CN103527863A - Fiber guide pipe with far-infrared heating function - Google Patents
Fiber guide pipe with far-infrared heating function Download PDFInfo
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- CN103527863A CN103527863A CN201310033912.4A CN201310033912A CN103527863A CN 103527863 A CN103527863 A CN 103527863A CN 201310033912 A CN201310033912 A CN 201310033912A CN 103527863 A CN103527863 A CN 103527863A
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- 238000010438 heat treatment Methods 0.000 title claims abstract description 49
- 239000000835 fiber Substances 0.000 title claims abstract description 46
- 238000009413 insulation Methods 0.000 claims abstract description 14
- 239000000463 material Substances 0.000 claims abstract description 11
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 10
- 239000004917 carbon fiber Substances 0.000 claims abstract description 10
- 239000006260 foam Substances 0.000 claims abstract description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 230000000694 effects Effects 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- -1 polyphenylene Polymers 0.000 claims description 6
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 5
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 5
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 4
- 229920002530 polyetherether ketone Polymers 0.000 claims description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims description 4
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920001721 polyimide Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims 2
- 229920006380 polyphenylene oxide Polymers 0.000 claims 2
- 229920000265 Polyparaphenylene Polymers 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- 238000005282 brightening Methods 0.000 claims 1
- 238000005485 electric heating Methods 0.000 claims 1
- 229920002521 macromolecule Polymers 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 150000003568 thioethers Chemical class 0.000 claims 1
- 239000002131 composite material Substances 0.000 abstract description 10
- 238000004321 preservation Methods 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 abstract description 2
- 230000020169 heat generation Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 description 10
- 239000000047 product Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
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- 238000005516 engineering process Methods 0.000 description 3
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- 239000012767 functional filler Substances 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
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- 238000001764 infiltration Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L9/00—Rigid pipes
- F16L9/14—Compound tubes, i.e. made of materials not wholly covered by any one of the preceding groups
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L53/00—Heating of pipes or pipe systems; Cooling of pipes or pipe systems
- F16L53/30—Heating of pipes or pipe systems
- F16L53/35—Ohmic-resistance heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L57/00—Protection of pipes or objects of similar shape against external or internal damage or wear
- F16L57/06—Protection of pipes or objects of similar shape against external or internal damage or wear against wear
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/02—Shape or form of insulating materials, with or without coverings integral with the insulating materials
- F16L59/029—Shape or form of insulating materials, with or without coverings integral with the insulating materials layered
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/04—Arrangements using dry fillers, e.g. using slag wool
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L59/00—Thermal insulation in general
- F16L59/08—Means for preventing radiation, e.g. with metal foil
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Thermal Insulation (AREA)
- Pipe Accessories (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
Abstract
本发明提供的一种具有远红外加热功能的纤维导向管,管壁从外向内由1-蒙皮;2-保温层;3-反射层;4-加热层; 6-内衬层,共五层组成,其中4-加热层中包含5-碳纤维加热丝。保温层为一种100%闭孔聚甲基丙烯酰亚胺(PMI)硬质泡沫,热变形温度为180-240℃,比强度和比刚度高,起到隔热、保温、支撑纤维导向管的作用;加热层为含有纯黑体材料碳纤维加热丝的电热转换层;内衬层为具有自润滑作用的高分子层,主要起到减少输送纤维与导向管摩擦的作用。本发明远红外加热功能纤维导向管具有升温迅速、发热均匀、使用寿命长等特点,可在3分钟内升温至135℃,满足轻质高强复合材料在线成形连续喂料纤维快速加热需要。
A kind of fiber guiding pipe with far-infrared heating function provided by the present invention, the pipe wall is from outside to inside by 1-skin; 2-insulating layer; 3-reflecting layer; 4-heating layer; Layer composition, in which 4-heating layer contains 5-carbon fiber heating wire. The insulation layer is a 100% closed-cell polymethacrylimide (PMI) rigid foam, with a heat distortion temperature of 180-240°C, high specific strength and specific stiffness, and plays a role in heat insulation, heat preservation, and support for fiber guide pipes The heating layer is an electrothermal conversion layer containing carbon fiber heating wire made of pure black body material; the inner lining layer is a polymer layer with self-lubricating effect, which mainly plays the role of reducing the friction between the conveying fiber and the guide tube. The far-infrared heating functional fiber guide tube of the present invention has the characteristics of rapid temperature rise, uniform heat generation, and long service life. It can heat up to 135°C within 3 minutes, and meets the needs of rapid heating of light-weight and high-strength composite materials for online forming and continuous feeding of fibers.
