CN103525260A - Environment-friendly ultraviolet curing primer and preparation method thereof - Google Patents
Environment-friendly ultraviolet curing primer and preparation method thereof Download PDFInfo
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- CN103525260A CN103525260A CN201310457188.8A CN201310457188A CN103525260A CN 103525260 A CN103525260 A CN 103525260A CN 201310457188 A CN201310457188 A CN 201310457188A CN 103525260 A CN103525260 A CN 103525260A
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- 238000002360 preparation method Methods 0.000 title claims description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims abstract description 26
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims abstract description 13
- -1 ethoxyl methyl Chemical group 0.000 claims abstract description 11
- AOBIOSPNXBMOAT-UHFFFAOYSA-N 2-[2-(oxiran-2-ylmethoxy)ethoxymethyl]oxirane Chemical compound C1OC1COCCOCC1CO1 AOBIOSPNXBMOAT-UHFFFAOYSA-N 0.000 claims abstract description 7
- OOJBEQBXIJTMIN-UHFFFAOYSA-N europium 1,1,1-trifluoropentane-2,4-dione Chemical compound FC(C(=O)CC(C)=O)(F)F.[Eu] OOJBEQBXIJTMIN-UHFFFAOYSA-N 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims abstract description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 15
- 239000000843 powder Substances 0.000 claims description 12
- 230000007613 environmental effect Effects 0.000 claims description 10
- LJRSZGKUUZPHEB-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxypropoxy)propoxy]propyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COC(C)COC(=O)C=C LJRSZGKUUZPHEB-UHFFFAOYSA-N 0.000 claims description 6
- POLZHVHESHDZRD-UHFFFAOYSA-N 2-hydroxyethyl 2-methylprop-2-enoate;phosphoric acid Chemical compound OP(O)(O)=O.CC(=C)C(=O)OCCO POLZHVHESHDZRD-UHFFFAOYSA-N 0.000 claims description 6
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 241001330002 Bambuseae Species 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 6
- 239000003610 charcoal Substances 0.000 claims description 6
- 239000010977 jade Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 claims description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 3
- 241000628997 Flos Species 0.000 claims description 3
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 3
- HVVWZTWDBSEWIH-UHFFFAOYSA-N [2-(hydroxymethyl)-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(CO)(COC(=O)C=C)COC(=O)C=C HVVWZTWDBSEWIH-UHFFFAOYSA-N 0.000 claims description 3
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 4
- 239000000178 monomer Substances 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 abstract 2
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 abstract 1
- 206010059866 Drug resistance Diseases 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 238000000889 atomisation Methods 0.000 abstract 1
- KTLFENNEPHBKJD-UHFFFAOYSA-K benzyl(trimethyl)azanium;tribromide Chemical compound [Br-].[Br-].[Br-].C[N+](C)(C)CC1=CC=CC=C1.C[N+](C)(C)CC1=CC=CC=C1.C[N+](C)(C)CC1=CC=CC=C1 KTLFENNEPHBKJD-UHFFFAOYSA-K 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000003847 radiation curing Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000007761 roller coating Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
Environment-friendly ultraviolet curing primer comprises the components in parts by weight as follows: 45-50 parts of epoxy acrylate, 2-3 parts of ethoxyl methyl acrylic ester phosphate, 10-12 parts of tripropylene glycol diacrylate, 1-2 parts of trifluoroacetyl acetone europium, 1-3 parts of tetrahydrofuran, 3-5 parts of 3-propargyl chloride, 1-2 parts of benzyl trimethyl ammonium tribromide, 3-4 parts of 1-hydroxyl-cyclohexyl-phenyl ketone (184), 1-2 parts of glycol diglycidyl ether, 3-4 parts of isocyanuric acid trimethyl ester and 3-4 parts of a dispersing agent. The paint has excellent water resistance, hot water resistance, drug resistance, cohesiveness and toughness, active reaction monomers substitute for an organic solvent, a few organic matters are volatilized, and the paint is safe and environment-friendly; and the paint is good in atomization effect, device wrapping effect, adherence and rubbing property, can serve as the primer suitably and is not corroded for a long time.
Description
Technical field
The invention belongs to paint field, relate in particular to a kind of environmental protection ultraviolet cured primer and preparation method thereof.
