CN103653200B - Cold plasma pesticide degradation instrument - Google Patents
Cold plasma pesticide degradation instrument Download PDFInfo
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- CN103653200B CN103653200B CN201310620286.9A CN201310620286A CN103653200B CN 103653200 B CN103653200 B CN 103653200B CN 201310620286 A CN201310620286 A CN 201310620286A CN 103653200 B CN103653200 B CN 103653200B
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- 230000015556 catabolic process Effects 0.000 title claims abstract description 46
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 46
- 239000000575 pesticide Substances 0.000 title claims abstract description 34
- 230000005495 cold plasma Effects 0.000 title claims abstract description 20
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 13
- 239000010949 copper Substances 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 230000017525 heat dissipation Effects 0.000 claims description 5
- -1 polytetrafluoroethylene Polymers 0.000 claims description 5
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 235000012055 fruits and vegetables Nutrition 0.000 abstract description 5
- 231100000167 toxic agent Toxicity 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 241000219112 Cucumis Species 0.000 abstract 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 abstract 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 abstract 1
- 238000000034 method Methods 0.000 description 3
- 150000002894 organic compounds Chemical class 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000001064 degrader Substances 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 238000006385 ozonation reaction Methods 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Catching Or Destruction (AREA)
- Plasma Technology (AREA)
Abstract
Description
技术领域 technical field
本发明涉及消毒设备,特别是一种冷等离子体农药降解仪。 The invention relates to disinfection equipment, in particular to a cold plasma pesticide degradation instrument.
背景技术 Background technique
目前,农药已经广泛用于瓜果、蔬菜等农作物的种植中,喷洒农药能有效降低病虫害,提高农作物的产量,但农药对人体危害极大并且带有农药的瓜果蔬菜清洗起来很麻烦且不彻底。农药大部分都是有机物,传统的降解方法包括光解、水解、催化臭氧化、超声波照射、电离辐射降解等。但这些方法去除降解农药的效率都十分有限,并且会附带产生有毒的化合物。 At present, pesticides have been widely used in the cultivation of fruits, vegetables and other crops. Spraying pesticides can effectively reduce pests and diseases and increase the yield of crops. However, pesticides are extremely harmful to the human body and the fruits and vegetables with pesticides are very troublesome and difficult to clean. thorough. Most of the pesticides are organic substances, the traditional degradation methods include photolysis, hydrolysis, catalytic ozonation, ultrasonic irradiation, ionizing radiation degradation and so on. However, the efficiency of these methods for removing and degrading pesticides is very limited, and toxic compounds will be produced incidentally.
研究表明,放电产生的等离子体中不仅含有臭氧、氢氧离子等,还有大量的高能电子,这些都有助于有机化合物的降解。而农药大多数都是有机化合物,采用等离子体降解农药是一种切实有效的途径。 Studies have shown that the plasma generated by the discharge not only contains ozone, hydroxide ions, etc., but also a large number of high-energy electrons, which all contribute to the degradation of organic compounds. Most of the pesticides are organic compounds, and the use of plasma to degrade pesticides is a practical and effective way.
目前还没有采用等离子体来降解农药的设备。 There is currently no device that uses plasma to degrade pesticides.
发明内容 Contents of the invention
本发明的目的在于提供一种冷等离子体农药降解仪,能够提高去除降解农药的效率,并且避免附带产生的有毒化合物。 The purpose of the present invention is to provide a cold plasma pesticide degrader, which can improve the efficiency of removing degraded pesticides and avoid the accompanying toxic compounds.
本发明公开的一种一种冷等离子体农药降解仪包括降解箱和电源,所述降解箱一侧开有箱门,在降解箱中设置有放电模块,放电模块由阳极、阴极和夹在阳极、阴极之间的介质层构成;降解箱外部还设置有控制显示模块,所述阳极、阴极、电源和控制显示模块通过导线连接起来。所述阳极为若干铜片组成的铜片阵列,阴极为金属网。 A kind of cold plasma pesticide degradation instrument disclosed by the present invention includes a degradation box and a power supply, and a box door is opened on one side of the degradation box, and a discharge module is arranged in the degradation box, and the discharge module is composed of an anode, a cathode, and an anode , and a dielectric layer between the cathodes; a control display module is also arranged outside the degradation box, and the anode, cathode, power supply and control display module are connected by wires. The anode is a copper sheet array composed of several copper sheets, and the cathode is a metal mesh.
