CN102433044A - Ink for 3D digital ink-jet ceramic tile - Google Patents
Ink for 3D digital ink-jet ceramic tile Download PDFInfo
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- CN102433044A CN102433044A CN2011103427607A CN201110342760A CN102433044A CN 102433044 A CN102433044 A CN 102433044A CN 2011103427607 A CN2011103427607 A CN 2011103427607A CN 201110342760 A CN201110342760 A CN 201110342760A CN 102433044 A CN102433044 A CN 102433044A
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- ink
- ceramic tile
- dispersion agent
- digital ink
- jet ceramic
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- 239000000919 ceramic Substances 0.000 title claims abstract description 31
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 15
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000006185 dispersion Substances 0.000 claims description 20
- 239000003086 colorant Substances 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 9
- 230000000996 additive effect Effects 0.000 claims description 9
- 229910018137 Al-Zn Inorganic materials 0.000 claims description 5
- 229910018573 Al—Zn Inorganic materials 0.000 claims description 5
- 229910017082 Fe-Si Inorganic materials 0.000 claims description 5
- 229910017133 Fe—Si Inorganic materials 0.000 claims description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- AYAUBWSUZRFVQO-UHFFFAOYSA-N 2-[2-(4-phenyl-5-sulfanylidene-1h-1,2,4-triazol-3-yl)ethyl]benzo[de]isoquinoline-1,3-dione Chemical compound O=C1C(C=23)=CC=CC3=CC=CC=2C(=O)N1CCC1=NNC(=S)N1C1=CC=CC=C1 AYAUBWSUZRFVQO-UHFFFAOYSA-N 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 13
- 239000000049 pigment Substances 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 2
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 abstract 2
- 229940051841 polyoxyethylene ether Drugs 0.000 abstract 2
- 229920000056 polyoxyethylene ether Polymers 0.000 abstract 2
- 239000000428 dust Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 41
- 238000011161 development Methods 0.000 description 21
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical group O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 210000003298 dental enamel Anatomy 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 239000011449 brick Substances 0.000 description 5
- 238000007639 printing Methods 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000013543 active substance Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 229910052593 corundum Inorganic materials 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000004021 humic acid Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229910001845 yogo sapphire Inorganic materials 0.000 description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical group O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000000693 micelle Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000035807 sensation Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 238000005829 trimerization reaction Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Inorganic materials [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000007688 edging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000004304 visual acuity Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses ink for a 3D digital ink-jet ceramic tile, which comprises a pigment, fatty alcohol-polyoxyethylene ether, n-butanol, n-octane, zirconium oxychloride, ammonia water and solids, wherein the content of each component is as follows: 18 to 40 weight percent of pigment; 12-17 wt% of fatty alcohol-polyoxyethylene ether; 0.5-5 wt% of n-butyl alcohol; 25-35 wt% of n-octane; 20-30 wt% of zirconium oxychloride; 15-25 wt% of ammonia water; 1 to 4 weight percent of solid. The ink for the 3D digital ink-jet ceramic tile provided by the invention has the advantages that the produced product has the effects of definition, stereoscopic impression and beautiful mirror surface, can highlight the tidiness and the brightness of the whole space, and has the characteristics of durability, skid resistance, dust prevention, easiness in cleaning and the like.
Description
Technical field
The present invention relates to the architectural pottery field, relate in particular to a kind of ink of the 3D of being used for digital ink-jet ceramic tile.
Background technology
Along with nation-building conservation-minded society, walk the megatrend of the road of Sustainable development; Under the overall background of ceramic industry industry transfer, ceramic production technology is gone on less energy-consumption, high is concentrated, robotization, technology is simple and clear, product is remarkably productive road become a kind of inevitable.
Along with development, the growth in the living standard of society, people are also increasingly high to the requirement of various home decorations.At first, along with country advocates the propaganda support of environmental protection, people hope to use environmentfriendly products to finishing material also more and more environmental protection, reduce the pollution to nature, and unordered exploitation is demanded, and reduces current pollution level.Secondly, along with development of science and technology, the developing of outlook, people are also increasingly high to the effect of decorating, and do not satisfied the effect that current silk screen and roll printing bring.Part human consumer requires that its textured pattern is more clear, resolving power is higher, naturalness is stronger, and the arbitrary color texture of reduction nature true to nature is unlimited true, is like nature itself.At last, part top-grade consumption person, even can come short run to customize self-designed pattern texture according to the demand of oneself.Therefore, the product of its production of most ceramic enterprise all begins to develop to the new demand of consumption, dominates the market, and makes the aspects such as sharpness, naturalness, gradation sense, environmental protection of its product reach the requirement in market.