Background technology
Development along with market economy, there is great variety in paint field, wherein UV coating has the advantages such as curing speed is fast, energy-conservation, ambient cure, superior performance, environmental protection, on it, ray velocity is fast, rete luminance brightness is high, and dry rear face is firm heat-resisting, and refractive power is effective, make ground produce strong main body sense, be widely used in the fields such as chemical industry, machinery, electronics light industry, communication.Due to its environment-friendly advantage, UV solidifies and to have obtained the strong support of relevant environment rules and the close attention of industry member, and UV radiation curing material is in market requirement rapid growth, and UV Radiation-curing system is just with multiple technologies combination, to overcome some defect, meet actual application.Now in printing industry; the packing that can make UV obtains some special effects: high glossiness, good ink protection feature, the slipping that can add control and rub resistance, low smell or do not have smell, low extract maybe cannot detect extract, and the provide protection to ink.
Current UV solidify material is various, but still in various degree exist some problems, such as: Organic pollutants, xanthochromia, explosive look, not low temperature resistant, the series of problems such as cost is high, corrosion-resistant, all need to continue improvement for different purposes, reduce production costs, expand purposes.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection ultraviolet cured primer and preparation method thereof, this coating has environmental protection, and organism volatilization is few, the feature that cohesiveness is good.
Technical scheme of the present invention is as follows:
A ultraviolet cured primer, is characterized in that being made by the raw material of following weight part: epoxy acrylate 45-50, hydroxyethyl meth acrylate phosphoric acid ester 2-3, tri (propylene glycol) diacrylate 10-12, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3,3-chloroallylene 3-5, benzyl trimethyl tribromide ammonium 1-2,1-hydroxyl-cyclohexyl-phenyl ketone (184) 3-4, ethylene glycol bis glycidyl ether 1-2, triglycidyl isocyanurate 3-4, dispersing auxiliary 3-4;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
The preparation method of described environmental protection ultraviolet cured primer, it is characterized in that comprising the following steps: by hydroxyethyl meth acrylate phosphoric acid ester, tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, tetrahydrofuran (THF), 3-chloroallylene, benzyl trimethyl tribromide ammonium, ethylene glycol bis glycidyl ether, mixing and stirring, be warming up to 50-60 ℃, add epoxy acrylate, under 600-700 rev/min, stir 15-20 minute, cool to 35 ℃ and add again below 1-hydroxyl-cyclohexyl-phenyl ketone (184), continue to stir 10-15 minute, obtain.
Beneficial effect of the present invention
Coating of the present invention has good water tolerance, hot water resistance, resistance physical property, cohesiveness, toughness, and replaces organic solvent with active reaction monomer, and organism volatilization is few, safety and environmental protection; Coating of the present invention, atomizing effect is good, and good to the parcel of device, adherence is good, and grinability is good, is suitable as priming paint and uses, and does not corrode for a long time.
Embodiment
A ultraviolet cured primer, is made by the raw material of following weight part: epoxy acrylate 47, hydroxyethyl meth acrylate phosphoric acid ester 2, tri (propylene glycol) diacrylate 11, trifluoroacetylacetone europium 1.4, tetrahydrofuran (THF) 2,3-chloroallylene 4, benzyl trimethyl tribromide ammonium 1.5,1-hydroxyl-cyclohexyl-phenyl ketone (184) 3.4, ethylene glycol bis glycidyl ether 1.6, triglycidyl isocyanurate 3, dispersing auxiliary 3.5;
Described dispersing auxiliary by following weight part (kilogram) raw material make: bamboo charcoal powder 4, jade powder 2, Flos Rosae Rugosae quintessence oil 2, xitix 1.5, pentaerythritol triacrylate 4.6, alcohol ester 12, Silane coupling agent KH550 1.4, ethyl acetate 16; Preparation method puts into 14% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3 hours, takes out, and uses deionized water wash 5 times, dry, be added in ethyl acetate, grind to obtain 25 μ m slurries, in slurry, add other remaining component, be heated to 53 ℃, stir 44 minutes; Continue to be warming up to 72 ℃, stirring reaction 2 hours, obtains.
The preparation method of described environmental protection ultraviolet cured primer, comprise the following steps: by hydroxyethyl meth acrylate phosphoric acid ester, tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, tetrahydrofuran (THF), 3-chloroallylene, benzyl trimethyl tribromide ammonium, ethylene glycol bis glycidyl ether, mixing and stirring, be warming up to 50 ℃, add epoxy acrylate, under 600 revs/min, stir 18 minutes, cool to 35 ℃ and add again below 1-hydroxyl-cyclohexyl-phenyl ketone (184), continue to stir 14 minutes, obtain.