(补入第0006段) (Add to paragraph 0006)
作为上述技术方案的再进一步改进,所述放电模块有若干个,分别相对安装在靠近降解箱内壁的位置。 As a further improvement of the above technical solution, there are several discharge modules, which are respectively installed relatively close to the inner wall of the degradation box.
作为上述技术方案的更进一步改进,所述放电模块有2个,分别安装在靠近与箱门相邻的两边内壁的位置。降解箱内相对的两个侧面都有放电模块,放电效率大大增加。 As a further improvement of the above technical solution, there are two discharge modules, which are respectively installed at positions close to the inner walls on both sides adjacent to the box door. There are discharge modules on the opposite sides of the degradation box, and the discharge efficiency is greatly increased.
作为上述技术方案的更进一步改进,所述铜片阵列、介质层和金属网从侧壁向内依次设置。 As a further improvement of the above technical solution, the copper sheet array, the dielectric layer and the metal mesh are sequentially arranged from the side wall inward.
作为上述技术方案的另一种改进,所述放电模块与外壁之间还设置有散热模块,用于对铜片进行散热。 As another improvement of the above technical solution, a heat dissipation module is further provided between the discharge module and the outer wall for heat dissipation of the copper sheet.
作为上述技术方案的另一种改进,所述降解箱内部底面上还设置有可旋转托盘。 As another improvement of the above technical solution, a rotatable tray is also arranged on the inner bottom surface of the degradation box.
作为上述技术方案的另一种改进,所述介质层为聚四氟乙烯。 As another improvement of the above technical solution, the dielectric layer is polytetrafluoroethylene.
与传统农药降解设备相比,本发明公开的冷等离子体农药降解仪,对农药降解的效果好、操作简单,不会附带产生的有毒化合物,安全可靠。可作为家用的瓜果蔬菜农药去除设备。 Compared with traditional pesticide degradation equipment, the cold plasma pesticide degradation instrument disclosed by the present invention has good effect on pesticide degradation, simple operation, no toxic compounds produced incidentally, and is safe and reliable. It can be used as household pesticide removal equipment for fruits and vegetables.
附图说明 Description of drawings
图1是冷等离子体农药降解仪结构正视图; Fig. 1 is the front view of the structure of the cold plasma pesticide degradation instrument;
图2是冷等离子体农药降解仪结构左视图; Fig. 2 is the left view of the structure of the cold plasma pesticide degradation instrument;
图3是冷等离子体农药降解仪结构俯视图。 Fig. 3 is a top view of the structure of the cold plasma pesticide degradation instrument.
具体实施方式 detailed description
下面结合附图对本发明的实施方式作详细说明。 Embodiments of the present invention will be described in detail below in conjunction with the accompanying drawings.
如图1、图2和图3所示,本发明公开的一种冷等离子体农药降解仪,包括降解箱和电源7,所述降解箱一侧开有箱门8,有2个放电模块分别相对安装在靠近与箱门8相邻的两边内壁的位置,放电模块与外壁之间还设置有散热模块4,用于对铜片进行散热。放电模块由从侧壁向内依次设置的若干铜片组成的铜片阵列3、金属网1和夹在铜片阵列3、金属网1之间的聚四氟乙烯介质层2构成,多个铜板组成阵列,放电效率高。降解箱外部还设置有控制显示模块5,控制显示模块5主要包括开关和定时器,能控制设备的开关和处理时间。所述铜片阵列3、金属网1、电源7和控制显示模块5通过导线连接起来。所述降解箱内部底面上还设置有可旋转托盘6,被处理的物品放在可旋转托盘6上。整个降解箱由一层绝缘层包裹。 As shown in Fig. 1, Fig. 2 and Fig. 3, a kind of cold plasma pesticide degradation instrument disclosed by the present invention includes a degradation box and a power supply 7, and a door 8 is opened on one side of the degradation box, and two discharge modules are respectively arranged. Relatively installed near the inner walls on both sides adjacent to the box door 8, a heat dissipation module 4 is also arranged between the discharge module and the outer wall for heat dissipation of the copper sheet. The discharge module is composed of a copper sheet array 3, a metal mesh 1, and a polytetrafluoroethylene dielectric layer 2 sandwiched between the copper sheet array 3 and the metal mesh 1, which are sequentially arranged from the side wall inward. Multiple copper sheets Composed of arrays, the discharge efficiency is high. A control display module 5 is also arranged outside the degradation box, and the control display module 5 mainly includes a switch and a timer, which can control the switch and processing time of the equipment. The copper sheet array 3, the metal mesh 1, the power supply 7 and the control display module 5 are connected by wires. A rotatable tray 6 is also arranged on the inner bottom surface of the degradation box, and the articles to be processed are placed on the rotatable tray 6 . The entire degradation box is wrapped by a layer of insulation.