Description
技术领域 technical field
本发明涉及一种具有远红外加热功能的纤维导向管,属于复合材料成形领域。The invention relates to a fiber guide tube with far-infrared heating function, which belongs to the field of composite material forming.
背景技术 Background technique
轻质高强复合材料直接在线成形技术是指将长纤维与树脂、功能性填料等在双螺杆设备中共混、浸渍、有效复合,然后经精确称量、保温输送、快速模压成形等工艺直接得到复合材料制品,该工艺具有生产效率高、自动化程度高、工艺调节灵活、产品强度高、可设计性强、成本低等优点。与传统的复合材料制造技术相比,轻质高强复合材料直接在线成形技术省却了中间工艺环节,可直接采购基础原材料一次加工成型,不需半成品加工过程,成形制件纤维长度可控、纤维分布均匀,可提供更加优异的强度、硬度、抗冲击性、抗疲劳性,能替代汽车、工程机械、舰船、建筑等领域中现有的钢铁结构部件。The direct online forming technology of lightweight high-strength composite materials refers to blending, impregnating, and effectively compounding long fibers, resins, and functional fillers in twin-screw equipment, and then directly compounding them through processes such as accurate weighing, heat preservation and transportation, and rapid molding. Material products, this process has the advantages of high production efficiency, high degree of automation, flexible process adjustment, high product strength, strong designability, and low cost. Compared with the traditional composite material manufacturing technology, the direct online forming technology of lightweight high-strength composite materials saves intermediate process links, and can directly purchase basic raw materials for one-time processing and molding without the need for semi-finished product processing. The fiber length and fiber distribution of the formed parts are controllable Uniform, can provide more excellent strength, hardness, impact resistance, fatigue resistance, and can replace existing steel structural components in the fields of automobiles, construction machinery, ships, and construction.
为保证轻质高强复合材料制品中纤维长度、纤维分布状态可控,在混料过程纤维连续喂料进入双螺杆设备前需进行加热处理,根据树脂基体的不同纤维加热温度范围为80~150℃。国外设备采用加热辊的方式进行对连续喂料纤维进行加热,存在散热快、能耗高等问题。目前国内对纤维连续喂料加热设备的研究比较少。In order to ensure controllable fiber length and fiber distribution in lightweight high-strength composite products, heating treatment is required before the fibers are continuously fed into the twin-screw equipment during the mixing process. The heating temperature range for fibers is 80~150°C according to the different resin matrix. . Foreign equipment uses heating rollers to heat the continuous feeding fiber, which has problems such as fast heat dissipation and high energy consumption. At present, there are relatively few domestic researches on fiber continuous feeding heating equipment.
发明内容 Contents of the invention
本发明针对轻质高强复合材料直接在线成形工艺对喂料纤维快速加热的要求,提供一种具有远红外加热功能的纤维导向管,由此可实现纤维连续输送的同时快速加热,从而满足轻质高强复合材料在线成形工艺要求,达到提高成形制件的机械、力学性能的目的。Aiming at the requirements of the direct online forming process of lightweight and high-strength composite materials on the rapid heating of feeding fibers, the present invention provides a fiber guide tube with far-infrared heating function, which can realize rapid heating while continuously conveying fibers, thereby meeting the requirements of light weight and high-strength composite materials. The on-line forming process of high-strength composite materials is required to achieve the purpose of improving the mechanical and mechanical properties of formed parts.
本发明提供的一种具有远红外加热功能的纤维导向管,管壁从外向内由1-蒙皮;2-保温层;3-反射层;4-加热层; 6-内衬层,共五层组成,其中4-加热层中包含5-碳纤维加热丝。A kind of fiber guiding pipe with far-infrared heating function provided by the present invention, the pipe wall is from outside to inside by 1-skin; 2-insulating layer; 3-reflecting layer; 4-heating layer; Layer composition, in which 4-heating layer contains 5-carbon fiber heating wire.
