CN103496262A - Temperature-displaying plane presswork and printing technology thereof - Google Patents
Temperature-displaying plane presswork and printing technology thereof Download PDFInfo
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Abstract
The invention provides temperature-displaying plane presswork and a printing technology of the temperature-displaying plane presswork. The temperature-displaying plane presswork comprises two layers of structures, namely, a printing carrier and temperature sensing ink layers. More than one temperature sensing ink layer set is included, each temperature sensing ink layer set comprises a pattern layer on the bottom layer and a covering layer on the upper portion of the pattern layer, and the decoloration points of the covering layers are less than those of the pattern layer in the same temperature sensing ink layer set. The ink layers are manufactured through an echelonment printing technology, and the plane presswork which is blended, printed and completed by using temperature sensing off-color materials through the new technology can display temperature by sensing the temperature and changing colors through numbers, characters and patterns.
Description
Technical field
The present invention relates to heat-sensitive variable colour planographic product technical field, be specially a kind of temperature display planographic product and typography thereof.
Background technology
The planographic product have a wide range of applications in market segments such as small stores, household articles, the consumer goods, as marble paper, patterned adhesive sticker, flat plastic printed matter etc., especially marble paper has irreplaceable effect on the decoration of the vessel such as glass, pottery, stainless steel, enamel, plastics.Current existing alternating temperature planographic product are a lot, it is single heat discoloration that prior art is used temperature-sensing color-changing material---surface color and polish vary with temperature and develop the color, colour killing and variable color, properties of materials is not carried out to process spread, more do not possess the function of numeral (word, figure) temperature display and picture and text conversion.And, in prior art, all there is no to solve in marble paper the feasible scheme that repeatedly changes and solve the technical problems such as reversible transformation of a plurality of temperature sections, multiple patterns in same pattern of the color pattern of multi-layer on same position.
Summary of the invention
Purpose of the present invention is exactly to provide a kind of temperature display planographic product and typography thereof for the defect of above-mentioned existence.The planographic product that the present invention utilizes temperature-sensing color-changing material to be completed for printing by new technique allotment can be with numeral, word and figure heat discoloration displays temperature.
Temperature display planographic product of the present invention and printing technology scheme thereof are that the flat product of this planographic comprise double-layer structure: printing carrier, and temperature sensing ink layer; The temperature sensing ink layer comprises more than one group, and one group of temperature sensing ink layer comprises the patterned layer of bottom and the cover layer of patterned layer top, and the patterned layer of same group is identical with tectal color; When tectal pattern and/or character colour developing, cover or hide pattern and/or the character of same group of patterned layer fully; In same group of temperature sensing ink layer, tectal achromic point is lower than the achromic point of patterned layer; Except the patterned layer adjacent with printing carrier, temperature is transparent or semitransparent shape higher than the temperature sensing ink layer of achromic point.
The patterned layer adjacent with printing carrier, temperature is transparent, translucent or opaque shape higher than achromic point.
Further, same group of temperature sensing ink layer, the achromic point temperature difference of tectal achromic point and patterned layer>1 ℃.
The temperature sensing ink layer comprises more than two groups, between group and group, is to distribute up and down, tectal achromic point in one group of the below temperature sensing ink layer of the achromic point of patterned layer in the temperature sensing ink layer of one group of top≤adjacent.
The temperature sensing ink layer comprises more than two groups, between group and group, is horizontal distribution.
Contain the temperature-sensitive microcapsule powder in the temperature sensing ink layer.The temperature sensing ink layer is that resin ready-mixed oil or aqueous emulsion mediation temperature-sensitive microcapsule powder form, wherein temperature sensing ink or temperature-sensitive aqueous emulsion can be for glass, for pottery, resin printing ink, resin printing ink for stainless steel, plastics form with the blending inks such as resin printing ink mediation temperature-sensitive microcapsule powder, according to practical application, selected.
In the patterned layer of temperature sensing ink layer on the same group, the temperature-sensitive microcapsule powder does not form different patterns and/or character.
Described printing carrier water shifts a kind of in membranelle paper, self-adhesive paper, plastics, can be prepared into marble paper, temperature display self-adhesive paper, temperature display plastic sheeting or other paper products etc.