The wear-resisting base paint of this UV photocuring can adopt the form of construction work of roller coating, showering, spraying to construct.The paint spraying making by above scheme sticking power on plank is all better than secondary, resistance to 75% ethanol is more than 24 hours, alkaline-resisting 24 hours above, acidproof more than 48 hours, the cold cycling that tolerates subzero 40 degree and 40 degree does not ftracture for 10 times, resistance to 15% salt solution is more than 60 hours, hardness can regulate between 3H at 2HB, and abrasion resistance index turns above 4000.
Claims (2)
1. an environmental protection ultraviolet cured primer, is characterized in that being made by the raw material of following weight part: epoxy acrylate 45-50, hydroxyethyl meth acrylate phosphoric acid ester 2-3, tri (propylene glycol) diacrylate 10-12, trifluoroacetylacetone europium 1-2, tetrahydrofuran (THF) 1-3,3-chloroallylene 3-5, benzyl trimethyl tribromide ammonium 1-2,1-hydroxyl-cyclohexyl-phenyl ketone (184) 3-4, ethylene glycol bis glycidyl ether 1-2, triglycidyl isocyanurate 3-4, dispersing auxiliary 3-4;
Described dispersing auxiliary is made by the raw material of following weight part: bamboo charcoal powder 4-5, jade powder 2-3, Flos Rosae Rugosae quintessence oil 1-2, xitix 1-2, pentaerythritol triacrylate 4-5, alcohol ester 12 3-4, Silane coupling agent KH550 1-2, ethyl acetate 14-18; Preparation method puts into 10-15% hydrochloric acid soln by bamboo charcoal powder, jade powder to steep 3-4 hour, takes out, with deionized water wash repeatedly, dry, be added in ethyl acetate, grind to obtain 20-40 μ m slurry, in slurry, add other remaining component, be heated to 50-55 ℃, stir 40-50 minute; Continue to be warming up to 70-75 ℃, stirring reaction 1-2 hour, obtains.
2. the preparation method of environmental protection ultraviolet cured primer according to claim 1, it is characterized in that comprising the following steps: by hydroxyethyl meth acrylate phosphoric acid ester, tri (propylene glycol) diacrylate, trifluoroacetylacetone europium, tetrahydrofuran (THF), 3-chloroallylene, benzyl trimethyl tribromide ammonium, ethylene glycol bis glycidyl ether, mixing and stirring, be warming up to 50-60 ℃, add epoxy acrylate, under 600-700 rev/min, stir 15-20 minute, cool to 35 ℃ and add again below 1-hydroxyl-cyclohexyl-phenyl ketone (184), continue to stir 10-15 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457188.8A CN103525260A (en) | 2013-09-30 | 2013-09-30 | Environment-friendly ultraviolet curing primer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310457188.8A CN103525260A (en) | 2013-09-30 | 2013-09-30 | Environment-friendly ultraviolet curing primer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103525260A true CN103525260A (en) | 2014-01-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310457188.8A Pending CN103525260A (en) | 2013-09-30 | 2013-09-30 | Environment-friendly ultraviolet curing primer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525260A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250339A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing vacuum coating foundation and finish |
| CN102190938A (en) * | 2010-03-19 | 2011-09-21 | 刘立新 | High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system |
| CN102206463A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Vacuum plating UV cured primer |
| CN102732133A (en) * | 2012-06-29 | 2012-10-17 | 惠州市长润发涂料有限公司 | Anti-sagging spraying prime coat |
-
2013
- 2013-09-30 CN CN201310457188.8A patent/CN103525260A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101250339A (en) * | 2008-04-03 | 2008-08-27 | 惠州市长润发涂料有限公司 | Ultraviolet light curing vacuum coating foundation and finish |
| CN102190938A (en) * | 2010-03-19 | 2011-09-21 | 刘立新 | High-wear-resistance antiscratch and antifouling solid wood board ultraviolet (UV) curable coating system |
| CN102206463A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | Vacuum plating UV cured primer |
| CN102732133A (en) * | 2012-06-29 | 2012-10-17 | 惠州市长润发涂料有限公司 | Anti-sagging spraying prime coat |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |
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| RJ01 | Rejection of invention patent application after publication |