CN103709810A - Weather resistant and anticorrosive epoxy resin automobile paint - Google Patents
Weather resistant and anticorrosive epoxy resin automobile paint Download PDFInfo
- Publication number
- CN103709810A CN103709810A CN201310630147.4A CN201310630147A CN103709810A CN 103709810 A CN103709810 A CN 103709810A CN 201310630147 A CN201310630147 A CN 201310630147A CN 103709810 A CN103709810 A CN 103709810A
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- Prior art keywords
- paint
- weather
- epoxy resin
- hour
- cooled
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000003973 paint Substances 0.000 title claims abstract description 17
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 14
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 14
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims abstract description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 10
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 7
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 7
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 claims abstract description 7
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims abstract description 7
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims abstract description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims abstract description 4
- 229920003180 amino resin Polymers 0.000 claims abstract description 4
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229940043232 butyl acetate Drugs 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- PFTAWBLQPZVEMU-UKRRQHHQSA-N (-)-epicatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UKRRQHHQSA-N 0.000 claims description 3
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 claims description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
- 244000077995 Coix lacryma jobi Species 0.000 claims description 3
- 241000276489 Merlangius merlangus Species 0.000 claims description 3
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- -1 polytetrafluoroethylene Polymers 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 3
- 229940082004 sodium laurate Drugs 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 229910052720 vanadium Inorganic materials 0.000 claims description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 229940008841 1,6-hexamethylene diisocyanate Drugs 0.000 abstract 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 abstract 1
- 235000013773 glyceryl triacetate Nutrition 0.000 abstract 1
- 239000001087 glyceryl triacetate Substances 0.000 abstract 1
- 230000014759 maintenance of location Effects 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 239000005033 polyvinylidene chloride Substances 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 229960002622 triacetin Drugs 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a paint, in particular to a weather resistant and anticorrosive epoxy resin automobile paint, which is made of the following raw materials in parts by weight: 28-35 of E-20 epoxy resin, 8-10 of polyvinylidene chloride, 18-22 of methylated amino resin, 3-5 of pentaerythritol, 3-4 of potassium titanate whisker, 0.8-1.2 of an accelerator DTDM, 15-20 of triethylene glycol Di-2-ethylhexoate, 4-5 of shell powder, 8-10 of acrylonitrile, 2-3 of zinc borate, 2-3 of ferroferric oxide, 12-15 of glyceryl triacetate, 3-5 of 1, 6-hexamethylene diisocyanate, 1-2 of dicumyl peroxide, 5-6 of an assistant, 10-12 of xylene, and 10-12 of butyl acetate. The paint provided by the invention has good adhesion to metals and plastics, is not easy to fall off, has a bright and full paint film, is resistant to sunlight irradiation, has long color retention, also has the characteristics of weather and aging resistance, oil resistance, environmental condition corrosion delaying and the like, and is safe and reliable to use.
Description
Technical field
The present invention relates to a kind of paint, be specifically related to a kind of weather-proof corrosion-proof ring epoxy resins automobile finish and preparation technology thereof.
Background technology
Paint is seen everywhere in schedule life; it has been mainly the effect of protection and decoration, and according to different environments for use, the kind of paint is also varied; traditional paint ubiquity smell weighs, easily comes off, perishable; the problems such as inadequate environmental protection, can not meet the service requirements of human consumer to paint, therefore; need to improve the formula of original paint; the practicality and the weather resistance that increase paint, reduce its harm to environment and human body, and can adapt to various environment for use conditions.
Summary of the invention
The object of the invention is to, a kind of weather-proof corrosion-proof ring epoxy resins automobile finish is provided, to achieve these goals, the technical solution used in the present invention is as follows:
A kind of weather-proof corrosion-proof ring epoxy resins automobile finish, it is characterized in that, material of the present invention is made by the raw material of following weight part: E-20 epoxy resin 28-35, polyvinylidene dichloride 8-10, methyl-etherified aminoresin 18-22, tetramethylolmethane 3-5, potassium titanate crystal whisker 3-4, vulkacit D TDM0.8-1.2, triglycol two 2-ethylhexoate 15-20, oyster shell whiting 4-5, vinyl cyanide 8-10, zinc borate 2-3, Z 250 2-3, glycerine triacetate 12-15, hexamethylene diisocyanate 3-5, dicumyl peroxide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12.
Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
Described a kind of weather-proof corrosion-proof ring epoxy resins automobile finish, its preparation technology is:
(1) tetramethylolmethane, potassium titanate crystal whisker, triglycol two 2-ethylhexoates, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds vinyl cyanide, glycerine triacetate, hexamethylene diisocyanate, dicumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Compared with prior art, the present invention's paint possesses following advantage: good with the sticking power of metal and plastics, and difficult drop-off, paint film light is full, and resistance to terrestrial solar radiation is protected look lasting, also weather-proof aging, and oil resistant delays envrionment conditions corrosion, long service life.
Embodiment
Embodiment
The present embodiment paint is made by following weight part raw material: E-20 epoxy resin 35, polyvinylidene dichloride 10, methyl-etherified aminoresin 22, tetramethylolmethane 5, potassium titanate crystal whisker 4, vulkacit D TDM1.2, triglycol two 2-ethylhexoates 20, oyster shell whiting 5, vinyl cyanide 10, zinc borate 3, Z 250 3, glycerine triacetate 15, hexamethylene diisocyanate 5, dicumyl peroxide 2, auxiliary agent 6, dimethylbenzene 12, butylacetate 12.
Described auxiliary agent is made by the raw material of following weight part: loess 2, polytetrafluoroethylene powder 5, altax 2, Silane coupling agent KH550 4, sodium laurate 2, jade 2, Whitfield's ointment 3, phthalic ester 40, Tenox PG 4, coix seed oil 3, vanadium diboride 2, l-Epicatechol 3; Preparation method sends into loess, jade in calcining furnace and at 720-740 ℃, calcines 3 hours, then takes out, and sends in 15% hydrochloric acid soln and soaks 3 hours, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 600 order powders; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 50 minutes is cooling, grinds to form slurry, obtains.
Described a kind of weather-proof corrosion-proof ring epoxy resins automobile finish, its preparation technology is:
(1) tetramethylolmethane, potassium titanate crystal whisker, triglycol two 2-ethylhexoates, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, react 4 hours;
(2) material of step (1) is cooled to 70-85 ℃, adds vinyl cyanide, glycerine triacetate, hexamethylene diisocyanate, dicumyl peroxide, stirring reaction 4 hours;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, stirring reaction, after 60 minutes, is cooled to room temperature, grinds to form 60 μ m slurries, obtains.
The performance test results of the present invention's paint is:
Above-mentioned test is all followed relevant criterion and is carried out.
Claims (2)
1. a weather-proof corrosion-proof ring epoxy resins automobile finish, it is characterized in that, this paint is made by the raw material of following weight part: E-20 epoxy resin 28-35, polyvinylidene dichloride 8-10, methyl-etherified aminoresin 18-22, tetramethylolmethane 3-5, potassium titanate crystal whisker 3-4, vulkacit D TDM 0.8-1.2, triglycol two 2-ethylhexoate 15-20, oyster shell whiting 4-5, vinyl cyanide 8-10, zinc borate 2-3, Z 250 2-3, glycerine triacetate 12-15, hexamethylene diisocyanate 3-5, dicumyl peroxide 1-2, auxiliary agent 5-6, dimethylbenzene 10-12, butylacetate 10-12;
Described auxiliary agent is made by the raw material of following weight part: loess 1-2, polytetrafluoroethylene powder 4-5, altax 1-2, Silane coupling agent KH550 3-4, sodium laurate 1-2, jade 1-2, Whitfield's ointment 2-3, phthalic ester 35-40, Tenox PG 3-4, coix seed oil 2-3, vanadium diboride 1-2, l-Epicatechol 2-3; Preparation method sends into loess, jade in calcining furnace and calcine 2-3 hour at 720-740 ℃, then takes out, and sends in the hydrochloric acid soln of 10-15% and soaks 2-3 hour, filters, and obtains filter residue, with clear water, cleans, and dries, grinds to form 400-600 order powder; Gained powder mixes with other remaining component, is heated to 60-70 ℃, and stirring reaction 40-50 minute is cooling, grinds to form slurry, obtains.
