-25 | 2014-06-25 | 蚌埠凯盛工程技术有限公司 | High temperature-resistant waterproof organic silicon impregnating varnish |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140402 |
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