CN106115920B - The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge - Google Patents
The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge Download PDFInfo
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- 239000010802 sludge Substances 0.000 title claims abstract description 85
- 239000010865 sewage Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title claims abstract description 26
- 238000006396 nitration reaction Methods 0.000 title abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 80
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 14
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000012163 sequencing technique Methods 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 35
- 238000000855 fermentation Methods 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 33
- 230000004151 fermentation Effects 0.000 claims description 32
- 230000002572 peristaltic effect Effects 0.000 claims description 27
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 19
- 229910052760 oxygen Inorganic materials 0.000 claims description 19
- 239000001301 oxygen Substances 0.000 claims description 19
- 238000005273 aeration Methods 0.000 claims description 17
- 238000004062 sedimentation Methods 0.000 claims description 15
- 206010021143 Hypoxia Diseases 0.000 claims description 11
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 6
- 235000021391 short chain fatty acids Nutrition 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 4
- 239000001632 sodium acetate Substances 0.000 claims description 4
- 235000017281 sodium acetate Nutrition 0.000 claims description 4
- 238000003860 storage Methods 0.000 claims description 4
- 238000009825 accumulation Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- 230000007954 hypoxia Effects 0.000 claims 2
- 238000001556 precipitation Methods 0.000 claims 2
- 230000003203 everyday effect Effects 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 abstract description 22
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 20
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 15
- 239000011574 phosphorus Substances 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 8
- 238000006243 chemical reaction Methods 0.000 abstract description 5
- 239000005416 organic matter Substances 0.000 abstract description 5
- 206010002660 Anoxia Diseases 0.000 description 9
- 241000976983 Anoxia Species 0.000 description 9
- 230000007953 anoxia Effects 0.000 description 9
- 241000894006 Bacteria Species 0.000 description 8
- 238000002156 mixing Methods 0.000 description 7
- 229920000388 Polyphosphate Polymers 0.000 description 6
- 229920000037 Polyproline Polymers 0.000 description 6
- 239000001205 polyphosphate Substances 0.000 description 6
- 235000011176 polyphosphates Nutrition 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 238000011081 inoculation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 2
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 150000004666 short chain fatty acids Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- JEGUKCSWCFPDGT-UHFFFAOYSA-N h2o hydrate Chemical compound O.O JEGUKCSWCFPDGT-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- -1 save the cost Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/305—Nitrification and denitrification treatment characterised by the denitrification
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
- C02F3/307—Nitrification and denitrification treatment characterised by direct conversion of nitrite to molecular nitrogen, e.g. by using the Anammox process
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/105—Phosphorus compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2203/00—Apparatus and plants for the biological treatment of water, waste water or sewage
- C02F2203/006—Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment Of Sludge (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge, belong to municipal sewage treatment and sludge biochemical treatment field.The removal and the effect of part short-cut nitrification and denitrification that organic matter and phosphorus are carried out in the first SBR of reactor, during which by DO and pH real-time control, and pass through the removal of spoil disposal realization phosphorus.The first SBR of reactor water outlet enters the 2nd SBR of reactor and carries out Anammox reaction, to achieve the purpose that advanced nitrogen dephosphorization.The present invention is by the way that by excess sludge and sanitary sewage mixed processing, the problem of realizing short distance nitration cannot be stablized by being able to solve sanitary sewage because ammonia nitrogen concentration is low, can also be saved carbon source, be improved denitrogenation dephosphorizing efficiency, while realize that sludge reduction is handled.
Description
Technical field
The present invention relates to the method for realizing municipal sewage part short distance nitration and Anammox using fermented sludge and
The optimal control of device belongs to municipal sewage treatment and sludge biochemical treatment field.This technique is suitable for the low city C/N, C/P
The reinforcing advanced nitrogen dephosphorization of sanitary sewage.
