CN103643131B - A kind of insulating corrosion woven wire steel wire and application method thereof - Google Patents
A kind of insulating corrosion woven wire steel wire and application method thereof Download PDFInfo
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- CN103643131B CN103643131B CN201310583475.3A CN201310583475A CN103643131B CN 103643131 B CN103643131 B CN 103643131B CN 201310583475 A CN201310583475 A CN 201310583475A CN 103643131 B CN103643131 B CN 103643131B
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 77
- 239000010959 steel Substances 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005260 corrosion Methods 0.000 title claims abstract description 25
- 230000007797 corrosion Effects 0.000 title claims abstract description 23
- 238000009413 insulation Methods 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 10
- 229910000679 solder Inorganic materials 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 17
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- 238000010791 quenching Methods 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 238000003723 Smelting Methods 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 238000002203 pretreatment Methods 0.000 claims description 12
- 229910052720 vanadium Inorganic materials 0.000 claims description 11
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 11
- 230000000171 quenching effect Effects 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052804 chromium Inorganic materials 0.000 claims description 9
- 239000011651 chromium Substances 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 239000011572 manganese Substances 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 239000011733 molybdenum Substances 0.000 claims description 9
- 229910001120 nichrome Inorganic materials 0.000 claims description 9
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 9
- 238000007669 thermal treatment Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims description 8
- 239000010955 niobium Substances 0.000 claims description 8
- 229910052698 phosphorus Inorganic materials 0.000 claims description 8
- 239000011574 phosphorus Substances 0.000 claims description 8
- 238000005554 pickling Methods 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 8
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 8
- 229910052721 tungsten Inorganic materials 0.000 claims description 8
- 239000010937 tungsten Substances 0.000 claims description 8
- 229910000677 High-carbon steel Inorganic materials 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 235000019628 coolness Nutrition 0.000 claims description 4
- 238000005098 hot rolling Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 238000007751 thermal spraying Methods 0.000 claims description 4
- 230000003245 working effect Effects 0.000 abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
Abstract
The invention discloses a kind of insulating corrosion woven wire steel wire and application method thereof, this steel wire manufacturing process is relatively simple, insulation, protection against corrosion and cost is lower, its application method can save steel, extend the work-ing life of woven wire, the application method of this insulating corrosion woven wire steel wire, steel wire respectively level and vertically arranged in a crossed manner, horizontal wire and vertical steel wire are more than 5 or 5, the spacing of vertical steel wire is 2 times of horizontal wire, solder joint is spaced apart in the horizontal direction with vertical direction, improve the hardness of woven wire, and the object of anti-corrosion insulation can be reached.
Description
Technical field
The present invention relates to a kind of manufacture and application method of steel wire, especially relate to a kind of manufacture and application method thereof of insulating corrosion woven wire steel wire.
Background technology
At present along with the raising that building energy conservation requires, the requirement for the woven wire used as fence is also more and more higher.The woven wire of prior art is easy to be opened, and the intensity of steel wire and toughness are not, under long-term exposing to the weather drenches with rain, are very easily corroded, and for the woven wire that ordinary steel wire makes, also cannot play the effect of insulation.
Along with the high speed development of science and technology, netting purposes relates to industry and the high-tech areas such as oil, chemical industry, automobile, papermaking, food, building, Aeronautics and Astronautics.The woven wire made of wireline can the requirement of proof strength and toughness, but the manufacture of wireline may use multiple material, and manufacturing process is more loaded down with trivial details, therefore also cannot meet the requirement of low cost.
Summary of the invention
Technical problem to be solved by this invention is, overcome the shortcoming of prior art, a kind of insulating corrosion woven wire steel wire and application method thereof be provided, this steel wire manufacturing process is relatively simple, insulation, protection against corrosion and cost is lower, its application method can save steel, extends the work-ing life of woven wire.
