CN103608632B - Utilize the LNG being used for fuel with the system and method for the LPG boil-off gas that liquefies - Google Patents
Utilize the LNG being used for fuel with the system and method for the LPG boil-off gas that liquefies Download PDFInfo
- Publication number
- CN103608632B CN103608632B CN201280026200.3A CN201280026200A CN103608632B CN 103608632 B CN103608632 B CN 103608632B CN 201280026200 A CN201280026200 A CN 201280026200A CN 103608632 B CN103608632 B CN 103608632B
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- Prior art keywords
- lng
- vaporizer
- bog
- lpg
- tank
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
- F25J1/0025—Boil-off gases "BOG" from storages
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C1/00—Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0045—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by vaporising a liquid return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0201—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
- F25J1/0202—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration in a quasi-closed internal refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0221—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop
- F25J1/0224—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop in combination with an internal quasi-closed refrigeration loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
- F25J1/0275—Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
- F25J1/0277—Offshore use, e.g. during shipping
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- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0292—Refrigerant compression by cold or cryogenic suction of the refrigerant gas
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2201/00—Vessel construction, in particular geometry, arrangement or size
- F17C2201/05—Size
- F17C2201/052—Size large (>1000 m3)
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2205/00—Vessel construction, in particular mounting arrangements, attachments or identifications means
- F17C2205/03—Fluid connections, filters, valves, closure means or other attachments
- F17C2205/0302—Fittings, valves, filters, or components in connection with the gas storage device
- F17C2205/0323—Valves
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/033—Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/03—Mixtures
- F17C2221/032—Hydrocarbons
- F17C2221/035—Propane butane, e.g. LPG, GPL
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- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0107—Single phase
- F17C2223/0123—Single phase gaseous, e.g. CNG, GNC
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- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
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- F17C2223/0146—Two-phase
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- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F17C2223/033—Small pressure, e.g. for liquefied gas
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- F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
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- F17C2225/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F17C2225/0169—Liquefied gas, e.g. LPG, GPL subcooled
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/032—Treating the boil-off by recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/032—Treating the boil-off by recovery
- F17C2265/033—Treating the boil-off by recovery with cooling
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/032—Treating the boil-off by recovery
- F17C2265/033—Treating the boil-off by recovery with cooling
- F17C2265/034—Treating the boil-off by recovery with cooling with condensing the gas phase
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/032—Treating the boil-off by recovery
- F17C2265/033—Treating the boil-off by recovery with cooling
- F17C2265/035—Treating the boil-off by recovery with cooling with subcooling the liquid phase
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/05—Regasification
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0102—Applications for fluid transport or storage on or in the water
- F17C2270/0105—Ships
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/06—Splitting of the feed stream, e.g. for treating or cooling in different ways
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2210/00—Processes characterised by the type or other details of the feed stream
- F25J2210/62—Liquefied natural gas [LNG]; Natural gas liquids [NGL]; Liquefied petroleum gas [LPG]
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/64—Propane or propylene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/66—Butane or mixed butanes
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/34—Details about subcooling of liquids
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Abstract
本发明涉及用于液化LPG蒸发气体(BOG)的方法和系统,所述系统包括LNG燃料供应系统和LPG货物系统,其中所述LNG燃料系统包括至少一个LNG燃料罐23、LNG燃料管线5和第二LNG燃料管线13,其中所述LPG货物系统包括至少一个LPG货物罐20、BOG管线1、至少一个再液化单元100和冷凝管线3;其中所述系统还包括:提供于LNG燃料罐23与第二LNG燃料管线13之间的LNG燃料管线5上的至少一个汽化器15、22,其中所述至少一个汽化器15、22与所述LPG货物系统进行热交换。The present invention relates to a method and system for liquefying LPG boil-off gas (BOG), said system comprising an LNG fuel supply system and an LPG cargo system, wherein said LNG fuel system comprises at least one LNG fuel tank 23, an LNG fuel pipeline 5 and a second Two LNG fuel pipelines 13, wherein the LPG cargo system includes at least one LPG cargo tank 20, BOG pipeline 1, at least one reliquefaction unit 100 and condensation pipeline 3; wherein the system also includes: provided between the LNG fuel tank 23 and the second At least one vaporizer 15, 22 on the LNG fuel pipeline 5 between the two LNG fuel pipelines 13, wherein the at least one vaporizer 15, 22 performs heat exchange with the LPG cargo system.
Description
技术领域technical field
本发明涉及用于利用用于燃料的LNG以液化LPG蒸发气体(boiloff)的系统和方法。The present invention relates to systems and methods for utilizing LNG for fuel to liquefy LPG boiloff.
背景技术Background technique
当前技术current technology
KR20100102872公开了用在复杂船只或浮式生产储卸船上的同时接收LPG和LNG流的方法。KR20100102872描述的发明解决了在压缩和液化之前如何利用LNG蒸发气体的低温来冷凝LPG蒸发气体以减少LPG再液化系统的复杂性。KR20100102872 discloses a method for simultaneous reception of LPG and LNG streams on complex vessels or floating production storage and offloading vessels. The invention described in KR20100102872 solves how to utilize the low temperature of the LNG boil-off gas to condense the LPG boil-off gas before compression and liquefaction to reduce the complexity of the LPG reliquefaction system.
与本发明相反KR20100102872使用LNG蒸发气体的显热以冷凝LPG蒸发气体,所述本发明与LNG燃料气体系统组合使用LNG的潜热和显热的组合以冷凝LPG蒸发气体。KR20100102872 uses sensible heat of LNG boil-off gas to condense LPG boil-off gas in contrast to the present invention which uses a combination of latent and sensible heat of LNG in combination with an LNG fuel gas system to condense LPG boil-off gas.
US5860294描述了用于冷凝来自惰性气体和气态烃的混合物的气态烃(特别是如在LPG/LEG船(LEG=液化乙烯气)的储存罐中发现的)的方法。US5860294 describes a method for condensing gaseous hydrocarbons from a mixture of inert gases and gaseous hydrocarbons, in particular as found in storage tanks of LPG/LEG ships (LEG=Liquefied Ethylene Gas).