Background technique
In biological denitrification process, denitrifying bacterium needs organic matter as electron donor reduction-oxidation state as heterotroph
Nitrogen;In Biological Phosphorus Removal Process, polyP bacteria absorbs short chain fatty acids VFA synthesis PHA storage in the cell in anaerobism section, aerobic
Section decomposed P HA is as energy needed for excessive suction phosphorus.So organic carbon source is extremely important for biological carbon and phosphorous removal.However,
The problem of China's most cities sewage generally existing carbon source wretched insufficiency, its own carbon source is unable to satisfy wanting for denitrogenation dephosphorizing
Ask so that water outlet be difficult to it is up to standard.By adding methanol, although the outer carbon source such as sodium acetate can achieve good outlet effect, but
It is that cost is too high, but also will increase excess sludge production.Nearly 1/3 organic matter is converted to sludge inside sewage, remaining dirty
The processing disposition of mud is also a great problem, so carbon source in sewage is insufficient and excess sludge processing cost is too high asks to solve
Topic, can be by exploitation excess sludge internal carbon source come enhanced sewage treatment plant biological carbon and phosphorous removal.Excess sludge anaerobic fermentation energy
Generating a large amount of short chain fatty acids can be used as high-quality carbon source during biological carbon and phosphorous removal, Lai Tigao sewage denitrification and dephosphorization effect
Fruit, while realizing the minimizing processing of sludge.Selection utilization can be separated for fermentation liquid and sludge by developing excess sludge internal carbon source
Fermentation liquid can also directly utilize its sludge fermentation mixture.The problems such as in view of operating cost, only utilizes sludge fermentation supernatant
Liquid cost is too high, can choose and utilizes excess sludge fermenting mixture.
The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge, with remaining dirty
Mud and municipal sewage are research object, short by the anaerobic phosphorus release of the first SBR of sequencing batch reactor, aerobic phosphorus absorption and part first
Journey nitrification, denitrification dephosphorization effect carry out the removal of organic matter and nitrogen phosphorus, and the water outlet of the first SBR of sequencing batch reactor is using sequence
Advanced nitrogen is realized in the Anammox processing of the 2nd SBR of batch reactor, improves the denitrification percent of system.Certainly using sewage plant
The sludge of body discharge saves the expense of additional carbon as carbon source while improving denitrogenation dephosphorizing efficiency;It is sent out using sludge
The process of sludge and separation of fermentative broth, save the cost is omitted in ferment mixture, while realizing sludge reduction processing.
Summary of the invention
In view of the deficiencies of the prior art, the present invention proposes that a kind of utilization fermented sludge realizes municipal sewage part short distance nitration
With the method and apparatus of Anammox, excess sludge mixture is pumped into handle low C/N, C/P sanitary sewage batch-type it is anti-
It answers in the first SBR of device, polyP bacteria largely releases phosphorus using the abundant carbon source progress in sludge fermentation mixture and sanitary sewage, and stores up
A large amount of PHA are deposited, next aeration carries out part short distance nitration and polyP bacteria inhales the reaction of phosphorus, and removal part ammonia nitrogen is converted
For nitrite nitrogen and nitrate nitrogen, anoxia stirring in short-term is entered back into, carries out denitrifying phosphorus uptake, it is by nitrate nitrogen and residual on last stage
Remaining phosphorus ligands;The 2nd SBR that the first SBR water outlet is pumped into inoculation anaerobic ammonium oxidation sludge is subjected to Anammox reaction again,
Ammonia nitrogen and nitrite nitrogen are removed, to achieve the purpose that advanced nitrogen dephosphorization.
