SBR utilizes sludge internal carbon source to process the apparatus and method of city domestic sewage advanced nitrogen dephosphorization
Technical field
The present invention relates to SBR and utilize sludge internal carbon source to process the apparatus and method of city domestic sewage advanced nitrogen dephosphorization, belong to mud and sewage processing technology field.
Background technology
Traditional anoxic anaerobism in aerobic SBR, denitrifying bacterium preferentially utilizes carbon source to carry out denitrification, and when anaerobism, polyP bacteria is often released the reduction of phosphorus effect because of the shortage of carbon source, and also the aerobic suction phosphorus of polyP bacteria is restricted thus, when aerobic in addition, nitrifier carries out nitration reaction, i.e. NH
4 +-N is oxidized to NO
2 --N, NO
3 --N, though ammonia nitrogen has reduced in water outlet, TN is still very high, is difficult to reach one-level A standard, wants advanced nitrogen dephosphorization, need add outer carbon source, this has increased running cost undoubtedly.
Short chain fatty acid is the high-quality carbon source of biological carbon and phosphorous removal, during sludge anaerobic fermentation, can produce a large amount of short chain fatty acids, and this short chain fatty acid can replace additional carbon to remove ammonia nitrogen and the phosphorus of sewage for sewage treatment process, yet follow the generation of short chain fatty acid, sludge fermentation process can discharge ammonia nitrogen and the phosphorus of higher concentration, for avoiding increasing technical load, when using fermented liquid as carbon source, need to remove ammonia nitrogen and phosphorus wherein.
Therefore the present invention utilizes the sludge fermentation liquid carbon source of removing ammonia nitrogen and phosphorus that nitrogen is removed by rear-mounted denitrification, when the lower cycle will start, denitrifying bacteria is no longer fought for carbon source with polyP bacteria, polyP bacteria just can utilize the carbon source in municipal effluent to release phosphorus, finally reaches not only without additional carbon but also object that can advanced nitrogen dephosphorization.
Summary of the invention
Object of the present invention is exactly for improving low C/N/P domestic sewage denitrifying effect, reduce running cost, has proposed the apparatus and method that SBR utilizes the dephosphorization of sludge internal carbon source Treating Municipal Sewage advanced nitrogen.In these apparatus and method, municipal effluent enters aerobic/anaerobic/anoxic sbr reactor device, in one-period, first polyP bacteria utilizes the carbon source in former water to carry out anaerobic phosphorus release under anaerobism, follow aerobic lower nitrifier and carry out nitration reaction, polyP bacteria suction phosphorus, under last anoxic, denitrifying bacteria utilizes the raw fermented liquid that is rich in short chain fatty acid of sludge anaerobic fermentation to produce to carry out denitrification, repeat above process, remove nitrogen, phosphorus in municipal effluent.
The object of the invention is to solve by following solution: the device characteristic that SBR utilizes sludge internal carbon source to process the dephosphorization of city domestic sewage advanced nitrogen is: be provided with sludge fermentation tank 1, separation of fermentative broth pond 2, fermented liquid denitrogenation dephosphorizing pond 3, carbon source reserve tank 4, municipal effluent case 5, aerobic/anaerobic/anoxic sbr reactor device 6.
Described sludge fermentation tank 1 is an airtight pond body, is provided with the first agitator 1.1, the one pH probes 1.2, by shore pipe, is connected with separation of fermentative broth pond 2;
Described separation of fermentative broth pond 2 is connected with fermented liquid denitrogenation dephosphorizing pond 3 by row's fermented liquid pipe;
Described fermented liquid denitrogenation dephosphorizing pond 3 is provided with the second agitator 3.1, by liquid discharge pipe, is connected with carbon source reserve tank 4;
Described carbon source reserve tank 4 is an airtight casing, by the first intake pump 4.1, is connected with aerobic/anaerobic/anoxic sbr reactor device 6;
Described municipal effluent case 5 is connected with aerobic/anaerobic/anoxic sbr reactor device 6 by the second intake pump 5.1;
Described aerobic/anaerobic/anoxic sbr reactor device 6 is a unlimited reactor, be provided with the 2nd pH probe 6.1, dissolved oxygen probe 6.2, the 3rd agitator 6.3, the aerating system consisting of air compressor machine 6.4, gas meter 6.5, aeration head 6.6 carries out oxygenation to aerobic/anaerobic/anoxic sbr reactor device, by sludge pipe, is connected with sludge fermentation tank 1.