所述的保温层为一种100%闭孔聚甲基丙烯酰亚胺(PMI)硬质泡沫,热变形温度为180-240℃,比强度和比刚度高,起到隔热、保温、支撑纤维导向管的作用;The insulation layer is a 100% closed-cell polymethacrylimide (PMI) rigid foam with a heat distortion temperature of 180-240°C, high specific strength and specific stiffness, and plays a role in heat insulation, heat preservation and support The role of the fiber guide tube;
所述的加热层为含有纯黑体材料碳纤维加热丝的电热转换层,耐温性能≥280℃,电热转换效率≥95%;The heating layer is an electrothermal conversion layer containing carbon fiber heating wire made of pure black body material, with a temperature resistance of ≥ 280°C and an electrothermal conversion efficiency of ≥ 95%;
所述的内衬层为具有自润滑作用的高分子层,包括聚苯硫醚PPS,环氧树脂、聚酰亚胺PI、聚四氟乙烯PTFE、聚醚醚酮PEEK中一种或多种组成的薄膜状材料,主要起到减少输送纤维与导向管摩擦的作用;The inner lining layer is a polymer layer with self-lubricating effect, including one or more of polyphenylene sulfide PPS, epoxy resin, polyimide PI, polytetrafluoroethylene PTFE, polyetheretherketone PEEK The film-like material composed mainly plays the role of reducing the friction between the conveying fiber and the guide tube;
所述的蒙皮为由聚丙烯、聚氯乙烯、聚苯醚、聚苯乙烯中的一种或多种材料涂覆在保温层外部形成;The skin is formed by coating one or more materials of polypropylene, polyvinyl chloride, polyphenylene ether, and polystyrene on the outside of the insulation layer;
所述的反射层为铝或其氧化物形成的表面光亮薄膜状材料。The reflective layer is a film-like material with bright surface formed by aluminum or its oxide.
本发明采用闭孔聚甲基丙烯酰亚胺(PMI)硬质泡沫作为纤维导向管的保温层,在同等泡沫密度中,它具有最高的比强度和比刚度,可起到支撑纤维输送管的作用,保证纤维输送管不变形、不弯曲;保温层的热变形温度高达180-240℃,其在180℃以及0.7MPa压力下蠕变压缩低于2%,可满足纤维加热温度范围80~150℃内的保温、隔热需要。The present invention uses closed-cell polymethacrylimide (PMI) rigid foam as the insulation layer of the fiber guide pipe, which has the highest specific strength and specific stiffness in the same foam density, and can play a role in supporting the fiber conveying pipe. Function, to ensure that the fiber delivery pipe does not deform or bend; the thermal deformation temperature of the insulation layer is as high as 180-240°C, and its creep compression is less than 2% at 180°C and 0.7MPa pressure, which can meet the fiber heating temperature range of 80-150 The heat preservation and heat insulation needs in ℃.
为了满足连续喂料纤维快速加热需要,本发明采用纯黑体材料碳纤维发热体组成输送管的加热层,其发出的远红外线易被纤维、水等吸收,使输送过程中纤维中的水分被完全除去,从而有效避免制品缺陷。此外,更重要的是碳纤维发热体具有升温迅速、发热均匀、热交换速度快、耐高温、高热能力强、使用寿命长、且功率可随意调节等优点,适应轻质高强复合材料对输送纤维的加热工况要求,保证纤维进入双螺杆料筒时与熔融树脂具有近似的温度,从而将料筒中熔体的温度波动控制在最低范围,有利于满足树脂对纤维的充分浸润包覆、纤维定长剪断、纤维均匀分布等工艺要求。In order to meet the needs of rapid heating of continuous feeding fibers, the invention adopts pure black body material carbon fiber heating element to form the heating layer of the conveying pipe, and the far infrared rays emitted by it are easily absorbed by fibers and water, so that the moisture in the fibers is completely removed during the conveying process , so as to effectively avoid product defects. In addition, the more important thing is that the carbon fiber heating element has the advantages of rapid heating, uniform heating, fast heat exchange, high temperature resistance, high heat capacity, long service life, and power can be adjusted at will, etc. It is suitable for lightweight and high-strength composite materials. The requirements of heating conditions ensure that the fiber enters the twin-screw barrel at a similar temperature to the molten resin, thereby controlling the temperature fluctuation of the melt in the barrel to the lowest range, which is conducive to satisfying the full infiltration and coating of the fiber by the resin and the fixed length of the fiber. Cutting, uniform distribution of fibers and other process requirements.