Temperature display planographic product are marble paper, and marble paper comprises three-decker: bottom is that water shifts membranelle paper, and intermediate layer is the temperature sensing ink layer, but the superiors are coated with dyestripping.
The typography of above-mentioned temperature display planographic product, step comprises:
(1) patterned layer in first group of temperature sensing ink layer of printing on printing carrier, achromic point is a;
(2) cover layer of first group of temperature sensing ink layer of printing on the patterned layer of first group of temperature sensing ink layer, achromic point is b;
The cover layer top of (3) first groups of temperature sensing ink layers or the patterned layer of printing second group of temperature sensing ink layer at the parallel position of first group of temperature sensing ink layer, achromic point is c;
The cover layer of second group of temperature sensing ink layer of printing on the patterned layer of (4) second groups of temperature sensing ink layers, achromic point is d;
(5) repeat above step printing temperature sensing ink layer.
Wherein, a>b >=c>d.
Wherein, the applying step of marble paper is:
(1) marble paper is soaked to water Rio 0.5-2 minute, water shifts membranelle paper natural separation;
(2) will remove the marble paper that water shifts membranelle paper and be transferred to vessel surface, and the water between marble paper and vessel and air will be scraped totally, and make marble paper fully sturdy;
(3) but after drying, the dyestripping on marble paper is taken off to the pattern that on vessel, only remaining Intermediate Gray has the temperature-sensitive microcapsule powder to form and/or the temperature sensing ink layer of character;
(4) enter the baking oven decoration firing, through excess temperature, 180 ° of-200 ° of decoration firings, the abundant combination of temperature sensing ink layer and vessel surface, form high-intensity chain junctor.
The alleged achromic point of the present invention, refer to that temperature-sensitive microcapsule powder in the temperature sensing ink layer arrives the temperature spot that color disappears or changes after this temperature.Lower than achromic point, the temperature-sensitive microcapsule powder colour developing in the temperature sensing ink layer, reach or, higher than achromic point, the temperature-sensitive microcapsule powder color in the temperature sensing ink layer disappears or changes.
For example, achromic point is 31 ℃, develops the color for red temperature-sensitive microcapsule powder, below 31 ℃ the time, shows redly, and temperature reaches and surpasses 31 ℃, the red disappearance or the flavescence look.
Beneficial effect of the present invention is: temperature display planographic product of the present invention and typography thereof, to utilize temperature-sensing color-changing material to pass through echelon typography printing marble paper, with character and pattern heat discoloration displays temperature, greatly enriched the effect of plane pattern, made temperature-sensing color-changing material performance maximum function.
On printing carrier, when printing first prints a group of high temperature section in order, cover again one group that prints low temperature section, like this by the printing of the ladder sequence of cryosphere covering high-temperature layer, solved the reversible transformation that repeatedly changes and solve a plurality of temperature sections, multiple patterns in same printed matter pattern of the color pattern of multi-layer on planographic product levels same position, made the material behavior performance ultimate attainment.On marble paper, but last seal dyestripping is to use in order to protect with the water applique transferring.There are product decoration, digital temperature display and the multiple functions such as word, figure multiple conversions.
the accompanying drawing explanation:
Figure 1 shows that marble paper of the present invention uses the status architecture schematic diagram;
Figure 2 shows that the marble paper display graphics schematic diagram in embodiment 1.
Wherein, 1. water shifts membranelle paper, but 2. dyestripping, 3. temperature sensing ink layer, 4. vessel.
the specific embodiment:
In order to understand better the present invention, below with instantiation, describe technical scheme of the present invention in detail, but the present invention is not limited thereto.
The alleged achromic point of the present invention, refer to that temperature-sensitive microcapsule powder in temperature sensing ink layer 3 arrives the temperature spot that color disappears or changes after this temperature.Lower than achromic point, the temperature-sensitive microcapsule powder colour developing in the temperature sensing ink layer, reach or, higher than achromic point, the temperature-sensitive microcapsule powder color in the temperature sensing ink layer disappears or changes.