Municipal effluent, the treatment scheme of mud in this device are: the excess sludge of SBR discharge enters the fermentation of sludge fermentation tank, according to SRT discharge fermenting mixture to separation of fermentative broth pond, carry out mud-water separation, high fermentation liquid after separation enters fermented liquid denitrogenation dephosphorizing pond and removes ammonia nitrogen and the phosphorus in fermented liquid, and the fermented liquid that is rich in afterwards short chain fatty acid enters in carbon source reserve tank for aerobic/anaerobic/anoxic sbr reactor device; Municipal effluent enters aerobic/anaerobic/anoxic sbr reactor device, in one-period, first polyP bacteria utilizes the carbon source in former water to carry out anaerobic phosphorus release under anaerobism, follow aerobic lower nitrifier and carry out nitration reaction, polyP bacteria suction phosphorus, under last anoxic, denitrifying bacteria utilizes the raw fermented liquid that is rich in short chain fatty acid of sludge anaerobic fermentation to produce to carry out denitrification.
SBR utilizes sludge internal carbon source to process the method for city domestic sewage advanced nitrogen dephosphorization, it is characterized in that comprising following content:
1) unloading phase: inoculation denitrogenation dephosphorizing mud, to SBR, is controlled sludge concentration at 1500-2500mg/L; The excess sludge that is 6000-8000mg/L by concentration is added to sludge fermentation tank anaerobism and stirs, and controlled fermentation pH is at 9-10, temperature 25-30 ℃.
2) operation phase:
Sludge fermentation tank: control sludge retention time SRT at 6-8d, enter mud concentration at 6000-8000mg/L mg/L, pH is at 9-10 in fermentation, temperature is at 25-30 ℃, according to SRT discharge fermenting mixture to separation of fermentative broth pond, carry out mud-water separation, high fermentation liquid after separation enters fermented liquid denitrogenation dephosphorizing pond, according to the content of ammonia nitrogen and phosphorus in fermented liquid denitrogenation dephosphorizing pond, add wherein magnesium salts and phosphoric acid salt, make Mg:P:N mol ratio=1.2:0.8:1 to remove ammonia nitrogen and the phosphorus in fermented liquid, the fermented liquid that is rich in afterwards short chain fatty acid enters in carbon source reserve tank for aerobic/anaerobic/anoxic sbr reactor device.
Aerobic/anaerobic/anoxic sbr reactor device: after municipal effluent enters, first anaerobism stirs, and follows aerobic stirring, control dissolved oxygen concentration at 2-4mg/L, then stop aeration and will in the fermented liquid input reaction in carbon source reserve tank, continue to stir, then standing draining, finally idle.Control draining ratio at 0.4-0.6, in reactor, sludge concentration is at 1500-2500mg/L, and sludge age is at 10-15d, and the mud of discharge is as the mud source of sludge fermentation tank.
The apparatus and method that SBR of the present invention utilizes sludge internal carbon source to process the dephosphorization of city domestic sewage advanced nitrogen have the following advantages:
1) without additional carbon, utilize sludge internal carbon source to carry out denitrification denitrogenation, reduced running cost;
2) by rear-mounted denitrification, utilize the sludge fermentation liquid carbon source of removing ammonia nitrogen and phosphorus that nitrogen is removed, when the lower cycle will start, denitrifying bacteria is no longer fought for carbon source with polyP bacteria, and polyP bacteria just can utilize the carbon source in municipal effluent to release phosphorus;
3) mud of aerobic/anaerobic/anoxic sbr reactor device discharge, directly as the mud source of sludge fermentation tank, is realized self sludge carbon source exploitation, simultaneously mud decrement.
Accompanying drawing explanation
Fig. 1 is that SBR of the present invention utilizes sludge internal carbon source to process the apparatus structure schematic diagram of city domestic sewage advanced nitrogen dephosphorization.
In figure, 1 is that sludge fermentation tank, 2 is that separation of fermentative broth pond, 3 is that fermented liquid denitrogenation dephosphorizing pond, 4 is that carbon source reserve tank, 5 is that municipal effluent case, 6 is aerobic/anaerobic/anoxic sbr reactor device; 1.1 is that the first agitator, 1.2 is a pH probe; 3.1 is the second agitator; 4.1 is the first intake pump; 5.1 is the second intake pump; 6.1 is that the 2nd pH probe, 6.2 is that dissolved oxygen probe, 6.3 is that the 3rd agitator, 6.4 is that air compressor machine, 6.5 is that gas meter, 6.6 is aeration head.
