CN103639558B - Thermal-ultrasonic-electromagnetic multi-field compound reflow soldering method - Google Patents
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/30—Assembling printed circuits with electric components, e.g. with resistor
- H05K3/32—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits
- H05K3/34—Assembling printed circuits with electric components, e.g. with resistor electrically connecting electric components or wires to printed circuits by soldering
- H05K3/341—Surface mounted components
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Abstract
热-超声-电磁多场复合再流焊方法,涉及一种再流焊方法。所述方法步骤如下:将印制电路板置于回流焊加热板中间位置,回流焊加热板下方放置磁场线垂直于倒装PCB组件表面的“山”形磁铁,在中间磁芯柱位置缠绕耐强电流的线圈;超声触头通过精密光学的对准装置拾取带有焊球的芯片元件并与PCB电路板上的焊盘对准;开启回流焊加热板,当回流焊加热板温度达到保温区时,在互连过程中开始施加超声和磁场,完成再流焊过程。本发明在热板-超声再流焊技术基础上施加定向的磁场,通过磁场强度和方向的调控实现较低温度下IMCs的定向、择优、快速生长,旨在在较低温度下快速获得力学性能优异的焊点,以提高电子器件可靠性。
The thermal-ultrasonic-electromagnetic multi-field composite reflow soldering method relates to a reflow soldering method. The steps of the method are as follows: place the printed circuit board at the middle position of the reflow soldering heating plate, place a “mountain” shaped magnet whose magnetic field lines are perpendicular to the surface of the flip-chip PCB assembly under the reflow soldering heating plate, and wind a durable magnet at the position of the middle magnetic core post. Strong current coil; the ultrasonic contact picks up the chip components with solder balls through the precision optical alignment device and aligns them with the pads on the PCB circuit board; turns on the reflow soldering heating plate, when the temperature of the reflow soldering heating plate reaches the heat preservation zone At this time, ultrasonic and magnetic fields are applied during the interconnection process to complete the reflow soldering process. The invention applies a directional magnetic field on the basis of the hot plate-ultrasonic reflow soldering technology, and realizes the orientation, preference, and rapid growth of IMCs at a lower temperature through the regulation of the magnetic field strength and direction, aiming at quickly obtaining mechanical properties at a lower temperature Excellent solder joints to improve electronic device reliability.
Description
技术领域technical field
本发明涉及一种再流焊方法,具体涉及一种热-超声-磁场复合条件下的再流焊方法。The invention relates to a reflow soldering method, in particular to a reflow soldering method under the combined conditions of thermal-ultrasonic-magnetic field.
背景技术Background technique
为了满足电子系统的多功能化、高性能、低功率损耗、小尺寸等发展需求,电子电路表面组装技术(SMT,SurfaceMountTechnology)已成为电子封装技术的核心之一,并向着高密度、三维立体、微机电系统一体化的方向发展。随着封装密度的提高,焊点尺寸日益减小,金属间化合物(IntemetallicCompounds-IMCs)在焊点中所占比例越来越大,界面IMCs逐渐成为焊点的主要组成单元,当有限个不同取向的IMCs晶粒在微焊点中比重增大到一定程度时,焊点在各种载荷下的力学行为将与原始材料以及相同材料大焊点产生显著差异,界面IMCs成为焊点可靠性主导的趋势日益彰显。许多研究表明钎料同焊盘界面的IMCs与焊点可靠性密切相关。IMCs晶体力学性质的各向异性,具有不同择优取向IMCs的焊点将表现出不同的力学行为。因此如何获得力学和物理性能优异晶体取向的IMCs是对再流焊技术的挑战。In order to meet the development needs of electronic systems such as multi-functionality, high performance, low power loss, and small size, electronic circuit surface mount technology (SMT, Surface Mount Technology) has become one of the cores of electronic packaging technology, and is moving towards high density, three-dimensional, three-dimensional, Development in the direction of MEMS integration. With the increase of packaging density, the size of solder joints is decreasing day by day, and the proportion of intermetallic compounds (Intermetallic Compounds-IMCs) in solder joints is increasing, and the interface IMCs gradually become the main constituent units of solder joints. When the proportion of IMCs grains in micro-solder joints increases to a certain extent, the mechanical behavior of the solder joints under various loads will be significantly different from that of the original material and large solder joints of the same material, and the interface IMCs will become the dominant factor for the reliability of solder joints. The trend is becoming increasingly apparent. Many studies have shown that the IMCs at the solder-pad interface are closely related to solder joint reliability. Due to the anisotropy of the crystal mechanical properties of IMCs, solder joints with different preferred orientations of IMCs will exhibit different mechanical behaviors. Therefore, how to obtain IMCs with crystal orientation with excellent mechanical and physical properties is a challenge to reflow soldering technology.