The present invention is achieved through the following technical solutions:
(1) starting of excess sludge fermentor: excess sludge fermentor (2) is semi batch reacor, sludge retention time
SRT controlled pH 9~10 at 6~20 days;Excess sludge fermenting mixture to fermenting mixture is discharged daily according to SRT to store
Simultaneously isometric fresh excess sludge is added to excess sludge fermentor (2) in tank (9);
(2) batch-type reaction the starting of the first SBR of sequencing batch reactor: is injected using short distance nitration sludge as seed sludge
The first SBR (13) of device, while the city domestic sewage to add sodium acetate injects sanitary sewage water tank (8) as raw water, makes into water
C/N ratio maintains 5~6, squeezes into the first SBR (13) of sequencing batch reactor by third peristaltic pump, that is, intake pump (10), transports daily
In 2~3 periods of row, than maintaining 50~80%, each period includes water inlet for draining, and anaerobism stirs, aeration, and anoxia stirring is sunk
It forms sediment, drains, leave unused, run reactor under the above conditions, when aerobic last nitrite accumulation rate is greater than 95%, water outlet TP exists
When 1mg/L or less, the Start-up and Adjustment of the first SBR (13) of sequencing batch reactor is completed;
(3) starting of the 2nd SBR of sequencing batch reactor: using anaerobic ammonium oxidation granular sludge or floc sludge as inoculation
Sludge injects the 2nd SBR (20) of sequencing batch reactor, meanwhile, with NH4 +- N and NO2 —The mass concentration ratio of N is 1:1~1.3
Water distribution is water inlet injection intermediate water tank (17), squeezes into the 2nd SBR (20) of sequencing batch reactor, water inlet while anaerobism by peristaltic pump
Stirring, as water outlet NH4 +- N concentration < 1mg/L or NO2 -When-N concentration < 1mg/L, the starting of the 2nd SBR of sequencing batch reactor is completed
Debugging;
(4) after sequencing batch reactor the first SBR and the 2nd SBR is respectively completed starting, by the two series operation: batch-type is anti-
Device the first SBR (13) each cycle is answered successively to undergo water inlet and sludge fermentation mixture, anaerobism stirring, aeration, anoxia stirring, precipitating
Drain 5 processes;Sequencing batch reactor the 2nd SBR (20) each cycle successively undergoes water inlet (i.e. the water outlet of the first SBR), anoxic to stir
It mixes, 3 processes of sedimentation and drawing.
The first SBR of sequencing batch reactor:
I water inlet, fermenting mixture set inflow as the 1/2~4/5 of reactor effective volume, are into fermenting mixture amount
The 1/50~1/10 of volume of intaking both is controlled by time switch, and after system starting, the sewage in sewage water tank (8) is logical
It crosses intake pump (10) and enters the first SBR (13) of sequencing batch reactor, the fermentation during water inlet, in excess sludge fermentor (2)
Mixture enters the first SBR (13) by the second peristaltic pump (11);The index of substance is as follows in fermenting mixture: SCOD 3380
± 420mg/L, SCFAs are 1221 ± 40mg COD/L, NH4 +- N is 198 ± 20mg/L, PO4 3-- P is 95 ± 10mg/L;
Enter anaerobism agitation phases after the stirring water inlet of II anaerobism, sets mixing time as 3~3.5h, polyP bacteria utilizes
Abundant carbon source progress in fermenting mixture and sanitary sewage largely releases phosphorus, and stores a large amount of PHA;;
III aeration opens air compressor machine (16), oxygen is provided to the first SBR (13) of sequencing batch reactor, by the ammonia in water inlet
Nitrogen is converted into oxidation state nitrogen;It maintains dissolved oxygen DO in 0.5~1.5mg/L by real-time control apparatus, and monitors pH, setting aeration
Time (inflection point that ammonia valley point rises after referring to that pH value is fallen before), NH before 1~2h and ammonia valley point occur4 +- N is under low oxygen conditions
Short distance nitration effect occurs, while aeration time control preceding achievable NH is occurred into ammonia valley point4 +The part short distance nitration of-N gathers
Phosphorus bacterium suction part PO4 3--P;
IV anoxia stirring sets 0.5~1h of mixing time, the NO generated when anoxic can guarantee aeration in short-term3 —N passes through
Denitrification removal, while by remaining PO4 3-- P is acted on by denitrification dephosphorization and being removed;;
VI sedimentation and drawing sets 1~2h of sedimentation time, drains, is discharged into intermediate water tank (17) after mud-water separation, drains ratio
It is 50%~80%.