For example, achromic point is 31 ℃, develops the color for red temperature-sensitive microcapsule powder, below 31 ℃ the time, shows redly, and temperature reaches and surpasses 31 ℃, the red disappearance or yellowing.
Planographic product of the present invention comprise double-layer structure: printing carrier and temperature sensing ink layer 3; Temperature sensing ink layer 3 comprises more than one group, and one group of temperature sensing ink layer 3 comprises the patterned layer of bottom and the cover layer of patterned layer top, and the patterned layer of same group is identical with tectal color; When tectal pattern and/or character colour developing, cover or hide pattern and/or the character of same group of patterned layer fully; In same group of temperature sensing ink layer 3, tectal achromic point is lower than the achromic point of patterned layer; Except the patterned layer adjacent with printing carrier, temperature is transparent or semitransparent shape higher than the temperature sensing ink layer 3 of achromic point.
The patterned layer adjacent with printing carrier, temperature is transparent, translucent or opaque shape higher than achromic point.
Further, same group of temperature sensing ink layer 3, the achromic point temperature difference of tectal achromic point and patterned layer>1 ℃.
Temperature sensing ink layer 3 comprises more than two groups, between group and group, is to distribute up and down, tectal achromic point in one group of the below temperature sensing ink layer 3 of the achromic point of patterned layer in the temperature sensing ink layer 3 of one group of top≤adjacent.
Temperature sensing ink layer 3 comprises more than two groups, between group and group, is horizontal distribution.
Contain the temperature-sensitive microcapsule powder in temperature sensing ink layer 3.Temperature sensing ink layer 3 is that resin ready-mixed oil or aqueous emulsion mediation temperature-sensitive microcapsule powder form, wherein temperature sensing ink or temperature-sensitive aqueous emulsion can be for glass, for pottery, resin printing ink, resin printing ink for stainless steel, plastics form with the blending inks such as resin printing ink mediation temperature-sensitive microcapsule powder, according to practical application, selected.
In the patterned layer of temperature sensing ink layer 3 on the same group, the temperature-sensitive microcapsule powder does not form different patterns and/or character.
Embodiment 1
Numeral temperature display marble paper: same five-pointed star pattern occurring below 20 ℃, 23 ℃, 31 ℃, 38 ℃, the numeral that manifests during 43 ℃ of temperature sections changes and the state of change color.
The marble paper step of preparation process is:
(1) shift the patterned layer in first group of temperature sensing ink layer 3 of serigraphy on membranelle paper 1 at water, be lurid mulle while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, temperature-sensitive microcapsule powder clear area is arranged in the middle of mulle, form numeral " 43 ", achromic point is more than 50 ℃, reach achromic point after this patterned layer can be transparent or opaque state;
(2) cover layer of first group of temperature sensing ink layer 3 of serigraphy on the patterned layer of first group of temperature sensing ink layer 3, be provided with in cover layer while with the temperature-sensitive microcapsule powder, forming colour developing and be lurid mulle, the mulle shape size is consistent with the mulle in lower floor adjacent patterns layer, and achromic point is 43 ℃;
The patterned layer of second group of temperature sensing ink layer 3 of serigraphy on the cover layer of (3) first groups of temperature sensing ink layers 3, be orange mulle while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, temperature-sensitive microcapsule powder clear area is arranged in the middle of mulle, form numeral " 38 ", achromic point is 43 ℃;
The cover layer of second group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (4) second groups of temperature sensing ink layers 3, be provided with in cover layer while with the temperature-sensitive microcapsule powder, forming colour developing and be orange mulle, the mulle shape size is consistent with the mulle in lower floor adjacent patterns layer, and achromic point is 38 ℃;
The patterned layer of the 3rd group of temperature sensing ink layer 3 of serigraphy on the cover layer of (5) second groups of temperature sensing ink layers 3, the mulle taken on a red color while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, temperature-sensitive microcapsule powder clear area is arranged in the middle of mulle, form numeral " 31 ", achromic point is 38 ℃;
The cover layer of the 3rd group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (6) the 3rd groups of temperature sensing ink layers 3, be provided with the mulle taken on a red color while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, the mulle shape size is consistent with the mulle in lower floor adjacent patterns layer, and achromic point is 31 ℃;
The patterned layer of the 4th group of temperature sensing ink layer 3 of serigraphy on the cover layer of (7) the 3rd groups of temperature sensing ink layers 3, brownish mulle while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, temperature-sensitive microcapsule powder clear area is arranged in the middle of mulle, form numeral " 23 ", achromic point is 31 ℃;
The cover layer of the 4th group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (8) the 4th groups of temperature sensing ink layers 3, be provided with brownish mulle while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, the mulle shape size is consistent with the mulle in lower floor adjacent patterns layer, and achromic point is 23 ℃;
Can also proceed the serigraphy achromic point on the cover layer of (9) the 4th groups of temperature sensing ink layers 3 lower than the temperature sensing ink layer group of 20 ℃, rule is the same;
(10) but cover dyestripping liquid above temperature sensing ink layer 3.