In order to solve above technical problem, the invention provides a kind of insulating corrosion woven wire steel wire and application method thereof:
A kind of insulating corrosion woven wire steel wire, its manufacturing process is divided into following steps:
Step 1: take high carbon steel as base-material, base-material and alloy are added in stove and carry out smelting to obtain blank, the temperature of smelting is 1000-1100 DEG C, need after smelting terminates to be incubated 0.5-0.75h, the add-on of alloy is the 6-7% of base-material weight, the mass percent component of alloy is: carbon 0.5-0.54%, silicon: 0.78-0.82%, manganese: 0.45-0.5%, chromium: 1.07-1.16%, molybdenum: 0.11-0.18%, tungsten: 0.03-0.07%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.045-0.075%, niobium: 0.3-0.42%, 0-0.08% residual element, and all the other are Fe;
Step 2: the blank material hot-rolled obtained step 1 is to the steel wire of desired size, then the thermal treatment of expansion hydrogen is carried out, and remove heat scale through mechanical dephosphorizing equipment, then enter that rinse bath, pickling tank and phosphating equipment carry out cleaning respectively successively, pickling and bonderizing, finally enter drying plant to dry, obtain pre-treatment steel wire;
Step 3: adopt water-cooled to be cooled to room temperature with the rate of cooling of 10-12 DEG C/s to the pre-treatment steel wire that step 2 obtains;
Step 4: send in thermal spraying apparatus to the pre-treatment steel wire obtained in step 3, the nichrome powder be mixed in proportion is sprayed surface at steel wire uniformly by spray gun, the thickness of its spraying is 0.04mm, then enters process furnace and is heated to 860-880 DEG C rapidly, insulation 1min;
Step 5: the steel wire coated to the nichrome obtained in step 4 carries out quenching process process and drying treatment successively.
A kind of application method of insulating corrosion woven wire steel wire, steel wire respectively level and vertically arranged in a crossed manner, horizontal wire and vertical steel wire are more than 5 or 5, and the spacing of vertical steel wire is 2 times of horizontal wire, and solder joint is spaced apart in the horizontal direction with vertical direction.
The technical scheme that the present invention limits further is:
The mass percent component of aforementioned alloy is: carbon 0.5%, silicon: 0.82%, manganese: 0.5%, chromium: 1.07%, molybdenum: 0.11%, tungsten: 0.07%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.045%, niobium: 0.42%, 0.08% residual element, and all the other are Fe.
The mass percent component of aforementioned alloy is: carbon 0.54%, silicon: 0.78%, manganese: 0.45%, chromium: 1.16%, molybdenum: 0.18%, tungsten: 0.03%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.075%, niobium: 0.3%, 0.05% residual element, and all the other are Fe.
Further, expansion hydrogen thermal treatment in abovementioned steps 2 specifically comprises: steel wire hot rolling obtained enters stove and is heated to 850 ± 10 DEG C and is incubated 0.75h, water-cooled to 150 ± 10 DEG C, and then be heated to 650 ± 15 DEG C of insulation 1.5h, stove is chilled to 360 ± 20 DEG C of air coolings of coming out of the stove.
Aforementioned quenching process is for carry out quench treatment with high pressure spray jetting or hardening liquid.
The invention has the beneficial effects as follows:
Adds vanadium in present component, the toughness of steel, elasticity, wear resistance can be improved and resist performance, and making steel tight, and vanadium in steel is highly stable, not easily by hydrochloric acid, sulfuric acid decompose.Add the steel hardenability after vanadium good, the whole cross section of steel part can be made to obtain the mechanical property of uniformity and the quenching medium that steel part quenching stress is little can be selected, to reduce distortion and cracking.
Owing to adding manganese in present component: 0.45-0.5%, chromium: 1.07-1.16%, molybdenum: 0.11-0.18%, thus the atom active of C and N element can be improved, the air mass that each atom is formed can form strong interaction with dislocation, pinning dislocation, produce yield point elongation, make to need the external world to provide larger stress just can start dislocation.
