CN103524960B - A kind of anti-aging wear-resistant plastic - Google Patents
A kind of anti-aging wear-resistant plastic Download PDFInfo
- Publication number
- CN103524960B CN103524960B CN201310440720.5A CN201310440720A CN103524960B CN 103524960 B CN103524960 B CN 103524960B CN 201310440720 A CN201310440720 A CN 201310440720A CN 103524960 B CN103524960 B CN 103524960B
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- Prior art keywords
- mass parts
- resistant plastic
- plastics
- aging wear
- parts
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- 239000004033 plastic Substances 0.000 title claims abstract description 28
- 229920003023 plastic Polymers 0.000 title claims abstract description 28
- 230000003712 anti-aging effect Effects 0.000 title claims abstract description 16
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052582 BN Inorganic materials 0.000 claims abstract description 10
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002033 PVDF binder Substances 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 239000010949 copper Substances 0.000 claims abstract description 10
- 239000003365 glass fiber Substances 0.000 claims abstract description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 10
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 10
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 10
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims abstract description 10
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 claims abstract description 10
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- -1 dicumyl peroxides Chemical class 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 230000003245 working effect Effects 0.000 description 2
- 206010051246 Photodermatosis Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008845 photoaging Effects 0.000 description 1
- 210000001138 tear Anatomy 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of anti-aging wear-resistant plastic, be made up of following weight parts component: 110-115 mass parts PVDF, 10-15 mass parts formaldehyde, 10-14 mass parts PMMA, 10-15 mass parts glass fibre, 10-15 mass parts boron nitride, 10-13 mass parts zirconium white, the copper-loaded zirconium phosphate of 10-14 mass parts, 10-16 mass parts dicumyl peroxide alcohol and 10-13 mass parts triphenyl phosphite.The plastics that the present invention obtains have good anti-aging wear-resisting functions; And do not affect the physical strength of plastics; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of anti-aging wear-resistant plastic.
Technical background
Along with the development and progress of society and the raising day by day of living standard, the requirement of people to material is more and more higher.Because plastics have the advantages such as light weight, not corrosion, good insulating, so will plastics be used in a lot of links of household electrical appliances production.But the quality of much modified plastics is on the market unstable, its wear resisting property is not good, or easily weares and teares, and reduces work-ing life, and the good plastics of some effects, it obtains through complicated technique, but product cost is high.
Simultaneously in order to adapt to different Working environments and user demand, so can carry out improvement performance to plastics, and the plastics only with single function are competed in more and more fierce market now, more and more out inferior position.So need to carry out modification to plastics, make it have more than a kind of characteristic, thus strengthen the competitive power in market.
But the quality of modified plastics is on the market unstable, ageing resistance is not good, or easily aging, chaps, and reduces work-ing life.
Summary of the invention
For above shortcomings in prior art, the object of the invention is to provide a kind of anti-aging wear-resistant plastic.
The object of the invention is to be achieved through the following technical solutions: a kind of anti-aging wear-resistant plastic, is made up of following weight parts component: 110-115 mass parts PVDF, 10-15 mass parts formaldehyde, 10-14 mass parts PMMA, 10-15 mass parts glass fibre, 10-15 mass parts boron nitride, 10-13 mass parts zirconium white, the copper-loaded zirconium phosphate of 10-14 mass parts, 10-16 mass parts dicumyl peroxide alcohol and 10-13 mass parts triphenyl phosphite.
A kind of anti-aging wear-resistant plastic, is made up of following weight parts component: 114 mass parts PVDF, 14 mass parts formaldehyde, 13 mass parts PMMA, 14 mass parts glass fibre, 14 mass parts boron nitride, 13 mass parts zirconium whites, the copper-loaded zirconium phosphate of 13 mass parts, 15 mass parts dicumyl peroxide alcohol and 13 mass parts triphenyl phosphites.
A kind of anti-aging wear-resistant plastic, is made up of following weight parts component: 111 mass parts PVDF, 12 mass parts formaldehyde, 12 mass parts PMMA, 11 mass parts glass fibre, 11 mass parts boron nitride, 11 mass parts zirconium whites, the copper-loaded zirconium phosphate of 11 mass parts, 11 mass parts dicumyl peroxide alcohol and 11 mass parts triphenyl phosphites.
The beneficial effect that the present invention has: the plastics that the present invention obtains have good anti-aging wear-resisting functions; And do not affect the physical strength of plastics; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted.