采用家用220V交流电作输入,经过升压等处理产生电压在10KV左右、频率在10KHz左右的高压电并由绝缘导线传输到降解箱中,并且电源中含有保护电路,当电流过大时可以自动切断电源。放电模块的铜片阵列3作为阳极,金属网1作为阴极,中间是聚四氟乙烯介质层2,高压电通过阳极对阴极进行介质阻挡(DBD)放电,冷等离子体在金属网1附近产生。通过控制显示模块5可以调节等离子体产生的功率。由于放电模块是相对放置,还有可旋转托盘6,冷等离子体就能覆盖到物品表面,实现对瓜果蔬菜表面农药的降解作用。 Household 220V AC is used as input, and after boosting and other processing, high-voltage electricity with a voltage of about 10KV and a frequency of about 10KHz is transmitted to the degradation box by insulated wires, and the power supply contains a protection circuit, which can automatically when the current is too large. Cut off the power. The copper sheet array 3 of the discharge module is used as the anode, the metal mesh 1 is used as the cathode, and the middle is the polytetrafluoroethylene dielectric layer 2. The high voltage is discharged through the anode to the cathode by dielectric barrier (DBD), and the cold plasma is generated near the metal mesh 1 . The power generated by the plasma can be adjusted by controlling the display module 5 . Since the discharge modules are relatively placed and there is a rotatable tray 6, the cold plasma can cover the surface of the article to realize the degradation of pesticides on the surface of fruits and vegetables.
本发明具体应用途径很多,以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以作出若干改进,这些改进也应视为本发明的保护范围。 There are many specific application approaches of the present invention, and the above description is only a preferred embodiment of the present invention. It should be pointed out that for those of ordinary skill in the art, some improvements can also be made without departing from the principles of the present invention. Improvements should also be regarded as the protection scope of the present invention.
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CN104244558A (en) * | 2014-09-02 | 2014-12-24 | 大连民族学院 | Atmospheric pressure low-temperature plasma generation device and application thereof |
CN105495067A (en) * | 2014-09-25 | 2016-04-20 | 赵军 | Method for treatment of pesticide residue on dried Chinese wolfberry surfaces |
CN107410835A (en) * | 2017-04-05 | 2017-12-01 | 宁波欧琳厨具有限公司 | A kind of degradation of pesticide device |
CN112931761B (en) * | 2021-04-20 | 2023-06-02 | 山东大学 | Tea pesticide residue degradation and disinfection device and method based on atmospheric pressure cold plasma |
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US5704281A (en) * | 1997-01-15 | 1998-01-06 | Huang; Huo-Tu | Washing container |
CN2318833Y (en) * | 1998-03-07 | 1999-05-19 | 孙锐然 | Device for removing heavy metal and pesticide residue in fruits and vegetables |
JP2004321021A (en) * | 2003-04-22 | 2004-11-18 | Si Seiko Co Ltd | Method for removing residual agrochemical |
CN2613472Y (en) * | 2003-04-26 | 2004-04-28 | 清华大学 | Hydroxyl free radical-ozone generator of discharge catalyzing by nano titanium dioxide plasma |
KR100530702B1 (en) * | 2003-07-10 | 2005-11-23 | 코아텍주식회사 | Apparatus for treating agricultural chemicals using ultrasonic and ozone decomposing catalyst |
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CN102225791B (en) * | 2011-04-13 | 2013-01-30 | 山东大学 | A Radial Flow Dielectric Barrier Discharge Low Temperature Plasma Wastewater Treatment Device |
CN102448240B (en) * | 2012-01-31 | 2013-05-15 | 南京翰纳科技有限公司 | Needle Array Normal Temperature and Pressure Plasma Generator |
CN102814109B (en) * | 2012-08-29 | 2014-07-02 | 西安交通大学 | Device for waste gas treatment based on dielectric barrier corona discharge plasmas |
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