The 2nd SBR of sequencing batch reactor:
I water inlet is intake from intermediate water tank (17), is set inflow as the 1/2~3/4 of reactor effective volume, is passed through time control
Switch control;
II anoxia stirring sets 2~3h of mixing time, by the NH in the first SBR water outlet4 +- N and NO2 -- N passes through anaerobism ammonia
Oxidation removal;
IV sedimentation and drawing sets 1~2h of sedimentation time, drains after mud-water separation, and draining is than being 50%~75%.
In conclusion the present invention provides a kind of utilization excess sludge fermenting mixture reinforcing city domestic sewage advanced nitrogen
The control method and device of dephosphorization pass through sequencing batch reactor first using excess sludge and municipal sewage as research object first
Anaerobic phosphorus release, aerobic phosphorus absorption and the part short distance nitration of SBR, denitrification dephosphorization effect carry out the removal of organic matter and nitrogen phosphorus, sequence
The water outlet of the first SBR of batch reactor realizes advanced nitrogen using the Anammox processing of the 2nd SBR of sequencing batch reactor,
Improve the denitrification percent of system.Using the sludge of sewage plant itself discharge as carbon source, while improving denitrogenation dephosphorizing efficiency
Save the expense of additional carbon;It is omitted the process of sludge and separation of fermentative broth using sludge fermentation mixture, save the cost,
Sludge reduction processing is realized simultaneously.
Detailed description of the invention:
Fig. 1 is the structural schematic diagram of apparatus of the present invention
In figure: 1 --- the first peristaltic pump;2 --- excess sludge fermentor;3 --- the first blender;4 --- temperature control
Device processed;5 --- the first pH controller;6 --- process controller;7 --- computer;8 --- sewage water tank;9 --- fermentation is mixed
Close object holding vessel;10 --- third peristaltic pump;11 --- the second peristaltic pump;12 --- the first dissolved oxygen controller;13 --- sequence
The first SBR of batch reactor;14 --- the 2nd pH controller;15 --- the second blender;16 --- air compressor machine;17 --- it is intermediate
Water tank;18 --- the 4th peristaltic pump;19 --- the second dissolved oxygen controller;20 --- the 2nd SBR of sequencing batch reactor;21——
3rd pH controller;22 --- third blender;
Fig. 2 is the method for operation of sequencing batch reactor SBR.
Specific embodiment
The application patent is further illustrated in conjunction with attached drawing and example: as shown in Figure 1, the present invention includes excess sludge fermentation
Tank, sludge fermentation mixture holding vessel, sewage water tank, intermediate water tank, the first SBR of sequencing batch reactor, sequencing batch reactor
Two SBR.The effective volume of six devices is 5L, 3L, 30L, 30L, 12L, 9L respectively, and wherein excess sludge fermentor, sludge are sent out
Ferment mixture holding vessel and sequencing batch reactor SBR are made of organic glass;Intermediate water tank, sewage water tank are by organic plastics system
At.
The device includes that excess sludge is pumped into excess sludge fermentor (2) by the first pump peristaltic pump (1), excess sludge hair
First blender (3), temperature control equipment (4), the first pH controller (5) are installed in fermentation tank (2);Excess sludge fermentor (2)
It is connect with fermenting mixture holding vessel (9), fermenting mixture holding vessel (9) passes through the second peristaltic pump (11) and sequencing batch reactor
First SBR (13) connection;Sanitary sewage water tank (8) passes through third peristaltic pump, that is, intake pump (10) and sequencing batch reactor first
SBR (13) connection.Second blender (15), the first dissolved oxygen controller (12) are installed in the first SBR (13) of sequencing batch reactor
With the 2nd pH controller (14);Aeration head in the first SBR (13) of sequencing batch reactor is connect with air compressor machine (16), and batch-type is anti-
The first SBR (13) of device is answered to connect with intermediate water tank (17);Intermediate water tank (17) is reacted by the 4th peristaltic pump (18) with batch-type
The 2nd SBR (20) connection of device.Installation third blender (22), the control of the second dissolved oxygen in the 2nd SBR (20) of sequencing batch reactor
Device (19) and the 3rd pH controller (21).In addition, the process controller (6) that setting is connected with computer (7), to control first
Peristaltic pump (1), the second peristaltic pump (11), third peristaltic pump (10), the 4th peristaltic pump (18), the first blender (3), the second stirring
Device (15), third blender (22), temperature controller (4), the first pH controller (5), the 2nd pH controller (14), the 3rd pH control
Device (21) processed, the first dissolved oxygen controller (12), the second dissolved oxygen controller (19), air compressor machine (16).