Add niobium element in the present invention, it is larger with the avidity of C, adds after in steel and has precedence over C combination generation niobium carbide (NbC), effectively prevent intergranular corrosion.Add W elements in the present invention, red hardness and the heat resistance of steel can be improved, and the wear resistance of steel can be improved.
Expansion hydrogen thermal treatment in the present invention, ensures the content that can reduce hydrogen in steel wire further, prevents blank from producing Light spots crack and heat treatment stress brings out hydrogen induced cracking and hydrogen causes delay delayed fracture.
Present invention achieves the coated one deck nichrome of Steel Wire Surface, not only increase the intensity of compressor wire, and add the erosion resistance of compressor wire, wear resistance, oxidation-resistance, adds the work-ing life of compressor wire, save a large amount of resources, improve the competitive power of product.
The application of insulating corrosion steel wire provided by the invention in woven wire, can reduce rolled steel dosage, improves the hardness of woven wire, and can reach the object of anti-corrosion insulation.
Embodiment
Embodiment 1
The present embodiment provides a kind of insulating corrosion woven wire steel wire, and its manufacturing process is divided into following steps:
Step 1: take high carbon steel as base-material, base-material and alloy are added in stove and carry out smelting to obtain blank, the temperature of smelting is 1000-1100 DEG C, need after smelting terminates to be incubated 0.5-0.75h, the add-on of alloy is the 6-7% of base-material weight, the mass percent component of alloy is: carbon 0.5%, silicon: 0.82%, manganese: 0.5%, chromium: 1.07%, molybdenum: 0.11%, tungsten: 0.07%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.045%, niobium: 0.42%, 0.08% residual element, and all the other are Fe;
Step 2: the blank material hot-rolled obtained step 1 is to the steel wire of desired size, then the thermal treatment of expansion hydrogen is carried out, and remove heat scale through mechanical dephosphorizing equipment, then enter that rinse bath, pickling tank and phosphating equipment carry out cleaning respectively successively, pickling and bonderizing, finally enter drying plant to dry, obtain pre-treatment steel wire;
Wherein expand hydrogen thermal treatment specifically to comprise: steel wire hot rolling obtained enters stove and is heated to 850 ± 10 DEG C and is incubated 0.75h, water-cooled to 150 ± 10 DEG C, and then be heated to 650 ± 15 DEG C of insulation 1.5h, stove is chilled to 360 ± 20 DEG C of air coolings of coming out of the stove;
Step 3: adopt water-cooled to be cooled to room temperature with the rate of cooling of 10-12 DEG C/s to the pre-treatment steel wire that step 2 obtains;
Step 4: send in thermal spraying apparatus to the pre-treatment steel wire obtained in step 3, the nichrome powder be mixed in proportion is sprayed surface at steel wire uniformly by spray gun, the thickness of its spraying is 0.04mm, then enters process furnace and is heated to 860-880 DEG C rapidly, insulation 1min;
Step 5: the steel wire coated to the nichrome obtained in step 4 carries out quenching process process and drying treatment successively, and quenching process is for carry out quench treatment with high pressure spray jetting or hardening liquid.