The development of inkjet technology divides two stages.Fs is 2000-2006, and ink-jet system has only the solubility ink.In this stage because the low Color Range of employed solubility ink, poor stability and cost are high, big limitations the product various possibilities that can realize, restricted development.Subordinate phase, along with the technical progress of paint ink, qualitative leap has taken place in ink-jet system.Use these paint inks, the conventional color of ink-jet print system on almost can the printing market, and also price is also competitive.The leap of this technology influence even can expand landscape design to, and driven that more new installation producer comes into the market and Production of Ceramics enterprise pours in this field.
But at present, jetting ink has only four looks, and the part color still can't realize, and because of ink is an oiliness, so bring certain difficulty for the upgrading of subsequent product.
Summary of the invention
Technical problem to be solved by this invention is the deficiency that remedies prior art; Purpose is to provide a kind of ink of the 3D of being used for digital ink-jet ceramic tile; The product of its production has sharpness, stereoscopic sensation and graceful mirror effect; Can give prominence to the clean and tidy and beautiful of overall space, have characteristics such as durable, anti-skidding, dustproof, easy cleaning again.
For solving above technical problem, technical scheme of the present invention is a kind of ink of the 3D of being used for digital ink-jet ceramic tile, comprises colorant, AEO, propyl carbinol, octane, ammoniacal liquor and solids, and wherein components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 12wt%-17wt%;
Propyl carbinol 0.5wt%-5wt%;
Octane 25wt%-35wt%;
Ammoniacal liquor 15wt%-25wt%;
Solids 1wt%-4wt%.
More excellent ground, wherein each components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 13wt%-16wt%;
Propyl carbinol 1wt%-3wt%;
Octane 27wt%-32wt%;
Ammoniacal liquor 18wt%-22wt%;
Solids 1.5wt%-2.5wt%.
More excellent ground, the ink that is used for 3D digital ink-jet ceramic tile also comprises additive 1, the 2-Ucar 35, said content of additive is: 2wt%-5wt%.
More excellent ground, the ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, the content of said dispersion agent is: 1wt%-3wt%, said dispersion agent are phenylformic acid.
More excellent ground, the ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, the content of said dispersion agent is: 2wt%-4wt%, said dispersion agent are resin.
Compared with prior art; The ink that is used for 3D digital ink-jet ceramic tile provided by the invention; The product of its production has sharpness, stereoscopic sensation and graceful mirror effect, can give prominence to the clean and tidy and beautiful of overall space, has characteristics such as durable, anti-skidding, dustproof, easy cleaning again.
Embodiment
For those skilled in the art can understand technical scheme provided by the present invention better, set forth below in conjunction with specific embodiment.
The production technique of 3D digital ink-jet ceramic tile provided by the invention comprises the steps:
(1) preparation blank, cover-coat enamel;
(2) blank moulding in the mould brick forms the base brick, and the pressure of blank moulding is 2800Mpa/cm
2-3400Mpa/cm
2
(3) the base brick sintering after the moulding is dry, and sintering temperature is 1150 ℃-1800 ℃;
(4) dry body drenches glaze, and the flowability of glaze slip is 30S/100M1-40S/100M1, fluctuates to be that 0S-5S, glaze slip proportion are 175g/cm
2-190g/cm
2, the glaze amount is 0.05g/cm
2-0.15g/cm
2
(5) spray ink Printing, spray ink Printing speed with send the rotating speed of brick belt to be complementary, be set to 20m/min-25m/min;
(6) go into klining, firing temperature is 1080 ℃-1125 ℃;
(7) edging.
Blank comprises following component: SiO2:62.97%; Al2O3:16.61%; CaO:7.0%; MgO:0.18%; K2O:2.3%; Na2O:0.35%; Fe2O3:0.35%; Igloss: 8.64%; Above component is weight percentage.
Cover-coat enamel comprises following component: M01:70 part; M107:30 part; Methyl: 0.05 part; Trimerization: 0.25 part of water: 60 parts; Above component by weight;
M01 comprises following component: SiO2:45 part; Fe2O3:6 part; MnO2:7 part; Al2O3; 10 parts; CaO:1.0 part; PO5:8 part; NiO:3 part; CuO:4 part; Na2O:6 part; ZrO2:6 part; BaO2:1 part; Above component by weight.
M07 comprises following component: SiO2:49 part; Fe2O3:7.5 part; MnO2:5 part; Al2O3; 14 parts; CaO:2.5 part; PO5:5 part; NiO:2 part; CuO:2 part; Na2O:5 part; ZrO2:3 part; BaO2:1 part; Above component by weight.
