CN103524994B - A kind of Flame-retardant waterproof plastic - Google Patents
A kind of Flame-retardant waterproof plastic Download PDFInfo
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- CN103524994B CN103524994B CN201310440813.8A CN201310440813A CN103524994B CN 103524994 B CN103524994 B CN 103524994B CN 201310440813 A CN201310440813 A CN 201310440813A CN 103524994 B CN103524994 B CN 103524994B
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- mass parts
- flame
- plastics
- waterproof plastic
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- 239000004033 plastic Substances 0.000 title claims abstract description 30
- 229920003023 plastic Polymers 0.000 title claims abstract description 30
- 239000003063 flame retardant Substances 0.000 title claims abstract description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 16
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims abstract description 20
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 20
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 14
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 10
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 10
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims abstract description 10
- 239000008101 lactose Substances 0.000 claims abstract description 10
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 10
- 239000003549 soybean oil Substances 0.000 claims abstract description 10
- -1 propylene glycol ester Chemical class 0.000 claims abstract description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 239000011347 resin Substances 0.000 abstract description 2
- 229920005989 resin Polymers 0.000 abstract description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 230000003115 biocidal effect Effects 0.000 abstract 1
- 238000010292 electrical insulation Methods 0.000 abstract 1
- 229920001903 high density polyethylene Polymers 0.000 abstract 1
- 239000004700 high-density polyethylene Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 229910000039 hydrogen halide Inorganic materials 0.000 description 1
- 239000012433 hydrogen halide Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
Abstract
The invention discloses a kind of Flame-retardant waterproof plastic, be made up of following weight parts component: by 110-115 mass parts ABS, 60-65 mass parts PVC, 10-15 mass parts aluminium hydroxide, 10-15 mass parts clorafin, 5-8 mass parts lactose, 10-15 mass parts hexanodioic acid propylene glycol ester, 10-13 mass parts zirconium white, 20-24 mass parts soybean oil, 10-14 mass parts phosphorous acid ester and 10-15 mass parts dioctyl phthalate (DOP).The HDPE antibiotic plastic that the present invention obtains has good antibacterial, and consumption seldom just obviously can play anti-microbial effect; And do not affect the physical strength of plastics, particularly do not reduce the heat-drawn wire of plastics, mechanics temperature and electrical insulation capability; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of Flame-retardant waterproof plastic.
Technical background
In recent years, the fast development of electronic apparatus, building, aviation and automobile industry higher requirement that the performance of plastics is proposed.Wherein, the plastics of flame retardant type are nonflammable, and rate of flame propagation is little, mass loss rate and heat release rate lower, and there is certain self-extinguishing.But the flame retardant plastics performance used at present can not meet the demands, and adopts halogen flame more, and combustion processes can be released hydrogen halide and be caused serious harm to human body.
Simultaneously in order to adapt to different Working environments and user demand, so can carry out improvement performance to plastics, and the plastics only with single function are competed in more and more fierce market now, more and more out inferior position.So need to carry out modification to plastics, make it have more than a kind of characteristic, thus strengthen the competitive power in market.
But because plastics have the advantages such as light weight, not corrosion, good insulating, so plastics will be used in a lot of links of electronic product production.The quality of modified plastics is on the market unstable, and water resistance is not good, and some are at the electronic product of outdoor application, such as air-conditioner outdoor unit, outdoor electronic box, mobile phone etc., if splash or pour rainwater, or easily cause electric leakage, according to one-tenth harm, so good water-repellancy will be had.
Summary of the invention
For above shortcomings in prior art, the object of the invention is to provide a kind of Flame-retardant waterproof plastic.
The object of the invention is to be achieved through the following technical solutions: a kind of Flame-retardant waterproof plastic, is made up of following weight parts component: 110-115 mass parts ABS, 60-65 mass parts PVC, 10-15 mass parts aluminium hydroxide, 10-15 mass parts clorafin, 5-8 mass parts lactose, 10-15 mass parts hexanodioic acid propylene glycol ester, 10-13 mass parts zirconium white, 20-24 mass parts soybean oil, 10-14 mass parts phosphorous acid ester and 10-15 mass parts dioctyl phthalate (DOP).
A kind of Flame-retardant waterproof plastic, is characterized in that being made up of following weight parts component: 115 mass parts ABS, 64 mass parts PVC, 14 mass parts aluminium hydroxides, 13 mass parts clorafins, 7 mass parts lactose, 14 mass parts hexanodioic acid propylene glycol esters, 11 mass parts zirconium whites, 24 mass parts soybean oil, 13 mass parts phosphorous acid esters and 11 mass parts dioctyl phthalate (DOP)s.
A kind of Flame-retardant waterproof plastic, is characterized in that being made up of following weight parts component: 111 mass parts ABS, 61 mass parts PVC, 11 mass parts aluminium hydroxides, 12 mass parts clorafins, 6 mass parts lactose, 11 mass parts hexanodioic acid propylene glycol esters, 13 mass parts zirconium whites, 21 mass parts soybean oil, 11 mass parts phosphorous acid esters and 14 mass parts dioctyl phthalate (DOP)s.
The beneficial effect that the present invention has: the plastics that the present invention obtains have good fire-retardant and water-proof function; And do not affect the physical strength of plastics; To get well with the consistency of resin simultaneously, not move in plastics, do not separate out, be not extracted.