US5860294首先描述了与本发明中的再液化单元100相同的再液化系统,但是其具有下游第二冷凝器系统,目的是回收在正常货物冷凝器中不冷凝的气体混合物中的气态烃。US5860294 first describes a reliquefaction system identical to the reliquefaction unit 100 of the present invention, but with a downstream second condenser system for the purpose of recovering gaseous hydrocarbons in the gaseous mixture which would not condense in the normal cargo condenser.
为了使US5860294中的第二冷凝器发挥作用,主货物冷凝器必须正在运行并且在该交换器中必须发生部分冷凝。In order for the second condenser in US5860294 to function, the main cargo condenser must be running and partial condensation must occur in this exchanger.
在本发明中,第二冷凝器(22)位于货物再液化系统的上游,其不依赖于主货物冷凝器的运行。In the present invention, the second condenser (22) is located upstream of the cargo reliquefaction system, independent of the operation of the main cargo condenser.
KR20010077227描述了用于再液化LNG蒸发气体的方法,在其中所述LNG蒸发气体凭借运送至汽化器的部分LNG流被液化后输出到例如国家天然气分布网络。用LNG输出管线使蒸气气体冷凝物混合。没有冷凝物返回到储存罐中。KR20010077227 describes a method for reliquefaction of LNG boil-off gas, in which the LNG boil-off gas is liquefied by means of a part of the LNG stream sent to a vaporizer for export to eg the national natural gas distribution network. The vapor gas condensate is mixed with the LNG export line. No condensate was returned to the storage tank.
液态LNG在这里用于在使组合的LNG和冷凝物流汽化之前通过蒸发气体到LNG中的热交换/吸收来控制LNG储存罐的压力。Liquid LNG is used here to control the pressure of the LNG storage tank by heat exchange/absorption of the boil-off gas into the LNG prior to vaporizing the combined LNG and condensate stream.
EP1990272原理上与KR20010077227类似,但是冷凝物返回到储存罐中,汽化产物被传送至气体发动机作为燃料。EP1990272 is similar in principle to KR20010077227, but the condensate is returned to the storage tank and the vaporized product is sent to the gas engine as fuel.
US3306660描述了用于储存多组分低温流体的方法和系统,在其中捕获了自然蒸发掉的较大挥发性的组分,使其冷凝并再引回到储存罐中。泵送出的低温液体用于冷凝蒸发气体。US3306660 describes a method and system for storing multi-component cryogenic fluids in which the more volatile components that evaporate naturally are captured, condensed and reintroduced into storage tanks. The pumped cryogenic liquid is used to condense the evaporated gas.
WO2011062505描述了回收来自LNG储存罐的蒸发气体的工艺,在其中LNG运送至在其中吸收LNG蒸发气体的再冷凝罐。WO2011062505 describes a process for recovering boil-off gas from an LNG storage tank in which the LNG is sent to a recondensation tank where the LNG boil-off gas is absorbed.
US2795937描述了用于储存和运输液化气体的工艺和设备,在其中一个罐容纳液化天然气(LNG),一个罐容纳较高沸点的液体。LNG用作船上的燃料,其在进入燃烧发动机之前通过在较高沸点液体的罐液体中热交换而被汽化并加热。US2795937教导了该热交换防止了来自液体表面的任何蒸发气体,因此没有描述蒸发再液化系统。US2795937 describes a process and apparatus for storing and transporting liquefied gases, in which one tank contains liquefied natural gas (LNG) and one tank contains a higher boiling point liquid. LNG is used as fuel on board ships, where it is vaporized and heated by heat exchange in tank liquids of higher boiling point liquids before entering the combustion engines. US2795937 teaches that this heat exchange prevents any evaporative gas from the surface of the liquid, so no evaporative reliquefaction system is described.
US3864918描述了在其中捕获来自LNG货物罐的蒸发气体并且将其分成两个组分流的方法。第一流被压缩、冷却并液化。第二流用作驱动船的燃料。US3864918 describes a method in which boil-off gas from an LNG cargo tank is captured and split into two component streams. The first stream is compressed, cooled and liquefied. The second stream is used as fuel to drive the boat.
US2006/0053806描述了用于在船用LNG运输船上供应蒸发气体作为燃料并压力控制货物罐的系统。US2006/0053806 describes a system for supplying boil-off gas as fuel and pressure controlling cargo tanks on a marine LNG carrier.
发明内容Contents of the invention
现有的运输LPG(液化石油气)的船主要使用低速柴油发动机用于主推进并且使用多种类型的船用燃料油来为发动机供给燃料。然而,新的环境限制(现称为排放控制区)限制了硫、氮氧化物和颗粒物到环境的释放。在将来,还期望严格的全球排放限制。本行业已提出了满足新需求的几种选择,例如废气净化。另一种选择是使用清洁的贫(lean)燃烧燃料,如甲烷。对于为船舶工业特征的大的燃料消耗和高的航行范围需求,甲烷必须以其最有效的方式(即称为LNG(液化天然气)的液体状态)储存。Existing ships transporting LPG (Liquefied Petroleum Gas) mainly use low-speed diesel engines for main propulsion and various types of marine fuel oils to fuel the engines. However, new environmental restrictions (now called Emission Control Areas) limit the release of sulfur, nitrogen oxides and particulate matter to the environment. In the future, strict global emission limits are also expected. The industry has proposed several options to meet new needs, such as exhaust gas cleaning. Another option is to use clean, lean burning fuels such as methane. For the large fuel consumption and high range requirements that characterize the marine industry, methane must be stored in its most efficient form, namely in the liquid state known as LNG (Liquefied Natural Gas).
LNG燃料系统在本领域一般是公知的,标题为“ALNGfueltanksystemforatleastonegasengineusedforshippropulsion”的挪威专利申请第20093272号中公开了一种示例性系统。LNG fuel systems are generally known in the art, an exemplary system is disclosed in Norwegian Patent Application No. 20093272 entitled "ALNG fuel tank system for at least one gas engine used for ship propulsion".