Embodiment 2
The present embodiment provides a kind of insulating corrosion woven wire steel wire, and its manufacturing process is divided into following steps:
Step 1: take high carbon steel as base-material, base-material and alloy are added in stove and carry out smelting to obtain blank, the temperature of smelting is 1000-1100 DEG C, need after smelting terminates to be incubated 0.5-0.75h, the add-on of alloy is the 6-7% of base-material weight, the mass percent component of alloy is: carbon 0.54%, silicon: 0.78%, manganese: 0.45%, chromium: 1.16%, molybdenum: 0.18%, tungsten: 0.03%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.075%, niobium: 0.3%, 0.05% residual element, and all the other are Fe;
Step 2: the blank material hot-rolled obtained step 1 is to the steel wire of desired size, then the thermal treatment of expansion hydrogen is carried out, and remove heat scale through mechanical dephosphorizing equipment, then enter that rinse bath, pickling tank and phosphating equipment carry out cleaning respectively successively, pickling and bonderizing, finally enter drying plant to dry, obtain pre-treatment steel wire;
Wherein expand hydrogen thermal treatment specifically to comprise: steel wire hot rolling obtained enters stove and is heated to 850 ± 10 DEG C and is incubated 0.75h, water-cooled to 150 ± 10 DEG C, and then be heated to 650 ± 15 DEG C of insulation 1.5h, stove is chilled to 360 ± 20 DEG C of air coolings of coming out of the stove;
Step 3: adopt water-cooled to be cooled to room temperature with the rate of cooling of 10-12 DEG C/s to the pre-treatment steel wire that step 2 obtains;
Step 4: send in thermal spraying apparatus to the pre-treatment steel wire obtained in step 3, the nichrome powder be mixed in proportion is sprayed surface at steel wire uniformly by spray gun, the thickness of its spraying is 0.04mm, then enters process furnace and is heated to 860-880 DEG C rapidly, insulation 1min;
Step 5: the steel wire coated to the nichrome obtained in step 4 carries out quenching process process and drying treatment successively, and quenching process is for carry out quench treatment with high pressure spray jetting or hardening liquid.
Embodiment 3
The present embodiment provides a kind of application method of insulating corrosion woven wire steel wire, insulating corrosion steel wire respectively level and vertically arranged in a crossed manner, horizontal wire and vertical steel wire are more than 5 or 5, the spacing of vertical steel wire is 2 times of horizontal wire, and solder joint is spaced apart in the horizontal direction with vertical direction.
In addition to the implementation, the present invention can also have other embodiments.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop on the protection domain of application claims.
Claims (6)
1. an insulating corrosion woven wire steel wire, is characterized in that: its manufacturing process is divided into following steps:
Step 1: take high carbon steel as base-material, base-material and alloy are added in stove and carry out smelting to obtain blank, the temperature of described smelting is 1000-1100 DEG C, need after smelting terminates to be incubated 0.5-0.75h, the add-on of described alloy is the 6-7% of base-material weight, the mass percent component of described alloy is: carbon 0.5-0.54%, silicon: 0.78-0.82%, manganese: 0.45-0.5%, chromium: 1.07-1.16%, molybdenum: 0.11-0.18%, tungsten: 0.03-0.07%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.045-0.075%, niobium: 0.3-0.42%, 0-0.08% residual element, and all the other are Fe;
Step 2: the blank material hot-rolled obtained step 1 is to the steel wire of desired size, then the thermal treatment of expansion hydrogen is carried out, and remove heat scale through mechanical dephosphorizing equipment, then enter that rinse bath, pickling tank and phosphating equipment carry out cleaning respectively successively, pickling and bonderizing, finally enter drying plant to dry, obtain pre-treatment steel wire;
Step 3: adopt water-cooled to be cooled to room temperature with the rate of cooling of 10-12 DEG C/s to the pre-treatment steel wire that step 2 obtains;
Step 4: send in thermal spraying apparatus to the pre-treatment steel wire obtained in step 3, the nichrome powder be mixed in proportion is sprayed surface at steel wire uniformly by spray gun, the thickness of its spraying is 0.04mm, then enters process furnace and is heated to 860-880 DEG C rapidly, insulation 1min;
Step 5: the steel wire coated to the nichrome obtained in step 4 carries out quenching process process and drying treatment successively.
2. insulating corrosion woven wire steel wire according to claim 1, is characterized in that:
The mass percent component of described alloy is: carbon 0.5%, silicon: 0.82%, manganese: 0.5%, chromium: 1.07%, molybdenum: 0.11%, tungsten: 0.07%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.045%, niobium: 0.42%, 0.08% residual element, and all the other are Fe.
3. insulating corrosion woven wire steel wire according to claim 1, is characterized in that:
The mass percent component of described alloy is: carbon 0.54%, silicon: 0.78%, manganese: 0.45%, chromium: 1.16%, molybdenum: 0.18%, tungsten: 0.03%, phosphorus: 0.006%, sulphur: 0.0055%, vanadium: 0.075%, niobium: 0.3%, 0.05% residual element, and all the other are Fe.