附图说明: Description of drawings:
图1 一种具有远红外加热功能的纤维导向管横截面示意图Fig.1 Schematic diagram of the cross-section of a fiber guide tube with far-infrared heating function
图中:1-蒙皮;2-保温层;3-反射层;4-加热层;5-碳纤维加热丝;6-内衬层。In the figure: 1-skin; 2-insulation layer; 3-reflection layer; 4-heating layer; 5-carbon fiber heating wire; 6-inner lining.
具体实施方式: Detailed ways:
为了更好地理解本发明,下面结合附图和实施例对本发明做进一步的解释,但是应当明确的是本发明保护的范围并不局限于实施例表示的范围。In order to better understand the present invention, the present invention will be further explained below in conjunction with the accompanying drawings and examples, but it should be clear that the protection scope of the present invention is not limited to the scope indicated by the examples.
如图所示,本发明具有远红外加热功能的纤维导向管,管壁从外向内分别是聚氯乙烯膜形成的蒙皮、100%闭孔聚甲基丙烯酰亚胺(PMI)硬质泡沫组成的保温层、由金属铝直接压延成薄片状的反射层、含有碳纤维加热丝的电热转换加热层、由具有自润滑功能的聚四氟乙烯形成的内衬层,纤维导向管外径3~8cm、内径2~5cm,通电3分钟后,纤维导向管内温度为135℃。As shown in the figure, the fiber guide tube with far-infrared heating function of the present invention, the tube wall from the outside to the inside is the skin formed by polyvinyl chloride film, 100% closed-cell polymethacrylimide (PMI) rigid foam Insulation layer composed of metal aluminum, reflective layer directly calendered into thin sheets, electrothermal conversion heating layer containing carbon fiber heating wire, inner lining layer formed of polytetrafluoroethylene with self-lubricating function, fiber guide tube
Claims (6)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104896124B (en) * | 2015-04-17 | 2017-04-05 | 中国石油大学(华东) | A CO2 multi-stage throttling antifreeze valve |
CN114932785A (en) * | 2022-05-31 | 2022-08-23 | 中国第一汽车股份有限公司 | A vehicle heating device and a vehicle |
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JPH03121398A (en) * | 1989-03-23 | 1991-05-23 | Osaka Gas Co Ltd | Heat insulating material |
JPH0828778A (en) * | 1994-07-15 | 1996-02-02 | Nichifu Co Ltd | Heat insulation pipe provided with carbon heat generating body |
JPH08247346A (en) * | 1995-03-09 | 1996-09-27 | Nichifu Co Ltd | Water conveying hose for automatic car washer |
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CN202040475U (en) * | 2011-05-10 | 2011-11-16 | 苏浩淼 | Carbon fiber heat-tracing and foaming heat preservation water transportation pipe |
CN203273052U (en) * | 2013-01-29 | 2013-11-06 | 机械科学研究总院先进制造技术研究中心 | Fiber guiding pipe with far-infrared heating function |
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JPH08247346A (en) * | 1995-03-09 | 1996-09-27 | Nichifu Co Ltd | Water conveying hose for automatic car washer |
CN1202128A (en) * | 1995-09-20 | 1998-12-16 | 尤波诺尔股份有限公司 | Method and device for heating and/or crosslinking polymers |
CN201222017Y (en) * | 2008-04-30 | 2009-04-15 | 浙江华源电热有限公司 | Flexible heat-accompany sampling composite pipe |
CN201206695Y (en) * | 2008-06-02 | 2009-03-11 | 大庆市红岗区龙腾金属管业制造有限责任公司 | Interior heating polyurethane foam jacket pipe |
CN101749521A (en) * | 2008-12-12 | 2010-06-23 | 北京化工大学 | Closed hole-shaped vacuum foam for heat insulation and sound insulation and method for preparing same |
CN202040475U (en) * | 2011-05-10 | 2011-11-16 | 苏浩淼 | Carbon fiber heat-tracing and foaming heat preservation water transportation pipe |
CN203273052U (en) * | 2013-01-29 | 2013-11-06 | 机械科学研究总院先进制造技术研究中心 | Fiber guiding pipe with far-infrared heating function |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104896124B (en) * | 2015-04-17 | 2017-04-05 | 中国石油大学(华东) | A CO2 multi-stage throttling antifreeze valve |
CN114932785A (en) * | 2022-05-31 | 2022-08-23 | 中国第一汽车股份有限公司 | A vehicle heating device and a vehicle |
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