Cover-coat enamel comprises following component: 11# frit: 20; 18# frit: 40 parts; Air knife soil: 5 parts; Calcined kaolin: 5 parts; Zirconium silicate: 10 parts; Aluminum oxide: 5 parts; Methyl: 0.3 part; Trimerization: 0.05 part; Water: 35 parts; Above component by weight.The component of 11# frit is: 50 parts of SiO2, and 10 parts of Al2O3,9 parts of CaO, 5 parts of MgO, 3 parts of BaO, 2 parts of SrO, 13 parts of ZnO, 4 parts of K2O, Na2O2 part, 1 part of Li2O, 5 parts of B2O3,2 parts of ZrO2, above component is by weight.The component of 18# frit is: 63.5 parts of SiO2,12 parts of Al2O3,0.5 part of TiO2,1.5 parts of CaO, 0.5 part of MgO, 4 parts of K2O, and 4 parts of Na2O, 4 parts of Li2O, 20 parts of B2O3, above component is by weight.
The ink that is used for 3D digital ink-jet ceramic tile comprises colorant, AEO, propyl carbinol, octane, ammoniacal liquor and solids, and wherein components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 12wt%-17wt%;
Propyl carbinol 0.5wt%-5wt%;
Octane 25wt%-35wt%;
Ammoniacal liquor 15wt%-25wt%;
Solids 1wt%-4wt%.
The ink that is used for 3D digital ink-jet ceramic tile also comprises additive 1, the 2-Ucar 35, and said content of additive is: 2wt%-5wt%.
The ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, and the content of said dispersion agent is: 1wt%-3wt%, said dispersion agent are phenylformic acid.
The ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, and the content of said dispersion agent is: 2wt%-4wt%, said dispersion agent are resin.
The production technique of 3D digital ink-jet ceramic tile provided by the invention is innovated aspect following two:
1, strengthened the ratio of plastic material and add and put into softening agent, guaranteed that overglaze is wetting.Aborning because glaze plays powder easily, cause ink attach power excessively a little less than, make the ink color development shallow excessively, it is relatively poor to burn till the pattern effect sharpness, the pink colour color development is not good enough, the glaze surface evenness is general.Comprehensive each side factor research has found that the major cause of powder and the water-intake rate of base substrate have substantial connection, needs the present formula adjustment to base substrate.In blank raw material, add the softening agent Sodium salts humic acids, Sodium salts humic acids is joined ceramic base, can improve plasticity-, slip fluidity and the suspension of pug greatly.And can increase green body strength.Increase the sticking power of glaze and the rate of drying of glaze, reduce the cracking of glaze pore and glazed body.Learn that by test repeatedly Sodium salts humic acids addition in blank raw material is generally 1-3 ‰.If additive is excessive, it is slow excessively to cause base substrate to receive water, causes glaze wet excessively, immiscible with water because ink is an oiliness, the stratified segregation phenomenon of ink and glaze can occur.
2, increase the glaze glossiness, improve the color development of ink.Glaze has very big influence to the color development of color, is superior to other conventional bricks in order to make product glaze effect, and the clear and naturalness of outstanding more image is adjusted to the overglaze effect.The content of some composition in the glaze (like Zr, Ba) plays an important role to the color development of pink colour.In cover-coat enamel, because ink is responsive to the Zr in the glaze, Ba reaction, the content that zirconium white melts piece in the cover-coat enamel has very big influence to the color development of ink; Content is very few; Cover-coat enamel be transparence, the ink color development partially secretly, shallow partially, it is relatively poor to burn till the pattern effect sharpness; The pink colour color development is not good enough, and the glaze surface evenness is general.High more according to specific refractory power; Glossiness is good more, and " this principle is added the oxide compound that an amount of BaO, SnO2, ZrO2 etc. have high refractive index in glaze, find through continuous experimental study; the content of ZrO2 is 6.5-7%; the content of BaO is 1% o'clock, significantly improves the glaze glossiness, and the color development of ink is increased significantly.It is high to burn till the pattern effect sharpness, and the color color development is good, glaze whiteness, brightness height.
3, the pink colour color development is not very desirable in the jetting ink, in the color development of ink since in the industry to the darker situation of ubiquity color development on the color development of red pink colour, this has seriously restricted the rich of product colour.Because the Fe3+ that contains in the pink colour ink under the situation of burning till of reducing atmosphere, makes red originally Fe3+ be reduced to green Fe2+ easily, makes pink colour change, and causes it to be a bit darkish in color, and makes the color effects of pattern not reach the ideal requirement.Through adopting additive to come this to deal with problems, to using the consumption of color development that additive solves the pink colour ink through repeatedly comparing repeatedly, its test color development effect, simultaneous test is so adopt the proportioning composition of 0.05wt%-0.08wt%.
4, the solvent in the ink is to be transported to the carrier on the acceptor to inorganic non-metallic pigment (colorant, glaze) from stamping machine; Controlling simultaneously time of drying again; Make ink viscosity, surface tension etc. be difficult for changing with temperature variation, solvent generally adopts water-miscible organic solvent.We mainly adopt phenylformic acid dispersion agent, and through test of many times, its consumption helps inorganic non-metallic pigment (colorant, glaze) to be evenly distributed in the solvent, and guarantees that powder is not reunited before spray printing between 1wt%-3wt%.Add the dual function that the 2wt%-4wt% resin can play wedding agent and dispersion agent at ink, ensure that ceramic body or the colorant printed have certain intensity, be convenient to production operation, simultaneously the flowing property of adjustable ink.