LPG载运船通常具有多至四个货物罐,其中所述货物罐在运载一种类型的货物时共有共同的蒸气气氛。构造LPG载运船使得它们可以同时运载两种不同的货物。这意味着甲板上的管道系统是成对的,以能够完成两个货物系统的隔离。LPG载运船可例如在三个罐中装载有丙烷并且在第四货物罐中装载有丁烷。装载有丙烷的三个罐具有相通的蒸气空间,但是与丁烷蒸气空间完全隔绝。每一个甲板管道系统与多个再液化单元连接,确保了货物罐压力不超过最大容许压力。再液化单元将蒸发气体压缩至足够压力,以使得气体可凭借海水冷凝。冷凝物返回到货物罐。在这种方式中,使货物罐压力维持较低。对于在最大环境温度条件下满载并且航行的VLGC(巨型气体载运船,载货能力通常为约82.000m3),液化蒸发气体的燃料油消耗(至发生器)为约1900kg/天。现在还没有避免这种燃料油消耗的解决方案。此外,由于LNG比船用柴油的密度小约50%的事实,所以LNG将需要两倍的储存体积以维持相同量的能量。重要的是,增加的燃料储存体积以船载货能力为代价。另一个问题涉及在例如北海盆地中运输LPG,在这里航行时间短,从而停泊时间是总往返行程持续时间重要贡献者,因此减少停泊时间是非常重要的。LPG carriers typically have up to four cargo tanks that share a common vapor atmosphere when carrying one type of cargo. LPG carriers are constructed such that they can carry two different cargoes at the same time. This means that the piping systems on deck are paired to be able to complete the isolation of the two cargo systems. The LPG carrier may, for example, be loaded with propane in three tanks and butane in a fourth cargo tank. The three propane tanks have a communicating vapor space but are completely isolated from the butane vapor space. Each deck piping system is connected to multiple reliquefaction units, ensuring that the cargo tank pressure does not exceed the maximum allowable pressure. The reliquefaction unit compresses the boil-off gas to sufficient pressure so that the gas can condense against seawater. The condensate is returned to the cargo tank. In this way, the cargo tank pressure is maintained low. For a VLGC (Very Large Gas Carrier, cargo capacity typically about 82.000 m 3 ) fully loaded and sailing at maximum ambient temperature conditions, the fuel oil consumption (to the generator) of the liquefied boil-off gas is about 1900 kg/day. There is currently no solution to avoid this fuel oil consumption. Furthermore, due to the fact that LNG is approximately 50% less dense than marine diesel, LNG will require twice the storage volume to maintain the same amount of energy. Importantly, the increased fuel storage volume comes at the expense of the ship's cargo capacity. Another issue concerns the transport of LPG in eg the North Sea basin, where sailing times are short and thus berthing time is a significant contributor to the total round trip duration, so reducing berthing times is very important.
另一个运营成本问题是制冷压缩机的服务和维修,其因为任何旋转设备都具有基于运行时间的服务间隔。新建造的船通常具有五年的进坞间隔,同时,制冷压缩机具有约20000小时的服务间隔。因此,认为在航行时需要服务。因此,有利的是减少总运行时间,从而延长服务之间的时间以及优选具有与进坞间隔匹配的服务间隔。Another operating cost issue is service and repair of refrigeration compressors, since any rotating equipment has service intervals based on operating hours. Newly built ships typically have a docking interval of five years, while refrigeration compressors have a service interval of approximately 20,000 hours. Therefore, it is considered that service is required while sailing. Therefore, it would be advantageous to reduce the overall operating time, thereby extending the time between services and preferably having service intervals that match docking intervals.
因此,本发明的一个目的是提供用于利用用于燃料的LNG以液化LPG蒸发气体(BOG)的系统和方法,其设法解决以上问题中的至少一个。It is therefore an object of the present invention to provide a system and method for utilizing LNG for fuel to liquefy LPG boil-off gas (BOG) which manages to solve at least one of the above problems.
为了应付以上问题,本发明公开了用于液化LPG蒸发气体(BOG)的系统,所述系统包括LNG燃料供应系统和LPG货物系统,其中所述LNG燃料系统包括至少一个LNG燃料罐23、LNG燃料管线5和第二LNG燃料管线13;其中所述LPG货物系统包括至少一个LPG货物罐20、BOG管线1、至少一个再液化单元100和冷凝管线3;其中所述系统还包括:提供于LNG燃料罐23与第二LNG燃料管线13之间的LNG燃料管线5上的至少一个汽化器15、22,其中至少一个汽化器15、22与LPG货物系统进行热交换。In order to cope with the above problems, the present invention discloses a system for liquefying LPG boil-off gas (BOG), which includes an LNG fuel supply system and an LPG cargo system, wherein the LNG fuel system includes at least one LNG fuel tank 23, an LNG fuel Pipeline 5 and second LNG fuel pipeline 13; wherein said LPG cargo system includes at least one LPG cargo tank 20, BOG pipeline 1, at least one reliquefaction unit 100 and condensate pipeline 3; wherein said system also includes: At least one vaporizer 15, 22 on the LNG fuel line 5 between the tank 23 and the second LNG fuel line 13, wherein the at least one vaporizer 15, 22 is in heat exchange with the LPG cargo system.
本发明还公开了在包括LNG燃料供应系统和LPG货物系统的系统中液化LPG蒸发气体(BOG)的方法,其中所述LNG燃料系统包括至少一个LNG燃料罐23、第一LNG燃料管线5和第二LNG燃料管线13,其中所述LPG货物系统包括至少一个LPG货物罐20、BOG管线1、至少一个再液化单元100和冷凝管线3;其中所述方法包括:提供定位在LNG燃料罐与第二LNG燃料管线13之间的第一LNG燃料管线上的至少一个汽化器22、15;通过使流自LNG燃料罐的LNG汽化冷凝BOG;以及将冷凝的BOG以规定路线运送至LPG货物罐。通常,汽化器22、15的数目对应于可同时运输的货物的数目。这通常是两个。The present invention also discloses a method for liquefying LPG boil-off gas (BOG) in a system comprising an LNG fuel supply system and an LPG cargo system, wherein the LNG fuel system comprises at least one LNG fuel tank 23, a first LNG fuel pipeline 5 and a second Two LNG fuel pipelines 13, wherein the LPG cargo system includes at least one LPG cargo tank 20, a BOG pipeline 1, at least one reliquefaction unit 100 and a condensation pipeline 3; At least one vaporizer 22, 15 on the first LNG fuel line between the LNG fuel lines 13; condense the BOG by vaporizing the LNG flowing from the LNG fuel tank; and route the condensed BOG to the LPG cargo tank. In general, the number of carburetors 22, 15 corresponds to the number of goods that can be transported simultaneously. This is usually two.