When shifting printing on membranelle paper 1, water first prints in order a group of high temperature section, cover again one group that prints low temperature section, like this by the printing of the ladder sequence of cryosphere covering high-temperature layer, solved the variation relation that marble paper pattern pattern and/or character on the levels same position manifest and disappear with temperature.But finally printing dyestripping 2 is to use in order to protect with the water applique transferring.
The application of the marble paper of above-mentioned displays temperature and temperature change figure applique on glassware, pottery, stainless steel ware.
Concrete applying step is:
(1) marble paper is soaked in water to 1 minute, water shifts membranelle paper 1 natural separation;
(2) will remove the marble paper that water shifts membranelle paper 1 and be transferred to vessel surface, and the water between marble paper and vessel 4 and air will be scraped totally, and make marble paper fully sturdy;
(3) but after drying, the dyestripping 2 on marble paper is taken off to the pattern that on vessel, only remaining Intermediate Gray has the temperature-sensitive microcapsule powder to form and/or the temperature sensing ink layer 3 of character;
(4) enter the baking oven decoration firing, through excess temperature, 180 ° of-200 ° of decoration firings, temperature sensing ink layer 3 and vessel 4 fully combinations of surface, form high-intensity chain junctor.
The character related to, color even temperature all can be carried out suitable conversion or adjustment according to rule of the present invention.
Embodiment 2
The plastic sheeting of text transform---below be word " spring, summer, autumn, winter " variation with temperature and mutually conversion: in the time of 23 ℃, the spring word manifests other word and disappears, in the time of 38 ℃, the summer word manifests other word disappearance, in the time of 31 ℃, the autumn word manifests other word disappearance, and in the time of 5 ℃, the winter word manifests other word disappearance.
The plastic sheeting step of preparation process is:
(1) patterned layer in first group of temperature sensing ink layer 3 of printing on plastic sheeting, be " summer " azury word while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 50 ℃, reach achromic point after this patterned layer can be transparent or opaque state;
(2) cover layer of first group of temperature sensing ink layer 3 of serigraphy on the patterned layer of first group of temperature sensing ink layer 3, be pattern azury while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in cover layer, pattern can cover the character in lower floor's adjacent patterns layer fully, and achromic point is 38 ℃;
The patterned layer of second group of temperature sensing ink layer 3 of serigraphy on the cover layer of (3) first groups of temperature sensing ink layers 3, greeny " autumn " word while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 38 ℃;
The cover layer of second group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (4) second groups of temperature sensing ink layers 3, be provided with greeny pattern while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, pattern can cover the character in lower floor's adjacent patterns layer fully, and achromic point is 31 ℃;
The patterned layer of the 3rd group of temperature sensing ink layer 3 of serigraphy on the cover layer of (5) second groups of temperature sensing ink layers 3, be cyan " spring " word while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, and achromic point is 31 ℃;
The cover layer of the 3rd group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (6) the 3rd groups of temperature sensing ink layers 3, be provided with in cover layer while with the temperature-sensitive microcapsule powder, forming colour developing and be cyan pattern, pattern can cover the character in lower floor's adjacent patterns layer fully, and achromic point is 23 ℃;
The patterned layer of the 4th group of temperature sensing ink layer 3 of serigraphy on the cover layer of (7) the 3rd groups of temperature sensing ink layers 3, brownish " winter " word while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 5 ℃;
The cover layer of the 4th group of temperature sensing ink layer 3 of serigraphy on the patterned layer of (8) the 4th groups of temperature sensing ink layers 3, be provided with brownish pattern while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, the mulle shape size is consistent with the mulle in lower floor adjacent patterns layer, and achromic point is below 0 ℃;
(9) pass through fixedly temperature sensing ink layer 3 of enamel firing process, the abundant combination of temperature sensing ink layer 3 and frosting, form high-intensity chain junctor.
