CN103666043B - UV ink that a kind of quick solidifying sticking power is good and preparation method thereof - Google Patents
UV ink that a kind of quick solidifying sticking power is good and preparation method thereof Download PDFInfo
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- CN103666043B CN103666043B CN201310600485.3A CN201310600485A CN103666043B CN 103666043 B CN103666043 B CN 103666043B CN 201310600485 A CN201310600485 A CN 201310600485A CN 103666043 B CN103666043 B CN 103666043B
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Abstract
The invention discloses the UV ink that a kind of quick solidifying sticking power is good, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-40, ethyl propenoate 10-14, methylethylketone 10-12, aminoresin 20-23, dimethyl silicone oil 4-5, humic acid 1-2, stearyl alcohol 1-2, methacrylic ester 3-4, vinyl ether-type carbamate 20-24,2-hydroxyl-2? methyl-1? phenyl-1? acetone 4-6, tributyl tin trichloride 2-3, auxiliary agent 4-5; Auxiliary agent of the present invention improves the toughness of ink, makes distributes ink even, and maintains the stability of ink; Invention increases the snappiness of cured film, ensure the good adhesion of double exposure ink film, solidification rapidly, improves quality product.
Description
Technical field
The present invention relates to a kind of ink and preparation method thereof, UV ink that particularly a kind of quick solidifying sticking power is good and preparation method thereof.
Background technology
Ultraviolet light polymerization (UV) ink refers under uviolizing, utilizes the UV-light of different wave length and energy to make ink film forming and dry ink.Utilize different UV spectrum, can different-energy be produced, the monomer polymerization in different ink vehicle is become polymkeric substance, so the look film of UV ink has good machinery and chemical property.The curing mechanism of UV curable ink is, after the light trigger in system directly or indirectly absorbs ultraviolet luminous energy, from ground state transition to excited singlet, alters and jump to excited triplet state between being; Excited singlet or triplet state experience unit molecule or bimolecular chemical action after, produce can trigger monomer polymerization biologically active fragment, these fragments can be free radical, positively charged ion, negatively charged ion or ion radical.The major advantage of UV ink has: (1) is without solvent; (2) rate of drying is fast, and power consumption is few; (3) good luster, bright in luster; (4) water-fast, solvent resistant, wear resisting property is good.In UV ink, light trigger is that one is subject to light activated compound, after absorb light is shone, be excited into free radical, and energy trasfer, to photosensitivity molecule or photocrosslinking agent, makes UV ink that photocuring reaction occur.Current UV ink has become a kind of more ripe ink technology, and its pollutant emission is almost nil.Except not containing solvent, UV ink also just like not easily scumming, the advantages such as site is clear, the bright-coloured light of mass colour, and chemical resistance is excellent, low-consuming.
Summary of the invention
The object of this invention is to provide good UV ink of a kind of quick solidifying sticking power and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
The UV ink that quick solidifying sticking power is good, is made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-40, ethyl propenoate 10-14, methylethylketone 10-12, aminoresin 20-23, dimethyl silicone oil 4-5, humic acid 1-2, stearyl alcohol 1-2, methacrylic ester 3-4, vinyl ether-type carbamate 20-24, phenyl-1, methyl-1,2-hydroxyl-2 acetone 4-6, tributyl tin trichloride 2-3, auxiliary agent 4-5;
Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV ink that quick solidifying sticking power of the present invention is good, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, ethyl propenoate, methylethylketone, aminoresin, dimethyl silicone oil, humic acid, stearyl alcohol stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except the acetone of phenyl-1, methyl-1,2-hydroxyl-2 are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add phenyl-1, methyl-1,2-hydroxyl-2 acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The invention has the beneficial effects as follows: auxiliary agent of the present invention improves the toughness of ink, make distributes ink even, and maintain the stability of ink; Invention increases the snappiness of cured film, ensure the good adhesion of double exposure ink film, solidification rapidly, improves quality product.
Specific embodiments
Below by specific examples, the present invention is described in detail.
The UV ink that quick solidifying sticking power is good, is made up of the raw material of following weight part (kilogram): pigment dyestuff 1, urethane acrylate 30, ethyl propenoate 10, methylethylketone 10, aminoresin 20, dimethyl silicone oil 4, humic acid 1, stearyl alcohol 1, methacrylic ester 3, vinyl ether-type carbamate 20, phenyl-1, methyl-1,2-hydroxyl-2 acetone 4, tributyl tin trichloride 2, auxiliary agent 4;
Described auxiliary agent is prepared from by the raw material of following weight part (kilogram): nano diatomite powder 0.2, nano mica powder 0.2, silane resin acceptor kh-550 2, morpholine 1, neopentyl glycol 3, oxidation inhibitor 10351, linking agent TAC2, tri (propylene glycol) diacrylate 10,1-Methoxy-2-propyl acetate 5, Tenox PG 2, coix seed oil 1; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
The UV ink that quick solidifying sticking power of the present invention is good, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, ethyl propenoate, methylethylketone, aminoresin, dimethyl silicone oil, humic acid, stearyl alcohol stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except the acetone of phenyl-1, methyl-1,2-hydroxyl-2 are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add phenyl-1, methyl-1,2-hydroxyl-2 acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
The ink of gained, uses cross-hatching ox-hide tape stripping, draws compartment apart from 1mm, 100% attachment; Use the spirituous cotton balls of leaching, 300 grams of pressure wipings 50 times, are as good as shape; To be soaked in salad oil (normal temperature) 8 hours, to be as good as shape; Use and be soaked with the cotton balls of salt solution, 300 grams of pressure wipings 50 times, are as good as shape.