City domestic sewage used in specific example is derived from the septic tank of Beijing dependents' district, wherein COD
COD is in 180~200mg/L, NH4 +The concentration of-N is in 60~70mg/L, PO4 3-The concentration of-P is in 5.0~7.5mg/L, and C/N is 2
~4, C/P < 40, itself carbon source are unable to satisfy the purpose of advanced nitrogen dephosphorization.
Specific implementation process is as follows:
Excess sludge fermentor is semi batch reacor, and sludge concentration MLSS is in 7500~8000mg/L, sludge retention
Between SRT at 6 days, control pH 10 ± 0.2, temperature is at 30 ± 2 DEG C.Discharge the fermentation mixing of 833mL excess sludge daily according to SRT
The fresh excess sludge of 833mL is added to excess sludge fermentor to fermenting mixture holding vessel in object (FM).Sludge fermentation is mixed
The main indicator closed in object is as follows: SCOD is 3380 ± 420mg/L, and SCFAs is 1221 ± 40mg COD/L, NH4 +- N be 198 ±
20mg/L, PO4 3-- P is 95 ± 10mg/L.
The starting of the first SBR of sequencing batch reactor: sequencing batch reactor is injected using short distance nitration sludge as seed sludge
First SBR, while the city domestic sewage to add sodium acetate injects sanitary sewage water tank as raw water, makes to maintain into water C/N ratio
6, the first SBR of sequencing batch reactor is squeezed by intake pump, runs 2 periods daily, draining ratio maintains 70%, Mei Gezhou
Phase includes water inlet, and anaerobism stirring is aerated, anoxia stirring, precipitates, drain, leaves unused, run reactor under the above conditions, be a good
Oxygen end nitrite accumulation rate is greater than 95%, is discharged TP in 1mg/L or less, completes the starting of the first SBR of sequencing batch reactor
Debugging;
The starting of the 2nd SBR of sequencing batch reactor: dirty using anaerobic ammonium oxidation granular sludge or floc sludge as inoculation
Mud injects the 2nd SBR of sequencing batch reactor, meanwhile, with NH4 +- N and NO2 -The water distribution that the mass concentration ratio of-N is 1:1.3 be into
Water injects intermediate water tank, squeezes into the 2nd SBR of sequencing batch reactor, water inlet anaerobism stirring simultaneously, as water outlet NH by peristaltic pump4 +-N
Concentration < 1mg/L or NO2 -When-N concentration < 1mg/L, the Start-up and Adjustment of the 2nd SBR of sequencing batch reactor is completed;
After sequencing batch reactor the first SBR and the 2nd SBR is respectively completed starting, by the two series operation.Batch-type reaction
The first SBR each cycle of device successively undergoes water inlet and sludge fermentation mixture, anaerobism stirring, aeration, anoxia stirring, sedimentation and drawing 5
A process;The 2nd SBR each cycle of sequencing batch reactor successively undergoes water inlet (i.e. the water outlet of the first SBR), stirring, sedimentation and drawing 3
A process, such as Fig. 2.