Embodiment
Below in conjunction with drawings and Examples, the present invention will be further described: the device that SBR utilizes sludge internal carbon source to process the dephosphorization of city domestic sewage advanced nitrogen is provided with sludge fermentation tank 1, separation of fermentative broth pond 2, fermented liquid denitrogenation dephosphorizing pond 3, carbon source reserve tank 4, municipal effluent case 5, aerobic/anaerobic/anoxic sbr reactor device 6.
Described sludge fermentation tank 1 is an airtight pond body, is provided with the first agitator 1.1, the one pH probes 1.2, by shore pipe, is connected with separation of fermentative broth pond 2;
Described separation of fermentative broth pond 2 is connected with fermented liquid denitrogenation dephosphorizing pond 3 by row's fermented liquid pipe;
Described fermented liquid denitrogenation dephosphorizing pond 3 is provided with the second agitator 3.1, by liquid discharge pipe, is connected with carbon source reserve tank 4;
Described carbon source reserve tank 4 is an airtight casing, by the first intake pump 4.1, is connected with aerobic/anaerobic/anoxic sbr reactor device 6;
Described municipal effluent case 5 is connected with aerobic/anaerobic/anoxic sbr reactor device 6 by the second intake pump 5.1;
Described aerobic/anaerobic/anoxic sbr reactor device 6 is a unlimited reactor, be provided with the 2nd pH probe 6.1, dissolved oxygen probe 6.2, the 3rd agitator 6.3, the aerating system consisting of air compressor machine 6.4, gas meter 6.5, aeration head 6.6 carries out oxygenation to aerobic/anaerobic/anoxic sbr reactor device, by sludge pipe, is connected with sludge fermentation tank 1.
Test adopts Beijing University of Technology's dependents' district sanitary sewage as former water, and concrete water quality is as follows: COD concentration is 120-200mg/L;
-N concentration is 50-67mg/L,
-N≤0.5mg/L,
-N≤0.5mg/L.As shown in Figure 1, each reactor all adopts synthetic glass to make to pilot system, and SBR effective volume is 30L, sludge fermentation tank effective volume 4L.
Concrete operations are as follows:
1) unloading phase: inoculation denitrogenation dephosphorizing mud, to SBR, is controlled sludge concentration at 2000mg/L; The excess sludge that is 6000mg/L by concentration is added to sludge fermentation tank anaerobism and stirs, and controlled fermentation pH is at 9-10, temperature 25-30 ℃.
2) operation phase:
Sludge fermentation tank: control sludge retention time SRT at 8d, enter mud concentration at 6000mg/L, entering mud volume is 500mL, pH is at 9-10 in fermentation, temperature is at 25-30 ℃, according to SRT, discharge fermenting mixture to the separation of fermentative broth pond of 500mL every day and carry out mud-water separation, high fermentation liquid after separation enters fermented liquid denitrogenation dephosphorizing pond, add magnesium salts wherein and phosphoric acid salt makes Mg:P:N=1.2:0.8:1, remove ammonia nitrogen and phosphorus in fermented liquid, the fermented liquid that is rich in afterwards short chain fatty acid enters in carbon source reserve tank for aerobic/anaerobic/anoxic sbr reactor device.
Aerobic/anaerobic/anoxic sbr reactor device: start the second water pump 12L municipal effluent is squeezed into reactor, first anaerobism stirs 1h, follows aerobic stirring 2h, controls dissolved oxygen concentration at 2-4mg/L, then stops aeration, in on-line monitoring reactor
-N and
the concentration of-N, according to 1g
-N needs 1.72gCOD, 1g
-N needs the relation of 2.85gCOD, by the second water pump, by the fermented liquid input reactor in carbon source reserve tank, continues to stir 1.5h, then draining after standing 30min, finally idle 1h.Control draining ratio 0.4, in reactor, sludge concentration is at 2000mg/L, and sludge age is at 12d, and the mud of discharge is as the mud source of sludge fermentation tank.
Test-results shows: after stable, SBR effluent COD concentration is 36-53mg/L,
-N concentration 0.3-0.7mg/L,
-N concentration is 0.3-0.7mg/L,
-N concentration is 0.2-0.8mg/L, PO
4 3--P concentration is 0.2-0.4mg/L; Sludge fermentation is produced acid amount at 800-1000mg/L, mud decrement 30%.