附图说明Description of drawings
参照附图,通过从属专利权利要求和下文中的详细描述应理解本发明另一些有利的实施方案,其中:Further advantageous embodiments of the invention are understood from the dependent patent claims and the following detailed description with reference to the accompanying drawings, in which:
图1是当前技术的再液化单元的概述图;Figure 1 is an overview diagram of a reliquefaction unit of the current technology;
图2是根据本发明的系统的一个实施方案的概述图;Figure 2 is an overview diagram of one embodiment of the system according to the present invention;
图3是根据本发明的系统的另一个实施方案的概述图;Figure 3 is an overview diagram of another embodiment of the system according to the present invention;
具体实施方式detailed description
LPG应理解为作为液体货物储存和运输的石油气的一系列不同品种或产品。在多种石油气中,丙烷和丁烷是主要的实例;丙烷通常包括0体积%至5体积%的任意浓度的乙烷;丙烷中的丁烷含量为0体积%至20体积%的任意浓度。主要由丙烷(通常为70体积%至98体积%)组成的该混合物称为商用丙烷,并且下文中称为丙烷。LPG is to be understood as a range of different varieties or products of petroleum gas stored and transported as a liquid cargo. Of the various petroleum gases, propane and butane are prime examples; propane typically includes ethane in any concentration from 0% to 5% by volume; butane in propane can be present in any concentration from 0% to 20% by volume . This mixture consisting mainly of propane (typically 70% to 98% by volume) is called commercial propane, and is hereinafter referred to as propane.
丁烷可以是正丁烷和异丁烷与不饱和烃的可能级分的任意混合物,并且在下文中称为丁烷。Butane can be any mixture of n-butane and isobutane with possible fractions of unsaturated hydrocarbons and is referred to hereinafter as butane.
除了丙烷和丁烷外,LPG应最少包括以下品种:In addition to propane and butane, LPG shall at least include the following varieties:
氨、ammonia,
丁二烯、Butadiene,
丁烷-丙烷混合物(任意混合物)、butane-propane mixture (any mixture),
丁烯、Butene,
乙醚、ether,
丙烯、Propylene,
氯乙烯。vinyl chloride.
在低于环境的温度下储存和运输的LPG自然地持续释放一定量的蒸气。在货物罐中维持压力的正常方法是提取该蒸气,液化并将其以冷凝物返回到货物罐。再液化单元在下文中应理解为液化所述蒸气的制冷单元,前缀“再”指明液化来自液化气体的蒸气。LPG stored and transported at sub-ambient temperatures naturally and continuously releases a certain amount of vapor. The normal method of maintaining pressure in a cargo tank is to extract this vapor, liquefy it and return it to the cargo tank as condensate. A reliquefaction unit is understood hereinafter to be a refrigeration unit which liquefies said vapors, the prefix "re" designating the liquefaction of vapors from liquefied gases.
LPG在大于大气压的压力下或在低于环境的温度下或其组合以液体形式运输。本发明涉及在低于环境的温度下运输液化货物LPG的LPG载运船,称为全制冷式LPG载运船;在大于大气压的压力和低于环境的温度下运输液化货物LPG的LPG载运船。后者称为半制冷式/半加压式。LPG is transported in liquid form at a pressure greater than atmospheric pressure or at a temperature below ambient or a combination thereof. The present invention relates to an LPG carrier ship that transports liquefied cargo LPG at a temperature lower than the environment, called a fully refrigerated LPG carrier ship; an LPG carrier ship that transports liquefied cargo LPG at a pressure greater than atmospheric pressure and a temperature lower than the environment. The latter is called semi-refrigerated/semi-pressurized.
货物类型是上述LPG品种或产品中的任意一种。The cargo type is any one of the above-mentioned LPG varieties or products.
冷凝物应理解为液化蒸发气体,其中蒸发气体是由于恒定的热漏失至货物罐中而从货物中排放出的蒸气。Condensate is to be understood as liquefied boil-off gas, where boil-off gas is the vapor emitted from the cargo due to constant heat loss into the cargo tanks.
温热的货物是在当前货物罐压力下在高于LPG饱和温度的温度下装载的LPG。Warm cargo is LPG loaded at a temperature above the LPG saturation temperature at the current cargo tank pressure.
图1示出了与至少一个货物罐20连接的典型当前技术再液化单元100以供参考。未示出货物装载管线。来自货物罐20的蒸发气体经由蒸发气体管线1流至货物压缩机40,该货物压缩机通常是多级压缩机的第一级,在其中将蒸气压缩至中等压力。未通过图1所示的再液化单元处理的任意量的蒸气经由蒸发气体管线51流至并联的操作单元,未示出。Figure 1 shows a typical current art reliquefaction unit 100 connected to at least one cargo tank 20 for reference. Cargo loading lines are not shown. Boil-off gas from cargo tank 20 flows via boil-off gas line 1 to cargo compressor 40, which is typically the first stage of a multi-stage compressor, where the vapor is compressed to an intermediate pressure. Any amount of vapor not processed by the reliquefaction unit shown in Figure 1 flows via boil-off gas line 51 to a parallel operating unit, not shown.
从货物压缩机40经由管线46出来的蒸发气体进入在其中使蒸发气体接近于其饱和温度的经济器(economizer)43中。然后蒸发气体经由管线47从经济器43流至货物压缩机41,其中蒸发气体被压缩至对应于货物冷凝器42中可得到温度的始沸点压力。货物压缩机41通常是多级压缩机的第二级。偶尔需要多于两个的压缩级,并且它们通常与41串联。Boil-off gas from cargo compressor 40 via line 46 enters an economizer 43 where the boil-off gas is brought close to its saturation temperature. The boil-off gas then flows from the economizer 43 to the cargo compressor 41 via line 47 , where the boil-off gas is compressed to a bubble pressure corresponding to the temperature available in the cargo condenser 42 . The cargo compressor 41 is typically the second stage of a multi-stage compressor. Occasionally more than two compression stages are required, and they are usually in series with 41.