再流焊(亦称回流焊)是预先在印制电路板(PCB,PrintedCircuitBoard)焊盘施放适量焊料,贴放表面组装元器件,如BGA(BallGridArray)器件,经固化后,在利用外部热源使焊料再次流动已达到互连目的的一种工艺。Reflow soldering (also known as reflow soldering) is to apply an appropriate amount of solder on the printed circuit board (PCB, Printed Circuit Board) pad in advance, and place surface mount components, such as BGA (BallGridArray) devices. After curing, use an external heat source to use A process in which solder reflows to achieve interconnection purposes.
传统的表面贴装再流焊工艺主要有:热板传导再流焊、红外辐射加热再流焊、热风对流再流焊、红外热风再流焊、气相加热再流焊。其中热板传导再流焊和热风对流再流焊最为常用。这些再流焊工艺虽然能够满足互连的基本需求,但对于实现焊点界面处金属间化合物IMCs的定向生长的要求,却远不能满足。目前再流焊工艺的区别主要是加热方式、加热部位和热传导方式的不同,但难以控制焊点的微观组织,特别是焊点界面金属间化合物IMCs的晶粒取向,具体表现为:Traditional surface mount reflow soldering processes mainly include: hot plate conduction reflow soldering, infrared radiation heating reflow soldering, hot air convection reflow soldering, infrared hot air reflow soldering, and gas phase heating reflow soldering. Among them, hot plate conduction reflow soldering and hot air convection reflow soldering are the most commonly used. Although these reflow soldering processes can meet the basic needs of interconnection, they are far from meeting the requirements for the directional growth of intermetallic compound IMCs at the interface of solder joints. At present, the difference in reflow soldering process is mainly the difference in heating mode, heating position and heat conduction mode, but it is difficult to control the microstructure of solder joints, especially the grain orientation of intermetallic compound IMCs at the solder joint interface, as follows:
(1)热板传导再流焊。该方法是应用最早的再流焊方法。发热器件多为块形板,将电路基板放置在加热板上,热量随后传送至电路基板,再由焊膏传至表面贴砖器件,软钎焊膏受热熔化,进行器件与电路基板的焊接。该种技术主要适用于导热性良好的电路基板的单面贴装形式。(1) Hot plate conduction reflow soldering. This method is the earliest reflow soldering method. Most of the heating devices are block-shaped boards. The circuit substrate is placed on the heating plate, and the heat is then transferred to the circuit substrate, and then transferred to the surface tile device by the solder paste. The solder paste is heated and melted to weld the device and the circuit substrate. This technology is mainly suitable for single-sided mounting of circuit substrates with good thermal conductivity.
(2)热风对流再流焊。热风对流是利用加热器和风扇,使炉膛的空气不断加热并进行对流循环。该种方法具有很高的生产能力,操作成本也较低,但温度不稳定。(2) Hot air convection reflow soldering. Hot air convection uses heaters and fans to continuously heat and circulate the air in the furnace. This method has high production capacity and low operating cost, but the temperature is unstable.
(3)热-超声再流焊。该方法是在热板传导再流焊的基础上安装超声装置。超声震动导致焊盘和界面摩擦生热,促进焊点的熔化,可以在较低的温度下实现键合,从而避免了高温给元器件带来热损伤;超声有利于原子的扩散,可短时间内形成可靠焊点所需的金属间化合物IMCs,缩短工艺时间,提高生产效率。但超声对于焊点内部晶粒取向的作用影响不明显,有待进一步提高。(3) Thermo-ultrasonic reflow soldering. The method is to install an ultrasonic device on the basis of hot plate conduction reflow soldering. Ultrasonic vibration causes frictional heat generation between the pad and the interface, promotes the melting of solder joints, and can achieve bonding at a lower temperature, thus avoiding thermal damage to components caused by high temperature; ultrasonic is conducive to the diffusion of atoms, which can The intermetallic compound IMCs required to form reliable solder joints, shorten process time and improve production efficiency. However, the effect of ultrasound on the grain orientation inside the solder joint is not obvious, and needs to be further improved.
为此,许多研究表明:在再流焊过程中施加定向磁场,可有效的改变IMCs的形貌相貌和生长方式,使其定向择优生长,从而改善微互连焊点的力学性能。For this reason, many studies have shown that applying a directional magnetic field during reflow soldering can effectively change the morphology and growth mode of IMCs, making them directional and preferential growth, thereby improving the mechanical properties of micro-interconnection solder joints.