On plastic sheeting, when printing first prints a group of high temperature section in order, cover again one group that prints low temperature section, like this by the printing of the ladder sequence of cryosphere covering high-temperature layer, solved the variation relation that pattern pattern and/or character on the levels same position manifest and disappear with temperature.
Same, can be other patterns or figure by the text transform in " spring, summer, autumn, winter ", the color related to also can convert accordingly, adjust.
Embodiment 3
Pattern change is adhesive sticker---below be diverse location pattern variation with temperature and mutually conversion on same plane: in the time of 20 ℃, " flower " pattern manifests other pattern and disappears, in the time of 40 ℃, " sun " pattern manifests other pattern disappearance, in the time of 30 ℃, " maple leaf " pattern manifests other pattern disappearance, and in the time of 5 ℃, " snowflake " pattern manifests other pattern disappearance.
(1) patterned layer in first group of temperature sensing ink layer 3 of printing on self-adhesive paper, " sun " pattern presented while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 50 ℃, reach achromic point after this patterned layer can be transparent or opaque state;
(2) cover layer of first group of temperature sensing ink layer 3 of printing on the patterned layer of first group of temperature sensing ink layer 3, the circular pattern of pinkiness while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in cover layer, pattern can cover the solar pattern in lower floor's adjacent patterns layer fully, and achromic point is 45 ℃;
The patterned layer that second group of temperature sensing ink layer 3 printed on the right side of (3) first groups of temperature sensing ink layers 3, " maple leaf " pattern presented while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 40 ℃;
The cover layer of second group of temperature sensing ink layer 3 of printing on the patterned layer of (4) second groups of temperature sensing ink layers 3, be yellow regular pentagon pattern while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in cover layer, pattern can cover " maple leaf " pattern in the lower pattern layer fully, and achromic point is 35 ℃;
The patterned layer of the 3rd group of temperature sensing ink layer 3 of right side printing of (5) second groups of temperature sensing ink layers 3, " flower " pattern presented while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 30 ℃;
The cover layer of the 3rd group of temperature sensing ink layer 3 of printing on the patterned layer of (6) the 3rd groups of temperature sensing ink layers 3, be provided with the triangle pattern taken on a red color while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, pattern can cover " flower " pattern in the lower pattern layer fully, and achromic point is 20 ℃;
The patterned layer of the 4th group of temperature sensing ink layer 3 of right side printing of (7) the 3rd groups of temperature sensing ink layers 3, " snowflake " pattern presented while being provided with the colour developing formed with the temperature-sensitive microcapsule powder in patterned layer, achromic point is 10 ℃;
The cover layer of the 4th group of temperature sensing ink layer 3 of printing on the patterned layer of (8) the 4th groups of temperature sensing ink layers 3, be provided with brownish rectangular patterns while with the temperature-sensitive microcapsule powder, forming colour developing in cover layer, pattern can cover " snowflake " pattern in the lower pattern layer fully, and achromic point is below 0 ℃.
In printing, also can be according to the stack printing of the ladder sequence by cryosphere covering high-temperature layer, the pattern of temperature sensing ink layer 3 on the same group is not stackable, can mutually stagger yet.
Same, each pattern and color can be adjusted and be changed.