然后经压缩的蒸发气体经由管线48进入货物冷凝器42以凭借海水或通常高于海水温度的任何冷却介质冷凝。海水是迄今为止对于货物冷凝器42最常用的吸热器(heatsink),但是水和冷源的混合物也是可以的。冷源可以是任意合适的二醇。The compressed boil-off gas then enters cargo condenser 42 via line 48 to be condensed against seawater or any cooling medium that is generally at a temperature above seawater. Seawater is by far the most common heat sink for the cargo condenser 42, but a mixture of water and heat sink is also possible. The heat sink can be any suitable diol.
温热的冷凝物(得到的来自货物冷凝器42的冷凝蒸发气体)离开货物冷凝器42,经由管线49流至经济器43。管线50由管线49分支,其中小部分流经液位控制阀44,为温热冷凝物的主要部分提供需要的级间冷却和过冷。通常,液体接收器安装在管线49上,未示出。待返回到一个或更多个货物罐20的剩余温热冷凝物由50分支的地方流经经济器43内侧的盘管52并且以过冷状态离开盘管52。现在过冷的冷凝物经由管线3流回到货物罐。冷凝物生产阀45调节返回到一个或更多个货物罐20的冷凝物流的量。来自其他并联运转的再液化单元的冷凝物连接到管线3中,未示出。Warm condensate (the resultant condensed boil-off gas from cargo condenser 42 ) leaves cargo condenser 42 and flows via line 49 to economizer 43 . Line 50 branches off from line 49, a small portion of which passes through level control valve 44 to provide the required interstage cooling and subcooling for the main portion of the warm condensate. Typically, a liquid receiver is mounted on line 49, not shown. Where the remaining warm condensate to be returned to one or more cargo tanks 20 branches off from 50 , it flows through coil 52 inside economizer 43 and exits coil 52 in a subcooled state. The now subcooled condensate flows back to the cargo tank via line 3 . Condensate production valve 45 regulates the amount of condensate flow returned to one or more cargo tanks 20 . Condensate from other reliquefaction units operating in parallel is connected in line 3, not shown.
图2阐明了两个迄今为止不同的、分开的系统LNG燃料气体供应系统(点线之上)和LPG货物系统。LNG燃料气体供应系统配置有一个或更多个连接的LNG燃料罐23。燃料气体供应系统还配置有控制压力增大热交换器24中待汽化的LNG的量的阀27,以确保燃料罐23中或多或少的恒定蒸气压,从而确保燃料管线5中足够的燃料气体供应压力。根据公知的原理,使LNG供应至汽化器25,其中使LNG汽化并且所得蒸气流至过热器26,在其中蒸气被加热至优选的燃料气体温度,然后经由管线13转移至主发动机。图2还示出蒸气管线8和阀28,如果需要燃料罐23中的压力降低,则其允许将蒸发的LNG运送至过热器26。然而,在大多数情况下,蒸气管线8中没有气流。Figure 2 illustrates two hitherto distinct, separate systems LNG fuel gas supply system (above dotted line) and LPG cargo system. The LNG fuel gas supply system is configured with one or more connected LNG fuel tanks 23 . The fuel gas supply system is also equipped with a valve 27 that controls the amount of LNG to be vaporized in the pressure booster heat exchanger 24 to ensure a more or less constant vapor pressure in the fuel tank 23, thereby ensuring sufficient fuel in the fuel line 5 Gas supply pressure. According to known principles, LNG is supplied to vaporizer 25 where it is vaporized and the resulting vapor flows to superheater 26 where it is heated to the preferred fuel gas temperature before being transferred via line 13 to the main engine. Figure 2 also shows a vapor line 8 and a valve 28 which allows vaporized LNG to be delivered to the superheater 26 if a pressure drop in the fuel tank 23 is required. However, in most cases there is no gas flow in vapor line 8 .
发动机燃料气体注射压力取决于其是奥托(Otto)发动机还是柴油发动机,奥托发动机仅需要4巴的中等气体注射压力,而柴油发动机需要300至350巴的燃料气体注射压力。除了高压替代方案需要用于压力提升的专用泵之外,压力的这种显著差异对本发明具有有限的影响。未示出另外的泵系统,因为其对于本领域技术人员一般是已知的。Engine fuel gas injection pressure depends on whether it is an Otto engine or a diesel engine, an Otto engine requires only a medium gas injection pressure of 4 bar, while a diesel engine requires a fuel gas injection pressure of 300 to 350 bar. This significant difference in pressure has limited impact on the present invention, except that the high pressure alternative requires a dedicated pump for the pressure boost. Additional pump systems are not shown as they are generally known to those skilled in the art.
对于需要较高燃料气体压力的柴油发动机,如上所述,需要另外的与燃料管线5连接的LNG燃料泵以在进入汽化器25之前将LNG压力提升至所需的压力。在该实施方案中,蒸气管线8传送至安全位置或者替代地传送至使用用户,在大多数情况下蒸气管线8中没有气流。For diesel engines that require higher fuel gas pressure, as described above, an additional LNG fuel pump connected to the fuel line 5 is required to boost the LNG pressure to the required pressure before entering the carburetor 25 . In this embodiment, the vapor line 8 is delivered to a safe location or alternatively to the user, in most cases there is no gas flow in the vapor line 8 .
如以上参照图1所公开的,图2的LPG货物系统配置有再液化单元100和至少一个LPG货物罐20、使蒸发气体流至再液化单元100的BOG管线1以及使冷凝物经由阀45返回到货物罐20的冷凝管线3。As disclosed above with reference to FIG. 1 , the LPG cargo system of FIG. 2 is configured with a reliquefaction unit 100 and at least one LPG cargo tank 20 , a BOG line 1 for flowing boil-off gas to the reliquefaction unit 100 and returning condensate via valve 45 Condensate line 3 to cargo tank 20 .