Embodiment
embodiment 1
The preparation of Flame-retardant waterproof plastic: stirrer is put in 110-115 mass parts ABS, 60-65 mass parts PVC, 10-15 mass parts aluminium hydroxide, 10-15 mass parts clorafin, 5-8 mass parts lactose, 10-15 mass parts hexanodioic acid propylene glycol ester, 10-13 mass parts zirconium white, 20-24 mass parts soybean oil, 10-14 mass parts phosphorous acid ester and the mixing of 10-15 mass parts dioctyl phthalate (DOP), put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures; The salient features of the material that the present embodiment is prepared is as follows: tensile strength MPa(GB/T1040-2006): 33-37, elongation at break %(GB/T 1040-2006): 12-16; Shock strength kJ/m
2(GB/T1043-2008): 3.2-4.4; Flexural strength MPa(GB/T9341-2000): 45-46; Oxygen index %(GB/T2406-2008): 3, vertical combustion rank UL-94:V0.
embodiment 2
The preparation of Flame-retardant waterproof plastic: stirrer is put in 115 mass parts ABS, 64 mass parts PVC, 14 mass parts aluminium hydroxides, 13 mass parts clorafins, 7 mass parts lactose, 14 mass parts hexanodioic acid propylene glycol esters, 11 mass parts zirconium whites, 24 mass parts soybean oil, 13 mass parts phosphorous acid esters and the mixing of 11 mass parts dioctyl phthalate (DOP)s, put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures.
embodiment 3
The preparation of Flame-retardant waterproof plastic: stirrer is put in 111 mass parts ABS, 61 mass parts PVC, 11 mass parts aluminium hydroxides, 12 mass parts clorafins, 6 mass parts lactose, 11 mass parts hexanodioic acid propylene glycol esters, 13 mass parts zirconium whites, 21 mass parts soybean oil, 11 mass parts phosphorous acid esters and the mixing of 14 mass parts dioctyl phthalate (DOP)s, put into Banbury mixer banburying after stirring, internally mix temperature is 170-175 DEG C, rotating speed is 900-950rpm; Then by the mixture after banburying through granulator granulation, obtain particle, particle put into tank cooling, then dry at normal temperatures.
Claims (3)
1. a Flame-retardant waterproof plastic, is characterized in that being made up of following weight parts component: 110-115 mass parts ABS, 60-65 mass parts PVC, 10-15 mass parts aluminium hydroxide, 10-15 mass parts clorafin, 5-8 mass parts lactose, 10-15 mass parts hexanodioic acid propylene glycol ester, 10-13 mass parts zirconium white, 20-24 mass parts soybean oil, 10-14 mass parts phosphorous acid ester and 10-15 mass parts dioctyl phthalate (DOP).
2.
according to claim 1a kind of Flame-retardant waterproof plastic, is characterized in that being made up of following weight parts component: 115 mass parts ABS, 64 mass parts PVC, 14 mass parts aluminium hydroxides, 13 mass parts clorafins, 7 mass parts lactose, 14 mass parts hexanodioic acid propylene glycol esters, 11 mass parts zirconium whites, 24 mass parts soybean oil, 13 mass parts phosphorous acid esters and 11 mass parts dioctyl phthalate (DOP)s.
3.
according to claim 1a kind of Flame-retardant waterproof plastic, is characterized in that being made up of following weight parts component: 111 mass parts ABS, 61 mass parts PVC, 11 mass parts aluminium hydroxides, 12 mass parts clorafins, 6 mass parts lactose, 11 mass parts hexanodioic acid propylene glycol esters, 13 mass parts zirconium whites, 21 mass parts soybean oil, 11 mass parts phosphorous acid esters and 14 mass parts dioctyl phthalate (DOP)s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310440813.8A CN103524994B (en) | 2013-09-25 | 2013-09-25 | A kind of Flame-retardant waterproof plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310440813.8A CN103524994B (en) | 2013-09-25 | 2013-09-25 | A kind of Flame-retardant waterproof plastic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103524994A CN103524994A (en) | 2014-01-22 |
| CN103524994B true CN103524994B (en) | 2015-10-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310440813.8A Expired - Fee Related CN103524994B (en) | 2013-09-25 | 2013-09-25 | A kind of Flame-retardant waterproof plastic |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107610845A (en) * | 2017-09-13 | 2018-01-19 | 如皋市乐恒化工有限公司 | A kind of preparation method of composite insulating material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041734A (en) * | 2006-03-21 | 2007-09-26 | 哈尔滨鑫达高分子材料股份有限公司 | Green environmental protective flame-proof ABS alloy |
| CN101274987A (en) * | 2008-05-13 | 2008-10-01 | 福建师范大学 | A preparation method of a halogen-free flame-retardant plastic masterbatch based on calcium hydroxide and its special resin |
| CN102190835A (en) * | 2010-03-14 | 2011-09-21 | 池州学院 | Preparation method of novel environment-friendly type polyvinyl chloride (PVC)/acrylonitrile butadiene styrene (ABS) alloy material for cable |
-
2013
- 2013-09-25 CN CN201310440813.8A patent/CN103524994B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101041734A (en) * | 2006-03-21 | 2007-09-26 | 哈尔滨鑫达高分子材料股份有限公司 | Green environmental protective flame-proof ABS alloy |
| CN101274987A (en) * | 2008-05-13 | 2008-10-01 | 福建师范大学 | A preparation method of a halogen-free flame-retardant plastic masterbatch based on calcium hydroxide and its special resin |
| CN102190835A (en) * | 2010-03-14 | 2011-09-21 | 池州学院 | Preparation method of novel environment-friendly type polyvinyl chloride (PVC)/acrylonitrile butadiene styrene (ABS) alloy material for cable |
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| CN103524994A (en) | 2014-01-22 |
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