发明内容Contents of the invention
本发明的目的是提供一种热-超声-电磁多场复合再流焊方法,在热板-超声再流焊技术基础上施加定向的磁场,通过磁场强度和方向的调控实现较低温度下IMCs的定向、择优、快速生长,旨在在较低温度下快速获得力学性能优异的焊点,以提高电子器件可靠性。The purpose of the present invention is to provide a thermal-ultrasonic-electromagnetic multi-field composite reflow soldering method, which applies a directional magnetic field on the basis of the hot plate-ultrasonic reflow soldering technology, and realizes IMCs at lower temperatures by adjusting the magnetic field strength and direction The directional, selective, and rapid growth of the aim to quickly obtain solder joints with excellent mechanical properties at lower temperatures to improve the reliability of electronic devices.
本发明的热-超声-电磁多场复合再流焊方法的工艺过程如下:The technical process of the heat-ultrasonic-electromagnetic multi-field composite reflow soldering method of the present invention is as follows:
第一步、放置PCB电路基板:The first step is to place the PCB circuit substrate:
将印制电路板置于回流焊加热板中间位置,回流焊加热板下方放置磁场线垂直于倒装PCB组件表面的“山”形磁铁,在中间磁芯柱位置缠绕耐强电流的线圈;Place the printed circuit board in the middle of the reflow soldering heating plate, place a "mountain"-shaped magnet whose magnetic field lines are perpendicular to the surface of the flip-chip PCB assembly under the reflow soldering heating plate, and wind a high-current-resistant coil at the middle magnetic core post;
第二步、拾取、对准芯片元件:The second step, picking up and aligning chip components:
超声触头通过精密光学的对准装置拾取带有焊球的芯片元件并与PCB电路板上的焊盘对准;The ultrasonic contact picks up the chip components with solder balls through the precise optical alignment device and aligns them with the pads on the PCB circuit board;
第三步、热-超声-磁场再流焊:The third step, thermal-ultrasonic-magnetic field reflow soldering:
开启回流焊加热板,当回流焊加热板温度达到保温区时,在互连过程中开始施加超声和磁场,加载超声的时间为1~5s,超声频率在20~65kHz,加载磁场的时间为1~30s,磁场强度的范围在0.1~40T,完成再流焊过程。Turn on the reflow soldering heating plate, when the temperature of the reflow soldering heating plate reaches the holding zone, start to apply ultrasound and magnetic field during the interconnection process, the time for loading ultrasound is 1-5s, the frequency of ultrasound is 20-65kHz, and the time for loading magnetic field is 1 ~30s, the range of magnetic field strength is 0.1~40T, and the reflow soldering process is completed.
本发明提供的热-超声-磁场复合条件下再流焊技术是基于现有的热-超声再流焊基础上施加磁场,以此改变再流焊工艺时间和改善焊点组织、性能的方法。在再流焊过程中施加磁场主要基于以下两方面原理:强磁场可以将高强度的能量无接触的传递到材料的原子尺度,改变原子排列、匹配和迁移等行为,进而改变材料的组织、结构和性能。磁场在材料的制备中主要有两大作用:一是磁场取向,二是磁场控制流体的流动。利用磁场有可能控制微焊点重熔后结晶过程中晶体生长的形态、大小、分布和取向等,从而控制微焊点的组织,最后中获得力学和物理性能优异的焊点。The thermal-ultrasonic-magnetic field composite reflow soldering technology provided by the present invention is based on the existing thermal-ultrasonic reflow soldering and applies a magnetic field to change the reflow soldering process time and improve the structure and performance of solder joints. The application of a magnetic field in the reflow process is mainly based on the following two principles: a strong magnetic field can transfer high-intensity energy to the atomic scale of the material without contact, change the behavior of atomic arrangement, matching and migration, and then change the organization and structure of the material and performance. The magnetic field has two main functions in the preparation of materials: one is the orientation of the magnetic field, and the other is that the magnetic field controls the flow of the fluid. It is possible to control the shape, size, distribution and orientation of crystal growth during the crystallization process of micro-solder joints by using a magnetic field, thereby controlling the structure of micro-solder joints, and finally obtaining solder joints with excellent mechanical and physical properties.