考虑到正常航行,运载丙烷的最大环境温度条件下的典型VLGC(巨型气体载运船)到货物罐系统中的热漏失为约425kW。所得的LPG蒸发速率平均为约3300至3800kg/小时。此外,VLGC上典型安装的推进电源为14MW,最大连续额定下的典型能量消耗为7500kJ/kWh,在该条件下需要的LNG量为约2120kg/小时。因此,对于所有的实践方面,LNG的制冷潜力消除了对负载航行期间运行再液化单元的需要,特别地对于低于最大设计的环境温度和/或最大持续额定下的速度的需要。事实上,在这些条件下,可完全排除再液化操作。The heat loss of a typical VLGC (Very Large Gas Carrier) into the cargo tank system at maximum ambient temperature conditions carrying propane is about 425 kW, considering normal voyages. The resulting LPG evaporation rate averaged about 3300 to 3800 kg/hour. Furthermore, a typical installed propulsion power source on a VLGC is 14MW, the typical energy consumption at maximum continuous rating is 7500kJ/kWh, and the amount of LNG required under these conditions is about 2120kg/hour. Thus, for all practical purposes, the refrigeration potential of LNG eliminates the need to operate the reliquefaction unit during load voyages, particularly for speeds below maximum design ambient temperature and/or maximum sustained rating. In fact, under these conditions, reliquefaction operations can be completely eliminated.
因此,根据本发明的用于利用用于燃料的LNG以液化LPG蒸发气体的系统,包括提供于LNG燃料罐23与第二LNG燃料管线13之间的LNG燃料管线5上的至少一个汽化器15、22,其中所述至少一个汽化器15、22与LPG货物系统进行热交换,有效地将LNG燃料系统整合到LPG蒸发气体系统中。Therefore, the system for utilizing LNG for fuel to liquefy LPG boil-off gas according to the present invention includes at least one vaporizer 15 provided on the LNG fuel line 5 between the LNG fuel tank 23 and the second LNG fuel line 13, 22, wherein said at least one vaporizer 15, 22 is in heat exchange with the LPG cargo system, effectively integrating the LNG fuel system into the LPG boil-off gas system.
安装在直接供给至汽化器22的蒸发气体线上的专用鼓风机是明显的选择,但是在已安装有货物压缩机时以另外的设备为代价。因此,该解决方案可能不是优选的,所以未示出。或者,蒸气至汽化器22的自由流动也是可以的,然而,对于该组合应考虑回送泵(returnpump)。A dedicated blower installed on the boil-off gas line directly fed to the carburetor 22 is an obvious option, but at the expense of additional equipment when a cargo compressor is already installed. Therefore, this solution may not be preferred and is therefore not shown. Alternatively, a free flow of vapor to the vaporizer 22 is also possible, however, a return pump should be considered for this combination.
根据本发明的第一实施方案,至少一个汽化器22是BOG冷凝器,其适合于通过使通过压力经由管线5自燃料罐23流出的LNG汽化来冷凝BOG。冷凝物经由管线2传送回货物罐20。反过来看,LNG凭借蒸发气体被汽化,根据蒸发和燃料消耗的量,LNG可被部分汽化、完全汽化或完全汽化并过热。所得产物离开22,进入使任何剩余的LNG汽化的汽化器25。来自汽化器25的蒸气流到蒸气被加热至优选的燃料气体温度的过热器26。在LNG蒸发和燃料消耗的量使得离开至少一个汽化器22的蒸气过热的情况下,可省略汽化器25和过热器二者。在LNG蒸发和燃料消耗的量使得离开至少一个汽化器22的蒸气被完全汽化的情况下,可省略汽化器25。According to a first embodiment of the invention, at least one vaporizer 22 is a BOG condenser suitable for condensing BOG by vaporizing LNG flowing out of fuel tank 23 via line 5 by pressure. The condensate is sent back to cargo tank 20 via line 2 . Conversely, LNG is vaporized by means of boil-off gas, and depending on the amount of vaporization and fuel consumption, LNG can be partially vaporized, completely vaporized, or completely vaporized and superheated. The resulting product exits 22 and enters vaporizer 25 where any remaining LNG is vaporized. Vapor from vaporizer 25 flows to superheater 26 where the vapor is heated to the preferred fuel gas temperature. Where the amount of LNG vaporization and fuel consumption is such that the vapor leaving at least one vaporizer 22 is superheated, both the vaporizer 25 and the superheater may be omitted. The vaporizer 25 may be omitted where the amount of LNG vaporization and fuel consumption is such that the vapor leaving at least one vaporizer 22 is completely vaporized.
在上述实施方案中,自燃料罐23流出的所有LNG通过汽化器22。然而,在一些情况(例如,没有足够气体蒸发或没有蒸发气体)下,控制通过汽化器的LNG的流可能是有利的。根据本发明的一个实施方案,分别在汽化器22前面和与其并联地设置两个阀29、30,使得当在BOG管线1中没有BOG时,阀29打开并且阀30关闭,反之亦然。阀29、30将流至汽化器22、15的LNG的量调节为BOG管线1中存在的可用BOG和当前LNG消耗的量。该实施方案确保了离开汽化器22、15的所得产物被完全汽化,使蒸气转移至蒸气被加热至优选的燃料气体温度的过热器26。通过已知原理进行调节,未示出。使汽化器22、15中不需要的任何过量的LNG直接转移至汽化器25,在这里过量的LNG被汽化后转移至过热器26。阀29、30可同样很好地用三路通替代,未示出。因此,阀布置29、30代表提供相同功能性的任何替代阀布置。In the above embodiment, all of the LNG flowing from the fuel tank 23 passes through the vaporizer 22 . However, in some situations (eg, not enough gas is vaporized or there is no boil-off gas), it may be advantageous to control the flow of LNG through the vaporizer. According to one embodiment of the invention, two valves 29, 30 are arranged respectively before and parallel to the vaporizer 22, so that when there is no BOG in the BOG line 1, the valve 29 is open and the valve 30 is closed and vice versa. The valves 29 , 30 regulate the amount of LNG flowing to the vaporizers 22 , 15 to the available BOG present in the BOG line 1 and the current LNG consumption. This embodiment ensures that the resulting product leaving the vaporizer 22, 15 is completely vaporized, allowing the vapor to be transferred to the superheater 26 where the vapor is heated to the preferred fuel gas temperature. Adjustment is performed by known principles, not shown. Any excess LNG not required in vaporizers 22, 15 is diverted directly to vaporizer 25 where it is vaporized and then transferred to superheater 26. The valves 29, 30 could equally well be replaced by three-way connections, not shown. Accordingly, the valve arrangements 29, 30 represent any alternative valve arrangements providing the same functionality.