First SBR:
I water inlet, 1/2 that fermenting mixture inflow is reactor effective volume, i.e. 6L.It is water inlet into fermenting mixture amount
The 3/50 of volume is both controlled by time switch, and after system starting, the sewage in raw water water tank enters sequence by intake pump
The first SBR of batch reactor, during water inlet, the fermenting mixture in fermenting mixture holding vessel enters first by peristaltic pump
SBR.;
Enter anaerobism agitation phases after the stirring water inlet of II anaerobism, sets mixing time as 3h, polyP bacteria utilizes fermentation
Abundant carbon source progress in mixture and sanitary sewage largely releases phosphorus, and stores a large amount of PHA;
III aeration maintains dissolved oxygen DO in 0.5~1.5mg/L by real-time control apparatus, and monitors pH, when setting is aerated
Between in 2h (ammonia valley point occur before), NH4 +Short distance nitration effect occurs under low oxygen conditions for-N, while aeration time being controlled in ammonia
Valley point achievable NH before occurring4 +The part short distance nitration of-N, polyP bacteria suction part PO4 3--P;
IV anoxia stirring sets mixing time 1h, the NO generated when anoxic can guarantee aeration in short-term3 -- N passes through anti-nitre
Change removal, while by remaining PO4 3-- P is acted on by denitrification dephosphorization and being removed;
V sedimentation and drawing sets sedimentation time 2h, drains after mud-water separation, is discharged into intermediate water tank, draining is than being 70%.
2nd SBR:
I is intake from intermediate water tank water intake, is set inflow as the 1/2 of reactor effective volume, i.e. 4.5L, is opened by time control
Close control;
II anoxia stirring sets mixing time 3h, by the NH in the first SBR water outlet4 +- N and NO2 -- N passes through Anammox
Effect removal;
IV sedimentation and drawing sets sedimentation time 2h, drains after mud-water separation, and draining is than being 60%.
The results showed that COD concentration is 30~43mg/L, NH in water outlet after stable4 +- N concentration be 0.2~
2.5mg/L, TN removal rate are 80~85%;PO4 3-- P concentration is 0.1~0.7mg/L, and removal rate is 90%~97%.
Claims (1)
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CN201610799348.0A CN106115920B (en) | 2016-08-31 | 2016-08-31 | The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge |
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CN201610799348.0A CN106115920B (en) | 2016-08-31 | 2016-08-31 | The method and apparatus for realizing municipal sewage part short distance nitration and Anammox using fermented sludge |
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CN106865773B (en) * | 2017-04-07 | 2020-02-11 | 北京工业大学 | Device and method for realizing partial shortcut nitrification-anaerobic ammonia oxidation by adding hydroxylamine |
CN107021560A (en) * | 2017-06-09 | 2017-08-08 | 北京工业大学 | The method and apparatus for realizing sewerage short-cut nitration denitrification in SBR using sludge fermentation thing |
CN108439595B (en) * | 2018-04-04 | 2021-01-05 | 北京工业大学 | A method for realizing partial short-range nitrification-Anammox/denitrification of sewage by using sludge fermentation products |
CN108793398B (en) * | 2018-06-08 | 2021-06-25 | 北京工业大学 | Method and device for short-range denitrification coupled with anammox deep denitrification using sludge fermentation mixture as carbon source |
CN109553247B (en) * | 2018-12-28 | 2021-08-31 | 中国人民大学 | A method for realizing anaerobic ammonia oxidation based on heterotrophic nitrification process |
CN110002595A (en) * | 2019-05-10 | 2019-07-12 | 北京工业大学 | Two sections of sequencing batch reactors realize the treatment process of municipal sewage denitrogenation dephosphorizing coupling sludge fermentation |
CN112607861B (en) * | 2020-12-10 | 2023-02-03 | 北京工业大学 | Process for treating municipal sewage by using excess sludge fermentation carbon source to strengthen denitrification dephosphorization, partial short-cut denitrification and anaerobic ammonia oxidation |
CN113716694A (en) * | 2021-08-24 | 2021-11-30 | 北京工业大学 | Device and method for deep denitrification of landfill leachate based on sludge fermentation liquor in-situ induction short-cut denitrification coupling anaerobic ammonia oxidation |
CN115745167B (en) * | 2022-10-19 | 2024-04-26 | 北京工业大学 | A device and method for realizing carbon source adsorption and enhanced nitrogen and phosphorus removal and synchronous sludge reduction in low carbon-nitrogen ratio urban sewage |
CN117865347B (en) * | 2024-01-04 | 2025-02-14 | 长江生态环保集团有限公司 | A continuous flow reaction device and operation method for promoting rapid formation of granular sludge |
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