附图说明Description of drawings
图1为“山”形磁芯通电螺旋管磁场线分布示意图;Figure 1 is a schematic diagram of the distribution of magnetic field lines in a "mountain" shaped magnetic core energized spiral tube;
图2为回流焊加热板剖面图;Figure 2 is a cross-sectional view of the reflow soldering heating plate;
图3为热-超声-电磁复合再流焊工艺整体示意图;Figure 3 is an overall schematic diagram of the thermal-ultrasonic-electromagnetic composite reflow process;
图4为超声触头下倒装PCB组件示意图;Figure 4 is a schematic diagram of a flip-chip PCB assembly under an ultrasonic contact;
图5为超声触头下倒装PCB组件剖面图;Figure 5 is a cross-sectional view of the flip-chip PCB assembly under the ultrasonic contact;
图中,1-红外测温仪:监测再流焊过程中焊点的温度,通过数据光纤传输至电脑;2-回流焊加热板:为再流焊工艺提供热源,通过预设程序可设置预热区、再流区、冷却区三个过程的温度曲线;3-“山”形磁铁:引导磁场线分布;4-超声触头:为再流焊过程中提供不同功率的超声,通过预设程序改变超声触头的频率、振动方向(横向和纵向),真空吸嘴吸附芯片元器件并与PCB板对准,通过超声压头施加压力;5-线圈:缠绕于“山”形磁铁中间磁芯,形成通电螺旋管产生竖直方向的磁场,不同的线圈匝数可调节磁场强度;6-倒装PCB组件:将带有BGA凸点的元器件组装到PCB板上;7-特斯拉计:根据霍尔效应制成的测量磁感应强度的仪器,可测量倒装PCB组件部位的磁场强度;8-直流电源:为线圈提供不同方向的稳定的直流电;9-导线:输送电流;10-芯片元件,11-BGA焊球,12-焊盘,13-PCB基板;14-导热基板;15-高温加热膜;16-隔热基板。In the figure, 1-infrared thermometer: monitor the temperature of the solder joint during the reflow soldering process, and transmit it to the computer through the data optical fiber; 2-reflow soldering heating plate: provide heat source for the reflow soldering process, and the preset program can be set Temperature curves of the three processes of hot zone, reflow zone, and cooling zone; 3-"mountain"-shaped magnet: guide the distribution of magnetic field lines; 4-ultrasonic contactor: provide different power ultrasound for reflow soldering process, through preset The program changes the frequency and vibration direction (horizontal and vertical) of the ultrasonic contact, the vacuum nozzle absorbs the chip components and aligns with the PCB board, and applies pressure through the ultrasonic indenter; 5-coil: wound in the middle of the "mountain" shaped magnet Core, forming a energized spiral tube to generate a vertical magnetic field, different coil turns can adjust the magnetic field strength; 6-Flip-chip PCB assembly: assemble components with BGA bumps on the PCB board; 7-Tesla Meter: An instrument for measuring magnetic induction intensity based on the Hall effect, which can measure the magnetic field intensity of flip-chip PCB components; 8-DC power supply: provide stable DC power in different directions for the coil; 9-wire: transmit current; 10- Chip components, 11-BGA solder balls, 12-welding pads, 13-PCB substrate; 14-thermal conduction substrate; 15-high temperature heating film; 16-heat insulation substrate.
具体实施方式Detailed ways
下面结合附图对本发明的技术方案作进一步的说明,但并不局限于此,凡是对本发明技术方案进行修改或者等同替换,而不脱离本发明技术方案的精神和范围,均应涵盖在本发明的保护范围中。The technical solution of the present invention will be further described below in conjunction with the accompanying drawings, but it is not limited thereto. Any modification or equivalent replacement of the technical solution of the present invention without departing from the spirit and scope of the technical solution of the present invention should be covered by the present invention. within the scope of protection.
本发明的热-超声-电磁多场复合再流焊方法的工艺过程如下:The technical process of the heat-ultrasonic-electromagnetic multi-field composite reflow soldering method of the present invention is as follows:
第一步、放置PCB电路基板:The first step is to place the PCB circuit substrate:
将PCB基板13置于回流焊加热板2中间位置,回流焊加热板2的加热温度范围为50~400℃。回流焊加热板2下方放置磁场线垂直于倒装PCB组件6表面的“山”形磁铁3,在中间磁芯柱位置缠绕耐强电流的线圈5(例如紫铜线圈、超导材质线圈),以便获得大范围的磁场强度,磁场强度范围在0.1~40T。The PCB substrate 13 is placed in the middle of the reflow soldering heating plate 2, and the heating temperature range of the reflow soldering heating plate 2 is 50-400°C. The "mountain" shaped magnet 3 whose magnetic field lines are perpendicular to the surface of the flip-chip PCB assembly 6 is placed under the reflow soldering heating plate 2, and a coil 5 (such as a copper coil, a superconducting material coil) with high current resistance is wound at the middle magnetic core column position, so that Obtain a wide range of magnetic field strength, and the magnetic field strength ranges from 0.1 to 40T.