在再液化100单元中的货物压缩机40、41周围布置管道系统使得其以单级压缩方式运行。以单级压缩方式布置货物压缩机40、41对于本领域技术人员是显而易见的并且所提议的是几种可能的解决方案之一。在单级压缩方式中,容量较高并且通常仅需要运行一个压缩机,因此使得总压缩机运行时间总体减少。然后,来自LPG货物罐20的蒸发气体在管线1中直接流至货物压缩机40、41,在所述货物压缩机中使蒸发气体的压力适度提升。在管线48或49上的方便位置处,蒸发气体经由管线61分支并流至汽化器22,在所述汽化器中使蒸发气体冷凝并经由管线2返回到货物罐20。阀71和72调节应进行蒸发气体分支的位置。Piping is arranged around the cargo compressors 40, 41 in the reliquefaction 100 unit so that they operate in single stage compression. Arranging the cargo compressors 40, 41 in a single-stage compression would be obvious to a person skilled in the art and what is proposed is one of several possible solutions. In single stage compression, the capacity is higher and generally only one compressor needs to be run, thus resulting in an overall reduction in total compressor run time. The boil-off gas from the LPG cargo tank 20 then flows in line 1 directly to the cargo compressors 40, 41 where the pressure of the boil-off gas is raised moderately. At a convenient location on line 48 or 49 , the boil-off gas branches off via line 61 and flows to vaporizer 22 where it is condensed and returned to cargo tank 20 via line 2 . Valves 71 and 72 regulate the position at which evaporative gas branching should take place.
在本发明的又一个实施方案中,至少一个汽化器15是冷凝物过冷器(subcooler),其提供于再液化单元100与货物罐20之间的冷凝管线3上,冷凝物过冷器15适合于通过使来自燃料罐23的LNG汽化来使LPG冷凝物过冷。参照BOG冷凝器22,如上述的实施方案中可单独使用冷凝物过冷器。In yet another embodiment of the invention, at least one evaporator 15 is a condensate subcooler provided on the condensate line 3 between the reliquefaction unit 100 and the cargo tank 20, the condensate subcooler 15 being suitable for To subcool the LPG condensate by vaporizing the LNG from the fuel tank 23 . Referring to the BOG condenser 22, a condensate subcooler alone may be used as in the embodiments described above.
在本发明的一个优选实施方案中,如以下更详细公开的,提供汽化器15和汽化器22二者,增加了操作灵活性以及当可用时对LNG中过量的制冷剂容量的利用。在该实施方案中,提供阀16和17以能够绕开或通过汽化器15。In a preferred embodiment of the present invention, as disclosed in more detail below, both vaporizer 15 and vaporizer 22 are provided, increasing operational flexibility and utilization of excess refrigerant capacity in LNG when available. In this embodiment, valves 16 and 17 are provided to be able to bypass or pass vaporizer 15 .
根据本发明的一个示例性实施方案,从LPG货物罐20中排出的蒸发气体在管线1中直接流至货物压缩机40、41,在所述货物压缩机中使蒸发气体的压力适度提升。在再液化100单元中的货物压缩机40、41周围布置管道系统使得其以单级压缩方式运行。来自货物压缩机40、41的经适度压缩的蒸发气体经由管线2流至汽化器22,在所述汽化器中使蒸发气体冷凝并返回到货物罐20。According to an exemplary embodiment of the present invention, the boil-off gas discharged from the LPG cargo tank 20 flows in line 1 directly to the cargo compressors 40, 41 where the pressure of the boil-off gas is raised moderately. Piping is arranged around the cargo compressors 40, 41 in the reliquefaction 100 unit so that they operate in single stage compression. Moderately compressed boil-off gas from cargo compressors 40 , 41 flows via line 2 to vaporizer 22 where it is condensed and returned to cargo tank 20 .
在汽化器22中,BOG通过使通过压力经由管线5流自燃料罐23的LNG汽化而被冷凝。经冷凝的BOG经由管线2传送回到货物罐20。反过来看,LNG凭借蒸发气体被汽化,根据存在的蒸发和通用燃料消耗的量,LNG可被部分汽化、完全汽化或完全汽化并过热。所得产物离开汽化器22并进入汽化器25,在所述汽化器中使任何剩余的LNG汽化。来自汽化器25的蒸气经由管线12转移至过热器(superheater)26,在所述过热器中使蒸气加热至优选的燃料气体温度。在LNG蒸发和燃料消耗的量使得离开至少一个汽化器22的蒸气过热的情况下,可省略汽化器25和过热器二者。在LNG蒸发气体和燃料消耗的量使得离开至少一个汽化器22的蒸气被完全汽化的情况下,可省略汽化器25。In the vaporizer 22 BOG is condensed by vaporizing the LNG flowing from the fuel tank 23 through the line 5 under pressure. The condensed BOG is sent back to cargo tank 20 via line 2 . Conversely, LNG is vaporized by means of boil-off gas, which can be partially vaporized, fully vaporized, or fully vaporized and superheated, depending on the amount of vaporization present and general fuel consumption. The resulting product exits vaporizer 22 and enters vaporizer 25 where any remaining LNG is vaporized. Vapor from vaporizer 25 is transferred via line 12 to superheater 26 where it is heated to the preferred fuel gas temperature. Where the amount of LNG vaporization and fuel consumption is such that the vapor leaving at least one vaporizer 22 is superheated, both the vaporizer 25 and the superheater may be omitted. Where the LNG boil-off gas and fuel consumption are such that the vapor leaving at least one vaporizer 22 is completely vaporized, the vaporizer 25 may be omitted.