Claims (10)
1. temperature display planographic product, is characterized in that, comprises double-layer structure: printing carrier, and temperature sensing ink layer; The temperature sensing ink layer comprises more than one group, and one group of temperature sensing ink layer comprises the patterned layer of bottom and the cover layer of patterned layer top, and the patterned layer of same group is identical with tectal color; When tectal pattern and/or character colour developing, cover or hide pattern and/or the character of same group of patterned layer fully; In same group of temperature sensing ink layer, tectal achromic point is lower than the achromic point of patterned layer; Except the patterned layer adjacent with printing carrier, temperature is transparent or semitransparent shape higher than the temperature sensing ink layer of achromic point.
2. temperature display planographic product according to claim 1, is characterized in that, the patterned layer adjacent with printing carrier, and temperature is transparent, translucent or opaque shape higher than achromic point.
3. temperature display planographic product according to claim 1, is characterized in that, same group of temperature sensing ink layer, the achromic point temperature difference of tectal achromic point and patterned layer>1 ℃.
4. temperature display planographic product according to claim 1, it is characterized in that, the temperature sensing ink layer comprises more than two groups, between group and group, is to distribute up and down, tectal achromic point in one group of the below temperature sensing ink layer of the achromic point of patterned layer in the temperature sensing ink layer of one group of top≤adjacent.
5. temperature display planographic product according to claim 1, is characterized in that, the temperature sensing ink layer comprises more than two groups, between group and group, is horizontal distribution.
6. temperature display planographic product according to claim 1, is characterized in that, contains the temperature-sensitive microcapsule powder in the temperature sensing ink layer.
7. temperature display planographic product according to claim 6, is characterized in that, in the patterned layer of temperature sensing ink layer on the same group, the temperature-sensitive microcapsule powder does not form different patterns and/or character.
8. according to the arbitrary described temperature display planographic product of claim 1-7, it is characterized in that, described printing carrier is that water shifts a kind of in membranelle paper, self-adhesive paper, plastics.
9. temperature display planographic product according to claim 8, is characterized in that, temperature display planographic product are marble paper, and marble paper comprises three-decker: bottom is that water shifts membranelle paper, and intermediate layer is the temperature sensing ink layer, but the superiors are coated with dyestripping.
10. the typography of described temperature display planographic product as arbitrary as claim 1-8, is characterized in that, step comprises:
(1) patterned layer in first group of temperature sensing ink layer of printing on printing carrier, achromic point is a;
(2) cover layer of first group of temperature sensing ink layer of printing on the patterned layer of first group of temperature sensing ink layer, achromic point is b;
The cover layer top of (3) first groups of temperature sensing ink layers or the patterned layer of printing second group of temperature sensing ink layer at the parallel position of first group of temperature sensing ink layer, achromic point is c;
The cover layer of second group of temperature sensing ink layer of printing on the patterned layer of (4) second groups of temperature sensing ink layers, achromic point is d;
(5) repeat above step printing temperature sensing ink layer;
Wherein, a>b >=c>d.
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| CN108352135A (en) * | 2015-10-22 | 2018-07-31 | Cj第制糖株式会社 | Printed matter for temperature sensing display package and packaging material using same |
| CN109016770A (en) * | 2018-07-23 | 2018-12-18 | 企鹅兰登（北京）文化发展有限公司 | A kind of printed matter and its application method of reversible temperature-sensitive changing content |
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| CN102862406A (en) * | 2012-09-21 | 2013-01-09 | 中山市天嘉纸品有限公司 | Paper printing color changing process and color-changeable paper printed matter |
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| CN108352135A (en) * | 2015-10-22 | 2018-07-31 | Cj第制糖株式会社 | Printed matter for temperature sensing display package and packaging material using same |
| US10900845B2 (en) | 2015-10-22 | 2021-01-26 | CI Cheiljedang Corporation | Printed material for temperature sensing display package and packaging material using the same |
| CN109016770A (en) * | 2018-07-23 | 2018-12-18 | 企鹅兰登（北京）文化发展有限公司 | A kind of printed matter and its application method of reversible temperature-sensitive changing content |
| CN109016770B (en) * | 2018-07-23 | 2020-05-22 | 企鹅兰登（北京）文化发展有限公司 | Printed matter capable of reversibly sensing temperature change content and use method thereof |
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