第二步、拾取、对准芯片元件:The second step, picking up and aligning chip components:
超声触头4通过精密光学的对准装置(例如,倒扣焊中的光学对准系统)拾取带有焊球的芯片元件10并与PCB基板13上的焊盘12对准。超声频率的范围为20~65kHz。此外,超声触头4也可对已经装配完毕的PCB组件施加压力,范围在0~20N即可满足微焊点互连的技术要求。The ultrasonic contactor 4 picks up the chip component 10 with solder balls and aligns it with the pad 12 on the PCB substrate 13 through a precise optical alignment device (for example, an optical alignment system in flip-bonding). Ultrasonic frequencies range from 20 to 65 kHz. In addition, the ultrasonic contact 4 can also exert pressure on the assembled PCB components, and the range of 0-20N can meet the technical requirements of micro-solder joint interconnection.
第三步、热-超声-磁场再流焊:The third step, thermal-ultrasonic-magnetic field reflow soldering:
首先,开启回流焊加热板2开关,回流焊加热板2经预热后达到保温温度(由无铅焊球材质决定,温度范围在50~400℃,保温时间在1~30s)。当温度达到保温区时,开启超声和直流电源8开关,在互连过程中开始施加超声和磁场。加载超声的时间一般为1~5s,超声频率可调,范围在20~65kHz;加载磁场的时间为1~30s,磁场强度的范围在0.1~40T。关闭回流焊加热板2开关、超声装置开关、直流电源8开关完成再流焊过程。First, turn on the reflow soldering heating plate 2 switch, and the reflow soldering heating plate 2 reaches the holding temperature after preheating (determined by the material of the lead-free solder ball, the temperature range is 50-400°C, and the holding time is 1-30s). When the temperature reaches the heat preservation zone, the ultrasonic and DC power supply 8 switches are turned on, and the ultrasonic and magnetic fields are applied during the interconnection process. The ultrasonic loading time is generally 1-5s, and the ultrasonic frequency is adjustable in the range of 20-65kHz; the magnetic field loading time is 1-30s, and the magnetic field strength ranges from 0.1-40T. Turn off the reflow soldering heating plate 2 switch, the ultrasonic device switch, and the DC power supply 8 switch to complete the reflow soldering process.
需特别说明:本发明中要保证磁场线垂直于倒装PCB组件6表面,并且磁场强度能够满足0.1~40T范围内变化。因此,一方面设计了“山”形磁铁3(图1),磁阻相对于“柱”形磁芯磁阻小,磁场线容易约束,在相对较小的电流下就可产生足够强度的磁场;另一方面,采用三明治结构的回流焊加热板(图2),控制其厚度在2~3mm。回流焊加热板顶层为光滑面的导热基板14,厚度可控在1mm内;中间层为高温加热膜(云母片加热膜)15,厚度可控在1mm内(温度范围在30~500℃);底层贴近磁芯材料,选择具备隔热材质的隔热基板16,厚度控制在1mm内。此种加热板制作简单,加热速率快,温度可控,并且经磁场线穿透后仍能够满足实验要求。It needs special explanation: in the present invention, it is necessary to ensure that the magnetic field lines are perpendicular to the surface of the flip-chip PCB assembly 6, and the magnetic field intensity can satisfy the variation within the range of 0.1-40T. Therefore, on the one hand, the "mountain" shaped magnet 3 (Fig. 1) is designed, the reluctance is smaller than that of the "column" shaped core, the magnetic field lines are easily constrained, and a magnetic field of sufficient strength can be generated under a relatively small current ; On the other hand, the reflow soldering heating plate with sandwich structure (Figure 2) is used to control its thickness at 2-3mm. The top layer of the reflow heating plate is a smooth heat-conducting substrate 14, the thickness of which can be controlled within 1 mm; the middle layer is a high-temperature heating film (mica sheet heating film) 15, and the thickness can be controlled within 1 mm (temperature range is 30 ~ 500 ° C); The bottom layer is close to the magnetic core material, and the heat insulating substrate 16 with heat insulating material is selected, and the thickness is controlled within 1mm. The heating plate is simple to manufacture, has a fast heating rate, and can control the temperature, and can still meet the experimental requirements after being penetrated by the magnetic field lines.
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