5, in ceramic ink (PH=7.0), add a spot of propyl carbinol, working sample viscosity after the induction stirring finds that the adding of a spot of alcohol has significantly reduced the viscosity of ceramic ink; When the adding propyl carbinol was between 1wt%-2wt%, system viscosity was reduced to about 11mPa.s, the viscosity upper limit that requires near continuous printer very much; The surface tension of sample also has reduction slightly when reducing viscosity, and the alcohol branch that the back adds will be embedded between the active agent molecule of micelle surface, forms mixed micelle with tensio-active agent; Reduce repulsive force between surface active agent ion; Remedy the defective of tensio-active agent rete, improve the surfactant interface film, increase the flexibility at interface; Make the interface be easy to bending, promote micellar stable.In addition, they will change the character of solvent, thereby change the interaction between interfacial film and solvent, and the both has produced active effect to the viscosity that reduces system, and adding a spot of alcohol in the ceramic ink is feasible with the viscosity property of improving ink.
To the above-mentioned explanation of the disclosed embodiments, make this area professional and technical personnel can realize or use the present invention.Multiple modification to these embodiment will be conspicuous concerning those skilled in the art, and defined General Principle can realize under the situation that does not break away from the spirit or scope of the present invention in other embodiments among this paper.Therefore, the present invention will can not be restricted to these embodiment shown in this paper, but will meet and principle disclosed herein and features of novelty the wideest corresponding to scope.
Claims (5)
1. an ink that is used for 3D digital ink-jet ceramic tile is characterized in that, comprises colorant, AEO, propyl carbinol, octane, ammoniacal liquor and solids, and wherein components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 12wt%-17wt%;
Propyl carbinol 0.5wt%-5wt%;
Octane 25wt%-35wt%;
Ammoniacal liquor 15wt%-25wt%;
Solids 1wt%-4wt%.
2. the ink that is used for 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, wherein each components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 13wt%-16wt%;
Propyl carbinol 1wt%-3wt%;
Octane 27wt%-32wt%;
Ammoniacal liquor 18wt%-22wt%;
Solids 1.5wt%-2.5wt%.
3. the ink that is used for 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, also comprises additive 1, the 2-Ucar 35, and said content of additive is: 2wt%-5wt%.
4. the ink that is used for 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, also comprises dispersion agent, and the content of said dispersion agent is: 1wt%-3wt%, said dispersion agent are phenylformic acid.
5. the ink that is used for 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, also comprises dispersion agent, and the content of said dispersion agent is: 2wt%-4wt%, said dispersion agent are resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103427607A CN102433044A (en) | 2011-11-02 | 2011-11-02 | Ink for 3D digital ink-jet ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011103427607A CN102433044A (en) | 2011-11-02 | 2011-11-02 | Ink for 3D digital ink-jet ceramic tile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102433044A true CN102433044A (en) | 2012-05-02 |
Family
ID=45981396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103427607A Pending CN102433044A (en) | 2011-11-02 | 2011-11-02 | Ink for 3D digital ink-jet ceramic tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102433044A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666043A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink having quick solidification effect and good adhesive attraction |
| CN108862294A (en) * | 2017-05-08 | 2018-11-23 | 上海大学 | A kind of nanometer of praseodymium zirconium yellow material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446699A (en) * | 2002-12-09 | 2003-10-08 | 武汉理工大学 | Technique for transfer printing porcelain image by using ink-jet printer and its transfer ink |
| CN102153904A (en) * | 2011-01-12 | 2011-08-17 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
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2011
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1446699A (en) * | 2002-12-09 | 2003-10-08 | 武汉理工大学 | Technique for transfer printing porcelain image by using ink-jet printer and its transfer ink |
| CN102153904A (en) * | 2011-01-12 | 2011-08-17 | 郑州鸿盛数码科技股份有限公司 | Ceramic transfer digital printing ink-jet ink and using method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103666043A (en) * | 2013-11-25 | 2014-03-26 | 铜陵方正塑业科技有限公司 | UV printing ink having quick solidification effect and good adhesive attraction |
| CN103666043B (en) * | 2013-11-25 | 2016-04-13 | 铜陵方正塑业科技有限公司 | UV ink that a kind of quick solidifying sticking power is good and preparation method thereof |
| CN108862294A (en) * | 2017-05-08 | 2018-11-23 | 上海大学 | A kind of nanometer of praseodymium zirconium yellow material and preparation method thereof |
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Application publication date: 20120502 |