2. a kind of weather-proof corrosion-proof ring epoxy resins automobile finish as claimed in claim 1, its manufacture craft is:
(1) tetramethylolmethane, potassium titanate crystal whisker, triglycol two 2-ethylhexoates, auxiliary agent are mixed, join in dimethylbenzene, butyl acetate solvent, be heated to 120-130 ℃, reaction 3-4 hour;
(2) material of step (1) is cooled to 70-85 ℃, adds vinyl cyanide, glycerine triacetate, hexamethylene diisocyanate, dicumyl peroxide, stirring reaction 3-4 hour;
(3) material of step (2) is cooled to 50-65 ℃, adds other leftover materials, after stirring reaction 40-60 minute, be cooled to room temperature, grind to form 20-60 μ m slurry, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630147.4A CN103709810A (en) | 2013-11-29 | 2013-11-29 | Weather resistant and anticorrosive epoxy resin automobile paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310630147.4A CN103709810A (en) | 2013-11-29 | 2013-11-29 | Weather resistant and anticorrosive epoxy resin automobile paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709810A true CN103709810A (en) | 2014-04-09 |
Family
ID=50403182
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310630147.4A Pending CN103709810A (en) | 2013-11-29 | 2013-11-29 | Weather resistant and anticorrosive epoxy resin automobile paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709810A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881448A (en) * | 2014-02-25 | 2014-06-25 | 安徽普源分离机械制造有限公司 | Weather-proof antiseptic epoxy resin paint for car |
| CN104371482A (en) * | 2014-10-31 | 2015-02-25 | 无锡阳工机械制造有限公司 | High-temperature resistant mechanical coating |
| CN105153834A (en) * | 2015-08-21 | 2015-12-16 | 无锡乐华自动化科技有限公司 | Anticorrosive coating for hub |
| CN109679416A (en) * | 2019-01-03 | 2019-04-26 | 珠海市威旗防腐科技股份有限公司 | A kind of aqueous vinylidene chloride coating and preparation method thereof |
| CN114456652A (en) * | 2022-03-14 | 2022-05-10 | 中航百慕新材料技术工程股份有限公司 | Water-based anticorrosive paint and preparation method and application thereof |
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|---|---|---|---|---|
| CN1152595A (en) * | 1995-12-08 | 1997-06-25 | 刘泽江 | Corrosion-resistance paint |
| EP1116758A2 (en) * | 1999-12-23 | 2001-07-18 | Solutia Austria GmbH | Aqeous coating compound |
| CN1456618A (en) * | 2003-05-29 | 2003-11-19 | 四川大学 | Vehicle finish with polymer/inorganic composite nano-powder and preparing method thereof |
| CN101384677A (en) * | 2005-08-17 | 2009-03-11 | 日本帕卡濑精株式会社 | Water-based surface treatment agent for metal materials and surface-coated metal materials |
| CN101492588A (en) * | 2009-02-23 | 2009-07-29 | 衡阳市化工研究所有限公司 | Interpenetrating polymer network anticorrosion paint and production method thereof |
| CN102643594A (en) * | 2011-02-22 | 2012-08-22 | 项妙祥 | Durable fresh-maintained preservative primer |
-
2013
- 2013-11-29 CN CN201310630147.4A patent/CN103709810A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1152595A (en) * | 1995-12-08 | 1997-06-25 | 刘泽江 | Corrosion-resistance paint |
| EP1116758A2 (en) * | 1999-12-23 | 2001-07-18 | Solutia Austria GmbH | Aqeous coating compound |
| CN1456618A (en) * | 2003-05-29 | 2003-11-19 | 四川大学 | Vehicle finish with polymer/inorganic composite nano-powder and preparing method thereof |
| CN101384677A (en) * | 2005-08-17 | 2009-03-11 | 日本帕卡濑精株式会社 | Water-based surface treatment agent for metal materials and surface-coated metal materials |
| CN101492588A (en) * | 2009-02-23 | 2009-07-29 | 衡阳市化工研究所有限公司 | Interpenetrating polymer network anticorrosion paint and production method thereof |
| CN102643594A (en) * | 2011-02-22 | 2012-08-22 | 项妙祥 | Durable fresh-maintained preservative primer |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103881448A (en) * | 2014-02-25 | 2014-06-25 | 安徽普源分离机械制造有限公司 | Weather-proof antiseptic epoxy resin paint for car |
| CN104371482A (en) * | 2014-10-31 | 2015-02-25 | 无锡阳工机械制造有限公司 | High-temperature resistant mechanical coating |
| CN105153834A (en) * | 2015-08-21 | 2015-12-16 | 无锡乐华自动化科技有限公司 | Anticorrosive coating for hub |
| CN109679416A (en) * | 2019-01-03 | 2019-04-26 | 珠海市威旗防腐科技股份有限公司 | A kind of aqueous vinylidene chloride coating and preparation method thereof |
| CN114456652A (en) * | 2022-03-14 | 2022-05-10 | 中航百慕新材料技术工程股份有限公司 | Water-based anticorrosive paint and preparation method and application thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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Application publication date: 20140409 |