4. according to the insulating corrosion woven wire steel wire in claims 1 to 3 described in any one claim, it is characterized in that, expansion hydrogen thermal treatment in step 2 specifically comprises: steel wire hot rolling obtained enters stove and is heated to 850 ± 10 DEG C and is incubated 0.75h, water-cooled to 150 ± 10 DEG C, and then being heated to 650 ± 15 DEG C of insulation 1.5h, stove is chilled to 360 ± 20 DEG C of air coolings of coming out of the stove.
5., according to the insulating corrosion woven wire steel wire in claims 1 to 3 described in any one claim, it is characterized in that, described quenching process is for carry out quench treatment with high pressure spray jetting or hardening liquid.
6. according to the application method of the insulating corrosion woven wire steel wire in claims 1 to 3 described in any one claim, it is characterized in that: described steel wire level and vertically arranged in a crossed manner respectively, described horizontal wire and vertical steel wire are more than 5 or 5, the spacing of described vertical steel wire is 2 times of horizontal wire, and solder joint is spaced apart in the horizontal direction with vertical direction.
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CN109127765A (en) * | 2018-08-07 | 2019-01-04 | 辽宁通达建材实业有限公司 | A kind of pipe line steel filament processing process improving pipeline steel wire stress corrosion performance |
CN112210806B (en) * | 2020-08-13 | 2021-10-08 | 法尔胜泓昇集团有限公司 | Anti-corrosion steel wire with molybdenum disulfide coating and preparation process thereof |
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JP2007131945A (en) * | 2005-10-12 | 2007-05-31 | Nippon Steel Corp | High strength steel wire with excellent ductility and method for producing the same |
CN101331243A (en) * | 2006-10-12 | 2008-12-24 | 新日本制铁株式会社 | High-strength wire rod excellent in drawing properties and manufacturing method thereof |
CN101763916A (en) * | 2009-12-30 | 2010-06-30 | 甘肃天拓冶金科技有限公司 | Production method for copper-clad steel double-metal wire |
CN102418178A (en) * | 2011-09-26 | 2012-04-18 | 吴江伊兰吉纺织品有限公司 | Preparation method of wear-resistant steel wire ring |
CN103255279A (en) * | 2013-05-20 | 2013-08-21 | 天津高盛钢丝绳有限公司 | Heat treatment process of steel wire |
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US20100028196A1 (en) * | 2006-11-09 | 2010-02-04 | Masayuki Hashimura | High Strength Spring Steel and High Strength Heat Treated Steel Wire for Spring |
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2007131945A (en) * | 2005-10-12 | 2007-05-31 | Nippon Steel Corp | High strength steel wire with excellent ductility and method for producing the same |
CN101331243A (en) * | 2006-10-12 | 2008-12-24 | 新日本制铁株式会社 | High-strength wire rod excellent in drawing properties and manufacturing method thereof |
CN101763916A (en) * | 2009-12-30 | 2010-06-30 | 甘肃天拓冶金科技有限公司 | Production method for copper-clad steel double-metal wire |
CN102418178A (en) * | 2011-09-26 | 2012-04-18 | 吴江伊兰吉纺织品有限公司 | Preparation method of wear-resistant steel wire ring |
CN103255279A (en) * | 2013-05-20 | 2013-08-21 | 天津高盛钢丝绳有限公司 | Heat treatment process of steel wire |
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Effective date of registration: 20190517 Address after: 212219 Changsheng Village, Baqiao Town, Yangzhou City, Zhenjiang City, Jiangsu Province Patentee after: Jiangsu forest building new material Limited by Share Ltd Address before: 212219 Second Bridge Industrial Zone, Baqiao Town, Yangzhong City, Zhenjiang City, Jiangsu Province Patentee before: Jiangsu Tianshun Metal Material Group Co., Ltd. |