Claims (2)
1. the UV ink that a quick solidifying sticking power is good, it is characterized in that, be made up of the raw material of following weight part: pigment dyestuff 1-3, urethane acrylate 30-40, ethyl propenoate 10-14, methylethylketone 10-12, aminoresin 20-23, dimethyl silicone oil 4-5, humic acid 1-2, stearyl alcohol 1-2, methacrylic ester 3-4, vinyl ether-type carbamate 20-24,2-hydroxyl-2-methyl-1-phenyl-1-acetone 4-6, tributyl tin trichloride 2-3, auxiliary agent 4-5; Described auxiliary agent is prepared from by the raw material of following weight part: nano diatomite powder 0.2-0.3, nano mica powder 0.2-0.3, silane resin acceptor kh-550 2-3, morpholine 1-2, neopentyl glycol 3-4, oxidation inhibitor 10351-2, linking agent TAC2-3, tri (propylene glycol) diacrylate 10-12,1-Methoxy-2-propyl acetate 5-10, Tenox PG 2-3, coix seed oil 1-2; Its preparation method is by each mixing of materials, is heated to 60-70 DEG C, and stirring reaction 30-40 minute, to obtain final product.
2. the UV ink that quick solidifying sticking power is good according to claim 1, it is characterized in that, be made up of following concrete steps: first add pigment dyestuff, urethane acrylate, ethyl propenoate, methylethylketone, aminoresin, dimethyl silicone oil, humic acid, stearyl alcohol stirring and evenly mixing, be heated to 80-90 DEG C, stir 25-35 minute; Then all the other remaining components except 2-hydroxyl-2-methyl-1-phenyl-1-acetone are added, stirring reaction 3-5 hour; Finally be cooled to 60-70 DEG C, add 2-hydroxyl-2-methyl-1-phenyl-1-acetone, stirring reaction 40-50 minute, after cooling, grinding obtains 20-40 μm of slurry, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310600485.3A CN103666043B (en) | 2013-11-25 | 2013-11-25 | UV ink that a kind of quick solidifying sticking power is good and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310600485.3A CN103666043B (en) | 2013-11-25 | 2013-11-25 | UV ink that a kind of quick solidifying sticking power is good and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103666043A CN103666043A (en) | 2014-03-26 |
| CN103666043B true CN103666043B (en) | 2016-04-13 |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194471B (en) * | 2014-07-28 | 2016-06-15 | 蚌埠首创滤清器有限公司 | A kind of printing-ink being modifiied preparation by wasted ink powder |
| CN104263062B (en) * | 2014-09-03 | 2016-04-27 | 安徽雅美油墨有限公司 | A kind of high absorption abrasion-resistance water environmental protection photocuring tin printing ink |
| CN104312265B (en) * | 2014-11-11 | 2016-04-27 | 合肥皖为电气设备工程有限责任公司 | Molten color inhibition plastic printing ink of a kind of environment-friendly type alcohol and preparation method thereof |
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| CN1339054A (en) * | 1999-01-29 | 2002-03-06 | 日清制油株式会社 | Coating material or ink compositions |
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN102321407A (en) * | 2011-09-06 | 2012-01-18 | 南昌航空大学 | Electron beam cured tin printing ink |
| CN102433044A (en) * | 2011-11-02 | 2012-05-02 | 广东新中源陶瓷有限公司 | Ink for 3D digital ink-jet ceramic tile |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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2013
- 2013-11-25 CN CN201310600485.3A patent/CN103666043B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1339054A (en) * | 1999-01-29 | 2002-03-06 | 日清制油株式会社 | Coating material or ink compositions |
| CN1970656A (en) * | 2006-11-23 | 2007-05-30 | 北京印刷学院 | Thermoforming plastic printing ink adopting ultraviolet-infra red drying technology |
| CN102321407A (en) * | 2011-09-06 | 2012-01-18 | 南昌航空大学 | Electron beam cured tin printing ink |
| CN102993824A (en) * | 2011-09-14 | 2013-03-27 | 中国科学院化学研究所 | UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN102433044A (en) * | 2011-11-02 | 2012-05-02 | 广东新中源陶瓷有限公司 | Ink for 3D digital ink-jet ceramic tile |
| CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
| CN103342921A (en) * | 2013-07-29 | 2013-10-09 | 中国科学院化学研究所 | Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate |
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| CN103666043A (en) | 2014-03-26 |
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