Embodiment
embodiment 1
The preparation of anti-aging wear-resistant plastic: stirrer is put in the mixing of 110-115 mass parts PVDF, 10-15 mass parts formaldehyde, 10-14 mass parts PMMA, 10-15 mass parts glass fibre, 10-15 mass parts boron nitride, 10-13 mass parts zirconium white, the copper-loaded zirconium phosphate of 10-14 mass parts, 10-16 mass parts dicumyl peroxide alcohol and 10-13 mass parts triphenyl phosphite, put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures; The salient features of the material that the present embodiment is prepared is as follows: tensile strength MPa(GB/T1040-2006): 35-37, elongation at break %(GB/T1040-2006): 15-16; Shock strength kJ/m
2(GB/T1043-2008): 3-4; Flexural strength MPa(GB/T9341-2000): 45-46; 500h photoaging shock strength conservation rate: 100%.
embodiment 1
The preparation of anti-aging wear-resistant plastic: stirrer is put in the mixing of 114 mass parts PVDF, 14 mass parts formaldehyde, 13 mass parts PMMA, 14 mass parts glass fibre, 14 mass parts boron nitride, 13 mass parts zirconium whites, the copper-loaded zirconium phosphate of 13 mass parts, 15 mass parts dicumyl peroxide alcohol and 13 mass parts triphenyl phosphites, put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures.
embodiment 1
The preparation of anti-aging wear-resistant plastic: stirrer is put in the mixing of 111 mass parts PVDF, 12 mass parts formaldehyde, 12 mass parts PMMA, 11 mass parts glass fibre, 11 mass parts boron nitride, 11 mass parts zirconium whites, the copper-loaded zirconium phosphate of 11 mass parts, 11 mass parts dicumyl peroxide alcohol and 11 mass parts triphenyl phosphites, put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures.
Claims (3)
1. an anti-aging wear-resistant plastic, is characterized in that being made up of following weight parts component: 110-115 mass parts PVDF, 10-15 mass parts formaldehyde, 10-14 mass parts PMMA, 10-15 mass parts glass fibre, 10-15 mass parts boron nitride, 10-13 mass parts zirconium white, the copper-loaded zirconium phosphate of 10-14 mass parts, 10-16 mass parts dicumyl peroxide and 10-13 mass parts triphenyl phosphite.
2. the anti-aging wear-resistant plastic of one according to claim 1, is characterized in that being made up of following weight parts component: 114 mass parts PVDF, 14 mass parts formaldehyde, 13 mass parts PMMA, 14 mass parts glass fibre, 14 mass parts boron nitride, 13 mass parts zirconium whites, the copper-loaded zirconium phosphate of 13 mass parts, 15 mass parts dicumyl peroxides and 13 mass parts triphenyl phosphites.
3. the anti-aging wear-resistant plastic of one according to claim 1, is characterized in that being made up of following weight parts component: 111 mass parts PVDF, 12 mass parts formaldehyde, 12 mass parts PMMA, 11 mass parts glass fibre, 11 mass parts boron nitride, 11 mass parts zirconium whites, the copper-loaded zirconium phosphate of 11 mass parts, 11 mass parts dicumyl peroxides and 11 mass parts triphenyl phosphites.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310440720.5A CN103524960B (en) | 2013-09-25 | 2013-09-25 | A kind of anti-aging wear-resistant plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310440720.5A CN103524960B (en) | 2013-09-25 | 2013-09-25 | A kind of anti-aging wear-resistant plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103524960A CN103524960A (en) | 2014-01-22 |
| CN103524960B true CN103524960B (en) | 2016-01-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310440720.5A Active CN103524960B (en) | 2013-09-25 | 2013-09-25 | A kind of anti-aging wear-resistant plastic |
Country Status (1)
| Country | Link |
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| CN (1) | CN103524960B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104017313B (en) * | 2014-03-14 | 2016-07-06 | 江苏大学 | One kind graphite type carbon nitride/polyvinylidene fluoride composite material and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7179863B2 (en) * | 2002-10-03 | 2007-02-20 | Arkema France | Use of a film based PVDF, PMMA or a blend thereof for covering articles made of a thermoset |
| CN1772799A (en) * | 2005-10-27 | 2006-05-17 | 复旦大学 | A kind of thermosensitive temperature material and preparation method thereof |
| CN102336992A (en) * | 2010-07-19 | 2012-02-01 | 刘波 | Preparation method of special material for fluorine-containing plastic film |
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2013
- 2013-09-25 CN CN201310440720.5A patent/CN103524960B/en active Active
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| Publication number | Publication date |
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| CN103524960A (en) | 2014-01-22 |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20151104 Address after: 226300, Jiangsu, Nantong province Tongzhou District Stone Town Industrial Park Applicant after: Zheng Wanchun Address before: Wujiang District of Suzhou City, Jiangsu province 215212 Lili Town Industrial Park of arch bridge Applicant before: Wujiang Tianyuan Plastic Co., Ltd. |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Song Dongqiang Inventor after: Chen Hongwei Inventor before: Xiao Weirong |
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| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161009 Address after: 226300, Jiangsu, Nantong province Tongzhou District stone port town stone West Village 14 groups Patentee after: NANTONG ZHANPENG PLASTIC CO., LTD. Address before: 226300, Jiangsu, Nantong province Tongzhou District Stone Town Industrial Park Patentee before: Zheng Wanchun |