在上述实施方案中,流自燃料罐23的所有LNG通过汽化器22。然而,在一些情况(例如,没有足够气体蒸发或没有蒸发气体)下,控制通过汽化器的LNG的流可能是有利的。根据本发明的一个实施方案,分别在汽化器22前面和与其并联地提供两个阀29、30,使得当在BOG管线1中没有BOG时阀29打开并且阀30关闭,反之亦然。两个阀29、30还将流至汽化器22、15的LNG的量调节为BOG管线1中存在的可用BOG和当前LNG消耗的量。流至汽化器22、15的LNG被完全汽化,蒸气转移至过热器26,在所述过热器中蒸气被加热至优选的燃料气体温度。使汽化器22、15中不需要的任何过量的LNG直接转移至汽化器25,在所述汽化器中过量的LNG被汽化后转移至过热器26。两个阀29、30可用提供相同功能性的任何三路通代替。In the above embodiment, all of the LNG flowing from the fuel tank 23 passes through the vaporizer 22 . However, in some situations (eg, not enough gas is vaporized or there is no boil-off gas), it may be advantageous to control the flow of LNG through the vaporizer. According to one embodiment of the invention, two valves 29, 30 are provided respectively before and in parallel with the vaporizer 22, so that the valve 29 is open and the valve 30 is closed when there is no BOG in the BOG line 1 and vice versa. Both valves 29 , 30 also regulate the amount of LNG flowing to the vaporizers 22 , 15 to the amount of available BOG present in the BOG line 1 and the current LNG consumption. The LNG flowing to the vaporizers 22, 15 is completely vaporized and the vapor is transferred to the superheater 26 where it is heated to the preferred fuel gas temperature. Any excess LNG not required in the vaporizers 22 , 15 is diverted directly to the vaporizer 25 where it is vaporized and then transferred to the superheater 26 . Both valves 29, 30 may be replaced by any three-way providing the same functionality.
以上所公开的示例性实施方案主要涉及在负载航行期间当LNG燃料消耗较高时系统的使用。然而,在装载期间,蒸发气体速率为其最大值,LNG燃料消耗为低端的,因此,可用于液化BOG的LNG的量有限。因此,必须将再液化单元100投入运行。The exemplary embodiments disclosed above are primarily concerned with the use of the system during loaded voyages when LNG fuel consumption is high. However, during loading, the boil-off gas rate is at its maximum and the LNG fuel consumption is on the low side, therefore, the amount of LNG available to liquefy BOG is limited. Therefore, the reliquefaction unit 100 must be put into operation.
在这些条件下,自然应考虑在作为液化单元预冷器的22中利用最佳装载期间可用的减少量的LNG。然而,由于例如在压缩机入口处(特别是当装载较温热货物时)的烟雾问题,所以这不是最佳的解决方案。Under these conditions, it is natural to consider utilizing the reduced amount of LNG available during optimal loading in the liquefaction unit precooler 22 . However, this is not an optimal solution due to smoke problems eg at the compressor inlet (especially when loading warmer cargo).
代替使蒸发气体预冷,使冷凝物过冷减少了货物罐20中的闪蒸气体生成,因此通过不必使闪蒸气体再循环回到货物压缩机增加了系统性能。Instead of precooling the boil-off gas, subcooling the condensate reduces flash gas generation in the cargo tank 20, thus increasing system performance by not having to recycle the flash gas back to the cargo compressor.
在装载期间,所有的蒸发气体经由管线1直接运送至,在所述再液化单元中使蒸发气体冷凝并经由管线3返回再液化单元。冷凝物过冷器15位于线3上,使用LNG作为冷却剂。使冷凝物的温度降低至优选不低于-50℃后使其返回到货物罐。冷凝物温度取决于货物的类型,对于较温热的货物类型其可以较高。During loading, all the boil-off gas is sent via line 1 directly to the reliquefaction unit where it is condensed and returned via line 3 to the reliquefaction unit. Condensate subcooler 15 is located on line 3 and uses LNG as coolant. The condensate is returned to the cargo tank after the temperature of the condensate is lowered to preferably not below -50°C. The condensate temperature depends on the type of cargo and can be higher for warmer cargo types.
如前所述,构造LPG运输船使得它们可同时运载两种不同的货物,所述两种货物可以是丙烷和丁烷。然后使汽化器22、15以串联顺序运行使得首先LNG在至少一个汽化器22中凭借丙烷汽化,然后汽化的LNG经由管线74流至运行丁烷的并联单元上的管线80。所得较温热的汽化LNG经由管线5返回到燃料气体系统。图3示出了这样的布置,基于其可使系统的一个罐装载有丁烷并且三个罐装载有丙烷。通常,安装四个再液化单元100,但是在航行期间通常两个是备用的,特别是当根据本发明使用LNG作为燃料时。如由图可看出的,汽化器22的并联运行也是可以的。图3未示出备用的再液化单元。As previously mentioned, LPG carriers are constructed such that they can simultaneously carry two different cargoes, which may be propane and butane. The vaporizers 22, 15 are then run in series order such that first the LNG is vaporized with propane in at least one vaporizer 22 and then the vaporized LNG flows via line 74 to line 80 on the parallel unit running butane. The resulting warmer boil-off LNG is returned via line 5 to the fuel gas system. Figure 3 shows an arrangement by which it is possible to have a system with one tank charged with butane and three tanks charged with propane. Typically, four reliquefaction units 100 are installed, but usually two are spared during a voyage, especially when using LNG as fuel according to the invention. As can be seen from the figure, parallel operation of the carburetors 22 is also possible. Figure 3 does not show the spare reliquefaction unit.
虽然附图和以上描述中已详细阐明和描述了本发明,但是这样的阐明和描述应认为是说明性或示例性的,而不是限制性的,并且不旨在将本发明限制为所公开的实施方案。互异从属权利要求中所引述的某些特征的仅有事实不表明这些特征的组合不能被有利地使用。权利要求中的附图标记不应解释为限制本发明。While the invention has been illustrated and described in detail in the drawings and foregoing description, such illustration and description are to be considered illustrative or exemplary and not restrictive, and are not intended to limit the invention to the disclosed implementation plan. The mere fact that certain features are recited in mutually different dependent claims does not indicate that a combination of these features cannot be used to advantage. Reference signs in the claims shall not be construed as limiting the invention.
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PCT/NO2012/000042 WO2012165967A1 (en) | 2011-05-30 | 2012-05-30 | Utilization of lng used for fuel to liquefy lpg boil off |
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